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Geology and ground-water resources of Fillmore County, Nebraska, with a section on chemical quality of the water

Fillmore County, an area 24 miles square, lies in the eastern part of the Nebraska loess plain. Although tributaries of the Big Blue River have eroded valleys into this plain, much of the original surface is intact. Broad flats and numerous shallow undrained depressions characterize the plain. The county is underlain by unconsolidated deposits of Quaternary age to depths ranging from about 80 to 450 feet. The upper part of this depositional sequence consists largely of wind-deposited clayey silt, and the lower part of stream-deposited sand and gravel. In part of the county, deposits of glacial till also are included. The Quaternary deposits mantle an eroded surface of marine-deposited strata of Cretaceous age. The lower deposits of Quaternary age are saturated and constitute a highly productive aquifer throughout much of the county. The saturated zone ranges from about 20 to 350 feet in thickness. Replenishment to this aquifer, derived principally from precipitation, is believed to average about 1.4 inches per year. Because the quantity of ground water pumped per year exceeds the average annual quantity of recharge, some of the water used for irrigation is from storage. Consequently, water levels in wells .are declining. This trend is likely to continue. The ground water is of the calcium bicarbonate type and is hard, but it is chemically suitable for irrigation use on most soils in the county.

Nebraska

Legacy of the fumigant 1,2-dibromo-3-chloropropane (DBCP) in California groundwater

The fumigant pesticide 1,2-dibromo-3-chloropropane (DBCP) was widely used in California agriculture during the 1960s and 1970s before being banned in 1979. Despite this ban, DBCP continues to contaminate groundwater due to its persistence and mobility. This study evaluates the distribution, historical trends, and projected persistence of DBCP in California using data from over 13,000 public supply wells and additional domestic, irrigation, and observation wells (1980-2022). Since 2010, DBCP has been detected in 9% of public supply wells statewide, with higher frequencies in the San Joaquin Valley (21%) and upper Santa Ana River watershed (13%), where DBCP use was most prevalent. Approximately 70% of wells had decreasing concentration trends, whereas increases were more common in deeper wells, indicating downward vertical migration of the DBCP front. Groundwater age estimates show that recharge timing aligns with the 1960s–1970s loading period, enabling reconstruction of peak inputs and providing a basis for age based modeling. To estimate future persistence, we applied a one dimensional advection–dispersion model that simulates long term declines in peak concentrations based on groundwater age, historical loading, and a 38 year degradation half life. Model projections suggest that concentrations above the maximum contaminant level may persist in a declining number of wells until approximately 2080 (range: 2048–2109), with longer persistence in the San Joaquin Valley. The simplified modeling framework, based on age distributions typical of wells capturing peak concentrations, can provide practical regional scale assessment of non-point source contaminants where long-term monitoring exists. This study highlights how the legacy of DBCP contamination will likely affect California's groundwater resources throughout the 21st century.

California

Processes affecting the distribution of selenium in shallow groundwater of agricultural areas, western San Joaquin Valley, California

A study was undertaken to evaluate the processes affecting the chemistry of shallow groundwater associated with agricultural drainage systems in the western San Joaquin Valley, California. The study was prompted by a need for an understanding of selenium mobility in areas having high selenium concentrations in shallow groundwater. Groundwater samples were collected along transects in three artificially drained fields where the age of the drainage system varied (15, 6, and 1.5 years). Selenium concentrations in the drain water also varied (430, 58, and 3700 μg/L, respectively). Isotopic enrichment and chemical composition of the groundwater samples indicate that saline- and selenium-enriched water has evolved as a result of evaporation or transpiration of groundwater. This evaporated, isotopically enriched water is being displaced by more recent, less saline irrigation water percolating through the root zone. This displacement seems to be a process whereby sodium chloride and sodium sulfate water is being replaced by more dilute calcium sulfate and calcium bicarbonate water.

California

Water in the Elizabethtown area: A study of a limestone terrane in north-central Kentucky

The Elizabethtown area of north-central Kentucky contains aquifers and streams that yield adequate quantities of water of suitable quality for most individual domestic needs as well as for industrial, public supply, and irrigation uses. The area consists of typical karst with numerous sinkholes and subsurface drainage. The bedrock structure controls, in part, the availability of ground water. Potentiometric and structure contours suggest that wells, springs, and streams on anticlines are more likely to have smaller yields or flows and possibly be more affected by droughts, than those on synclines. Water wells, tapping the St. Louis Limestone of Late Mississippian age, yield from less than 1 to about 540 gallons per minute. The average well is 93 feet deep and has a static water level of 40 feet. Well depths range from 43 to 335 feet. The low average discharges of springs during 7 consecutive days for a 10-year period range from 0.4 to 13.4 cubic feet per second. Stream discharges average from less than 0.002 cubic feet per second in the headlands, to 458 cubic feet per second for Nolin River at White Mills, just beyond the area of study. Low average discharges of streams during 7 consecutive days for a 10-year interval range from zero to 34 cubic feet per second. Along many intervals of Middle Creek and North Fork Nolin River, during periods of low flow, there may be no surface flow. Such losing streams are common in karstland which lacks surface drainage. The quality of water from wells and springs is typical of a limestone terrane. It is chiefly a calcium bicarbonate or calcium sulfate type of water. The water is moderately hard to very hard. The water quality of streams at baseflow is similar to that of the ground water. During periods of precipitation, water in streams is diluted by the overland runoff and contains fewer dissolved solids. Water in the basal gypsum-hearing part of the St. Louis Limestone is likely to have sulfate content in excess of 250 milligrams per liter. The water from this zone may also contain excessive dissolved solids. Water from rocks that have shale beds below the St. Louis Limestone is likely to be saline.

Kentucky

Arsenic, chromium, uranium, and vanadium in rock, alluvium, and groundwater, Mojave River and Morongo Areas, western Mojave Desert, southern California

Trace elements within groundwater that originate from aquifer materials and pose potential public-health hazards if consumed are known as geogenic contaminants. The geogenic contaminants arsenic, chromium, and vanadium can form negatively charged ions with oxygen known as oxyanions. Uranium complexes with bicarbonate and carbonate to form negatively charged ions having aqueous chemistry similar to oxyanions. The concentrations of arsenic, chromium, uranium, and vanadium in groundwater result from the combined effects of (1) geologic abundance within aquifer materials; (2) the fraction of these elements that have weathered from and sorbed to the surfaces of mineral grains and are potentially available to groundwater; and (3) the aqueous chemistry of dissolved oxyanions in groundwater during different redox conditions and pH, both of which are affected by hydrogeology, including the length of time groundwater has been in contact with aquifer materials. Concentrations of arsenic, chromium, uranium, and vanadium were measured in samples of (1) rock, surficial alluvium, and drill cuttings using portable (handheld) X-ray fluorescence (pXRF); (2) operationally defined fractions extractable from these materials; and (3) water from wells sampled between 2000 and 2018 within the 3,500 square mile Mojave River area and Morongo area of the western Mojave Desert, southern California. Regionally, rock and surficial alluvium in the Mojave River and Morongo areas are high in arsenic, low in chromium and uranium, and near the average bulk continental crust concentration for vanadium. Locally, high chromium concentrations are present in mafic rock within the San Gabriel Mountains; high uranium concentrations are present in felsic rock within the San Bernardino Mountains; and high arsenic, uranium, and vanadium concentrations are present in extrusive (volcanic) felsic rock within uplands surrounding groundwater basins along the Mojave River downstream from Barstow, California. Elemental assemblages identified using principal component analyses (PCA) of pXRF data were used to characterize felsic, mafic, and felsic volcanic source terranes in rock, surficial alluvium, and in geologic material penetrated by selected monitoring wells drilled between 1994 and 2018. Highly felsic alluvium associated with recent deposition from the Mojave River was identified along the 90-mile length of the floodplain aquifer along the river. The thickness of these highly felsic alluvial deposits ranged from 200 feet (ft) near Victorville and near Barstow to a thin veneer about 30 ft thick downstream from Victorville and downstream portions of the floodplain aquifer within the Mojave Valley. Groundwater in the Mojave River and Morongo areas was generally oxic and alkaline (pH≥7.5). Maximum concentrations of arsenic, hexavalent chromium [Cr(VI)], uranium, and vanadium in water from as many as 498 wells sampled between 2000 and 2018 were 360, 140, 1,470, and 690 micrograms per liter (μg/L), respectively. Water from 22 percent of sampled wells exceeded the U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL) for arsenic of 10 μg/L, with arsenic concentrations commonly exceeding the MCL in water from wells east of Barstow, deep wells in the Victorville fan, and in suboxic or reduced groundwater within the floodplain aquifer. Water from about 1 percent of sampled wells had Cr(VI) concentrations greater than the California MCL for total chromium of 50 μg/L, whereas 13 percent of sampled wells had Cr(VI) concentrations greater than the former California MCL of 10 μg/L. Hexavalent chromium concentrations were highest in water from wells in the Sheep Creek alluvial fan, eroded from mafic rock in the San Gabriel Mountains, although Cr(VI) concentrations greater than the former California MCL also were present elsewhere in the study area where mafic materials or older groundwater were present. Water from about 9 percent of sampled wells exceeded the EPA MCL for uranium of 30 μg/L, with concentrations exceeding the MCL commonly associated with irrigation return from agricultural land overlying the floodplain aquifer. Water from about 7 percent of sampled wells had vanadium concentrations greater than the California notification level of 50 μg/L; most of these wells were in the Victorville fan within the Mojave River area. In general, arsenic concentrations were higher in suboxic or reduced water; chromium concentrations were higher in oxic, alkaline (pH≥7.5) water; uranium concentrations were higher in circumneutral to slightly alkaline water (pH≤7.4); and vanadium concentrations were higher in highly alkaline (pH≥8.0) water, independent of redox status. Concentrations within geologic source terranes are not the sole factor controlling the concentrations of geogenic elements in groundwater. Differences in mineral weathering, pH-dependent sorption to surface-exchange sites on mineral grains, and aqueous geochemistry (especially redox status and pH) affect geogenic element concentrations in groundwater. Consequently, the relative abundances of arsenic, Cr(VI), uranium, and vanadium in groundwater differ from their relative abundances in the average bulk continental crust and their regional abundances in rock and surficial alluvium within groundwater basins of the western Mojave Desert. Processes that control the concentrations of arsenic, chromium, uranium, and vanadium in groundwater operate at the mineral-grain and aquifer scale. At the mineral-grain scale, sequential chemical extraction data show arsenic and uranium are more available to groundwater (under specific geochemical conditions) than chromium or vanadium, which largely are unavailable within unweathered mineral grains. Additionally, chromium and vanadium form few aqueous complexes and bind tightly with iron minerals within surface coatings on mineral grains making them less available to groundwater, whereas complexation with other dissolved ions enhances the solubility of uranium and, to a lesser extent, arsenic. Complexation also increases the valence (less negative charge) and increases the size of dissolved oxyanions and uranium complexes with bicarbonate and carbonate making them less readily sorbed to aquifer materials. At the aquifer scale, hydrogeology (including isolation of water in aquifers from surface sources of recharge, older groundwater age, and long contact times between groundwater and aquifer materials) combined with geochemical processes (such as silicate weathering) to produce alkaline groundwater. Desorption from sorption sites on the surfaces of mineral grains with increasing pH increases arsenic, chromium, and vanadium concentrations in water from wells and increases Cr(VI) concentrations as long as water remains oxic. Aqueous geochemistry and concentrations of geogenic contaminants also are affected by anthropogenic activities including (1) discharge of treated municipal wastewater, which may change the redox status of groundwater; (2) return from irrigated agriculture, which may alter the chemistry of groundwater and increase the solubility of trace elements such as uranium; and (3) groundwater pumping and subsequent water-level declines, which may change the source of water yielded by wells. The quality of water imported from northern California and infiltrated from ponds for groundwater recharge may be altered by naturally present trace elements, especially uranium in areas of agricultural land use or chromium within mafic alluvium.

California

Processes affecting the distribution of selenium in shallow ground water of agricultural areas, western San Joaquin Valley, California

A study was undertaken to evaluate the processes affecting the chemistry of shallow ground water associated with agricultural drainage systems in the western San Joaquin Valley, California. The study was prompted by a need for an understanding of selenium mobility in areas having high selenium concentrations in shallow ground water. Groundwater samples were collected along transects in three artificially drained fields where the age of the drainage system varied (15, 6, and 1.5 years). Selenium concentrations in the drainage water also varied (0F30, 58, and 3700 micrograms per liter, respectively). Isotopic enrichment and chemical composition of the ground-water samples indicate that saline- and selenium-enriched water has evolved as a result of evaporation of ground water. This evaporated, isotopically enriched water is being displaced by more recent, less saline irrigation water percolating through the root zone. This displace-ment seems to be a process whereby sodium chloride and sodium sulfate water is being replaced by more dilute calcium sulfate and calcium bicarbonate water.

California

Digital data sets that describe aquifer characteristics of the Rush Springs Aquifer in western Oklahoma

This diskette contains digitized aquifer boundaries and maps of hydraulic conductivity, recharge, and ground-water level elevation contours for the Rush Spring aquifer in western Oklahoma. This area encompasses all or part of Blaine, Caddo, Canadian, Comanche, Custer, Dewey, Grady, Stephens, and Washita Counties. These digital data sets were developed by Mark F. Becker to use as input into a computer model that simulated ground-water flow in the Rush Springs aquifer (Mark F. Becker, U.S. Geological Survey, written commun., 1997). For the purposes of modeling the ground-water flow in the Rush Springs aquifer, Mark F. Becker (written commun., 1997) defined the Rush Springs aquifer to include the Rush Springs Formation, alluvial and terrace deposits along major streams, and parts of the Marlow Formations, particularly in the eastern part of the aquifer boundary area. The Permian-age Rush Springs Formation consists of highly cross-bedded sandstone with some interbedded dolomite and gypsum. The Rush Springs Formation is overlain by Quaternary-age alluvial and terrace deposits that consist of unconsolidated clay, silt, sand, and gravel. The Rush Springs Formation is underlain by the Permian-age Marlow Formation that consists of interbedded sandstones, siltstones, mudstones, gypsum-anhydrite, and dolomite beds (Mark F. Becker, written commun., 1997). The parts of the Marlow Formation that have high permeability and porosity are where the Marlow Formation is included as part of the Rush Springs aquifer. The Rush Springs aquifer underlies about 2,400 square miles of western Oklahoma and is an important source of water for irrigation, livestock, industrial, municipal, and domestic use. Irrigation wells are reported to have well yields greater than 1,000 gallons per minute (Mark F. Becker, written commun., 1997). Mark F. Becker created some of the aquifer boundaries, hydraulic conductivity, and recharge data sets by digitizing parts of previously published surficial geology maps. The hydraulic conductivity and recharge values are the input data to the ground-water flow model (Mark F. Becker, written commun., 1997). The water-level elevation data set was prepared at a scale of 1:250,000 by Mark F. Becker (written commun., 1997) from water levels measured in wells prior to the year 1950. Ground-water flow models are numerical representations that simplify and aggregate natural systems. Models are not unique; different combinations of aquifer characteristics may produce similar results. Therefore, values of hydraulic conductivity and recharge used in the model and presented in this data set are not precise, but are within a reasonable range when compared to independently collected data.

Oklahoma

Generalized potentiometric surface of aquifers of Pleistocene age, Southern Louisiana, 1980

A map of potentiometric surface defines generalized water levels for 1980 in the Pleistocene aquifers of southern Louisiana. The map was prepared as part of the Western Gulf Coast Regional Aquifer-System Analysis study. The Pleistocene deposits in southern Louisiana consist of alternating beds of sand, gravel, silt, and clay deposited under fluvial, deltaic, and near-short marine conditions. The aquifers are mainly under artesian conditions and the regional flow direction is primarily southward. Areally definable cones of depression result from heavy pumpage in the Baton Rouge, Lake Charles, and New Orleans metropolitan areas and in the rice irrigation area of southwestern Louisiana. Where water levels differ vertically within the aquifer, the lowest water levels in the vertical section were used because these levels represented the thickest and most heavily pumped unit in the aquifer. The map represents regional water levels in the Pleistocene aquifers, and is not intended to show localized variations near pumping centers. (USGS)

Water-Resources Investigations Report

Aquifers of Arkansas: protection, management, and hydrologic and geochemical characteristics of groundwater resources in Arkansas

Sixteen aquifers in Arkansas that currently serve or have served as sources of water supply are described with respect to existing groundwater protection and management programs, geology, hydrologic characteristics, water use, water levels, deductive analysis, projections of hydrologic conditions, and water quality. State and Federal protection and management programs are described according to regulatory oversight, management strategies, and ambient groundwater-monitoring programs that currently (2013) are in place for assessing and protecting groundwater resources throughout the State. Physical attributes, groundwater geochemistry, and groundwater quality are described for each of the 16 aquifers of the State. Information in regard to the hydrology and geochemistry of each of the aquifers is summarized from about 550 historical and recent publications. Additionally, more than 8,000 sites with groundwater-quality data were obtained from the U.S. Geological Survey National Water Information System and the Arkansas Department of Environmental Quality databases and entered into a spatial database to investigate distribution and trends in chemical constituents for each of the aquifers. The 16 aquifers of the State were divided into two major physiographic regions of the State: the Coastal Plain Province (referred to as Coastal Plain) of eastern and southern Arkansas, which includes 11 of the 16 aquifers, and the Interior Highlands Division (referred to as Interior Highlands) of western Arkansas, which includes the remaining 5 aquifers. The 11 aquifers in the Coastal Plain consist of various geologic units that are Cenozoic in age and consist primarily of Cretaceous, Tertiary, and Quaternary sands, gravels, silts, and clays. Groundwater in the Coastal Plain represents one of the most valuable natural resources in the State, driving the economic engines of agriculture, while also supplying abundant water for commercial, industrial, and public-supply use. In terms of age from youngest to oldest, the aquifers of the Coastal Plain include Quaternary alluvial aquifers, including the Mississippi River Valley alluvial aquifer (the most important aquifer in Arkansas in terms of volume of use and economic benefits), the Jackson Group (a regional confining unit that served for decades as an important source of domestic supply), and the Cockfield, Sparta, Cane River, Carrizo, Wilcox, Nacatoch, Ozan, Tokio, and Trinity aquifers. The Mississippi River Valley alluvial aquifer accounts for approximately 94 percent of all groundwater used in the State, and the aquifer is used primarily for irrigation purposes. The Sparta aquifer is the second most important aquifer in terms of use, and the aquifer was used in the past dominantly as a source of public and industrial supply, although increasing irrigation use is occurring because of critically declining water levels in the Mississippi River Valley alluvial aquifer. Other aquifers of the Coastal Plain generally are used as important local sources of domestic, industrial, and public supply, in addition to other minor uses. Water quality generally is good for all aquifers of the Coastal Plain, except for elevated iron concentrations and localized areas of high salinity. The high salinity results from intrusion from underlying formations, evapotranspiration processes in areas of low recharge, and inadequate flushing in downgradient areas of residual salinity from deposition in marine environments. Trends in the spatial distribution of individual chemical constituents are related to position along the flow path for most aquifers of the Coastal Plain. These trends include elevated iron and nitrate concentrations with lower pH values and dissolved solids in groundwater from the outcrop areas, transitioning to lower iron and nitrate (related to changes in redox) and higher pH and dissolved solids (dominantly from the dissolution of carbonate minerals) in groundwater downgradient from outcrop areas. Groundwater generally trended from a calcium- to a sodium-bicarbonate water type with increasing cation exchange along the flow path. The Interior Highlands of western Arkansas has less reported groundwater use than other areas of the State, reflecting a combination of factors. These factors include prevalent and increasing use of surface water, less intensive agricultural uses, lower population and industry densities, lesser potential yield of the resource, and lack of detailed reporting. The overall low yields of aquifers of the Interior Highlands result in domestic supply as the dominant use, with minor industrial, public, and commercial-supply use. Where greater volumes are required for growth of population and industry, surface water is the greatest supplier of water needs in the Interior Highlands. The various aquifers of the Interior Highlands generally occur in shallow, fractured, well-indurated, structurally modified bedrock of this mountainous region of the State, as compared to the relatively flat-lying, unconsolidated sediments of the Coastal Plain. In terms of age from youngest to oldest, the aquifers of the Interior Highlands include: the Arkansas River Valley alluvial aquifer, the Ouachita Mountains aquifer, the Western Interior Plains confining system, the Springfield Plateau aquifer, and the Ozark aquifer. Spatial trends in groundwater geochemistry in the Interior Highlands differ greatly from trends noted for aquifers of the Coastal Plain. In the Coastal Plain, the prevalence of long regional flow paths results in regionally predictable and mappable geochemical changes along the flow paths. In the Interior Highlands, short, topographically controlled flow paths (from hilltops to valleys) within small watersheds represent the predominant groundwater-flow system. As such, dense data coverage from numerous wells would be required to effectively characterize these groundwater basins and define small-scale geochemical changes along any given flow path for aquifers of the Interior Highlands. Changes in geochemistry generally were related to rock type and residence time along individual flow paths. Dominant changes in geochemistry for the Ouachita Mountains aquifer and the Western Interior Plains confining system are attributed to rock/water interaction and changes in redox zonation along the flow path. In these areas, groundwater evolves along flow paths from a calcium- to a sodium-bicarbonate water type with increasing reducing conditions resulting in denitrification, elevated iron and manganese concentrations, and production of methane in the more geochemically evolved and strongest reducing conditions. In the Ozark and Springfield Plateau aquifers, rapid influx of surface-derived contaminants, especially nitrogen, coupled with few to no attenuation processes was attributed to the karst landscape developed on Mississippian- and Ordovician-age carbonate rocks of the Ozark Plateaus. Increasing nitrate concentrations are related to increasing agricultural land use, and areas of mature karst development result in higher nitrate concentrations than areas with less karst features.

Arkasas

Ground-water conditions and storage capacity in the San Joaquin Valley, California

The San Joaquin Valley includes roughly the southern two-thirds of the Great Central Valley of California. It is a broad structural trough surrounded by mountains. The northern part of the valley drains through the San Joaquin River northward to San Francisco Bay ; the southern part of the valley normally is a basin of interior drainage tributary to evaporation sumps in the trough of the valley, chiefly Tulare and Buena Vista Lake beds. In years of normal discharge most of the streamflow in the southern part of the valley not diverted for irrigation finds its way to Tulare and Buena Vista Lake beds. In the historic past, however, during years of heavy floods the low divide between Buena Vista and Tulare Lakes and the low divide between Tulare Lake and the San Joaquin River were overtopped and through-flowing drainage occurred over the full length of the valley. Because the Tulare Lake bed is the lowest point and also the largest sump, this whole basin of interior drainage is commonly referred to as the Tulare Lake drainage basin. Average annual precipitation ranges from more than 15 inches in the north- eastern part of the valley to less than 4 inches in the southwestern part. The precipitation decreases from north to south and from east to west across the valley. Streamflow, the critical quantity in the water supply, depends almost wholly on the amount and distribution of precipitation in the Sierra Nevada to the east. Much of this precipitation falls as snow, and the snowpack acts as a natural reservoir retaining much of the annual runoff until late spring and early summer. The mean seasonal runoff to the San Joaquin Valley is nearly 10 million acre- feet, of which about two-thirds is tributary to the San Joaquin River; the remaining third is tributary to Tulare Lake drainage basin. In 1952 about 8.5 million acre-feet of surface water was diverted for irrigation. Withdrawals of ground water for irrigation in 1952 approximated 7.5 million acre-feet. The surface of the San Joaquin Valley is not a featureless plain but is characterized by various types of physiography such as dissected uplands, low alluvial plains and fans, river flood plains and channels, and overflow lands and lake bottoms. The dissected uplands fringe the valley along its mountain borders. They are underlain by unconsolidated to semiconsolidated continental deposits of late Tertiary and early Quaternary age which have been moderately tilted and folded. The topography of these uplands ranges from deeply dissected hill land having a relief of several hundred feet to gently rolling land whose relief Is only a few feet. The low plains and fans border the dissected uplands along their valley- ward margins. They are generally fiat to gently undulating and featureless and are underlain by undeformed to slightly deformed alluvial deposits of Quaternary age. The river flood plains and channels lie along the San Joaquia and Kings Rivers in the axial part of the valley and along the major east-side streams. Where the rivers are incised below the general land surface, the flood plains are well defined; but in the axial trough of the valley, where the rivers are flanked by low-lying overflow lands, the flood-plain and channel deposits are confined to the stream channel and to the natural levees that slope away from the river. Overflow lands and lake bottoms include the historic beds of Tulare, Buena Vista, and Kern Lakes in the southern part of the valley, and the low-lying lands in the axial trough between the low alluvial plains and fans and the natural levees of the San Joaquin River and its major tributaries. They are level and featureless and are underlain by lake and swamp deposits of Recent age. The San Joaquin Valley is a great structural downwarp between the tilted block of the Sierra Nevada on the east and the complexly folded and faulted Coast Ranges on the we

Water Supply Paper

Water resources of Taos County, New Mexico

In Taos County, ground water generally is unconfined and moves toward the Rio Grande or perennial streams. Water quality is good except in some areas where water has high values of specific conductance and hardness and contains high concentrations of dissolved solids and fluoride. Most wells are completed in alluvial sediments of Quaternary and Tertiary age in the Costilla Plains. A few wells are completed in basalt of the Taos Plateau and in alluvium of stream channels in the Sangre de Cristo Mountains. Depths to water in wells range from less than 1 to 1,080 feet below land surface. Well yields range from 1 to 3,000 gallons per minute. Water levels in wells in Sunshine Valley dropped 5 to 50 feet between 1955 and 1970. Ground-water irrigation has since declined and water levels have risen. Surface-water records show the county is a net producer of water. The average discharge gained in the Rio Grande as it flows through the county was 271,700 acre-feet per year for water years 1931-89. The highest mean monthly discharge occurs in May or June due to snowmelt runoff. Water quality ranges from good in upstream reaches to fair in lower reaches. Surface water was the source for 93 percent of water withdrawn in 1990, but ground water was used for all public supply, domestic, and industrial purposes. The largest water use is irrigation. About 28,500 acres were irrigated in 1990; alfalfa, native pasture, and planted pasture accounted for 91 percent of this acreage.

New Mexico

Hydrogeology and quality of ground water in the upper Arkansas River basin from Buena Vista to Salida, Colorado, 2000-2003

The upper Arkansas River Basin between Buena Vista and Salida, Colorado, is a downfaulted basin, the Buena Vista-Salida structural basin, located between the Sawatch and Mosquito Ranges. The primary aquifers in the Buena Vista-Salida structural basin consist of poorly consolidated to unconsolidated Quaternary-age alluvial and glacial deposits and Tertiary-age basin-fill deposits. Maximum thickness of the alluvial, glacial, and basin-fill deposits is about 5,000 feet, but 95 percent of the water-supply wells in Chaffee County are no more than 300 feet deep. Hydrologic conditions in the 149-square mile study area are described on the basis of hydrologic and geologic data compiled and collected during September 2000 through September 2003. The principal aquifers described in this report are the alluvial-outwash and basin-fill aquifers. An estimated 3,443 wells pumped about 690 to 1,240 acre-feet for domestic and household use in Chaffee County during 2003. By 2030, projected increases in the population of Chaffee County, Colorado, may require use of an additional 4,000 to 5,000 wells to supply an additional 800 to 1,800 acre-feet per year of ground water for domestic and household supply. The estimated specific yield of the upper 300 feet of the alluvial-outwash and basin-fill aquifers ranged from about 0.02 to 0.2. Current (2003) and projected (2030) ground-water withdrawals by domestic and household wells are less than 1 percent of the estimated 472,000 acre-feet of drainable ground water in the upper 300 feet of the subsurface. Locally, little water is available in the upper 300 feet. In densely populated areas, well interference could result in decreased water levels and well yields, which may require deepening or replacement of wells. Infiltration of surface water diverted for irrigation and from losing streams is the primary source of ground-water recharge in the semiarid basin. Ground-water levels in the alluvial-outwash and basin-fill aquifers vary seasonally with maximum water levels occurring in the early summer after snowmelt runoff peaks. Because of the drought during 2002, relatively large declines in ground-water levels occurred in about one-half of the monitored wells. Differences in water-level altitudes in shallow and deep wells indicate the potential for downward flow in upland areas and support results of preliminary cross-sectional models of ground-water flow. The apparent mean age of ground-water recharge ranged from about 1 to more than 48 years before 2001. The older (pre-1953) water was from wells that were located in ground-water discharge areas. Ground-water flow in the Buena Vista-Salida structural basin drains eastward toward the Arkansas River and, locally, toward the South Arkansas River. Ground water in the alluvial-outwash and basin-fill aquifers generally is calcium-bicarbonate water type with less than 250 milligrams per liter dissolved solids. Nitrate concentrations generally were less than 1 to 2 milligrams per liter and do not indicate widespread contamination of ground water from surface sources.

Scientific Investigations Report

Hydrologic evaluation of the Arikaree Formation near Lusk, Niobrara and Goshen counties, Wyoming

The Arikaree Formation of early Miocene age is an aquifer of large areal extent and is composed of very fine grained, poorly bedded, loosely to moderately cemented sandstone and interbedded silt, limestone, and many concretionary layers. The area studied is about 800 square miles in southern Niobrara and northern Goshen Counties of Wyoming. Long-term average annual recharge to the aquifer from streams and precipitation is estimated to total about 24,270 acre-feet. Pumpage from public-supply and irrigation wells is estimated to have totaled about 48,000 acre-feet from 1938 through 1972. This pumpage did not cause any noticeable decrease in natural discharge and it is assumed there has been no significant change in ground-water storage. Pumpage is estimated to total about 39,500 acre-feet for the 3-year period 1973 through 1975. A digital model was developed to simulate the ground-water system in the Arikaree Formation. The model can be used to indicate the general effect of applying hydraulic stresses to the aquifer. (Woodard-USGS)

Water-Resources Investigations Report

Availability of water in eastern Saunders County, Nebraska

The sand and gravel deposits of Quaternary age constitute the most important ground-water reservoir and are the source of nearly all the water pumped from wells in the area. An estimated 3.5 million acre-feet for good quality water is stored in these deposits and an additional 1.5 million acre-feet is stored in the underlying Dakota Sandstone. Even larger quantities are stored at greater depths in the Paleozoic dolomites and sandstones, but the water is of poorer quality. Pumpage for irrigation since 1956 is estimated to have ranged from about 2,500 acre-feet (1962) to about 6,000 acre-feet (1957). The town of Wahoo annually pumps about 460 acre-feet, and other towns pump an estimated total of 180 acre-feet. In 1963 the City of Lincoln pumped 27,000 acre-feet from its well field alongside the Platte River in the southeast corner of the area; since then pumpage has increased and probably is likely to continue to do so. Pumping at Lincoln city well field induces recharge from Platte River. The quantity of ground water pumped to date is very small compared to the amount of water stored in the rocks. Furthermore, most of the ground water withdrawn has been replaced by infiltrating precipitation and by influent seepage from the Platte River. The large quantity of ground water in storage in addition to the flow of the Platte River indicates that the water resources of the area, if managed properly, can be developed much more extensively without appreciably depleting the supply.

Nebraska

Dissolved-solids concentrations of ground water in the Sacramento Valley, California

The general quality of the ground water in the Sacramento Valley , Calif., in terms of dissolved-solids concentration is considered good for irrigation, domestic, and most other uses. This map shows the distribution of dissolved-solids concentrations and is based on about 1,330 chemical analyses collected from about 900 wells between 1974 and 1978. On the west side of the valley some of the smaller streams contribute water of higher dissolved-solids concentrations to the ground water. The sources of these waters are thought to be the upper Cretaceous Chico Formation or marine deposits of Early Cretaceous age that are exposed in the Coast Ranges. (USGS)

Hydrologic Atlas

Hydrology of the Ogallala aquifer in Ford County, southwestern Kansas

The rapid increase of ground-water withdrawal has caused concern over the future use of the Ogallala aquifer, the principal source of water in Ford County, in southwestern Kansas. Saturated portions of deposits of Tertiary and Quaternary age--excluding the Arkansas River alluvium--form the Ogallala aquifer. Saturated thickness of the Ogallala ranged from 0 to about 350 feet on the downthrown side of the Crooked Creek-Fowler fault and from 0 to about 120 feet on the upthrown side. Ground-water withdrawal was calculated by two methods. The time-discharge method computed withdrawal of about 81,000 acre-feet during 1980 and about 58,000 acre-feet during 1981. The irrigation-requirement method computed withdrawal of about 121,000 acre-feet during 1980 and about 131,000 acre-feet during 1981. Results from the irrigation-requirement method are probably closer to the actual amount of ground-water withdrawal because of problems encountered when applying the time-dischargemethod. Water-level declines between 1939 and 1981 ranged from about 10 to 50 feet. Water withdrawal from the Ogallala aquifer depleted the volume of water in storage by about 688,000 acre-feet (8 percent) during this same period. If withdrawals continue to the point where the water table drops below the top of the bedrock surface on the upthrown side of the Crooked Creek-Fowler fault, base flow in the Arkansas River could cease. (USGS)

Water-Resources Investigations Report

Inset groundwater-flow models for the Cache and Grand Prairie Critical Groundwater Areas, northeastern Arkansas

The water resources in the Mississippi alluvial plain, located in parts of Missouri, Kentucky, Tennessee, Mississippi, Louisiana, and Arkansas, supports a multibillion-dollar agricultural industry that relies heavily on pumping of groundwater for irrigation of crops and aquaculture. The primary source of groundwater for agricultural-related pumping is the Mississippi River Valley alluvial aquifer, which has declined in storage for decades; secondary groundwater sources include the middle Claiborne aquifer and Wilcox aquifer system. Two areas in northeastern Arkansas that lie within the Mississippi alluvial plain, part of the Cache and Grand Prairie regions, have been designated as Critical Groundwater Areas owing to decades of groundwater declines that resulted from past and current water use. The multidisciplinary Mississippi Alluvial Plain project, led by the U.S. Geological Survey, and funded by their Water Availability and Use Science Program, included objectives to develop numerical groundwater models in focus regions, including the part of the Cache and Grand Prairie regions of northeastern Arkansas. Two inset models were developed using the child model capabilities of MODFLOW 6, the U.S. Geological Survey’s Modular Hydrologic Model simulation software. Both models, called the Cache model and Grand Prairie model, simulated the groundwater system and surface-water/groundwater interactions for the Mississippi River Valley alluvial aquifer and underlying Tertiary-age aquifers and confining units to the Midway confining unit. Each model was spatially discretized into 500-meter x 500-meter orthogonal cells on a grid with 5-meter constant-thickness vertical layers that represented the Mississippi River Valley alluvial aquifer and increasing thickness layers for the aquifers and confining units below the alluvial aquifer. The Cache and Grand Prairie models were calibrated with the PEST++ iterative ensemble smoother Version 5 and employed high dimensional parameterization schemes of 13,740 and 30,436 parameters, respectively. The Cache mean absolute residual for groundwater-level observations within each model domain for the priority well was 1.58 meters. Grand Prairie mean absolute residuals for the alluvial aquifer and middle Claiborne aquifer groundwater-level observations were 2.71 and 10.78 meters, respectively. The groundwater budgets for the Cache and Grand Prairie models were characterized by substantial outflows to irrigation wells, which constituted about 52 and 54 percent of all outflows, with the primary source of water to those wells being releases from unconfined aquifer storage.

Arkansas

Quality and sources of ground water used for public supply in Salt Lake Valley, Salt Lake County, Utah, 2001

Ground water supplies about one-third of the water used by the public in Salt Lake Valley, Utah. The occurrence and distribution of natural and anthropogenic compounds in ground water used for public supply in the valley were evaluated. Water samples were collected from 31 public-supply wells in 2001 and analyzed for major ions, trace elements, radon, nutrients, dissolved organic carbon, methylene blue active substances, pesticides, and volatile organic compounds. The samples also were analyzed for the stable isotopes of water (oxygen-18 and deuterium), tritium, chlorofluorocarbons, and dissolved gases to determine recharge sources and ground-water age. Dissolved-solids concentration ranged from 157 to 1,280 milligrams per liter (mg/L) in water from the 31 public-supply wells. Comparison of dissolved-solids concentration of water sampled from the principal aquifer during 1988-92 and 1998-2002 shows a reduction in the area where water with less than 500 mg/L occurs. Nitrate concentration in water sampled from 12 of the 31 public-supply wells was higher than an estimated background level of 2 mg/L, indicating a possible human influence. At least one pesticide or pesticide degradation product was detected at a concentration much lower than drinking-water standards in water from 13 of the 31 wells sampled. Chloroform was the most frequently detected volatile organic compound (17 of 31 samples). Its widespread occurrence in deeper ground water is likely a result of the recharge of chlorinated public-supply water used to irrigate lawns and gardens in residential areas of Salt Lake Valley. Environmental tracers were used to determine the sources of recharge to the principal aquifer used for public supply in the valley. Oxygen-18 values and recharge temperatures computed from dissolved noble gases in the ground water were used to differentiate between mountain and valley recharge. Maximum recharge temperatures in the eastern part of the valley generally are below the range of valley water-table temperatures indicating that mountain-block recharge must constitute a substantial fraction of recharge to the principal aquifer in this area. Together, the recharge temperature and stable-isotope data define two zones with apparently high proportions of valley recharge on the east side of the valley. The possibility of water samples containing a substantial proportion of water recharged before thermonuclear testing began in the early 1950s (pre-bomb) was evaluated by comparing the initial tritium concentration of each sample (measured tritium plus measured tritiogenic helium-3) to that of local precipitation at the apparent time of recharge. Three interpreted-age categories were determined for water from the sampled wells: (1) dominantly pre-bomb; (2) dominantly modern; and (3) modern or a mixture of pre-bomb and modern. Apparent tritium/helium-3 ages range from 3 years to more than 50 years. Water generally becomes older with distance from the mountain front, with the oldest water present in the discharge area. The presence of anthropogenic compounds at concentrations above reporting levels and elevated nitrate concentrations (affected wells) in the principal aquifer is well correlated with the distribution of interpreted-age categories. All of the wells (10 of 10) with dominantly modern water are affected. Seventy percent (7 of 10) of the wells with dominantly modern or a mixture of modern and pre-bomb waters are affected. Only 1 of the 11 wells with dominantly pre-bomb water is affected. Anthropogenic compounds were not detected in water with an apparent age of more than 50 years, except for water from one well. All of the samples that consisted mostly of modern water contained at least one anthropogenic compound.

Utah