Geology topics

Research about Pensacola, Florida

Source-linked reports with geographic coverage including Pensacola, Florida.

6 recordsLinked to original sources

USGS2025

Borehole geophysical time-series logging to monitor passive ISCO treatment of residual chlorinated-ethenes in a confining bed, NAS Pensacola, Florida

In-situ chemical oxidation (ISCO) is a common method to remediate chlorinated ethene contaminants in groundwater. Monitoring the effectiveness of ISCO can be hindered because of insufficient observations to assess oxidant delivery. Advantageously, potassium permanganate, one type of oxidant, provides the opportunity to use its strong electrical signal as a surrogate to track oxidant delivery using time-series borehole geophysical methods, like electromagnetic (EM) induction logging. Here we report a passive ISCO (P-ISCO) experiment, using potassium permanganate cylinders emplaced in boreholes, at a chlorinated ethene contamination site, Naval Air Station Pensacola, Florida. The contaminants are found primarily at the base of a shallow sandy aquifer in contact with an underlying silty-clay confining bed. We used results of the time-series borehole logging collected between 2017 and 2022 in 4 monitoring wells to track oxidant delivery. The EM-induction logs from the monitoring wells showed an increase in EM response primarily along the contact, likely from pooling of the oxidant, during P-ISCO treatment in 2021. Interestingly, concurrent natural gamma-ray (NGR) logging showed a decrease in NGR response at 3 of the 4 wells possibly from the formation of manganese precipitates coating sediments. The coupling of time-series logging and well-chemistry data allowed for an improved assessment of passive ISCO treatment effectiveness.

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USGS2008

Controls on coastal dune morphology, shoreline erosion and barrier island response to extreme storms

The response of a barrier island to an extreme storm depends in part on the surge elevation relative to the height and extent of the foredunes which can exhibit considerable variability alongshore. While it is recognized that alongshore variations in dune height and width direct barrier island response to storm surge, the underlying causes of the alongshore variation remain poorly understood. This study examines the alongshore variation in dune morphology along a 11 km stretch of Santa Rosa Island in northwest Florida and relates the variation in morphology to the response of the island during Hurricane Ivan and historic and storm-related rates of shoreline erosion. The morphology of the foredune and backbarrier dunes was characterized before and after Hurricane Ivan using Empirical Orthogonal Function (EOF) analysis and related through Canonical Correlation Analysis (CCA). The height and extent of the foredune, and the presence and relative location of the backbarrier dunes, varied alongshore at discrete length scales (of ~ 750, 1450 and 4550 m) that are statistically significant at the 95% confidence level. Cospectral analysis suggests that the variation in dune morphology is correlated with transverse ridges on the inner-shelf, the backbarrier cuspate headlands, and the historical and storm-related trends in shoreline change. Sections of the coast with little to no dune development before Hurricane Ivan were observed in the narrowest portions of the island (between headlands), west of the transverse ridges. Overwash penetration tended to be larger in these areas and island breaching was common, leaving the surface close to the watertable and covered by a lag of shell and gravel. In contrast, large foredunes and the backbarrier dunes were observed at the widest sections of the island (the cuspate headlands) and at crest of the transverse ridges. Due to the large dunes and the presence of the backbarrier dunes, these areas experienced less overwash penetration and most of the sediment from the beachface and dunes was deposited within the upper-shoreface. It is argued that this sediment is returned to the beachface through nearshore bar migration following the storm and that the areas with larger foredunes and backbarrier dunes have smaller rates of historical shoreline erosion compared to areas with smaller dunes and greater transfer of sediment to the washover terrace. Since the recovery of the dunes will vary depending on the availability of sediment from the washover and beachface, it is further argued that the alongshore pattern of dune morphology and the response of the island to the next extreme storm is forced by the transverse ridges and island width through alongshore variations in storm surge and overwash gradients respectively. These findings may be particularly important for coastal managers involved in the repair and rebuilding of coastal infrastructure that was damaged or destroyed during Hurricane Ivan.

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USGS2007

Chloroethene dechlorination in acidic groundwater: Implications for combining fenton's treatment with natural attenuation

A sulfuric acid leak in 1988 at a chloroethene-contaminated groundwater site at the Naval Air Station Pensacola has resulted in a long-term record of the behavior of chloroethene contaminants at low pH and a unique opportunity to assess the potential impact of source area treatment technologies, which involve acidification of the groundwater environment (e.g., Fenton's-based in situ chemical oxidation), on downgradient natural attenuation processes. The greater than 75 percent decrease in trichloroethene (TCE) concentrations and the shift in contaminant composition toward predominantly reduced daughter products (dichloroethene [DCE] and vinyl chloride [VC]) that were observed along a 30-m groundwater flow path characterized by highly acidic conditions (pH = 3.5 ± 0.4) demonstrated that chloroethene reductive dechlorination can continue to be efficient under persistent acidic conditions. The detection of Dehalococcoides -type bacteria within the sulfuric acid/chloroethene co-contaminant plume was consistent with biotic chloroethene reductive dechlorination. Microcosm studies conducted with 14 C-TCE and 14 C-VC confirmed biotic reductive dechlorination in sediment collected from within the sulfuric acid/chloroethene co-contaminant plume. Microcosms prepared with sediment from two other locations within the acid plume, however, demonstrated only a limited mineralization to 14 CO 2 and 14 CO, which was attributed to abiotic degradation because no significant differences were observed between experimental and autoclaved control treatments. These results indicated that biotic and abiotic mechanisms contributed to chloroethene attenuation in the acid plume at NAS Pensacola and that remediation techniques involving acidification of the groundwater environment (e.g., Fenton's-based source area treatment) do not necessarily preclude efficient chloroethene degradation.

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USGS1988

Accumulation and bioconcentration of polycyclic aromatic hydrocarbons in a nearshore estuarine environment near a Pensacola (Florida) creosote contamination site

Long-term accumulation of creosote wastes at a wood-preserving facility near Pensacola, Florida, has produced high levels of organic contamination of groundwaters near Pensacola Bay. Impacts of this contamination on the nearshore environment of the bay were examined by analysis of water, sediment and tissues of two mollusc species. One of the species (Thais haemastoma) was native to the study area. Individuals of the other test species (Crassostrea virginica) were placed in cages at the test sites for a 6-week period. Contamination at the nearshore estuarine sites was assessed by comparison to a control site in an uncontaminated area of the bay, as well as a small stream which forms a direct surface-water link between the creosote storage ponds and the bay. The study focused on polycyclic aromatic hydrocarbons (PAH), the primary components of creosote. Very little PAH in water or in the surface layer of estuarine sediments was detected, despite heavy pollution of the stream sediments. This is attributed to various degradation processes which attack the PAH compounds once they discharge into the estuary, and to the likelihood of intermittent and localised release of contaminants to the estuary. Examination of sediment cores and mollusc tissues, which provide a record integrated over time and space, revealed some accumulation of a few PAH, notably fluoranthene, pyrene, benzo(a)anthracene, chrysene and phenanthrene. In the sediments, the highest concentrations of these compounds appeared below the surface, within a depth range of 8-13 cm. Bioaccumulation of fluoranthene, pyrene and phenanthrene in both mollusc species was up to ten times greater at test sites than at the control site. This contrasts with naphthalene, the bioaccumulation of which was no greater at test sites than at the control site. These differences in bioaccumulation factors relate to structural chemistry of the compounds which control their solubility, bioavailability, susceptibility to degradation and capacity for depuration by the organism.Long-term accumulation of creosote wastes at a wood-preserving facility near Pensacola, Florida, has produced high levels of organic contamination of groundwaters near Pensacola Bay. Impacts of this contamination on the nearshore environment of the bay were examined by analysis of water, sediment and tissues of two mollusc species. Very little PAH in water or in the surface layer of estuarine sediments was detected, despite heavy pollution of the stream sediments. This is attributed to various degradation processes which attack the PAH compounds once they discharge into the estuary, and to the likelihood of intermittent and localized release of contaminants to the estuary. There was some accumulation of a few PAH, notably fluoranthene, pyrene, benzo(a)anthracene, chrysene and phenanthrene. In the sediments, the highest concentrations of these compounds appeared below the surface, within a depth range of 8-13 cm. Bioaccumulation of fluoranthene, pyrene and phenanthrene in both mollusc species was up to ten times greater at test sites than at the control site. Differences in bioaccumulation factors relate to structural chemistry of the compounds which control their solubility, bioavailability, susceptibility to degradation and capacity for depuration by the organism.

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USGS1978

Preliminary hydrologic budget of the sand-and-gravel aquifer under unstressed conditions: with a section on water-quality monitoring, Pensacola, Florida

The sand-and-gravel aquifer is the only freshwater aquifer in southern Escambia County, Fla. Problems related to the development of the aquifer include sustained yield, contamination, and saltwater intrusion. A digital model was applied to the sand-and-gravel aquifer in central and southern Escambia County treating the aquifer 's 'main producing zone ' as a discrete, leaky, confined aquifer. Under conditions of no pumping, most values for the final-head matrix agreed with assumed values within 4 feet in the area of principal interest. Discharge per unit land area was 1.04 cubic feet per second per square mile, in close agreement with the base runoff streams maintained by the aquifer. Total natural aquifer discharge within the area of principal interest determined by the model was 159 million gallons per day. The applicability of the present non-unique calibration for predicting the effects of pumping is questionable; a multilayered model may be required. Effluent infiltrating from holding lagoons for spray irrigation at the Scenic Hills Sewage Plant may have affected the quality of local perched ground water in the sand-and-gravel aquifer. Observation wells drilled near areas of heavy pumping around Bayou Chico indicated no saltwater intrusion. (Woodard-USGS)

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USGS1971

Availability of ground water for public-water supply in the Pensacola area, Florida: interim report, June 1971

Statement of the problem Earlier hydrologic studies show that ample quantities of soft water of low dissolved solids content are obtainable from the sand-and-gravel aquifer in the Pensacola area. Some wells drilled for the city of Pensacola have yielded water with unacceptably high amounts of iron and carbon dioxide, and wells have had disappointingly low yields. The city, therefore, is seeking hydrologic information, including water-quality data, in an effort to avoid the high cost of well abandonment and to plan for future expansion of the water-supply system. Objectives and approach This study is intended to provide information on the quality and quantity of water available from the sand-and-gravel aquifer, the only fresh-water aquifer in the Pensacola area, and to delineate those areas favorable for public-supply well sites. The project area is southern Escambia County, from Pensacola to S.R. (State Road) 196 north of Quintette (fig. 1). During the first year, effort was concentrated in the southern half of the area, generally south of 30°30', which approximately coincides with Interstate Highway 10 in southeastern Escambia County. The investigation included the collection of well data, chemical analyses of water samples, test drilling, radioactivity logging of test holes and other wells, and water-level measurements.

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