Upper Cretaceous Shannon Sandstone reservoirs, Powder River Basin, Wyoming: Evidence for organic acid diagenesis?

Abstract

Comparison of the petrology of shallow and deep oil reservoirs in the Upper Cretaceous Shannon Sandstone Beds of the Steele Member of the Cody Shale strongly suggests that organic acids have had a more significant impact on the diagenetic alteration of aluminosilicate grains and carbonate cements in the deep reservoirs than in the shallow reservoirs. Vitrinite reflectance and Rock-Eval measurements, as well as the time-temperature index and kinetic modeling, indicate that deep reservoirs have been subjected to maximum temperatures of approximately 110-120 degrees C, whereas shallow reservoirs have reached only 75 degrees C. Only the deep reservoirs, therefore, have reached higher temperatures and have been (and some still are) within the zone (80-120 degrees C) of maximum organic acid production. Burial history reconstruction and paragenetic relations show that oil migration into Shannon reservoirs occurred in the middle to late Tertiary. In shallow reservoirs, detrital grains exhibit minor dissolution, sparse and small overgrowths, and secondary porosity created by dissolution of early calcite cement. However, deeper sandstones are characterized by extensive dissolution of detrital K-feldspar and detrital glauconite grains, and precipitation of abundant, large quartz and feldspar overgrowths. Quartz overgrowths commonly have crystallographically controlled etch pits. Throughout the Shannon and Steele, dissolution of glauconite and degradation of kerogen were probably aided by clay mineral/organic catalysis, which caused simultaneous reduction of iron and oxidation of kerogen. This process resulted in release of ferrous iron and organic acids and was promoted in the deep reservoirs by higher formation temperatures acco nting for more extensive dissolution of aluminosilicate grains. At the temperatures of deep Shannon reservoirs, alkalinity was buffered by organic acid anions so that iron released from glauconite precipitated as chlorite and abundant, multistage ferroan carbonate overgrowths. Carbonic acid produced from the dissolution of early calcite cement, decarboxylation of organic matter, and influx of meteoric water after Laramide uplift produced additional dissolution of cements and grains. Dissolution by organic acids and complexing by organic acid anions, however, best explain the intensity of diagenesis and absence of dissolution products in secondary pores and on etched surfaces of framework grains in deep reservoirs.