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Hydrogeology and ground-water flow of the drift and Platteville aquifer system, St. Louis Park, Minnesota

Three aquifers and two confining units have been delineated within the drift underlying the area near the site of a former coal-tar distillation and wood-preserving plant in St. Louis Park, Minnesota. The hydrogeologic units of the drift, in descending order, are the upper drift aquifer, the upper drift confining unit, the middle drift aquifer, the lower drift confining unit. and the lower drift aquifer. A contamination plume consisting of coal-tar derivatives exists in the drift aquifers and in the Platteville aquifer underlying the southern part of the plant site and areas to the south and east of the plant site. The upper drift aquifer has a maximum saturated thickness of about 25 feet. Horizontal hydraulic conductivities of the upper drift aquifer range from less than 1 to about 25 feet per day in peat areas and from about 50 to 400 feet per day in sand and gravel areas. The upper drift confining unit generally is less than 20 feet thick, with a maximum thickness of 62 feet. The saturated thickness of the middle drift aquifer generally is 20 to 30 feet in areas where the aquifer is both overlain and underlain by a confining unit. The horizontal hydraulic conductivity of the middle drift aquifer ranges from about 50 to 500 feet per day. The lower drift confining unit is as much as 50 feet thick. Model-computed vertical hydraulic conductivities for the upper and lower drift confining units ranged from 0.0002 to 5 feet per day. The lower drift aquifer consists of discontinuous sand and gravel deposits overlying Platteville Formation bedrock and has a maximum thickness of 20 feet where it is overlain by the lower drift confining unit. Water in the drift aquifers and in the Platteville aquifer generally flows from the northwest to the southeast under a hydraulic gradient of about 10 feet per mile. The drift confining units and the Glenwood confining unit. when present, control the vertical movement of water through the aquifers. Discontinuities in these confining units greatly influence patterns of ground-water flow. A numerical cross-sectional ground-water-flow model was used to test concepts of flow of ground water through the drift aquifers and the Platteville aquifer. particularly the effects of confining units and bedrock valleys on vertical flow. The model has eight layers representing, in descending order: ( 1) the upper drift aquifer. (2) the upper drift confining unit, (3) the middle drift aquifer, (4) the upper part of the lower drift confining unit, (5) the lower part of the lower drift confining unit and lower drift aquifer, (6) the Platteville aquifer and bedrock valley deposits, (7) the St. Peter aquifer, and (8) the Prairie du Chien-Jordan aquifer. A sensitivity analysis indicated that model-calculated hydraulic heads in the drift aquifers and in the Platteville aquifer were most sensitive to variations in: (1) the horizontal hydraulic conductivities of the middle drift aquifer, (2) the transmissivities of the Platteville and St. Peter aquifers, (3) the vertical hydraulic conductivities of the lower drift confining unit and the drift material filling the bedrock valley, and (4) the vertical hydraulic conductivity of the basal St. Peter confining unit. The model-calculated water budget indicated that recharge from infiltration of precipitation to the upper and middle drift aquifers and the upper drift confining unit accounts for about 41 percent of the total sources of water. The remaining 59 percent is from subsurface inflow from the west (through specified-head cells). About 70 percent of the outflow from the eastern model boundary was simulated as discharge from the model layers representing the Platteville aquifer and bedrock valley deposits and the St. Peter aquifer. The calibrated simulation indicated that about 99 percent of the total leakage of water from the drift aquifers and from the Platteville aquifer to the underlying St. Peter aquifer occurs through areas where the Glenwood confining unit is absent or discontinuous. Hypothetical changes of the hydraulic properties and the extent of confining units were simulated using the calibrated steady-state model. Increasing the vertical hydraulic conductivity of model layer 4, representing the upper part of the lower drift confining unit, by a factor of 100 in the western part of the cross section resulted in decreased model-calculated leakage to the St. Peter aquifer through the bedrock valley represented in the eastern part of the cross-sectional model. A hypothetical extension of vertical hydraulic conductivities representing the Glenwood confining unit along the entire cross-sectional model resulted in a 98 percent reduction in the model-calculated amount of water leaking from the Platteville aquifer and bedrock valley deposits to the underlying St. Peter aquifer. Model simulations indicate that vertical ground-water flow from the drift aquifers and from the Platteville aquifer to underlying bedrock aquifers is greatest through bedrock valleys. The convergence of flow paths near bedrock valleys and the greater volume of water moving through the valleys would likely result in both increased concentrations and greater vertical movement of contaminants in areas underlain by bedrock valleys as compared to areas not underlain by bedrock valleys. Model results also indicate that field measurements of hydraulic head might not help locate discontinuities in confining units and additional test drilling to locate discontinuities might be necessary.

Minnesota

Simulation of ground-water flow in the St Peter aquifer in an area contaminated by coal-tar derivatives, St Louis Park, Minnesota

A model constructed to simulate ground-water flow in part of the Prairie du Chien-Jordan and St. Peter aquifers, St. Louis Park, Minnesota, was used to test hypotheses about the movement of ground water contaminated with coal-tar derivatives and to simulate alternatives for reducing the downgradient movement of contamination in the St. Peter aquifer. The model, constructed for a previous study, was applied to simulate the effects of current ground-water withdrawals on the potentiometric surface of the St. Peter aquifer. Multiaquifer wells served as conduits for vertical exchange of water from the St. Peter aquifer to the Prairie du Chien-Jordan aquifer. Model simulations predict that the multiaquifer wells have the potential to limit downgradient migration of contaminants in the St. Peter aquifer caused by cones of depression created around the multiaquifer wells. Differences in vertical leakage to the St. Peter aquifer may exist in areas of bedrock valleys. Model simulations indicate that these differences are not likely to affect significantly the general patterns of ground-water flow. Model simulations also indicated that drawdown caused by pumping two wells, each pumping at 75 gallons per minute and located about 1 mile southeast of the source of contamination, would be effective in controlling movement and volume of contaminated ground water in the immediate area of the source of contamination. Some contamination may already have moved beyond the influence of these wells, however, because of a complex set of hydraulic conditions.

Minnesota

Ground-water flow in the Prairie du Chien-Jordan aquifer related to contamination by coal-tar derivatives, St. Louis Park, Minnesota

A three-dimensional, ground-water-flow model of the Prairie du Chien-Jordan aquifer and associated hydrogeologic units was developed to evaluate the movement of coal-tar derivatives from a coal-tar distillation and wood-preserving plant in St. Louis Park, Minnesota. A finite-difference grid was superimposed on the modeled area, which includes most of eastern Hennepin County. The individual cells are 400-foot squares in the center of the grid (St. Louis Park area); the cells increase in dimension toward the outside limits of the grid. Five geologic units are represented by four layers in the model. These units include the Jordan Sandstone, the Prairie du Chien Group (dolomite and sandy dolomite), the basal confining unit of the St. Peter Sandstone (silty and sandy shale), the St. Peter Sandstone, and glacial deposits in bedrock valleys. The model was calibrated for steady-state conditions for a period before significant ground-water development (1885-1930) and for a period of significant pumping stress (winter conditions, 1970 fs). A transient calibration was accomplished by simulation of a period during which seasonal changes in potentiometric head in the Prairie du Chien-Jordan aquifer were significant (1977-80). Sensitivity testing indicated that leakage to the upper model layer and the vertical hydraulic conductivity of the basal confining unit of the St. Peter Sandstone were the model hydrologic properties which, when changed, resulted in the greatest changes in model-calculated water levels. The calibrated model generally calculates water levels that are within 10 feet of measured values. Model simulations indicate that the potentiometric surface of the Prairie du Chien-Jordan aquifer would be raised by as much as 3 feet in the area of the plant site by water introduced into the aquifer through wells open to more than one aquifer system. The cones of impression created at these wells could have a significant impact on the transport of contaminants in the Prairie du Chien-Jordan. The presence of coal-tar derivatives in the aquifer has been difficult to explain in wells located upgradient from the plant site to the north, west, and southwest. Simulations suggest that, during periods of heavy withdrawal from certain of these wells (SLP10, SLP15, and SLP5), local hydraulic gradients may have been altered, resulting in the potential for the movement of contaminants from the area of the plant site to the wells. Cones of impression at multiaquifer wells near the plant site contributed to the alteration of local gradients. Simulation of a proposed gradient-control plan, in which lateral homogeneity and isotropy of individual hydro geologic units was assumed, indicates that the actions would be effective in limiting expansion of the contaminated volume in the Prairie du Chien-Jordan aquifer. The plan includes the control of withdrawal from five wells. The simulations also show, however, that modelcalculated potentiometric surfaces are sensitive to changes in withdrawal rates at wells not intended to be under the control of the plan. Management of discharge from these wells also will be important to overall effectiveness of the remedial-action plan.

Minnesota

Assessment of ground-water contamination by coal-tar derivatives, St. Louis Park area, Minnesota

Operation of a coal-tar distillation and wood-preserving facility in St. Louis Park, Minnesota, during 1918-72 contaminated ground water with coal-tar derivatives and inorganic chemicals. Coal-tar derivatives entered the groundwater system through three major paths: (1) Spills and drippings that percolated to the water table, (2) surface runoff and plant process water that was discharged to wetlands south of the former plant site, and (3) movement of coal tar directly into bedrock aquifers through a multiaquifer well on the site. In the drift, Platteville, and St. Peter aquifers, ground water flows laterally from west to east and vertically downward. Near the former plant site, creosote-like organic fluids have migrated vertically downward through the drift and are being partially dissolved by ground water. Ground water has preferentially mobilized low-molecular-weight compounds such as phenolic compounds, alkyl-benzenes, and naphthalene, although polynuclear aromatic hydrocarbons as heavy as benzo(a)pyrene have been mobilized at low concentrations. Sorption of high-molecular-weight compounds has retarded their migration down the hydraulic gradient compared to low-molecular-weight compounds in the plume. Some simple phenolic compounds are being degraded to methane and carbon dioxide by bacteria under anaerobic conditions in the drift-PlattevilleSt. Peter aquifer system. Other low-molecular-weight aromatic compounds are apparently being degraded by aerobic bacteria at the periphery of the plume where oxygen is available. Intermediate degradation products such as volatile fatty acids are likely present, but complete conversion of the organic contaminants to innocuous inorganic substances has not been demonstrated. Near and south of 36th and Wooddale Avenues, contaminants enter the St. Peter aquifer where the Glenwood confining unit has been eroded in a buried bedrock valley. Contaminants previously entered the Prairie du Chien-Jordan aquifer through at least one multiaquif er well (W38). Other sources of contaminants and the low concentrations of contaminants hamper delineation of the maximum areal extent of contaminants that are resistant to biologic degradation. These biorefractory compounds will probably continue to migrate down the hydraulic gradients in the drift and Platteville and St. Peter aquifers. Of particular concern with respect to the health risk to humans are the polynuclear aromatic hydrocarbons, which are a major constituent of coal tar and are found in municipal wells near the site that are completed in the Prairie du Chien-Jordan aquifer. The Prairie du Chien-Jordan aquifer lies 250 to 500 feet below land surface and is relatively well protected from nearsurface sources of contamination by overlying rocks. However, the aquifer has been contaminated since at least 1932 because coal-tar derivatives have entered the aquifer through multiaquifer wells. The most significant single source of contamination in the aquifer is a well drilled on the site in 1917 (well W23) that has contained liquid coal-tar since at least 1958. The introduction, dissolution, and movement of this coal-tar in ground water has contaminated nearby municipal wells. The composition of the tar in well W23, and the ratio of concentrations of individual compounds in water from well W23 to those in municipal well SLP15, are consistent with known hydrologic, chemical, and biologic processes, and the conclusion that contaminants in well SLP15 are due primarily to contaminants introduced at well W23. Most of the major polynuclear aromatic hydrocarbons in the tar, although slightly soluble in water and strongly sorbed by aquifer materials, have moved greater distances at higher concentrations than have the lower-molecular-weight, more soluble compounds such as phenolic compounds and naphthalene. The latter are apparently being degraded by bacteria. The direction and rate of contaminant movement within the Prairie du Chien-Jordan aquifer changes with time because the ground-water-flow system continually adjusts to hydraulic stresses caused by ground-water withdrawals and flow through multiaquifer wells. Contaminants can move rapidly through the Prairie du Chien-Jordan because the upper part of the aquifer is a carbonate rock having fracture and solution-channel permeability, low effective porosity, and relatively small surface area for sorption. Consequently, the concentration and composition of contaminants in water pumped from individual industrial and municipal wells completed in the aquifer fluctuate with time. Although contaminants have been in the aquifer for at least 50 years and their spatial distribution is complex, concentrations remain highest near their points of introduction through multiaquifer wells near and on the site of the former plant. Contaminants reached the Ironton-Galesville aquifer through at least two deep multiaquifer wells (W23 and W38), but the extent of contamination in this aquifer, and in the underlying Mount Simon-Hinckley aquifer, is not known.

Minnesota

Preliminary evaluation of ground-water contamination by coal-tar derivatives, St. Louis Park area, Minnesota

Operation of a coal-tar distillation and wood preserving plant for 1918-72 in St. Louis Park, Minnesota, resulted in ground-water contamination. This report presents the results of the first year (1979) of an ongoing study. By 1932, water in the Prairie du Chien-Jordan aquifer, the region 's major source of ground water, was contaminated 3,500 feet from the plant. The hydraulic characteristics of the Prairie du Chien-Jordan aquifer , its long contamination history, and fluctuating pumpage combine to creat a complex distribution of coal-tar derivatives observed in the aquifer. The Prairie du Chien-Jordan aquifer underlies the area at depths of 250 to 500 feet and is overlain by two bedrock aquifers (Platteville and St. Peter), two confining beds (Glenwood and basal part of St. Peter), and 70 to 100 feet of glacial drift. Multiaquifer wells in the area have permitted contaminated water from near-surface aquifers to flow downward into the Prairie du Chien-Jordan aquifer. Flow rates of 20 to 150 gallons per minute from the shallower aquifers into the Prairie du Chien-Jordan aquifer were observed in five wells. In the drift, a hydrocarbon fluid phase is moving vertically downward relative to the aqueous phase. Dissolved constituents in the drift and Platteville aquifer, the uppermost bedrock unit over most of the area, have moved at least 4,000 feet. Low-molecular-weight compounds are moving preferentially through the drift and Platteville aquifer system. (USGS)

Minnesota