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Origin of the Pd/Pt ratio of the J-M Reef, Stillwater Complex, Montana, USA

The J-M reef of the Stillwater Complex is characterized by a high Pd/Pt ratio (mean ~3.8 with a standard error of 0.03) with a homogeneous geospatial distribution at the deposit scale. In this contribution, we demonstrate that the Pd/Pt ratio of the reef is the product of equilibration of an immiscible sulfide liquid with a silicate melt rich in Pd relative to Pt. Despite the high tenors of the J-M reef sulfides (avg 2,700 ppm Pt and 770 ppm Pt), numerical modeling shows that the parental melts did not have extraordinary Pd and Pt concentrations. Instead, the initial composition of a plausible parental silicate melt can have Pd and Pt contents well within the expected range of a normal, mantle-derived partial melt (i.e., ~10–20 ppb for both Pd and Pt with Pd/Pt of ~1). The relative differences in the partitioning behavior of Pt and Pd between sulfide liquid and silicate melt are unlikely to produce a consistent Pd/Pt ratio across a wide range of silicate melt to sulfide liquid mass ratios (i.e., R factors). Instead, the pre-emplacement fractionation of Pt alloy from S-undersaturated silicate magma accounts for the homogeneous and high Pd/Pt ratio of the J-M reef. We show that batch equilibration of sulfide liquid with silicate melt can produce the high Pd/Pt ratios of the reef if the partition coefficients between sulfide liquid and silicate melt for Pd and Pt are extremely high (>10 6 ). In an alternative model, Pd enrichment could be achieved by sulfide upgrading in resident footwall mush even if the partition coefficients between sulfide liquid and silicate melt are relatively small (between 10 4 and 10 6 ) because the instantaneous mass ratio of silicate melt to sulfide liquid is small (R ≈ 100–700), so the partitioning behavior of Pt and Pd has little impact on the composition of sulfide liquid.

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Noble and base metal distribution and processes affecting ore tenors in the disrupted lower stratigraphy of the Stillwater Complex, USA

Exploration continues for contact-style Ni-Cu sulfide and chromitite-associated PGE mineralization in ultramafic rocks of the Stillwater Complex. At the Iron and Chrome Mountain areas, massive sulfides occur along the complex’s footwall contact and anomalous concentrations of PGE+Au are associated with the three lowermost chromitite seams. Southeast of Chrome Mountain, magmatic layering is highly disrupted by the presence of faults, magmatic breccias, serpentinized discordant dunites, pyroxenite pegmatoids, and disaggregated chromitite seams. The bulk rock chemistry, sulfide chemistry, and noble metal mineralogy of samples from this area were examined to determine the deportment of PGE and processes that led to enrichments in PGE, Au, Cu, Co and Ni. Results show that a sulfide liquid was the principal collector of PGE. If sulfide liquid was initially deposited with chromite, it was disaggregated or redistributed by subsequent melt or fluid infiltration, which may have resulted in the offset of peak PGE(+Cu, Ni) from peak Cr 2 O 3 concentrations, and upgraded PGE tenors. Upon cooling, PGE exsolved from sulfides to form discrete bismuth tellurides, arsenides, arsenic sulfides, antimonides, and alloys, commonly along the margins of sulfide globules. Calculated metal tenors are highest in the disseminated sulfides southwest of Chrome Mountain, whereas massive and net-textured sulfides near the Iron Mountain-Camp zone represent monosulfide solid solution cumulates. At progressively shallower levels, higher metal tenors combined with lower S/Se ratios are consistent with increasing R-factors from 100 to 100,000. Serpentinization and talc-tremolite alteration resulted in S loss through partial replacement of sulfides by secondary silicate+carbonate+magnetite+sulfide assemblages, further upgrading Ni-Cu-PGE tenors. The present work shows that processes responsible for the disruption of magmatic layering and post-magmatic fluid alteration along the intrusion’s lower contact led to noble and base metal enrichments.

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Electromagnetic and magnetic imaging of the Stillwater Complex, Montana, USA

Modelling and analysis of helicopter electromagnetic data result in resistivity and susceptibility models and derivatives of magnetic data that characterise shallow parts of the Stillwater Complex, critical for aiding exploration and expansion of globally scarce critical and battery mineral resources that include platinum group elements, nickel, copper and chromium. The magnetic susceptibly models derived from the electromagnetic data and the tilt derivative of the magnetic data image layering, mafic dikes, banded iron formation, and serpentinised peridotite. Known areas with contact-type mineralisation are generally characterised by low resistivities and susceptibilities where the volume of mineralised rock is large and/or the depth is shallow. We use iso-cluster and edge detection analysis of both resistivities and susceptibilities to identify potential mineralisation in poorly characterised regions as well as faults. Low resistivity layers beneath large landslides reflect water saturated porous slip surfaces which can interfere with drilling. This uncommon approach of tightly linking the resistivity and susceptibility models and magnetic anomaly data to rock property, surficial geologic, drill hole and soil geochemistry data to image the geology in the upper ∼100 m, aids identification of prospective mineralised regions as well landslides and faults that can impact mineral exploration and local hazards.

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The geochemical and textural transition between the Reef Package and its hanging wall, Stillwater Complex, Montana, USA

The highest grade Pd-Pt deposit on Earth, the J-M Reef, is hosted in coarse-grained to pegmatoidal cumulates called the Reef Package. Decades of mine development of the J-M Reef have revealed that a distinct discontinuity in rock fabric marks the top of the rock unit that hosts economic-grade sulfide mineralization. Mine geologists refer to this discontinuity as the hanging wall contact. This contact is the top of the Reef Package and is always locatable—either by the change in rock fabric or by distinctive hanging wall textures of silicate minerals—even when the reef sulfide mineralization is absent. This rather subtle textural feature is used reliably by mine geologists to follow the Reef during exploration and mine development. Although some high tenor sulfides (>1000 ppm Pd in 100% sulfide) are found sporadically in the hanging wall cumulates, these accumulations are too small to be economically viable. We present quantitative rock fabric data for four Reef Package and hanging wall intersections collected by electron back-scattered diffraction (EBSD). Plagioclase fabrics in the hanging wall are characterized by low variance in grain sizes and a strong point maximum concentration of (010) and a perpendicular girdle distribution of [100] consistent with an axial B-type fabric. These fabrics are indicative of either compaction of the crystal mush or crystal settling of nucleated crystals, the bulk magma in a chamber. Conversely, the fabrics of the Reef Package show higher variance grain in size distributions and weak to undeveloped preferred orientation of plagioclase crystals that did not undergo significant alignment or textural equilibration of plagioclase grains. The absence of foliation in the Reef Package stands in contrast both to hanging wall fabrics and to other reported EBSD datasets of plagioclase crystals orientations from the Bushveld Complex, the Skaergaard Intrusion, and the Rum Intrusion. Furthermore, plagioclase crystal size distributions for the Reef Package show flatter slopes and convex profiles with fewer crystals at small size fractions indicating the dissolution of small crystals during partial melting and textural coarsening (i.e . Ostwald ripening) and crystal growth. Crystal growth was favored over the nucleation of new crystals during prolonged interaction with a hot infiltrating melt into the resident mush resulting in the coarse-grained textures of the Reef Package cumulates. The hanging wall contact represents a boundary between partially remelted crystal mush of the Reef Package, where sulfide mineralization formed and accumulated, and an overlying essentially barren cumulate pile. The hanging wall cumulates formed following the cessation of footwall erosion and the resumption of crystal accumulation by normal magma chamber processes.

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Mapping the 3-D extent of the Stillwater Complex, Montana—Implications for potential platinum group element exploration and development

Geophysical models characterize the exposed and interpreted buried extent of the Stillwater Complex, critical for understanding the origin of the layered mafic intrusion and its associated high-grade platinum group element resources. The 3D models, constrained by gravity, magnetic, xenolith, seismic, borehole, and rock property data indicate that the likely maximum extent of the Stillwater Complex beneath Phanerozoic cover is ~10 times greater than its outcrop, ~2240 km 2 . The thickness values are poorly constrained but vary from ~7000 to 12,000 m, depending on crustal and mantle density variations and depths to the top of the lower crust and mantle. This thickness may include dense metasedimentary units of the basin into which the Stillwater Complex intruded. Using the modeled thickness results in a volume estimate of ~24,700 km 3 , albeit poorly constrained. New analyses of xenoliths from the Cretaceous Sliderock and Suzie Peak intrusions produce ages of 2706–2716 Ma, corresponding to the age of the Stillwater Complex, and 2813 Ma, corresponding to the age of Archean gneissic basement. Seismic reflectors in inferred Archean crystalline basement, possibly including the Stillwater Complex, dip ~25–30° north, with segments dipping as much as 70° north. Layered reflectors beneath the Phanerozoic sedimentary section and above the inferred Archean crystalline basement may represent metasedimentary units, perhaps a southern extension of the Mesoproterozoic Belt Basin. The potential field models and the seismic reflection data suggest that the Stillwater Complex was dipping northward prior to deposition of Cambrian strata, perhaps uplifted in the late Archean or Proterozoic as previously proposed, and that during Laramide times, faulting and intrusions highly disrupted the complex. Temperature measurements from boreholes help constrain the depths of feasible mining of the complex.

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A geologic and mineral exploration spatial database for the Stillwater Complex, Montana

The Stillwater Complex is a Neoarchean, ultramafic to mafic layered intrusion exposed in the Beartooth Mountains in south-central Montana. This igneous intrusion contains magmatic mineralization that is variably enriched in strategic and critical commodities such as chromium, nickel, and the platinum-group elements. One deposit, the J-M Reef, is the sole source of primary production and reserves for platinum-group elements in the United States. A large amount of information has been collected on the Stillwater Complex. In the 1930s, academics, the U.S. Geological Survey, and the [U.S.] Bureau of Mines initiated geologic investigations on the Stillwater Complex. Since that time, more than 600 publications on the Stillwater Complex have appeared in the scientific literature. Exploration and mining companies have collected even more information since the 1920s. This report provides essential spatially referenced datasets based on geologic mapping and mineral exploration activities conducted from the 1920s to the 1990s. This information will facilitate research on the complex and provide background material needed to explore for mineral resources and to develop sound land-management policy.

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Geologic map of the Stillwater Complex, Montana: A digital database

This report provides a digital version of the Geologic map of the Stillwater Complex, Montana by Page and Nokleberg (1974). Paper copies of the four geologic map sheets from the original report were scanned and initially attributed by Optronics Specialty Co., Inc. (Northridge, CA) and remitted to the U.S. Geological Survey for further attribution and publication of the geospatial digital files. The resulting digital geologic dataset can be queried in a geographic information system (GIS) in many ways to produce a variety of geological maps.

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Differentiation of the sulfides in the Basal Zone of the Stillwater Complex, Montana

Chemical leaching and analysis of the sulflde portion of rocks from a section of the Basal zone of the Stillwater Complex demonstrate that mole fractions of nickel, copper, cobalt, and sulfur in the sulfldes show trends and repeating patterns when plotted against stratigraphic position. These patterns are attributed to differentiation of immiscible sulflde liquids probably in response to differentiation of basaltic magma. Changes in composition of the immiscible sulflde liquids could most readily take place during the collection of the sulflde from the basaltic magma or during the crystallization of the sulflde liquid to the present assemblages of minerals.

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A Precambrian diamictite below the base of the Stillwater Complex, southwestern Montana

The metasedimentary rocks of Precambrian age below the base of the Stillwater Complex, southwestern Montana, contain a metamorphosed diamictite similar to diamictite in strata of late Precambrian and Early Cambrian age in Canada and the Western United States. The diamictite consists of a quartz-cordierite matrix containing an average 10-15 percent of rock fragments diverse in shape, size, angularity, lithologic types, and textures. The diamictite unit is poorly sorted, crops out discontinuously for 14 miles, and locally has a crude layering containing dropstones. Its origin is debatable, but the rock is suggestive of glacial marine deposition. The minimum age of the diamictite of the complex is 2,750 m.y. from U-Pb determination on zircon of intrusive quartz monzonite, the maximum 3,140 m.y. as determined on zircon from metasedimentary rocks interbedded with the diamictite.

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Platinum, palladium, and rhodium analyses of ultramafic and mafic rocks from the Stillwater Complex, Montana

Analyses by a combination fire- assay-solution-optical-emission spectrographic method of 137 rocks from the Stillwater Complex, Mont., indicate that platinum, palladium, and rhodium are preferentially concentrated in chromitite zones. The A chromitite zone (21 samples) has an average of 988.9 ppb (pans per billion, 10 -9 ) Pt, 2290.2 ppb Pd, and 245.9 ppb Rh and reaches a maximum (to date) of 8,000 ppb Pt, 11,000 ppb Pd, and 1,700 ppb Rh.

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