Modeling natural gas reservoirs: A simple model

Determination of interstitial chloride in shales and consolidated rocks by a precision leaching technique

We have devised a technique for determining chloride in interstitial water of consolidated rocks. Samples of rocks ranging from 5 to 10 g are crushed and sieved under controlled conditions and then ground with distilled water to submicron size in a closed mechanical mill. After ultra-centrifugation, chloride content is determined by coulometric titration. The chloride concentrations and total pore-water concentrations, obtained earlier from the same pore-water concentrations, obtained earlier from the same samples by low-temperature vacuum desiccation, are used to arrive at the "original" pore-water chloride concentrations by a simple iteration procedure. Interstitial chlorinity results obtained from Cretaceous and Jurassic strata in the Gulf of Mexico coastal areas ranged from 20 to 100 g/kg Cl with reproducibility approaching +/- 1%. We have also applied the technique to igneous and metamorphic bedrocks as well as ocean basalts containing 1 % water or less. Chloride values ranging from 6.7 to 20 g/kg with a reproducibility of about 5% were obtained.