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Research about Upper Mississippi River Basin

Source-linked reports with geographic coverage including Upper Mississippi River Basin.

At least 19 recordsLinked to original sources
USGS2026

Multivariate SWAT streamflow and surface water storage calibration enables upper Mississippi River Basin wetland change scenarios

Surface water storage (e.g., wetlands, lakes) is not typically considered in hydrological model calibrations. We tested a multivariate calibration process, incorporating Sentinel-1 and -2 surface water storage, for a Soil and Water Assessment Tool model across the 0.5 million km 2 Upper Mississippi River Basin. While 19% of the 2000 parameter sets adequately simulated discharge (Kling-Gupta efficiency >0.5), only 5% also adequately simulated surface water storage (mean absolute error <2 m), reducing model output uncertainty. Using the best calibrated model, we found that changes in surface water storage capacity most strongly affected discharge during the first annual peak flow (i.e., floods), when storage was filling. Increases in upstream surface water storage capacity resulted in projected decreases in peak flow and flashiness, with changes persisting downstream to the watershed outlet. Our findings demonstrate the importance of surface water storage in multivariate model calibration processes to inform river discharge and flood impact predictions.

Illinois, Indiana, Iowa, Minnesota, Missouri, Wisc↗
USGS2026

PFAS exposure suppresses leaf litter decomposition in a stream ecosystem

Decomposition of organic matter is critical to the biogeochemical cycling of carbon and nutrients in all ecosystems. In streams, decomposition can be influenced by anthropogenic impacts, including contaminants. Per- and polyfluoroalkyl substances (PFAS) are resistant to degradation and widespread in freshwater ecosystems, yet little is known about their influence on organic matter processing in streams. We paired an observational field study of a PFAS-impacted stream via food processing wastewater with a 28-day laboratory experiment to investigate PFAS effects on leaf litter processing using multiple lines of evidence. Leaf litter decomposition rates and microbial respiration were significantly lower downstream of the PFAS point-source compared to the paired upstream site. We hypothesized that PFAS suppressed microbial activity thereby resulting in slower decomposition rates. To investigate further and better isolate PFAS, we dosed aquatic mesocosms containing leaf packs with differing concentrations of perfluorooctane sulfonate (PFOS). Over the 28-day incubation, decomposition rates did not differ, but we observed lower respiration rates on day 28 and higher dissolved organic carbon (DOC) in PFOS-dosed mesocosms, suggesting that PFAS may suppress microbial activity and inhibit carbon processing. These results underscore that concerns regarding PFAS contamination extend beyond organismal toxicity to ecosystem-level effects. Further research is needed to understand the scale, implications, and mechanisms responsible for these changes.

Upper Mississippi River Basin↗
USGS2025

How do hydrological variability and human activities control the spatiotemporal changes of riverine nitrogen export in the Upper Mississippi River Basin?

Excessive nitrogen export from agricultural watersheds remains a critical water quality challenge, with the Upper Mississippi River Basin (UMRB) significantly contributing to downstream eutrophication and hypoxia in the Gulf. This study investigates the spatiotemporal dynamics of riverine nitrate plus nitrite (NO 3 – + NO 2 – -N) export across the UMRB at high spatial resolution (12-digit Hydrologic Unit Codes or HUC12 subwatershed scale) during 2001–2020 and quantifies the effects of anthropogenic activities and hydrological variability on riverine NO 3 – + NO 2 – -N export changes in the region between 2001–2005 and 2016–2020. Our results revealed hotspots of substantial increases in NO 3 – + NO 2 – -N yields across the UMRB, with distinct regional patterns in driving factors. Over the entire UMRB, NO 3 – + NO 2 – -N yields increased by 9.7 kg/ha/yr on average from 2001–2005 to 2016–2020, with anthropogenic activities contributing 4.8 kg/ha/yr and hydrological variability contributing 4.9 kg/ha/yr. The northern and western UMRB had combined influences from both anthropogenic activities and hydrological variability, while the east-central regions had predominantly hydrologically driven changes. Agricultural sources, including fertilizer, manure, and biological nitrogen fixation, collectively contributed over 80% of NO 3 – + NO 2 – -N loading throughout the basin. This framework for disentangling human and hydrological impacts provides critical insights for developing effective and targeted watershed management strategies to reduce nutrient losses and improve water quality.

Upper Mississippi River Basin↗
USGS2023

Bioavailability of dissolved organic matter varies with anthropogenic landcover in the Upper Mississippi River Basin

Anthropogenic conversion of forests and wetlands to agricultural and urban landcovers impacts dissolved organic matter (DOM) within streams draining these catchments. Research on how landcover conversion impacts DOM molecular level composition and bioavailability, however, is lacking. In the Upper Mississippi River Basin (UMRB), water from low-order streams and rivers draining one of three dominant landcovers (forest, agriculture, urban) was incubated for 28 days to determine bioavailable DOC (BDOC) concentrations and changes in DOM composition. The BDOC concentration averaged 0.49 ± 0.30 mg L −1 across all samples and was significantly higher in streams draining urban catchments (0.72 ± 0.34 mg L −1 ) compared to streams draining agricultural (0.28 ± 0.15 mg L −1 ) and forested (0.47 ± 0.17 mg L −1 ) catchments. Percent BDOC was significantly greater in urban (10% ± 4.4%) streams compared to forested streams (5.6% ± 3.2%), corresponding with greater relative abundances of aliphatic and N-containing aliphatic compounds in urban streams. Aliphatic compound relative abundance decreased across all landcovers during the bioincubation (average -4.1% ± 10%), whereas polyphenolics and condensed aromatics increased in relative abundance across all landcovers (average of +1.4% ± 5.9% and +1.8% ± 10%, respectively). Overall, the conversion of forested to urban landcover had a larger impact on stream DOM bioavailability in the UMRB compared to conversion to agricultural landcover. Future research examining the impacts of anthropogenic landcover conversion on stream DOM composition and bioavailability needs to be expanded to a range of spatial scales and to different ecotones, especially with continued landcover alterations.

Minnesota, Iowa, North Dakota, South Dakota, Wisco↗
USGS2020

Quantifying and mapping inundation regimes within a large river‐floodplain ecosystem for ecological and management applications

Spatial information on the distribution of ecosystem patterns and processes can be a critical component of designing and implementing effective management programs in river‐floodplain ecosystems. For example, translating how flood pulses detected within a stream gauge record are spatially manifested across a river‐valley bottom can be used to evaluate whether the current distribution of physical conditions has the potential to support priority habitats or if intervention is needed to meet desired goals. The size and complexity of large river‐floodplain systems can make mapping inundation dynamics a challenging task. We used a geospatial model to simulate 40 years (1972–2011) of daily surface‐water inundation depths for 11,331 km 2 of the Upper Mississippi River System floodplain. We identified discrete inundation events at each 4‐m × 4‐m pixel in the model as sequential days of submergence. We then quantified and mapped four aspects of inundation regime – event frequency, duration, magnitude, and timing – for each pixel. The spatial distribution of inundation regime attributes varied within and among multiple levels of river organization, including navigation pools and geomorphic reaches, but only event timing exhibited a strong down‐river trend. Non‐linear relations among inundation attributes and their geospatial distributions likely reflect complex interactions among topographic, hydrologic, and anthropogenic constraints on flooding dynamics. Together, our results reveal spatial gradients in inundation dynamics not captured by hydrologic data alone. Characterizing such diversity in inundation dynamics is important for testing hypotheses about ecological processes, developing models of ecosystem functions, and informing management actions.

Illinois, Indiana, Iowa, Minnesota, Missouri, Wisc↗
USGS2017

Biological and land use controls on the isotopic composition of aquatic carbon in the Upper Mississippi River Basin

Riverine ecosystems receive organic matter (OM) from terrestrial sources, internally produce new OM, and biogeochemically cycle and modify organic and inorganic carbon. Major gaps remain in the understanding of the relationships between carbon sources and processing in river systems. Here we synthesize isotopic, elemental, and molecular properties of dissolved organic carbon (DOC), particulate organic carbon (POC), and dissolved inorganic carbon (DIC) in the Upper Mississippi River (UMR) system above Wabasha, MN, including the main stem Mississippi River and its four major tributaries (Minnesota, upper Mississippi, St. Croix, and Chippewa Rivers). Our goal was to elucidate how biological processing modifies the chemical and isotopic composition of aquatic carbon pools during transport downstream in a large river system with natural and man-made impoundments. Relationships between land cover and DOC carbon-isotope composition, absorbance, and hydrophobic acid content indicate that DOC retains terrestrial carbon source information, while the terrestrial POC signal is largely replaced by autochthonous organic matter, and DIC integrates the influence of in-stream photosynthesis and respiration of organic matter. The UMR is slightly heterotrophic throughout the year, but pools formed by low-head navigation dams and natural impoundments promote a shift towards autotrophic conditions, altering aquatic ecosystem dynamics and POC and DIC composition. Such changes likely occur in all major river systems affected by low-head dams and need to be incorporated into our understanding of inland water carbon dynamics and processes controlling CO 2 emissions from rivers, as new navigation and flood control systems are planned for future river and water resources management.

Upper Mississippi River Basin↗
USGS2016

Digestive physiology comparisons of aquatic invertebrates in the Upper Mississippi River Basin

Limited information is available on the composition of digestive enzymes present in unionid mussels and the zebra mussel, Dreissena polymorpha . Available information is nearly exclusive to species used for culture purposes. A commercially available enzyme assay kit was used to examine the effect of habitat within an ecosystem, season, and species on the activities of several digestive enzymes. We used Amblema plicata to represent native unionids, D. polymorpha , and also Hydropsyche orris as an outgroup to compare differences between mussels and other macroinvertebrates. The data indicated that neither location nor time affect the activities of the digestive enzymes tested; species was the only factor to affect the activity. Differences were found mostly between four enzymes: naphthol-AS-BI-phosphohydrolase, acid phosphatase, alkaline phosphatase, and &beta;-galactosidase.

Upper Mississippi River Basin↗
USGS2013

Water and sediment temperatures at mussel beds in the upper Mississippi River basin

Native freshwater mussels are in global decline and urgently need protection and conservation. Declines in the abundance and diversity of North American mussels have been attributed to human activities that cause pollution, waterquality degradation, and habitat destruction. Recent studies suggest that effects of climate change may also endanger native mussel assemblages, as many mussel species are living close to their upper thermal tolerances. Adult and juvenile mussels spend a large fraction of their lives burrowed into sediments of rivers and lakes. Our objective was to measure surface water and sediment temperatures at known mussel beds in the Upper Mississippi (UMR) and St. Croix (SCR) rivers to estimate the potential for sediments to serve as thermal refugia. Across four mussel beds in the UMR and SCR, surface waters were generally warmer than sediments in summer, and were cooler than sediments in winter. This suggests that sediments may act as a thermal buffer for mussels in these large rivers. Although the magnitude of this effect was usually <3.0°C, sediments were up to 7.5°C cooler at one site in May, suggesting site-specific variation in the ability of sediments to act as thermal buffers. Sediment temperatures in the UMR exceeded those shown to cause mortality in laboratory studies. These data suggest that elevated water temperatures resulting from global warming, thermal discharges, water extraction, and/or droughts have the potential to adversely affect native mussel assemblages.

Upper Mississippi River Basin↗
USGS2003

Water-quality assessment of part of the Upper Mississippi River Basin Study Unit, Minnesota and Wisconsin — Nutrients, chlorophyll a, phytoplankton, and suspended sediment in streams, 1996-98

Stream water-quality data from part of the Upper Mississippi River Basin Study Unit (Study Unit) from 1995 through 1998 was used to describe the distribution of nutrients, chlorophyll a, phytoplankton, and suspended sediment; and the influence of natural and anthropogenic factors on reported concentrations, loads, and yields. During the study period, streamflows generally were near to greater than average. Agricultural land cover, particularly on tile-drained soils, had the most substantial influence on nutrients, chlorophyll a , and suspended sediment in the Study Unit. The greatest concentrations and yields of total nitrogen, dissolved nitrite plus nitrate nitrogen, dissolved nitrite nitrogen, total organic plus ammonia nitrogen, total phosphorus, and suspended sediment were measured in a stream representing agricultural land cover on tile-drained soils. Total nitrogen yields also were about 6 times greater in a stream representing agricultural land cover on tile-drained soils than in a stream representing agricultural land cover on naturally welldrained soils. Urban-residential land cover also influenced nutrients and suspended sediment in streams in the Study Unit. Concentrations and yields of total nitrogen, dissolved nitrite plus nitrate nitrogen, total organic plus ammonia nitrogen, total phosphorus, dissolved orthophosphate phosphorus (orthophosphate), and suspended sediment in streams representing urban-residential land cover were less than those representing agricultural land cover on tile drained soil, and greater than those on forested land cover. Nutrients and suspended sediment in the Mississippi, Minnesota, and St. Croix Rivers generally reflect the influence of primary land cover in drainage areas of streams tributary to these rivers. In the Mississippi River, total nitrogen, dissolved nitrite plus nitrate nitrogen, dissolved ammonia nitrogen, total phosphorus, dissolved orthophosphate, and suspended-sediment concentrations and loads increased substantially downstream of the confluence with the Minnesota River at Hastings, Minnesota. Greater concentrations and loads of dissolved orthophosphate in the Mississippi River at Hastings, Minnesota probably were caused by wastewater discharges from the Twin Cities Metropolitan Area (TCMA) and contributions from the Minnesota River. The median dissolved ammonia nitrogen concentration at the Mississippi River at Hastings, Minnesota, based on data collected during this study, was about one-half of the median concentrations previously reported for 1984-93, which can be attributed to reduced ammonia concentrations in municipal wastewater discharged from the TCMA. In the St. Croix River, total nitrogen, dissolved nitrite plus nitrate nitrogen, and total organic plus ammonia nitrogen concentrations were significantly greater at St. Croix Falls, Wisconsin compared to near Danbury, Wisconsin. All nutrient and suspended-sediment loads and yields in the St. Croix River increased in the downstream direction from near Danbury to St. Croix Falls, Wisconsin. Most sites had pronounced seasonal variations in dissolved nitrite plus nitrate nitrogen and dissolved ammonia nitrogen concentrations. At most sites, dissolved nitrite plus nitrate nitrogen concentrations were greatest in the winter and spring and least during the summer and fall. In contrast, the greatest dissolved nitrite plus nitrate nitrogen concentrations in the Little Cobb River near Beauford, Minnesota; Minnesota River near Jordan, Minnesota; and Mississippi River at Hastings and Red Wing, Minnesota occurred during the spring and summer. These seasonal variations in dissolved nitrite plus nitrate nitrogen concentrations may be the result of nitrogen cycling in the soils, as well as crop uptake and hydrologic conditions. The greatest concentrations of dissolved ammonia nitrogen at all sites occurred in the winter and spring. The maximum contaminant level for nitrate of 10 milligrams per liter (mg/L) as nitrogen set by the U.S. Environmental Protection Agency (USEPA) for drinking water was exceeded in 20 percent of the samples analyzed from the Little Cobb River near Beauford, Minnesota, and in 11 percent of the samples analyzed from the Minnesota River near Jordan, Minnesota. The greatest chlorophyll- a concentrations and algal abundances generally were measured in the Little Cobb River near Beauford, Minnesota; Minnesota River near Jordan, Minnesota; Mississippi River at Hastings, Minnesota; and the Mississippi River at Red Wing, Minnesota. Greater concentrations and algal abundances at these sites may have been the result of increased nitrogen and phosphorus concentrations. Total phosphorus concentrations at these sites most frequently exceeded the goal of 0.1 mg/L set by the USEPA to prevent eutrophication. Phytoplankton communities at these sites primarily were dominated by blue-green algae during the summer of 1996. In contrast, at most of the other sites, the phytoplankton community was dominated by diatoms.

Iowa, Minnesota, North Dakota, South Dakota, Wisco↗
USGS2003

Relation of periphyton and benthic invertebrate communities to environmental factors and land use at selected sites in part of the upper Mississippi River basin, 1996-98

The Upper Mississippi River Basin is one of the hydrologic systems selected for study by the National Water-Quality Assessment (NAWQA) Program of the U.S. Geological Survey. NAWQA utilizes a multi-disciplinary approach to explain factors that affect water quality. Part of the NAWQA design addresses the relation of land use and environmental factors to periphyton and benthic invertebrate communities in streams. This report focuses on a 122,000 square kilometer area of the Mississippi River Basin, including the Twin Cities metropolitan area (TCMA). The northeastern part of the study area is forested, the southwestern part is agricultural, and the central part is transitional between forest and agriculture. Sampling sites were selected based on a process that identified small streams in predominantly forested, agricultural, and urban settings, and large river sites on the Mississippi River and major tributaries. Periphyton and benthic invertebrate communities were evaluated at each site. Compared to the forested site, periphyton density and biovolume in small streams generally increased as nutrient concentrations associated with urban and agricultural land use increased. Periphyton communities varied within agricultural and urban streams, indicating that physical and chemical factors other than land use also affect periphyton communities. Benthic invertebrate communities also are affected by land use and associated stream habitat. There were few intolerant taxa (Ephemeroptera and Plecoptera) in urban streams, potentially due to high streamflow variability and contaminants from runoff. Ephemeroptera taxa richness was greatest in the agricultural streams. The most abundant Ephemeroptera taxa were those tolerant to high concentrations of suspended sediment. Richness of Plecoptera and Trichoptera taxa were greatest in the forested stream. Biological communities in the St. Croix and Minnesota River generally reflected relatively homogeneous land uses. Biological communities in the Mississippi River reflected changes in water quality and physical habitat as the Minnesota and St. Croix Rivers join the Mississippi River. Periphyton density and biovolume, and the relative abundance of blue-green algae density increased in the Mississippi River at the confluence compared to the Minnesota and St. Croix Rivers. Relative abundance of benthic invertebrate taxa richness and diversity generally decreased downstream in the large rivers as urban and agricultural land use become more prevalent. Impoundments and dredging of the Mississippi River in and downstream from the TCMA exacerbate effects of increasing river size to produce a more lake-like system.

Iowa, Minnesota, North Dakota, South Dakota, Wisco↗
USGS2000

Pesticides in streams in part of the Upper Mississippi River Basin, Minnesota and Wisconsin, 1974-94

Analysis of historical pesticide information by the National Water-Quality Assessment (NAWQA) Program indicates that land use and pesticide use affect detections of pesticides in streams in part of the Upper Mississippi River Basin (UMIS). Agricultural pesticide use was greatest in the Minnesota River Basin. Greater than twenty-seven times more herbicides than insecticides were used for agriculture. Pesticide detections were greatest in or downstream of agricultural and urban areas. Herbicides were detected most frequently in stream water; whereas, organochlorine insecticides were detected most frequently in streambed sediment. Most concentrations were below levels considered harmful to human and aquatic health.

Minnesota, Wisconsin↗
USGS2000

Water-quality assessment of part of the Upper Mississippi River Basin, Minnesota and Wisconsin: Trace elements in streambed sediment and fish livers, 1995-96

Trace elements were analyzed in streambed sediment and fish livers in part of the Upper Mississippi River Basin as part of the U.S. Geological Survey&rsquo;s National Water-Quality Assessment Program. The purpose of this report was to describe the occurrence and distribution of trace elements, describe the relations of concentrations measured to natural and anthropogenic factors, and describe any relation between concentrations in streambed sediment and fish livers. The study unit included the part of the Upper Mississippi River Basin from the river&rsquo;s source in northern Minnesota to the outlet of Lake Pepin, a natural lake on the river located near Red Wing, Minnesota. Streambed sediment samples were collected from 27 sites located throughout the study unit, and fish were obtained from 25 sites. The occurrence and distribution of trace elements in streambed sediment were related to land use and the composition of surficial glacial deposits covering the study unit. Concentrations of antimony, arsenic, cadmium, copper, lead, mercury, nickel, and zinc in streambed sediment were primarily related to urban land use. Concentrations of these elements generally were greatest in streambed sediment collected at sites within or near urban areas in the study unit. The greatest concentrations of most of these elements were measured in streambed sediment obtained from Shingle Creek. Lead concentrations in streambed sediment Shingle Creek increased in the downstream direction. This pattern probably reflects the past use of leaded gasoline, pesticides, or paints. Cadmium concentrations in sediment from the Mississippi River were greatest at Nininger, Minnesota and in Lake Pepin. This pattern suggested that inputs of cadmium into the river were from the TCMA. Arsenic concentrations were greatest in streambed sediment collected from Cedar Creek, Shingle Creek, and the Vermillion River. Increased arsenic and iron concentrations in sediment from Cedar Creek, the Vermillion River, and the most upstream site on Shingle Creek suggested a local source of sulfide minerals or preferential sorption of arsenic to streambed sediment. The greatest concentrations of mercury were measured in streambed sediment collected from the Mississippi River at Grand Rapids and Minneapolis, Minnesota; Shingle Creek at 46th Street in Minneapolis, Minnesota; the Namekagon River above Spring Lake Creek near Hayward, Wisconsin; the St. Croix River at Hudson, Wisconsin; and the Vermillion River near Empire, Minnesota. In fish livers, all of the trace elements analyzed were detected except antimony, beryllium, cobalt, and uranium. Trace element concentrations in fish livers generally did not show any pronounced patterns. Ranges for concentrations of arsenic, cadmium, chromium, copper, lead, mercury, nickel, selenium, and zinc were similar to those measured in 20 other NAWQA studies across the United States. Cadmium concentrations in fish livers were moderately correlated to fish length and weight. There were no relations between trace element concentrations in fish livers and streambed sediment.

Minnesota, Wisconsin↗
USGS2000

Nutrients and suspended sediment in snowmelt runoff from part of the Upper Mississippi River Basin, Minnesota and Wisconsin, 1997

The U.S. Geological Survey sampled snowmelt runoff from 42 stream sites during March and April 1997 in part of the Upper Mississippi River Basin, Minnesota and Wisconsin, to characterize nutrient and suspended-sediment concentrations, yields, and loads. Ancillary data from 12 sites provided data to estimate constituent loads delivered during snowmelt and 1997. The snowmelt period contributed from 1 to 50 percent of 1997 annual loads of total nitrogen, total phosphorus, and suspended sediment at small stream sites, and 17 to 70 percent of annual loads at mainstem river sites. Small streams in agricultural areas transported the greatest proportions of annual loads during snowmelt. Snowmelt from urban streams transported the least proportions of annual loads. Agricultural streams had significantly greater median yields (p < 0.025) of dissolved nitrite, nitrate, phosphorus, orthophosphate, total nitrogen, and total phosphorus than forested sites, and significantly greater median yields (p < 0.025) of dissolved nitrate and orthophosphate than all other land uses. In forested areas, yields of suspended sediment and all nutrient forms were significantly greater (p < 0.05) for streams draining impermeable deposits than permeable deposits.

Minnesota, Wisconsin↗
USGS1999

Relation of fish community composition to environmental and land use factors in part of the Upper Mississippi River Basin, 1995-97

Fish communities in the Upper Mississippi River Basin have been affected by changing environmental and land-use factors. Fish communities in small streams in agricultural and urban basins were compared to the fish community in a relatively undisturbed forested basin. In small streams, nutrient inputs from fertilizer, habitat modification from channelization, hydrologic modification from dams and tile drains, and increased water temperatures from loss of riparian shading have contributed to producing a change in fish community composition. In the large rivers, some of the changes that have occurred from sites upstream to downstream of the Twin Cities metropolitan area are primarily caused by the environmental effects of dams constructed as part of the lock and dam commercial navigation system. Although some of the differences upstream and downstream of the Twin Cities metropolitan area are due to zoogeographic variability, the major changes in the downstream community are shifts to more lentic species, species with higher thermal tolerance, and more planktivorous species. These changes are an extension of the changes observed in the small streams due to increased nutrients, increased water temperatures, and habitat alteration.

Minnesota↗
USGS1998

Pesticides and nitrate in surficial sand and gravel aquifers as related to modeled contamination susceptibility in part of the Upper Mississippi River Basin

The occurrence of pesticides and nitrate (nitrite plus nitrate as nitrogen) in surficial sand and gravel aquifers in parts of Minnesota and Wisconsin was summarized as part of an analysis of historical water-quality data for the Upper Mississippi River Basin study unit of the U.S. Geological Survey's National Water-Quality Assessment (NAWQA) Program. Water samples were collected by State and Federal agencies for pesticides (366) and nitrate (410) between 1971 and 1994 from wells completed in surficial sand and gravel aquifers. State agencies in Minnesota and Wisconsin have developed models to determine areas where ground water is susceptible to contamination based on geologic and hydrologic conditions (Schmidt, 1987, and Porcher, 1989). Water-quality data is evaluated with respect to the ground-water susceptibility models. The results also are evaluated with respect to overlying land use and land cover. Samples from wells with detectable levels of one or more pesticides or nitrate concentrations exceeding the U.S. Environmental Protection Agency's (USEPA) Maximum Contaminant Level (MCL) of 10 milligrams per liter (mg/L) generally coincided with areas of high contamination susceptibility. Furthermore, samples from wells located in areas of high contamination susceptibility had pesticide detection frequencies and nitrate concentrations that correlated to overlying land use and land cover. Samples from wells located in high susceptibility areas that were surrounded by cropland had greater pesticide detection frequencies and greater nitrate concentrations than wells located in similar susceptibility areas but surrounded by different land use and land cover types such as forest, urban, and wetlands.

Minnesota, Wisconsin↗
USGS1998

Nutrient sources within the Upper Mississippi River Basin, Minnesota and Wisconsin, 1991-93

The amount of nutrients contained in fertilizer, livestock manure, municipal wastewater, atmospheric deposition, and legume residues were quantified in each of the major drainage basins within the Upper Mississippi River Basin study unit (fig. 1) as part of the U.S. Geological Survey's National Water-Quality Assessment Program. These sources of nutrients may potentially affect surface- and ground-water quality, so knowledge about the relative importance of each source may assist in the management of surface and ground waters within the study unit. The relative importance of each nutrient source was expected to vary among each of the four drainage basins due to differences in land use across the study unit. Fertilizer and livestock manure were potentially large sources of nitrogen and phosphorus in each of the four drainage basins. However, nitrogen in legume residues was a more important source in the Upper Mississippi, St. Croix, and Lower Mississippi River Basins because hay comprised a larger part of the total acreage of crops grown in these basins. Atmospheric deposition comprised a larger percentage of the nitrogen sources in the St. Croix River Basin compared to the other three drainage basins probably because amounts of the other sources are relatively low. Nitrogen and phosphorus yields in streams were greatest in the Lower Mississippi River Basin and the Minnesota River Basin, where amounts of nonpoint sources of these constituents also were the greatest per square mile.

Minnesota, Wisconsin↗