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Research about Naval Air Warfare Center

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Microbial community response to a bioaugmentation test to degrade trichloroethylene in a fractured rock aquifer, Trenton, N.J

Bioaugmentation is a promising strategy for enhancing trichloroethylene (TCE) degradation in fractured rock. However, slow or incomplete biodegradation can lead to stalling at degradation byproducts such as 1,2-dichloroethene ( cis -DCE) and vinyl chloride (VC). Over the course of 7 years, we examined the response of groundwater microbial populations in a bioaugmentation test where an emulsified vegetable oil solution (EOS ® ) and a dechlorinating consortium (KB-1 ® ), containing the established dechlorinator Dehalococcoides (DHC), were injected into a TCE-contaminated fractured rock aquifer. Indigenous microbial communities responded within 2 days to added substrate and outcompeted KB-1 ® , and over the years of monitoring, several other notable turnover events were observed. Concentrations of ethene, the end product in reductive dechlorination, had the strongest correlations ( P < .05) with members of Candidatus Colwellbacteria but their involvement in reductive dechlorination is unknown and warrants further investigation.DHC never exceeded 0.6% relative abundance of groundwater microbial communities, despite its previously presumed importance at the site. Increased concentrations of carbon dioxide, acetic acid, and methane were positively correlated with increasing ethene concentrations; however, concentrations of cis- DCE and VC remained high by the end of the monitoring period suggesting preferential enrichment of indigenous partial dechlorinators over bioaugmented complete dechlorinators. This study highlights the importance of characterizing in situ microbial populations to understand how they can potentially enhance or inhibit augmented TCE degradation.

New Jersey

Hydraulic tomography: 3D hydraulic conductivity, fracture network, and connectivity in mudstone

We present the first demonstration of hydraulic tomography (HT) to estimate the three-dimensional (3D) hydraulic conductivity ( K ) distribution of a fractured aquifer at high-resolution field scale (HRFS), including the fracture network and connectivity through it. We invert drawdown data collected from packer-isolated borehole intervals during 42 pumping tests in a wellfield at the former Naval Air Warfare Center, West Trenton, New Jersey, in the Newark Basin. Five additional tests were reserved for a quality check of HT results. We used an equivalent porous medium forward model and geostatistical inversion to estimate 3D K at high resolution ( K blocks <1 m 3 ), using no strict assumptions about K variability or fracture statistics. The resulting 3D K estimate ranges from approximately 0.1 (highest- K fractures) to approximately 10 −13 m/s (unfractured mudstone). Important estimated features include: (1) a highly fractured zone (HFZ) consisting of a sequence of high- K bedding-plane fractures; (2) a low- K zone that disrupts the HFZ; (3) several secondary fractures of limited extent; and (4) regions of very low- K rock matrix. The 3D K estimate explains complex drawdown behavior observed in the field. Drawdown tracing and particle tracking simulations reveal a 3D fracture network within the estimated K distribution, and connectivity routes through the network. Model fit is best in the shallower part of the wellfield, with high density of observations and tests. The capabilities of HT demonstrated for 3D fractured aquifer characterization at HRFS may support improved in situ remediation for contaminant source zones, and applications in mining, repository assessment, or geotechnical engineering.

New Jersey

Estimated trichloroethene transformation rates due to naturally occurring biodegradation in a fractured-rock aquifer

Rates of trichloroethene (TCE) mass transformed by naturally occurring biodegradation processes in a fractured rock aquifer underlying a former Naval Air Warfare Center (NAWC) site in West Trenton, New Jersey, were estimated. The methodology included (1) dividing the site into eight elements of equal size and vertically integrating observed concentrations of two daughter products of TCE biodegradation&ndash; cis -dichloroethene ( cis -DCE) and chloride&ndash;using water chemistry data from a network of 88 observation wells; (2) summing the molar mass of cis -DCE, the first biodegradation product of TCE, to provide a probable underestimate of reductive biodegradation of TCE, (3) summing the molar mass of chloride, the final product of chlorinated ethene degradation, to provide a probable overestimate of overall biodegradation. Finally, lower and higher estimates of aquifer porosities and groundwater residence times were used to estimate a range of overall transformation rates. The highest TCE transformation rates estimated using this procedure for the combined overburden and bedrock aquifers was 945 kg/yr, and the lowest was 37 kg/yr. However, hydrologic considerations suggest that approximately 100 to 500 kg/yr is the probable range for overall TCE transformation rates in this system. Estimated rates of TCE transformation were much higher in shallow overburden sediments (approximately 100 to 500 kg/yr) than in the deeper bedrock aquifer (approximately 20 to 0.15 kg/yr), which reflects the higher porosity and higher contaminant mass present in the overburden. By way of comparison, pump-and-treat operations at the NAWC site are estimated to have removed between 1,073 and 1,565 kg/yr of TCE between 1996 and 2009.

New Jersey

Hydraulic and solute-transport properties and simulated advective transport of contaminated ground water in a fractured-rock aquifer at the Naval Air Warfare Center, West Trenton, New Jersey, 2003

Volatile organic compounds, predominantly trichloroethylene and its degradation products, have been detected in ground water at the Naval Air Warfare Center (NAWC), West Trenton, New Jersey. An air-stripping pump-and-treat system has been in operation at the NAWC since 1998. An existing ground-water-flow model was used to evaluate the effect of a change in the configuration of the network of recovery wells in the pump-and-treat system on flow paths of contaminated ground water. The NAWC is underlain by a fractured-rock aquifer composed of dipping layers of sedimentary rocks of the Lockatong and Stockton Formations. Hydraulic and solute-transport properties of the part of the aquifer composed of the Lockatong Formation were measured using aquifer tests and tracer tests. The heterogeneity of the rocks causes a wide range of values of each parameter measured. Transmissivity ranges from 95 to 1,300 feet squared per day; the storage coefficient ranges from 9 x 10-5 to 5 x 10-3; and the effective porosity ranges from 0.0003 to 0.002. The average linear velocity of contaminated ground water was determined for ambient conditions (when no wells at the site are pumped) using an existing ground-water-flow model, particle-tracking techniques, and the porosity values determined in this study. The average linear velocity of flow paths beginning at each contaminated well and ending at the streams where the flow paths terminate ranges from 0.08 to 130 feet per day. As a result of a change in the pump-and-treat system (adding a 165-foot-deep well pumped at 5 gallons per minute and reducing the pumping rate at a nearby 41-foot-deep well by the same amount), water in the vicinity of three 100- to 165-foot-deep wells flows to the deep well rather than the shallower well.

New Jersey

Ground-water levels and potentiometric surfaces, Naval Air Warfare Center, West Trenton, New Jersey, 2000

Water levels were measured in wells at the decommissioned Naval Air Warfare Center in West Trenton, N.J., during 2000. Water-level hydro­graphs prepared from data collected at seven obser­vation wells on the base show changes caused by seasonal and daily climate conditions and by the pumping of contaminated water from recovery wells. Stressed and unstressed potentiometric sur­faces for 2000 are similar in shape to those during 1995–99, but are not as deep. The greatest differ­ences between the potentiometric surfaces in 2000 and those in 1995–99 were caused by turning off sump pumps in NAWC buildings when the base was closed.

New Jersey