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USGS2025

Planning considerations related to contamination control for the return and analysis of Martian samples

The joint National Aeronautics and Space Administration and European Space Agency Mars Sample Return (MSR) Campaign is a proposed multi-mission effort to bring selected geological samples from Mars to Earth for the purpose of scientific investigation. Significant parts of these investigations could be affected by Earth-sourced contamination that is either misinterpreted as having a martian origin or that masks a martian signal. The Mars 2020 Perseverance rover implemented strict contamination control requirements to limit contamination of the samples during sample collection. Contamination control and contamination knowledge requirements have not yet been established for the samples after they arrive on Earth. The MSR Sample Receiving Facility (SRF) Contamination Panel (SCP) was tasked with defining the terrestrial biological, organic, and inorganic contamination limits for martian samples during their residence inside the SRF. To reach our recommendations, the SCP studied (i) the previously proposed limits and rationale of the Organic Contamination Panel, (ii) cleanliness levels achieved for sampling hardware by the M2020 mission, (iii) recent improvements in analytical technology and detection limits, (iv) updated information regarding the organic content of martian samples ( e.g. , from the Sample Analysis at Mars instrument on the Curiosity rover and laboratory analyses of martian meteorites), and (v) information about the composition and geologic context of samples being collected by the Perseverance rover for return to Earth.

Astrobiology↗

USGS1975

The interior of the earth

The center of the Earth lies nearly 4,000 miles beneath our feet. At present the nature of the Earth's interior is known only from indirect evidence collected from studies of rocks and minerals, seismic waves, heat flow from the interior, and the Earth's gravity and magnetic field and through comparisons of the Earth with other planets, with meteorites, and with the Sun and other stars.

General Interest Publication↗

USGS1909

Relations between local magnetic disturbances and the genesis of petroleum

No question in geology is more obscure than that of the origin of the numerous natural hydrocarbons commonly classified as asphalt, ozokerite, petroleum, and natural gas. Certain facts of occurrence and certain results of experiment are indeed established, but the interpretation to be placed upon them is so doubtful that the conclusion reached may almost be said to depend on predilection. A great number of the more important hydrocarbons found in petroleums can be produced artificially from organic substances, such as coal, wood, and fish oil, while identical or closely allied hydrocarbons result from the interaction of inorganic substances, such as cast iron and chlorhydric acid. In many places petroleum is closely associated with fossiliferous strata; but hydrocarbons likewise exist in meteorites and in volcanic gases; they are even expelled by heat from granite and basalt. The most orthodox opinion at the present day is that a part of the natural hydrocarbons is of organic origin and a part also of inorganic origin; but when it comes to estimating the relative importance of the two portions there is no approach to unanimity. Before making a suggestion, which in this connection appears to be of interest, it may be well to outline the arguments for the opposing views.

Bulletin↗

USGS2015

Indium: bringing liquid-crystal displays into focus

Introduction Indium is rare in the Earth’s crust. The continental crust contains an average of about 50 parts per billion of indium, whereas the oceanic crust contains about 72 parts per billion, which is similar to meteoritic abundances and comparable to the crustal abundance of silver. Indium minerals are rare in nature and only 12 indium minerals are known. In its elemental form, indium is a soft, lustrous, silver-white metal with a low melting point relative to other metals. It is ductile and malleable, even at temperatures approaching absolute zero, making it ideal for cryogenic applications. Indium was discovered in the mid-1800s by two German chemists who were investigating zinc ores from Freiberg, Saxony. They named it after the distinctive indigo-blue color observed in its emission spectrum. For years indium remained only a scientific curiosity and early applications of indium were few, but included manufacturing of light-emitting diodes and coatings for bearings used in aircraft engines. Indium-bearing nuclear control rods became more widely used in the 1970s, and today the major application of indium is in manufacturing liquid-crystal displays. Compared to more abundant industrial metals such as lead and zinc, information about the behavior and toxicity of indium in the environment is limited. However, many indium compounds have been proven to be toxic to animals.

Fact Sheet↗

USGS2015

Chesapeake Bay impact structure: A blast from the past

About 35 million years ago, a 2-mile-wide meteorite smashed into Earth in what is now the lower Chesapeake Bay in Virginia. The oceanic impact vaporized, melted, fractured, and displaced rocks and sediments and sent billions of tons of water, sediments, and rocks into the air. Glassy particles of solidified melt rock rained down as far away as Texas and the Caribbean. Large tsunamis affected most of the North Atlantic basin. The resulting impact structure is more than 53 miles wide and has a 23-mile-wide, filled central crater surrounded by collapsed sediments. Now buried by hundreds of feet of younger sediments, the Chesapeake Bay impact structure is among the 20 largest known impact structures on Earth. Since its discovery in the early 1990s, scientists have conducted deep drilling and geophysical surveys of the impact structure to find out more about its size, composition, structure, age, and biological effects and to understand its lingering influences on the regional groundwater system. These efforts culminated in the drilling of a 1-mile-deep, continuously sampled corehole in 2005 by an international group of scientists and agencies.

Chesapeake Bay↗

USGS2010

Coastal-change and glaciological map of the Ross Island area, Antarctica

Reduction in the area and volume of Earth?s two polar ice sheets is intricately linked to changes in global climate and to the resulting rise in sea level. Measurement of changes in area and mass balance of the Antarctic ice sheet was given a very high priority in recommendations by the Polar Research Board of the National Research Council. On the basis of these recommendations, the U.S. Geological Survey used its archive of satellite images to document changes in the cryospheric coastline of Antarctica and analyze the glaciological features of the coastal regions. The Ross Island area map is bounded by long 141? E. and 175? E. and by lat 76? S. and 81? S. The map covers the part of southern Victoria Land that includes the northwestern Ross Ice Shelf, the McMurdo Ice Shelf, part of the polar plateau and Transantarctic Mountains, the McMurdo Dry Valleys, northernmost Shackleton Coast, Hillary Coast, the southern part of Scott Coast, and Ross Island. Little noticeable change has occurred in the ice fronts on the map, so the focus is on glaciological features. In the western part of the map area, the polar plateau of East Antarctica, once thought to be a featureless region, has subtle wavelike surface forms (megadunes) and flow traces of glaciers that originate far inland and extend to the coast or into the Ross Ice Shelf. There are numerous outlet glaciers. Glaciers drain into the McMurdo Dry Valleys, through the Transantarctic Mountains into the Ross Sea, or into the Ross Ice Shelf. Byrd Glacier is the largest. West of the Transantarctic Mountains are areas of blue ice, readily identifiable on Landsat images, that have been determined to be prime areas for finding meteorites. Three subglacial lakes have been identified in the map area. Because McMurdo Station, the main U.S. scientific research station in Antarctica, is located on Ross Island in the map area, many of these and other features in the area have been studied extensively. The paper version of this map is available for purchase from the USGS Store.

IMAP↗

USGS2012

Review of rare earth element concentrations in oil shales of the Eocene Green River Formation

Concentrations of the lanthanide series or rare earth elements and yttrium were determined for lacustrine oil shale samples from the Eocene Green River Formation in the Piceance Basin of Colorado and the Uinta Basin of Utah. Unprocessed oil shale, post-pyrolysis (spent) shale, and leached shale samples were examined to determine if oil-shale processing to generate oil or the remediation of retorted shale affects rare earth element concentrations. Results for unprocessed Green River oil shale samples were compared to data published in the literature on reference materials, such as chondritic meteorites, the North American shale composite, marine oil shale samples from two sites in northern Tibet, and mined rare earth element ores from the United States and China. The Green River oil shales had lower rare earth element concentrations (66.3 to 141.3 micrograms per gram, μg g -1 ) than are typical of material in the upper crust (approximately 170 μg g -1 ) and were also lower in rare earth elements relative to the North American shale composite (approximately 165 μg g -1 ). Adjusting for dilution of rare earth elements by organic matter does not account for the total difference between the oil shales and other crustal rocks. Europium anomalies for Green River oil shales from the Piceance Basin were slightly lower than those reported for the North American shale composite and upper crust. When compared to ores currently mined for rare earth elements, the concentrations in Green River oil shales are several orders of magnitude lower. Retorting Green River oil shales led to a slight enrichment of rare earth elements due to removal of organic matter. When concentrations in spent and leached samples were normalized to an original rock basis, concentrations were comparable to those of the raw shale, indicating that rare earth elements are conserved in processed oil shales.

Utah;Colorado;Wyoming↗

USGS1982

Hydrotectonics; principles and relevance

Hydrotectonics combines the principles of hydraulics and rock mechanics. The hypothesis assumes that: (1) no faults are truly planar, (2) opposing noncongruent wavy wallrock surfaces form chambers and bottlenecks along the fault, and (3) most thrusting occurs beneath the water table. These physical constraints permit the following dynamics. Shear displacement accompanying faulting must constantly change the volume of each chamber. Addition of ground water liquefies dry fault breccia to a heavy incompressible viscous muddy breccia I call fault slurry. When the volume of a chamber along a thrust fault decreases faster than its fault slurry can escape laterally, overpressurized slurry is hydraulically injected into the base of near-vertical fractures in the otherwise impervious overriding plate. Breccia pipes commonly form where such fissures intersect. Alternating decrease and increase in volume of the chamber subjects this injection slurry to reversible surges that not only raft and abrade huge clasts sporadically spalled from the walls of the conduit but also act as a forceful hydraulic ram which periodically widens the conduit and extends its top. If the pipe perforates a petroleum reservoir, leaking hydrocarbons float to its top. Sudden faulting may generate a powerful water hammer that can be amplified at some distal narrow ends of the anastomosing plumbing system, where the shock may produce shatter cones. If vented on the Earth's surface, the muddy breccia, now called extrusion slurry, forms a mud volcano. This hypothesis suggests that many highly disturbed features presently attributed to such catastrophic processes as subsurface explosions or meteorite impacts are due to the rheology of tectonic slurry in an intermittently reactivated pressure-relief tube rooted in a powerful reciprocating hydrotectonic pump activated by a long-lived deep-seated thrust fault.

Open-File Report↗

USGS2007

Geologic Map of Part of the Western Hellas Planitia, Mars

Introduction Rock units were deposited on Mars by meteorite impact, volcanism, wind, flowing water, standing water, and ice, acting separately or in concert. Hellas Planitia, the deepest tract on Mars, is a broad depression lying within the high-rimmed, approximately 2,300-km-wide Hellas impact basin. The basin and the planitia are centered about 250 km east of the southeast corner of the map area. Like other stratigraphy-based planetary mapping (Wilhelms, 1990), we suggest the most likely origins for age relations and morphologies visible in the map area.

Scientific Investigations Map↗

USGS2009

Geologic Map of MTM 35337, 40337, and 45337 Quadrangles, Deuteronilus Mensae Region of Mars

Deuteronilus Mensae, first defined as an albedo feature at lat 35.0 deg N., long 5.0 deg E., by U.S. Geological Survey (USGS) and International Astronomical Union (IAU) nomenclature, is a gradational zone along the dichotomy boundary in the northern mid-latitudes of Mars. The boundary in this location includes the transition from the rugged cratered highlands of Arabia Terra to the northern lowland plains of Acidalia Planitia. Within Deuteronilus Mensae, polygonal mesas are prominent along with features diagnostic of Martian fretted terrain, including lobate debris aprons, lineated valley fill, and concentric crater fill. Lobate debris aprons, as well as the valley and crater fill deposits, are geomorphic indicators of ground ice, and their concentration in Deuteronilus Mensae is of great interest because of their potential association with Martian climate change. The paucity of impact craters on the surfaces of debris aprons and the presence of ice-cemented mantle material imply young (for example, Amazonian) surface ages that are consistent with recent climate change in this region of Mars. North of Deuteronilus Mensae are the northern lowlands, a potential depositional sink that may have had large standing bodies of water or an ocean in the past. The northern lowlands have elevations that are several kilometers below the ancient cratered highlands with significantly younger surface ages. The morphologic and topographic characteristics of the Deuteronilus Mensae region record a diverse geologic history, including significant modification of the ancient highland plateau and resurfacing of low-lying regions. Previous studies of this region have interpreted a complex array of geologic processes, including eolian, fluvial and glacial activity, coastal erosion, marine deposition, mass wasting, tectonic faulting, effusive volcanism, and hydrovolcanism. The origin and age of the Martian crustal dichotomy boundary are fundamental questions that remain unresolved at the present time. Several scenarios for its formation, including single and multiple large impact events, have been proposed and debated in the literature. Endogenic processes whereby crust is thinned by internal mantle convection and tectonic processes have also been proposed. Planetary accretion models and isotopic data from Martian meteorites suggest that the crust formed very early in Martian history. Using populations of quasi-circular depressions extracted from the topography of Mars, other studies suggest that the age difference between the highlands and lowlands could be ~100 m.y.. Furthermore, understanding the origin and age of the dichotomy boundary has been made more complicated due to significant erosion and deposition that have modified the boundary and its adjacent regions. The resulting diversity of terrains and features is likely a combined result of ancient and recent events. Detailed geologic analyses of dichotomy boundary zones are important for understanding the spatial and temporal variations in highland evolution. This information, and comparisons to other highland regions, can help elucidate the scale of potential environmental changes. Previous geomorphic and geologic mapping investigations of the Deuteronilus Mensae region have been completed at local to global scales. The regional geology was first mapped by Lucchitta (1978) at 1:5,000,000 scale using Mariner 9 data. This study concluded that high crater flux early in Martian history formed overlapping craters and basins that were later filled by voluminous lava flows that buried the impacted surface, creating the highlands. After this period of heavy bombardment, fluvial erosion of the highlands formed the canyons and valleys, followed by dissection that created the small mesas and buttes, and later, formation of the steep escarpment marking the present-day northern highland margin. After valley dissection, mass wasting and eolian processes caused lateral retreat of mesas and buttes

Scientific Investigations Map↗

USGS2014

Occurrence model for magmatic sulfide-rich nickel-copper-(platinum-group element) deposits related to mafic and ultramafic dike-sill complexes

Magmatic sulfide deposits containing nickel (Ni) and copper (Cu), with or without (±) platinum-group elements (PGE), account for approximately 60 percent of the world’s nickel production. Most of the remainder of the Ni production is derived from lateritic deposits, which form by weathering of ultramafic rocks in humid tropical conditions. Magmatic Ni-Cu±PGE sulfide deposits are spatially and genetically related to bodies of mafic and/or ultramafic rocks. The sulfide deposits form when the mantle-derived mafic and/or ultramafic magmas become sulfide-saturated and segregate immiscible sulfide liquid, commonly following interaction with continental crustal rocks. Deposits of magmatic Ni-Cu sulfides occur with mafic and/or ultramafic bodies emplaced in diverse geologic settings. They range in age from Archean to Tertiary, but the largest number of deposits are Archean and Paleoproterozoic. Although deposits occur on most continents, ore deposits (deposits of sufficient size and grade to be economic to mine) are relatively rare; major deposits are present in Russia, China, Australia, Canada, and southern Africa. Nickel-Cu sulfide ore deposits can occur as single or multiple sulfide lenses within mafic and/or ultramafic bodies with clusters of such deposits comprising a district or mining camp. Typically, deposits contain ore grades of between 0.5 and 3 percent Ni and between 0.2 and 2 percent Cu. Tonnages of individual deposits range from a few tens of thousands to tens of millions of metric tons (Mt) bulk ore. Two giant Ni-Cu districts, with ≥10 Mt Ni, dominate world Ni sulfide resources and production. These are the Sudbury district, Ontario, Canada, where sulfide ore deposits are at the lower margins of a meteorite impact-generated igneous complex and contain 19.8 Mt Ni; and the Noril’sk-Talnakh district, Siberia, Russia, where the ore deposits are in subvolcanic mafic intrusions related to flood basalts and contain 23.1 Mt Ni. In the United States, the Duluth Complex in Minnesota, comprised of a group of mafic intrusions related to the 1.1 Ga Midcontinent Rift system, represents a major Ni resource of 8 Mt Ni, but deposits generally exhibit low grades (0.2 percent Ni, 0.66 percent Cu) and remain in the process of being proven economic. The sulfides in magmatic Ni-Cu deposits generally constitute a small volume of the host rock(s) and tend to be concentrated in the lower parts of the mafic and/or ultramafic bodies, often in physical depressions or areas marking changes in the geometry of the footwall topography. In most deposits, the sulfide mineralization can be divided into disseminated, matrix or net, and massive sulfide, depending on a combination of the sulfide content of the rock and the silicate texture. The major Ni-Cu sulfide mineralogy typically consists of an intergrowth of pyrrhotite (Fe 7 S 8 ), pentlandite ([Fe, Ni] 9 S 8 ), and chalcopyrite (FeCuS 2 ). Cobalt, PGE, and gold (Au) are extracted from most magmatic Ni-Cu ores as byproducts, although such elements can have a significant impact on the economics in some deposits, such as the Noril’sk-Talnakh deposits, which produce much of the world’s palladium. In addition, deposits may contain between 1 and 15 percent magnetite associated with the sulfides.

Scientific Investigations Report↗

USGS1998

The clementine bistatic radar experiment: Evidence for ice on the moon

Ice deposits, derived from comets and water-bearing meteorites hitting the Moon over geological times, have long been postulated to exist in dark areas near the poles of the Moon. The characteristics of radio waves beamed from the Clementine spacecraft into the polar areas, reflected from the Moon's surface, and received on the large dish antennas of the Deep Space Network here on Earth show that roughly the volume of a small lake (0.9-1.8 km 3 ) of water ice makes up part of the Moon's surface layer near the south pole. The discovery of ice near the lunar south pole has important ramifications for a permanent return to the Moon. These deposits could be used to manufacture rocket propellant and to support human life on the Moon.

Solar System Research↗

USGS2014

Mineral resource of the month: Iron and steel

Iron is one of the most abundant elements on Earth, but it does not occur in nature in a useful metallic form. Although ancient people may have recovered some iron from meteorites, it wasn’t until smelting was invented that iron metal could be derived from iron oxides. After the beginning of the Iron Age in about 1200 B.C., knowledge of iron- and steelmaking spread from the ancient Middle East through Greece to the Roman Empire, then to Europe and, in the early 17th century, to North America. The first successful furnace in North America began operating in 1646 in what is now Saugus, Mass. Introduction of the Bessemer converter in the mid-19th century made the modern steel age possible. Pig iron is a high-carbon alloy made by smelting iron ore in a blast furnace with carbonaceous material, typically coke, as a reducing agent. Limestone is added to the iron ore-coke charge as a fluxing agent to remove impurities. Steel is produced from pig iron by removing some of the carbon in a basic oxygen converter and adding several alloying elements, such as manganese, chromium, copper, nickel, titanium, molybdenum, tungsten and vanadium. Steel is also made by recycling ferrous scrap in an electric arc furnace. There are many grades of steel, but the three major types of steel are carbon, alloy and stainless. About 93 percent of the steel made in the United States is carbon steel, which contains a maximum 2 percent carbon. Applications are found in appliances, construction, shipbuilding, containers and packaging, as well as in the automotive, machinery and equipment industries. Alloy steel, about 5 percent of annual production, contains as much as 4 percent alloying elements. Special applications for alloy steel include use in machined parts and tool fabrication. Stainless steel, which accounts for about 2 percent of annual steel production, is formed by adding chromium and usually nickel to steel to make it highly corrosion-resistant. Since 2008, steelmaking capacity has greatly exceeded apparent steel consumption, primarily as a result of China’s rapid economic expansion and rapidly increasing capacity. This has resulted in an influx of steel products into the United States and other steelmaking countries that already have excess capacity. Demand by China’s steelmakers has also driven unprecedented increases in the prices of iron ore and metallurgical coal. In the short term, steelmaking capacity, globally and especially in China, is expected to continue to exceed steel consumption, with steel prices and production costs remaining stable.

Earth↗

USGS2015

Visualizing impact structures using high-resolution LiDAR-derived DEMs: A case study of two structures in Missouri

Evidence suggests that a crypto-explosive hypothesis and a meteorite impact hypothesis may be partly correct in explaining several anomalous geological features in the middle of the United States. We used a primary geographic information science (GIScience) technique of creating a digital elevation model (DEM) of two of these features that occur in Missouri. The DEMs were derived from airborne light detection and ranging, or LiDAR. Using these DEMs, we characterized the Crooked Creek structure in southern Crawford County and the Weaubleau structure in southeastern St. Clair County, Missouri. The mensuration and study of exposed and buried impact craters implies that the craters may have intrinsic dimensions which could only be produced by collision. The results show elevations varying between 276 and 348 m for Crooked Creek and between 220 and 290 m for Weaubleau structure. These new high- resolution DEMs are accurate enough to allow for precise measurements and better interpretations of geological structures, particularly jointing in the carbonate rocks, and they show greater definition of the central uplift area in the Weaubleau structure than publicly available DEMs.

Missouri↗

USGS2014

Mineral resource of the month: Iron and steel

Earth↗

USGS1968

Chapter IX: Lunar theory and processes

Whereas the previous Surveyor missions were undertaken to examine mare surfaces as potential landing areas for the Apollo Program, the primary objective of the Surveyor VII mission, based on purely scientific motivations, was to explore a contrasting highland region and, specifically, to determine the chemistry of the highland material for comparison with the Surveyor V and VI chemical analyses at the mare sites. Site selection was limited to some extent by Surveyor operational constraints, but primarily by the requirements of 10-m-resolution photographs from the Lunar Orbiter Program for landing site certification. None of the nine sites studied in detail appeared capable of providing an unambiguous answer to the highland chemistry. The final selection of a site to the north of Tycho was based on the belief that the youthful character of the structure implied a minimum of contamination to the surface layers by foreign material via meteoritic processes. Moreover, the selection of a site near the rim of a major lunar crater promised insight into the “microscale” properties of a structure that represents the dominant morphologic feature on the moon.

Book chapter↗

USGS2025

Exploring Martian geothermal and liquid water potential with basin modeling

Assessing the potential for geothermal energy and liquid water presence in the Martian subsurface is crucial for future exploration and habitability studies. In this work, we employed comprehensive finite element model simulations adapted specifically for Martian conditions to estimate subsurface temperatures and the potential for liquid water at depth within Martian crater basins. Rock and fluid property values for basin fill were carefully adjusted to match Martian gravity, radiogenic heat generation, and compositional characteristics derived from rover analyses, Martian meteorite samples, and orbital spectroscopy data. Multiple modeling scenarios were explored to systematically evaluate end-member cases across critical variables such as heat flow, lithological composition, and average surface temperature. Sensitivity testing revealed that heat flow and average annual surface temperatures are the most important variables. Results were used in calculations based on a database of Martian craters to estimate the temperature of crater fill at depth. Our model results indicate significant potential for sustained liquid water in the subsurface within sedimentary deposits across a range of crater sizes and latitudes. They further suggest that viable geothermal reservoirs likely exist and are potentially accessible for future Martian missions seeking energy sources or exploring astrobiological hypotheses. This study provides a methodological framework for geothermal and hydrological assessments for the subsurface of Mars, contributing to ongoing planetary exploration strategies.

Conference Paper↗

USGS2012

Late Eocene impact microspherules: Stratigraphy, age and geochemistry

Recent discoveries of microtektite and related crystal bearing microspherule layers in deep-sea sediments of the west equatorial Pacific DSDP Sites 292, 315A and 462, off-shore New Jersey in Site 612 and in southern Spain have confirmed the presence of at least three microspherule layers in Late Eocene sediments. Moreover, these discoveries have extended the North American strewn field from the Caribbean and Gulf of Mexico region to the northwest Atlantic, and have established a third strewn field in western equatorial Pacific and Indian Ocean which may extend to the Mediterranean. Stratigraphically the oldest microspherule layer occurs in the planktonic foraminifer Globigerapsis semiinvoluta Zone about 0.5 m.y. prior to the closely spaced crystal bearing microspherule layer and North American microtektite layer in the Globorotalia cerroazulensis Zone. Major element composition of the G. semiinvoluta Zone layer and the crystal bearing microspherule layer overlap, but there is a clear trend towards higher Al 2 O 3 and FeO values in SiO 2 equivalent microspherules of the latter layer. The G. semiinvoluta Zone microspherules also contain a higher percentage of non-crystalline spherules (microtektites) than the crystal bearing microspherule layer, but lower than the North American microtektite layer. Excess iridium due to an abrupt increase in supply is associated with the middle crystal bearing microspherule layer and to a lesser extent with the other two layers. But, Ir excess due to concentration as a result of carbonate loss was also observed at two sites (462, 612). The three late Eocene microspherule layers do not precisely coincide with planktonic foraminiferal species extinctions, but a major faunal assemblage change is associated with the G. semiinvoluta Zone layer. Abundant pyrite is present in the North American microtektite layer of DSDP Site 612 suggesting reducing conditions possibly due to a sudden influx of biologic matter (dead bodies) to the ocean floor, and the crystal bearing microspherule layer coincides with five radiolarian extinctions. All three microspherule layers are associated with decreased carbonate possibly due to sudden productivity changes, increased dissolution as a result of sea-level and climate fluctuations, or the impact events.

New Jersey↗