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Research about United Kingdom

Source-linked reports with geographic coverage including United Kingdom.

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Spatially resolved source apportionment of per- and polyfluoroalkyl substances (PFAS) within a post-industrial river catchment

Source apportionment of per- and polyfluoroalkyl substances (PFAS) in rivers is typically based on water concentrations, which cannot quantify PFAS loads or define geographical source areas. This study applied a river catchment-scale approach to identify PFAS source zones and assess the relative importance of industrial PFAS sources in the River Mersey, UK – a post-industrial, densely populated catchment with diverse PFAS sources. Synoptic sampling and PFAS river load analysis identified key sub-catchments and river stretches contributing the majority of PFAS. Notably, the highest PFAS concentrations did not always correspond to the greatest loads. Most PFOS (64 %), PFOA (49 %), 6:2FTS (46 %) and PFHxS (56 %) were exported from the Upper Mersey sub-catchment, despite higher concentrations in northern sub-catchments, emphasising the importance of load-based monitoring. Mass balance analysis of loads highlighted substantial inputs from specific river stretches, notably the Lower Irwell (Bolton to Manchester City Centre), River Tame (Marple Bridge to Stockport), and Upper Mersey (Stockport to Urmston). While PFAS loads generally scaled with catchment area, yield (load per unit area) analysis identified disproportionately high exports from small headwater catchments, notably the upper River Roch (PFOA, PFHpA and PFHxA) and Glaze Brook (PFBS). Industrial sources in these sub-catchments (a waste management facility and landfills, respectively) were confirmed using gadolinium anomaly analysis and consented discharge records. More widely, gadolinium data suggested industrial discharges may contribute to PFAS occurrence at 62 % of our sample sites throughout the catchment. These findings demonstrate that spatial analysis of PFAS loads, rather than concentrations alone, is critical for identifying PFAS source areas. We present a scalable monitoring framework for PFAS source apportionment applied at the river catchment-scale that can be used by environmental managers to target and prioritise PFAS source areas for detailed monitoring and remediation.

River Mersey

Weather events influence survival and recruitment of Coereba flaveola (Bananaquit) in the Caribbean

The West Indies is considered a biodiversity hotspot and a priority for ecological conservation efforts. Understanding how environmental conditions influence the survival of resident avifauna is an important information need given the predicted increases in drought and the frequency and intensity of severe storms in the region. Throughout much of the Caribbean, Coereba flaveola (Bananaquit) are widespread and abundant, traits that may facilitate understanding their response to environmental changes in the region. We used a 10-yr capture–mark–recapture data set to examine C. flaveola survival, recruitment, population growth, and age structure in the context of monthly and seasonal precipitation and temperatures, drought conditions, and occurrence and intensity of storm events. Our models suggested wing length, occurrence of storms, and drought all influenced survival. Both the incidence of storms and drier-than-average conditions in the preceding wet season (April–June) decreased survival. The sex of bird and net hours influenced capture probability, but weather influences on recruitment were equivocal. During nonstorm years, mean population growth was stable at 1.019 (95% confidence interval [CI]: 0.962, 1.098) but dropped to 0.843 (95% CI: 0.795, 0.846) in storm years. Increasing frequency of storms, such as back-to-back years, would likely push the growth rate lower. A protracted pattern of increased storm frequency, especially if coupled with a subsequent drought during the wet season, may lead to localized extirpations or strongly reduced populations.

British Virgin Islands, Guana Island

Direct and indirect influences of macrophyte cover on abundance and growth of juvenile Atlantic salmon

1. The relationships between macrophytes and the physical and biological characteristics of the environments that aquatic organisms inhabit are complex. Previous studies have shown that the macrophytes, Ranunculus (subgenus Batrachium ), which are dominant in lowland chalk streams and widespread across Europe, can enhance juvenile Atlantic salmon abundance and growth to a greater degree than other physical and biological habitat characteristics. However, mechanistic understanding of how this effect might arise requires consideration of the direct and indirect relationships among habitat characteristics that are likely to be influenced by the presence of macrophyte cover. 2. We applied structural equation modelling to data collected during a 2-year in-river manipulative experiment in the River Frome (southern England, U.K.) designed to quantify the magnitude and the relative importance of direct and indirect influences of Ranunculus cover and other physical and biological variables, including water velocity, water depth, prey biomass and body size, and abundance of con- and hetero-specifics, on abundance and somatic growth of 0+ salmon. 3. Results indicated a strongly positive direct influence of Ranunculus cover on salmon abundance, as well as positive influences of Ranunculus on velocity heterogeneity and water depth that are indirectly related to decreased salmon abundance. Interestingly, there was no indication of a direct influence of Ranunculus cover on salmon growth, although Ranunculus was indirectly related to increased salmon growth through its positive influence on prey biomass, an effect mediated by velocity heterogeneity and proportion of fast velocities. 4. These findings provide novel mechanistic insights into the key role of Ranunculus in their native lowland rivers to enhance abundance and improve conditions for multiple food web components. Strategies to maintain or enhance naturally occurring Ranunculus in these rivers are therefore likely to return wide ranging ecosystem benefits, including for species of high conservation value, such as salmon. These mechanistic impacts on habitat heterogeneity and ecosystem productivity could generalise to native macrophytes in other river systems, particularly where habitat is dominated by vegetation in the absence of large substrates.

Dorset County

Assessment of peak flow scaling and Its effect on flood quantile estimation in the United Kingdom

Regional flood frequency analysis (RFFA) methods are essential tools to assess flood hazard and plan interventions for its mitigation. They are used to estimate flood quantiles when the at‐site record of streamflow data is not available or limited. One commonly used RFFA method is the index flood method (IFM), which assumes that peak floods satisfy the simple scaling hypothesis. In this work we present an integrated approach to assess the spatial scaling behavior of floods in the United Kingdom (UK) for 540 catchments, where the IFM is currently used operationally. This assessment employs product moments, probability weighted moments, and quantile analysis, and is applied to two different types of “hydrologically homogeneous” UK regions: geographical regions as defined in the Flood Studies Report (NERC, 1975) and pooling‐groups as defined in the updated Flood Estimation Handbook (FEH; Institute of Hydrology, 1999). To understand which variables play a significant role in the flood‐peak generating mechanism, the assessment approach considers scaling not only of drainage area alone but also of other hydro‐geomorphological variables. Results provided by the different methodologies consistently showed that only part (ranging from 30% to 70%) of the peak flow variability is explained by drainage area alone; this fraction increases (up to 80%–95%) when multiple regression is used. Supported by the peak flow spatial scaling assessment, we compared the proposed approach for peak flow quantile estimation with the current FEH method in ungauged catchments. The quantile regression method based on the pooling‐group outperforms the current FEH‐ungauged method, providing a 14% relative improvement in root mean square error over the entire country.

Water Resources Research

Temporal and spatial variation in pharmaceutical concentrations in an urban river system

Many studies have quantified pharmaceuticals in the environment, few however, have incorporated detailed temporal and spatial variability due to associated costs in terms of time and materials. Here, we target 33 physico-chemically diverse pharmaceuticals in a spatiotemporal exposure study into the occurrence of pharmaceuticals in the wastewater system and the Rivers Ouse and Foss (two diverse river systems) in the city of York, UK. Removal rates in two of the WWTPs sampled (a conventional activated sludge (CAS) and trickling filter plant) ranged from not eliminated (carbamazepine) to >99% (paracetamol). Data comparisons indicate that pharmaceutical exposures in river systems are highly variable regionally, in part due to variability in prescribing practices, hydrology, wastewater management, and urbanisation and that select annual median pharmaceutical concentrations observed in this study were higher than those previously observed in the European Union and Asia thus far. Significant spatial variability was found between all sites in both river systems, while seasonal variability was significant for 86% and 50% of compounds in the River Foss and Ouse, respectively. Seasonal variations in flow, in-stream attenuation, usage and septic effluent releases are suspected drivers behind some of the observed temporal exposure variability. When the data were used to evaluate a simple environmental exposure model for pharmaceuticals, mean ratios of predicted environmental concentrations (PECs), obtained using the model, to measured environmental concentrations (MECs) were 0.51 and 0.04 for the River Foss and River Ouse, respectively. Such PEC/MEC ratios indicate that the model underestimates actual concentrations in both river systems, but to a much greater extent in the larger River Ouse.

River Foss, River Ouse

Are exposure predictions, used for the prioritization of pharmaceuticals in the environment, fit for purpose?

Prioritization methodologies are often used for identifying those pharmaceuticals that pose the greatest risk to the natural environment and to focus laboratory testing or environmental monitoring toward pharmaceuticals of greatest concern. Risk-based prioritization approaches, employing models to derive exposure concentrations, are commonly used, but the reliability of these models is unclear. The present study evaluated the accuracy of exposure models commonly used for pharmaceutical prioritization. Targeted monitoring was conducted for 95 pharmaceuticals in the Rivers Foss and Ouse in the City of York (UK). Predicted environmental concentration (PEC) ranges were estimated based on localized prescription, hydrological data, reported metabolism, and wastewater treatment plant (WWTP) removal rates, and were compared with measured environmental concentrations (MECs). For the River Foss, PECs, obtained using highest metabolism and lowest WWTP removal, were similar to MECs. In contrast, this trend was not observed for the River Ouse, possibly because of pharmaceutical inputs unaccounted for by our modeling. Pharmaceuticals were ranked by risk based on either MECs or PECs. With 2 exceptions (dextromethorphan and diphenhydramine), risk ranking based on both MECs and PECs produced similar results in the River Foss. Overall, these findings indicate that PECs may well be appropriate for prioritization of pharmaceuticals in the environment when robust and local data on the system of interest are available and reflective of most source inputs.

City of York

Aeromagnetic surveys in the Aleutian, Marshall, and Bermuda Islands

Total‐intensity aeromagnetic surveys of the Aleutian Marshall , and Bermuda Islands were completed in 1948. The anomalies associated with the Aleutian volcanoes are attributed mainly to topographic relief and are not an indication of the degree of volcanic activity. Eniwetok presents a magnetic pattern that would be produced by an irregular‐shaped rimmed depression in the basement, modified by the two adjoining seamounts, and differs from Bikini, whose magnetic features would be produced by a broad seamount with irregular surface relief. The Bermuda survey demonstrated magnetic features typical of volcanic rocks. Comparison of an observed and a theoretical profile computed by Press and Ewing indicates that their assumptions are reasonably correct. The Aleutian Trench survey shows anomalies that are attributed to susceptibility contrasts but none that can be correlated with the trench. A traverse from Adak, Aleutian Islands , to Kwajalein, Marshall Islands , exhibited several large anomalies that are presumed to be caused by susceptibility contrasts but may be indications of uncharted seamounts. Two traverses, one from Cape May, N.J., to Bermuda and the other from Bermuda to Long Island , N.Y., reveal a change in the magnetic field approximately 300 miles from the Atlantic Coast that indicates a possible thinning of the sial and an exposure of sima.

Bermuda

Linking soil moisture balance and source-responsive models to estimate diffuse and preferential components of groundwater recharge

Results are presented of a detailed study into the vadose zone and shallow water table hydrodynamics of a field site in Shropshire, UK. A conceptual model is developed and tested using a range of numerical models, including a modified soil moisture balance model (SMBM) for estimating groundwater recharge in the presence of both diffuse and preferential flow components. Tensiometry reveals that the loamy sand topsoil wets up via macropore flow and subsequent redistribution of moisture into the soil matrix. Recharge does not occur until near-positive pressures are achieved at the top of the sandy glaciofluvial outwash material that underlies the topsoil, about 1 m above the water table. Once this occurs, very rapid water table rises follow. This threshold behaviour is attributed to the vertical discontinuity in the macropore system due to seasonal ploughing of the topsoil, and a lower permeability plough/iron pan restricting matrix flow between the topsoil and the lower outwash deposits. Although the wetting process in the topsoil is complex, a SMBM is shown to be effective in predicting the initiation of preferential flow from the base of the topsoil into the lower outwash horizon. The rapidity of the response at the water table and a water table rise during the summer period while flow gradients in the unsaturated profile were upward suggest that preferential flow is also occurring within the outwash deposits below the topsoil. A variation of the source-responsive model proposed by Nimmo (2010) is shown to reproduce the observed water table dynamics well in the lower outwash horizon when linked to a SMBM that quantifies the potential recharge from the topsoil. The results reveal new insights into preferential flow processes in cultivated soils and provide a useful and practical approach to accounting for preferential flow in studies of groundwater recharge estimation.

Shropshire County

The geochemistry of environmentally important trace elements in UK coals, with special reference to the Parkgate coal in the Yorkshire–Nottinghamshire Coalfield, UK

The Parkgate coal of Langsettian age in the Yorkshire–Nottinghamshire coalfield is typical of many coals in the UK in that it has a high sulphur (S) content. Detailed information on the distribution of the forms of S, both laterally and vertically through the seam, was known from previous investigations. In the present work, 38 interval samples from five measured sections of the coal were comprehensively analysed for major, minor and trace elements and the significance of the relationships established using both raw and centered log transformed data. The major elements are used to quantify the variations in the inorganic and organic coal components and determine the trace element associations. Pyrite contains nearly all of the Hg, As, Se, Tl and Pb and is also the major source of the Mo, Ni, Cd and Sb. The clays contain the following elements in decreasing order of association: Rb, Cs, Li, Ga, U, Cr, V, Sc, Y, Bi, Cu, Nb, Sn, Te and Th. Nearly all of the Rb is present in the clay fraction, whereas for elements such as V, Cu and U, a significant amount is thought to be present in the organic matter, based on the K vs trace element regression equations. Only Ge, and possibly Be, would appear to have a dominant organic source. The trace element concentrations are calculated for pyrite, the clay fraction and organic matter. For pyrite it is noted that concentrations agree with published data from the Yorkshire–Nottinghamshire coalfield and also that Tl concentrations (median of 0.33 ppm) in the pyrite are greater than either Hg or Cd. Unlike these elements, Tl has attracted less attention and possibly more information is needed on its anthropogenic distribution and impacts on man and the environment. A seawater source is thought to be responsible for the high concentrations of S, Cl and the non-detrital trace elements in the Parkgate coal. Indicative of the seawater control is the Th/U ratio, which expresses the detrital to non-detrital element contributions. Using other elements, similar ratios can be calculated, which in combination offer greater interpretative value.

Yorkshire–Nottinghamshire coalfield

Vertical accretion versus elevational adjustment in UK saltmarshes: An evaluation of alternative methodologies

Simultaneous measurements of vertical accretion from marker horizons and marsh-elevation change from sedimentation-erosion tables (SET) were made in selected marshes along the East Anglian coast of the UK in order to address the following objectives: to ascertain the validity of treating accretion measurements obtained within tidally dominated, minerogenic saltmarshes as equivalent to surface elevation changes; to explore the implications, in terms of physical and biological processes, of discrepancies between separately measured vertical accretion and elevation change within contrasting marsh types. Data were collected from several marsh environments at Scolt Head Island and Stiffkey on the North Norfolk coast and at an experimental managed realignment project near Tollesbury, Essex. Scolt Head Island was selected for its long-term datasets of marsh accretion, Stiffkey for its contrasting open coast-back barrier settings, and Tollesbury for its experimental management, in order to illustrate the potential application of the SET method and evaluate the relationship between vertical accretion and elevation change in a variety of marsh settings. The relationship between vertical accretion and elevation change varied widely among marsh settings of different age and height (within the tidal frame) at Scolt Head Island and Stiffkey. Rates of vertical accretion and elevation change were similar in the older and mid-height settings on Scolt Head Island, indicating control of elevation change by surface accretionary processes (e.g. sediment deposition). However, subsurface processes controlled elevation at three of the marsh sites. Spartina Marsh, the youngest and lowest of the back barrier settings at Scolt Head Island, exhibited continuous shallow subsidence (vertical accretion greater than elevation change) over a 4-year period, implying that compaction controls elevation change. In the upper part of Hut Marsh and the interior of the Stiffkey marshes, elevation change exceeded vertical accretion suggesting that subsurface processes (e.g. organic accumulation) controlled elevation in these settings. Surface accretionary processes control elevation change in both the highly dynamic, outer marsh at Stiffkey and the low, restored marsh at Tollesbury. Despite the occurrence of shallow subsidence, all sites gained elevation at an annual rate comparable to that of sea-level rise. In summary, the SET provides the means to critically evaluate the influence of vertical accretion measures on elevation and represents an improved method by which to evaluate the vulnerability of a marsh to sea-level rise.

Scolt Head Island Marsh, Stiffkey Marsh, Tollesbur

Window into the Caledonian orogen: Structure of the crust beneath the East Shetland platform, United Kingdom

Reprocessing and interpretation of commercial and deep seismic reflection data across the East Shetland platform and its North Sea margin provide a new view of crustal subbasement structure beneath a poorly known region of the British Caledonian orogen. The East Shetland platform, east of the Great Glen strike-slip fault system, is one of the few areas of the offshore British Caledonides that remained relatively insulated from the Mesozoic and later rifting that involved much of the area around the British Isles, thus providing an “acoustic window” into the deep structure of the orogen. Interpretation of the reflection data suggests that the crust beneath the platform retains a significant amount of its original Caledonian and older architecture. The upper to middle crust is typically poorly reflective except for individual prominent dipping reflectors with complex orientations that decrease in dip with depth and merge with a lower crustal layer of high reflectivity. The three-dimensional structural orientation of the reflectors beneath the East Shetland platform is at variance with Caledonian reflector trends observed elsewhere in the Caledonian orogen (e.g., north of the Scottish mainland), emphasizing the unique tectonic character of this part of the orogen. Upper to middle crustal reflectors are interpreted as Caledonian or older thrust surfaces that were possibly reactivated by Devonian extension associated with post-Caledonian orogenic collapse.

Geological Society of America Bulletin

Topographic effects on flow path and surface water chemistry of the Llyn Brianne catchments in Wales

Topographic shape is a watershed attribute thought to influence the flow path followed by water as it traverses a catchment. Flow path, in turn, may affect the chemical composition of surface waters. Topography is quantified in the hydrological model TOPMODEL as the relative frequency distribution of the index ln(atanB), where a is the upslope area per unit contour that drains past a point and tanB is the local surface slope. Spatial distributions of ln(atanB) were calculated for eight catchments in Wales on a 25 m x 25 m grid. Among the catchments, mean observed stream H+ concentration during high flow periods was highly correlated with the mean of the ln(atanB) distribution. The steady-state gain of a transfer function (time series) model relating H+ to discharge was positively correlated with the mean of the ln(atanB) distribution. These results suggest that during high flow periods, both the average stream acidity and the magnitude of fluctuations in H+ are conditioned by the topographic shape of the catchment. By performing a sensitivity analysis on TOPMODEL, we also show that as the mean of the ln(atanB) distribution for a catchment increases, so does its theoretical likelihood to produce significant quantities of surface and near-surface runoff. Our observed results in the Llyn Brianne catchments are consistent with this theoretical expectation in that surface or near-surface runoff is often higher in acidity than are deeper sources of hillslope runoff.

Wales

The Carlisle earthquake of December 26, 1979, in northern England

At 3:57 a.m on the morning after Christmas Day 1979, a large area of northern England and southern Scotland was shaken by an earthquake. In the mesoseismal area, a few miles north of Carlisle, chimneys toppled into the streets or fell through roofs, and people ran in panic into the open. Over a much wider area, including the densely populated industrial area of central Scotland, people were awakened, and ornaments and other small objects were disturbed. At distances over 120 miles from the epicenter, only a few people noted the tremor. Northern Ireland and the Isle of Man also expereienced the tremor but reportedly at no very great intensity. The distrubed area covered approximately 45,00 square miles.

Earthquake Information Bulletin (USGS)

Large-scale basin-and-dome pattern resulting from the interference of major folds

The geometry of individual major folds from the Glen Cannich area in the Northern Highlands of Scotland is described. The major folds are isoclinal, and their axial planes and fold limbs strike north or northeast and dip steeply; the fold axes plunge steeply toward the south or southeast. If pairs of individual folds are joined along a common axial-plane trace they form basins, domes, or other unusual culmination structures which resemble intensely flattened cylinders. As a group, the basins and domes form a continuous pattern , which covers an area of approximately 27 square miles, with possible extension into surrounding areas. This pattern has resulted from the interference of two sets of major folds , whereby the movement direction of the second fold set lay close to the axial plane of the first fold set. The geometrical conditions and /or intensity of the second folds that obtained during the second folding have rendered the first fold set unmappable, because the basins and domes are elongated entirely in the direction of the second fold set. The probable orientation of the first- fold axial plane is suggested by joining the culminations or depressions of the basm- and - dome pattern . Subsequent deformations have substantially altered the basin - and - dome pattern from its probable original form.

Scotland