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At least 181 records · Page 10Linked to original sources

Interannual to multidecadal climate forcings on groundwater resources of the U.S. West Coast

Study region The U.S. West Coast, including the Pacific Northwest and California Coastal Basins aquifer systems. Study focus Groundwater response to interannual to multidecadal climate variability has important implications for security within the water–energy–food nexus. Here we use Singular Spectrum Analysis to quantify the teleconnections between AMO, PDO, ENSO, and PNA and precipitation and groundwater level fluctuations. The computer program DAMP was used to provide insight on the influence of soil texture, depth to water, and mean and period of a surface infiltration flux on the damping of climate signals in the vadose zone. New hydrological insights for the region We find that PDO, ENSO, and PNA have significant influence on precipitation and groundwater fluctuations across a north-south gradient of the West Coast, but the lower frequency climate modes (PDO) have a greater influence on hydrologic patterns than higher frequency climate modes (ENSO and PNA). Low frequency signals tend to be preserved better in groundwater fluctuations than high frequency signals, which is a function of the degree of damping of surface variable fluxes related to soil texture, depth to water, mean and period of the infiltration flux. The teleconnection patterns that exist in surface hydrologic processes are not necessarily the same as those preserved in subsurface processes, which are affected by damping of some climate variability signals within infiltrating water.

California, Oregon, Washington↗

Preface [to special section on recent Loch Vale Watershed research]

Catchment-scale intensive and extensive research conducted over the last decade shows that our understanding of the biogeochemical and hydrologic processes in subalpine and alpine basins is not yet sufficiently mature to model and predict how biogeochemical transformations and surface water quality will change in response to climatic or human-driven changes in energy, water, and chemicals. A better understanding of these processes is needed for input to decision-making regulatory agencies and federal land managers. In recognition of this problem the National Research Council [1998] has identified as a critical research need an improved understanding of how global change will affect biogeochemical interactions with the hydrologic cycle and biogeochemical controls over the transport of water, nutrients, and materials from land to freshwater ecosystems. Improved knowledge of alpine and subalpine ecosystems is particularly important since high-elevation catchments are very sensitive to small changes in the flux of energy, chemicals, and water. Furthermore, alpine ecosystems may act as early warning indicators for ecosystem changes at lower elevations.

Colorado↗

Reactive iron transport in an acidic mountain stream in Summit County, Colorado: A hydrologic perspective

A pH perturbation experiment was conducted in an acidic, metal-enriched, mountain stream to identify relative rates of chemical and hydrologic processes as they influence iron transport. During the experiment the pH was lowered from 4.2 to 3.2 for three hours by injection of sulfuric acid. Amorphous iron oxides are abundant on the streambed, and dissolution and photoreduction reactions resulted in a rapid increase in the dissolved iron concentration. The increase occurred simultaneously with the decrease in pH. Ferrous iron was the major aqueous iron species. The changes in the iron concentration during the experiment indicate that variation exists in the solubility properties of the hydrous iron oxides on the streambed with dissolution of at least two compartments of hydrous iron oxides contributing to the iron pulse. Spatial variations of the hydrologic properties along the stream were quantified by simulating the transport of a coinjected tracer, lithium. A simulation of iron transport, as a conservative solute, indicated that hydrologie transport had a significant role in determining downstream changes in the iron pulse. The rapidity of the changes in iron concentration indicates that a model based on dynamic equilibrium may be adequate for simulating iron transport in acid streams. A major challenge for predictive solute transport models of geochemical processes may be due to substantial spatial and seasonal variations in chemical properties of the reactive hydrous oxides in such streams, and in the physical and hydrologic properties of the stream.

Geochimica et Cosmochimica Acta↗

Data integration reveals dynamic and systematic patterns of breeding habitat use by a threatened shorebird

Incorporating species distributions into conservation planning has traditionally involved long-term representations of habitat use where temporal variation is averaged to reveal habitats that are most suitable across time. Advances in remote sensing and analytical tools have allowed for the integration of dynamic processes into species distribution modeling. Our objective was to develop a spatiotemporal model of breeding habitat use for a federally threatened shorebird (piping plover, Charadrius melodus ). Piping plovers are an ideal candidate species for dynamic habitat models because they depend on habitat created and maintained by variable hydrological processes and disturbance. We integrated a 20-year (2000–2019) nesting dataset with volunteer-collected sightings (eBird) using point process modeling. Our analysis incorporated spatiotemporal autocorrelation, differential observation processes within data streams, and dynamic environmental covariates. We evaluated the transferability of this model in space and time and the contribution of the eBird dataset. eBird data provided more complete spatial coverage in our study system than nest monitoring data. Patterns of observed breeding density depended on both dynamic (e.g., surface water levels) and long-term (e.g., proximity to permanent wetland basins) environmental processes. Our study provides a framework for quantifying dynamic spatiotemporal patterns of breeding density. This assessment can be iteratively updated with additional data to improve conservation and management efforts, because reducing temporal variability to average patterns of use may cause a loss in precision for such actions.

Montana, North Dakota, South Dakota↗

Hydrology of the Black Hills area, South Dakota

The Black Hills Hydrology Study was initiated in 1990 to assess the quantity, quality, and distribution of surface water and ground water in the Black Hills area of South Dakota. This report summarizes the hydrology of the Black Hills area and the results of this long-term study. The Black Hills area of South Dakota and Wyoming is an important recharge area for several regional, bedrock aquifer systems and various local aquifers; thus, the study focused on describing the hydrologic significance of selected bedrock aquifers. The major aquifers in the Black Hills area are the Deadwood, Madison, Minnelusa, Minnekahta, and Inyan Kara aquifers. The highest priority was placed on the Madison and Minnelusa aquifers, which are used extensively and heavily influence the surface-water resources of the area. Within this report, the hydrogeologic framework of the area, including climate, geology, ground water, and surface water, is discussed. Hydrologic processes and characteristics for ground water and surface water are presented. For ground water, water-level trends and comparisons and water-quality characteristics are presented. For surface water, streamflow characteristics, responses to precipitation, annual yields and yield efficiencies, and water-quality characteristics are presented. Hydrologic budgets are presented for ground water, surface water, and the combined ground-water/surface-water system. A summary of study findings regarding the complex flow systems within the Madison and Minnelusa aquifers also is presented.

South Dakota↗

The need to consider temporal variability when modelling exchange at the sediment-water interface

Most conceptual or numerical models of flows and processes at the sediment-water interface assume steady-state conditions and do not consider temporal variability. The steady-state assumption is required because temporal variability, if quantified at all, is usually determined on a seasonal or inter-annual scale. In order to design models that can incorporate finer-scale temporal resolution we first need to measure variability at a finer scale. Automated seepage meters that can measure flow across the sediment-water interface with temporal resolution of seconds to minutes were used in a variety of settings to characterize seepage response to rainfall, wind, and evapotranspiration. Results indicate that instantaneous seepage fluxes can be much larger than values commonly reported in the literature, although seepage does not always respond to hydrological processes. Additional study is needed to understand the reasons for the wide range and types of responses to these hydrologic and atmospheric events.

Conference Paper↗

Model‐based decomposition of spatially varying temporal shifts in seasonal streamflow across north temperate US rivers.

Anthropogenically forced climate shifts disrupt the seasonal behavior of climatic and hydrologic processes. The seasonality of streamflow has significant implications for the ecology of riverine ecosystems and for meeting societal demands for water resources. We develop a hierarchical Bayesian model of daily streamflow to quantify how the shape of annual hydrographs are changing and to evaluate temporal trends in model-based hydrologic indices related to flow timing and magnitude shifts. We apply this model to 1,112 gages across the Northern US over the years 1965–2022. We identify large-scale patterns in temporal changes to streamflow profiles that are consistent with regional changes in hydroclimate, including decreasing seasonal flow variability in the Pacific Northwest and increasing winter flows in the northeastern United States. Within these regions we also observe fine-scale heterogeneity in streamflow timing and magnitude shifts, both of which have potentially significant implications for riverine ecosystem function and the ecosystem services they provide.

northern United States↗

Weathering processes in the Rio Icacos and Rio Mameyes watersheds in Eastern Puerto Rico: Chapter I in Water quality and landscape processes of four watersheds in eastern Puerto Rico

Streams draining watersheds of the two dominant lithologies (quartz diorite and volcaniclastic rock) in the Luquillo Experimental Forest of eastern Puerto Rico have very high fluxes of bedrock weathering products. The Río Blanco quartz diorite in the Icacos watershed and the Fajardo volcaniclastic rocks in the Mameyes watershed have some of the fastest documented rates of chemical weathering of siliceous rocks in the world. Rapid weathering produces thick, highly leached saprolites in both watersheds that lie just below the soil and largely isolate subsurface biogeochemical and hydrologic processes from those in the soil. The quartz diorite bedrock in the Icacos watershed weathers spheroidally, leaving large, relatively unweathered corestones that are enveloped by slightly weathered rock layers called rindlets. The rindlets wrap around the corestones like an onionskin. Within the corestones, biotite oxidation is thought to induce the spheroidal fracturing that leads to development of rindlets; plagioclase in the rindlets dissolves, creating additional pore spaces. Near the rindlet-saprolite interface, the remaining plagioclase dissolves, hornblende dissolves to completion, and precipitation of kaolinite, gibbsite, and goethite becomes pervasive. In the saprolite, biotite weathers to kaolinite and quartz begins to dissolve. In the soil layer, both quartz and kaolinite dissolve. The volcaniclastic bedrock of the Mameyes watershed weathers even faster than the quartz diorite bedrock of the Icacos watershed, leaving thicker saprolites that are devoid of all primary minerals except quartz. The quartz content of volcaniclastic bedrock may help to control watershed geomorphology; high-quartz rocks form thick saprolites that blanket ridges. Hydrologic flow paths within the weathering profiles vary with total fluid flux, and they influence the chemistry of streams. Under low-flow conditions, the Río Icacos and its tributaries are fed by rainfall and by groundwater from the fracture zones; during storm events, intense rainfall rapidly raises stream levels and water is flushed through the soil as shallow flow. As a result, weathering constituents that shed into streamwaters are dominated by rindlet-zone weathering processes during base flow and by soil weathering processes during stormflow. The upper reaches of the Mameyes watershed are characterized by regolith more than 35 meters thick in places that contains highly fractured rock embedded in its matrix. Weathering contributions to stream chemistry at base flow are predicted to be more spatially variable in the Mameyes watershed than in the Icacos watershed owing to the more complex subsurface weathering profile of the volcaniclastic bedrocks of the Mameyes watershed.

Professional Paper↗

Evaluating the influence of the Forestry Reclamation Approach on throughfall quantity in eastern Kentucky

The Appalachian Region is a rich forested ecosystem that has been impacted by coal mining. The Surface Mining Control and Reclamation Act of 1977 was enacted to resolve many of the environmental problems caused by surface mining. Reclamation practices resulted in excessive soil compaction and use of nonnative grasses and shrubs that have altered hydrologic processes. The Forestry Reclamation Approach (FRA) is a best practice for reestablishing forested ecosystems on mined lands in Appalachia. This project evaluated precipitation throughfall in reforested 10- and 20-year-old FRA sites and unmined 100-year-old forest stands as a metric for evaluating the return of forest hydrologic function after reclamation. Stands of coniferous and deciduous trees were evaluated independently for each age class. Throughfall rates were significantly impacted by tree type and age. Throughfall in coniferous trees was less than in deciduous trees, and throughfall in the 10-year-old deciduous trees tended to be highest. Throughfall was also significantly impacted by storm characteristics. Higher rainfall depth and longer duration resulted in significantly larger throughfall depths under both coniferous and deciduous stands, whereas increased intensity increased throughfall depths for the 10- and 100-year-old plots, but not for the 20-year-old plots. As canopy closure occurs in young FRA forests, throughfall rates resemble those reported for young, naturally regenerating forests in the region. Results may help guide management of forested watershed strategies to reduce surface runoff and local flooding on reclaimed surface mined lands.

Kentucky↗

Pocomoke Sound Sedimentary and Ecosystem History

Summary of Results: Pocomoke Sound Sediment and Sediment Processes Transport of sediment from coastal marshes. Analyses of pollen and foraminifera from surface sediments in Pocomoke Sound suggest that neither the upstream forested wetlands nor coastal marshes bordering the sound have contributed appreciably to particulate matter in the 10- to 1000-micron size range that is currently being deposited in the sound. Sediment processes derived from short-lived isotope. Analyses of beryllium-7, cesium-137 and lead-210 and redox sensitive elements from Pocomoke sediments showed that there has been a significant increase in anthropogenic elements since the late 1940's when the Delmarva Peninsula became more accessible from the Baltimore-Washington region. Cesium-137 was found to be a useful tool to determine changes in sedimentation within the system. Three major stages of sedimentation occurred. Before 1950, the system was equilibrium with the agriculture activity in the watershed, whereas urbanization and agricultural activity changes during and immediately preceding World War II resulted in increased sediment flux. Around 1970, the sediment flux diminished and there was an apparent increase in bank erosion sediment to the deeper parts of the system. Rates of sediment deposition. Radiocarbon, lead-210, and pollen dating of sediment cores from Pocomoke Sound indicate relatively continuous deposition of fine-grained sediments in the main Pocomoke channel at > ~7 m water depths. Mean sediment accumulation rates during the past few centuries were relatively high (>1 cm yr -1 ). The ages of coarser-grained sediments (sands) blanketing the shallow (< ~ 7 m water depth) flanks of Pocomoke Sound are not well constrained but were probably deposited discontinuously. Impacts of land-use on benthic biota. The Pocomoke Sound paleoecological record shows that in the 1940-50s and again in the 1970-80s, the sound experienced unprecedented changes in the benthic assemblages of both ostracodes and foraminifera that can be attributed to degradation in water quality. These changes represent perturbations to the natural variability in faunal assemblages, which are normally driven by climatically influenced changes in salinity regimes. Changes in 20th century benthic communities were characterized by the rise to dominance of facultative anaerobic taxa tolerant of hypoxia and detrital-feeding species, reflecting increased influx of organic matter, and perhaps greater turbidity. Results support the hypothesis of Orth et al. (2002) and Orth and Moore (1983) that unprecedented changes to the bay ecosystem affected submerged aquatic vegetation in the Tangiers-Pocomoke region prior to large-scale monitoring began in the 1970s and 80s. Comparison of Pocomoke paleoecological record with those from the mainstem bay indicate that environmental degradation during the 20th century was nearly synchronous bay-wide within the limits of sediment core chronology (10-20 years). Stable isotopic evidence for decadal water quality changes. Stable isotopic records from benthic foraminifera in Pocomoke Sound sediment cores, especially oxygen isotopes, document regional decadal and centennial climate processes which influence salinity and water quality over the past few centuries. These results provide indirect evidence for discharge-driven changes in freshwater and presumably river-borne sediment from the watershed to the sound. They are consistent with studies in the mainstem indicating the important influence of climatic and hydrological processes on water quality. Pollen evidence for high sedimentation and vegetation change during colonial land clearance. Pollen assemblages from sediment cores in Pocomoke Sound document high sedimentation rates (0.7->4.0 cm yr -1 ) at most sites throughout the Sound in post-Colonial time. These results confirm those from other regions of the bay that land-clearance increased the flux of river-borne sediment to certain r

Open-File Report↗

Sediment sources and connectivity linked to hydrologic pathways and geomorphic processes: A conceptual model to specify sediment sources and pathways through space and time

Sediment connectivity is a conceptualization for the transfer and storage of sediment among different geomorphic compartments across upland landscapes and channel networks. Sediment connectivity and dysconnectivity are linked to the water cycle and hydrologic systems with the associated multiscale interactions with climate, soil, topography, ecology, and landuse/landcover under natural variability and human intervention. We review current sediment connectivity and modeling approaches evaluating and quantifying water and sediment transfer in catchment systems. Many studies highlight the interaction between sediment and water in defining landscape connectivity, but many efforts to quantify and/or simulate sediment connectivity rely on the topographic/structural controls on sediment erosion and delivery. More recent modeling efforts integrate functional and structural connectivity to capture hydrologic properties influencing sediment delivery. Though the recent modeling development is encouraging, a comprehensive sediment connectivity framework, which integrates geomorphic and hydrologic processes across spatiotemporal scales, has not yet been accomplished. Such an effort requires understanding the hydrologic and geomorphic processes that control sediment source, storage, and transport at different spatiotemporal scales and across various geophysical conditions. We propose a path for developing this new understanding through an integrated hydrologic and sediment connectivity conceptual model that broadly categorizes dominant processes and patterns relevant to understanding sediment flux dynamics. The conceptual model describes hydrologic–sediment connectivity regimes through spatial-temporal feedback between hydrologic processes and geomorphic drivers. We propose that in combining hydrologic and sediment connectivity into a single conceptual model, patterns emerge such that catchments will exist in a single characteristic behavior at a particular instance, which would shift with space and time, and with landscape disturbances. Using the conceptual model as a “thinking” tool, we extract case studies from a multidisciplinary literature review—from hydrology, geomorphology, biogeochemistry, and watershed modeling to remote-sensing technology—that correspond to each of the dominant hydrologic–sediment connectivity regimes. Sediment and water interactions in real-world examples through various observational and modeling techniques illustrate the advancements in the spatial and temporal scales of landscape connectivity observations and simulations. The conceptual model and case studies provide a foundation for advancing the understanding and predictive capability of watershed sediment processes at multiple spatiotemporal scales. Plain language summary: Soil erosion and movement across the landscape are closely linked to rain events and flow pathways. Landscape connectivity is a way to consider how soil erosion from different parts of the landscape is connected to the streams. We explore where soil erosion occurs and how eroded soil moves across the landscape through the interaction with rainfall and drainage. The comprehensive understanding of sediment connectivity and its dependence on rainfall characteristics and watershed hydrology may help to inform the effective distribution of conservation funds and management actions to address water pollution from excess sediment.

Frontiers in Water↗

Hydrologic response of streams restored with check dams in the Chiricahua Mountains, Arizona

In this study, hydrological processes are evaluated to determine impacts of stream restoration in the West Turkey Creek, Chiricahua Mountains, southeast Arizona, during a summer-monsoon season (June&ndash;October of 2013). A paired-watershed approach was used to analyze the effectiveness of check dams to mitigate high flows and impact long-term maintenance of hydrologic function. One watershed had been extensively altered by the installation of numerous small check dams over the past 30&thinsp;years, and the other was untreated (control). We modified and installed a new stream-gauging mechanism developed for remote areas, to compare the water balance and calculate rainfall&ndash;runoff ratios. Results show that even 30&thinsp;years after installation, most of the check dams were still functional. The watershed treated with check dams has a lower runoff response to precipitation compared with the untreated, most notably in measurements of peak flow. Concerns that downstream flows would be reduced in the treated watershed, due to storage of water behind upstream check dams, were not realized; instead, flow volumes were actually higher overall in the treated stream, even though peak flows were dampened. We surmise that check dams are a useful management tool for reducing flow velocities associated with erosion and degradation and posit they can increase baseflow in aridlands.

Arizona↗

Synopsis of geologic and hydrologic results: Chapter A in Geological Survey research 1961

The Geological Survey is engaged in many different kinds of investigations in the fields of geology and hydrology. These investigations may be grouped into several broad, inter-related categories as follows: (a) Economic geology, including engineering geology (b) Regional geologic mapping, including detailed mapping and stratigraphic studies (c) Resource and topical studies (d) Ground-water studies (e) Surface-water studies (f) Quality-of-water studies (g) Field and laboratory research on geologic and hydrologic processes and principles. The Geological Survey also carries on investigations in its fields of competence for other Federal agencies that do not have the required specialized staffs or scientific facilities. Nearly all the Geological Survey's activities yield new data and principles of value in the development or application of the geologic and hydrologic sciences. The purpose of this report, which consists of 4 chapters, is to present as promptly as possible findings that have come to the fore during the fiscal year 1961 the 12 months ending June 30, 1961. The present volume, chapter A, is a synopsis of the highlights of recent findings of scientific and economic interest. Some of these findings have been published or placed on open file during the year; some are presented in chapters B, C, and D; still others have not been published previously. Only part of the scientific and economic results developed during the year can be presented in this synopsis. Readers who wish more complete or more detailed information should consult the bibliography of reports beginning on page A-156 of this volume, and the collection of short articles presented in the companion chapters as follows: Prof. Paper 424-B Articles 1 to 146 Prof. Paper 424-C Articles 147 to 292 Prof. Paper 424-D Articles 293 to 435 A list of investigations in progress in the Geologic and Water Resources Divisions with the names and addresses of the project leaders is given on pages A-110 to A-155 for those interested in work in progress in various areas or on special topics. During the fiscal year 1961, the services of the Geologic and Water Resources Divisions were utilized, or supported financially in part, by the many Federal and State agencies listed on pages A-106 to A-109. The Geological Survey has also cooperated from time to time with other agencies, and some of the work described in these chapters stems from work of previous years in cooperation with agencies not shown on the list. All cooperating agencies are identified where appropriate in the individual short articles in chapters B, C, and D, and they are mentioned in connection with some of the larger programs summarized in chapter A; because of space limitations, however, their contributions are mentioned in many of the short summary paragraphs contained in chapter A.

Professional Paper↗

Precipitation runoff modeling system (PRMS) as part of an integrated hydrologic model for the Osage Nation, northeastern Oklahoma, 1915–2014

Executive Summary The Osage Nation lacks a comprehensive tribal water plan to describe the quality and quantity of water resources in the Osage Nation, a 2,304-square-mile (mi 2 ) area of rolling pastures, tallgrass prairie, and mixed woodlands in northeastern Oklahoma. A tribal water plan can be used to help manage the sustainable development of surface and groundwater resources, thereby helping to provide a better future for the Osage Nation and their neighbors, while preserving water resources for the benefit of the surrounding environment and future generations. To help meet these goals and contribute to increased knowledge of the quantity and quality of water resources and the hydrologic processes and factors affecting those resources, the U.S. Geological Survey (USGS) in cooperation with the Osage Nation began studies to evaluate the surface-water and groundwater resources of the Osage Nation. An important component of these studies is the development and application of numerical models to improve quantification and understanding of the hydrologic system. These models are needed to estimate and quantify the effects of historical and potential future water resource development for the Osage Nation. This report describes the development and application of a precipitation-runoff model, the Osage Nation watershed model (ONWM). The ONWM is needed as a component of the Osage Nation integrated hydrologic model (ONIHM). At the time of this study, the ONIHM was being developed using the USGS computer software MODFLOW-One Water Hydrologic Flow Model (MODFLOW-OWHM). The intended use of the ONIHM is to simulate all surface-water and groundwater components of the hydrologic system for a 2,905-mi 2 study area centered on the Osage Nation. The ONWM was developed using the USGS Precipitation Runoff Modeling System, version 4 (PRMS-IV) computer software, also referred to as PRMS in this report, for an 8,343-mi 2 study area in northeastern Oklahoma and southeastern Kansas, centered on and including the areas of the Osage Nation and the ONIHM. The ONWM is to be used as part of the ONIHM to provide a direct coupling with spatially and temporally varying daily climate conditions affecting the ONIHM study area. As an integral part of the ONIHM, the ONWM (1) simulates the inflow boundary conditions from tributary basins in the region outside and surrounding the ONIHM area; (2) provides estimates of spatially and temporally distributed precipitation, air temperature, potential evapotranspiration (PET), actual evapotranspiration (ET), soil moisture, recharge, and streamflow in the ONIHM area; and (3) provides a preliminary water budget for the ONIHM area and the surrounding region, including tributary drainage basins outside of and next to the ONIHM. The specific objectives of this study were to use the ONWM to (1) provide a systematic inventory of the historical distribution of water inflows from precipitation (rain or snow) falling on the land surface and flowing through the surface-water network, (2) provide a historical context of the variability and spatial and temporal distribution of these waters, and (3) provide estimates of water inflows and potential observations to the ONIHM. The application of the ONWM as a component of the ONIHM is needed for planned simulations using the ONIHM to improve the understanding of the hydrologic system and to develop a fully comprehensive water budget, including the use and movement of water across the landscape, in the surface-water network, and in groundwater aquifers under historical and potential future conditions.

Oklahoma↗

Preliminary hydrogeologic assessment and study plan for a regional ground-water resource investigation of the Blue Ridge and Piedmont provinces of North Carolina

Prolonged drought, allocation of surface-water flow, and increased demands on ground-water supplies resulting from population growth are focuses for the need to evaluate ground-water resources in the Blue Ridge and Piedmont Provinces of North Carolina. Urbanization and certain aspects of agricultural production also have caused increased concerns about protecting the quality of ground water in this region. More than 75 percent of the State's population resides in the Blue Ridge and Piedmont Provinces in an area that covers 30,544 square miles and 65 counties. Between 1940 and 2000, the population in the Piedmont and Blue Ridge Provinces increased from 2.66 to 6.11 million; most of this increase occurred in the Piedmont. Of the total population, an estimated 1.97 million people, or 32.3 percent (based on the 1990 census), relied on ground water for a variety of uses, including commercial, industrial, and most importantly, potable supplies. Ground water in the Blue Ridge and Piedmont traditionally has not been considered as a source for large supplies, primarily because of readily available and seemingly limitless surface-water supplies, and the perception that ground water in the Blue Ridge and Piedmont Provinces occurs in a complex, generally heterogeneous geologic environment. Some reluctance to use ground water for large supplies derives from the reputation of aquifers in these provinces for producing low yields to wells, and the few high-yield wells that are drilled seem to be scattered in areas distant from where they are needed. Because the aquifers in these provinces are shallow, they also are susceptible to contamination by activities on the land surface. In response to these issues, the North Carolina Legislature supported the creation of a Resource Evaluation Program to ensure the long-term availability, sustainability, and quality of ground water in the State. As part of the Resource Evaluation Program, the North Carolina Division of Water Quality, Groundwater Section, in cooperation with the U.S. Geological Survey, initiated a multiyear study of ground water in the Blue Ridge and Piedmont Provinces. The study began in 1999. Most of the study area is underlain by a complex, two-part, regolith-fractured crystalline rock aquifer system. Thickness of the regolith throughout the study area is highly variable and ranges from 0 to more than 150 feet. The regolith consists of an unconsolidated or semiconsolidated mixture of clay and fragmental material ranging in grain size from silt to boulders. Because porosities range from 35 to 55 percent, the regolith provides the bulk of the water storage within the Blue Ridge and Piedmont ground-water system. At the base of the regolith is the transition zone where saprolite grades into unweathered bedrock. The transition zone has been identified as a potential conduit for rapid ground-water flow. If this is the case, the transition zone also may serve as a conduit for rapid movement of contaminants to nearby wells or to streams with channels that cut into 1 U.S. Geological Survey, Raleigh, North Carolina. 2 North Carolina Department of Environment and Natural Resources, Division of Water Quality, Groundwater Section. or through the transition zone. How rapidly a contaminant moves through the system largely may be a function of the characteristics of the transition zone. The transition zone is one of several topics identified during the literature review and data synthesis, for which there is a deficiency in data and understanding of the processes involved in the movement of ground water to surface water. Because the Blue Ridge and Piedmont study area is so large, and the hydrogeology diverse, it is not feasible to study all of the area in detail. A more feasible approach is to select areas that are most representative of the land use, geology, and hydrology to obtain an understanding of the hydrologic processes in the selected areas, and transfer the knowledge from these local "type areas" to similar regional hydrogeologic areas. For the purpose of this study, the term "type area" applies to a 10- to 100-square mile area within a hydrogeologic terrane where information is sufficient to develop and test a concept of ground-water flow by using analytical or numerical methods that can be validated by field measurements. Ideally, these type areas are selected to be representative of the flow system that is present wherever a particular hydrogeologic terrane is present. This report consists of two basic parts. The first part describes the results of a comprehensive review and synthesis of information and literature that provides the basic background for the study. This includes current (2002) knowledge regarding general geology and the hydrogeologic framework of the fractured-rock aquifer system that underlies the Blue Ridge and Piedmont Provinces. In spite of the quantity of information identified during the literature review and the amount of past work that has been documented, there are still research needs to be met. The second part of the report describes State ground-water issues and problems, available data, and data deficiencies. It also describes the design and implementation of efforts to characterize ground-water quality and to quantify factors that influence the movement and availability of ground water in the hydrogeologic terranes characterized by (1) massive or foliated crystalline rocks overlain by thick regolith and (2) massive or foliated crystalline rocks overlain by thin regolith. As of September 2001, seven sites had been identified as potential study sites to be used to characterize the hydrogeology and water quality of ype areas considered representative of the larger terranes. Detailed geologic mapping, core drilling, well installation, and surface and borehole geophysical surveys are in progress at four of the sites.

North Carolina↗

Hydrologic modeling to examine the influence of the forestry reclamation approach and climate change on mineland hydrology

Forests in the Appalachian region of the U.S. are threatened by a variety of short- and long-term pressures, including climate change, invasive species, and resource extraction. Surface mining for coal is one of the most important drivers of land-use change in the region, reducing native forest cover, causing forest fragmentation, eliminating intact soil, and affecting water resources. The Forestry Reclamation Approach (FRA) has been demonstrated as a successful best practice for restoring forests on mine-impacted landscapes, but little information exists on how the practice will affect hydrologic processes. A study was initiated to examine soil-water movement, as in-situ saturated hydraulic conductivity (K sat ), combined with soil porosity to quantify the potential influence on streamflow of reclaimed mines relative to an unmined, forested control site in eastern Kentucky. We compared different reclamation techniques and time since reclamation to determine the extent to which hydrologic function can be restored. We also simulated evapotranspiration at the watershed scale as a function of reclamation technique for both historical and projected (2050) climate. Results indicate that conventional grassland reclamation critically changes how soil water transitions to streamflow, primarily due to K sat variability that exceeds that measured for intact and FRA soils. Sites reclaimed using FRA exhibited a soil-water environment that was more similar to the unmined control. However, all reclaimed mine soils were thinner, retained and stored less soil water, and thus could provide less plant-available water during the growing season. The plant-available water stored in reclaimed landscapes may not be sufficient to support forest health and this is exacerbated by projected climate conditions. However, soil development under a combination of FRA techniques has the potential to mitigate this limitation.

Kentucky↗

Fate of 4-nonylphenol and 17β-estradiol in the Redwood River of Minnesota

The majority of previous research investigating the fate of endocrine-disrupting compounds has focused on single processes generally in controlled laboratory experiments, and limited studies have directly evaluated their fate and transport in rivers. This study evaluated the fate and transport of 4-nonylphenol, 17β-estradiol, and estrone in a 10-km reach of the Redwood River in southwestern Minnesota. The same parcel of water was sampled as it moved downstream, integrating chemical transformation and hydrologic processes. The conservative tracer bromide was used to track the parcel of water being sampled, and the change in mass of the target compounds relative to bromide was determined at two locations downstream from a wastewater treatment plant effluent outfall. In-stream attenuation coefficients ( k stream ) were calculated by assuming first-order kinetics (negative values correspond to attenuation, whereas positive values indicate production). Attenuation of 17β-estradiol ( k stream = −3.2 ± 1.0 day –1 ) was attributed primarily due to sorption and biodegradation by the stream biofilm and bed sediments. Estrone ( k stream = 0.6 ± 0.8 day –1 ) and 4-nonylphenol ( k stream = 1.4 ± 1.9 day –1 ) were produced in the evaluated 10-km reach, likely due to biochemical transformation from parent compounds (17β-estradiol, 4-nonylphenolpolyethoxylates, and 4-nonyphenolpolyethoxycarboxylates). Despite attenuation, these compounds were transported kilometers downstream, and thus additive concentrations from multiple sources and transformation of parent compounds into degradates having estrogenic activity can explain their environmental persistence and widespread observations of biological disruption in surface waters.

Minnesota↗

Antecedent flow conditions and nitrate concentrations in the Mississippi River basin

The relationship between antecedent flow conditions and nitrate concentrations was explored at eight sites in the 2.9 million square kilometers (km 2 ) Mississippi River basin, USA. Antecedent flow conditions were quantified as the ratio between the mean daily flow of the previous year and the mean daily flow from the period of record (Qratio), and the Qratio was statistically related to nitrate anomalies (the unexplained variability in nitrate concentration after filtering out season, long-term trend, and contemporaneous flow effects) at each site. Nitrate anomaly and Qratio were negatively related at three of the four major tributary sites and upstream in the Mississippi River, indicating that when mean daily streamflow during the previous year was lower than average, nitrate concentrations were higher than expected. The strength of these relationships increased when data were subdivided by contemporaneous flow conditions. Five of the eight sites had significant negative relationships ( p ≤ 0.05) at high or moderately high contemporaneous flows, suggesting nitrate that accumulates in these basins during a drought is flushed during subsequent high flows. At half of the sites, when mean daily flow during the previous year was 50 percent lower than average, nitrate concentration can be from 9 to 27 percent higher than nitrate concentrations that follow a year with average mean daily flow. Conversely, nitrate concentration can be from 8 to 21 percent lower than expected when flow during the previous year was 50 percent higher than average. Previously documented for small, relatively homogenous basins, our results suggest that relationships between antecedent flows and nitrate concentrations are also observable at a regional scale. Relationships were not observed (using all contemporaneous flow data together) for basins larger than 1 million km 2 , suggesting that above this limit the overall size and diversity within these basins may necessitate the use of more complicated statistical approaches or that there may be no discernible basin-wide relationship with antecedent flow. The relationships between nitrate concentration and Qratio identified in this study serve as the basis for future studies that can better define specific hydrologic processes occurring during and after a drought (or high flow period) which influence nitrate concentration, such as the duration or magnitude of low flows, and the timing of low and high flows.

Mississippi River Basin↗