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Relaxation of the structure of simple metal ion complexes in aqueous solutions at up to supercritical conditions

Robert A. Mayanovic·Sumedha Jayanetti·Alan J. Anderson·William A. Bassett·I.-M. Chou
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Abstract

Recently x-ray absorption fine structure (XAFS) studies of various ions in aqueous solutions showed a variation of cation-ligand bond lengths, often coupled with other structure changes, with increasing temperatures. Thus, the variations of the structure of several metal ion complexes with temperature based on observations from the X-ray absorption fine structure (XAFS) studies in the hope that it will stimulate the development of either first- principles theory or molecular dynamics simulations that might adequately describes these results are discussed.

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Robert A. Mayanovic, Sumedha Jayanetti, Alan J. Anderson, William A. Bassett, I.-M. Chou. 2003. Relaxation of the structure of simple metal ion complexes in aqueous solutions at up to supercritical conditions. https://doi.org/10.1063/1.1524616

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