Geology topics

Research about Michigan, Wisconsin

Source-linked reports with geographic coverage including Michigan, Wisconsin.

At least 55 records · Page 3Linked to original sources

USGS1998

Evaluation of the surface-water sampling design in the Western Lake Michigan Drainages in relation to environmental factors affecting water quality at base flow

Eight stream sites (Fixed Sites) were chosen to describe the variability in the water quality of the Western Lake Michigan Drainages (WMIC) Study Unit of the National Water-Quality Assessment program. These sites were chosen in areas (Relatively Homogeneous Units) dominated by unique combinations of the environmental factors thought to be most important in influencing water quality; namely, land use, surficial deposits, and bedrock type. A study was designed to determine (1) the applicability of streamflow, nutrient, and suspended sediment data regularly collected at these eight sites describing the variability in these characteristics throughout the Study Unit during base-flow conditions and (2) the applicability of the interpretive results made from data collected at these few sites to streams throughout the Study Unit. This was done by sampling the Fixed Sites and an additional 83 sites in Relatively Homogeneous Units throughout the Study Unit during summer base-flow conditions. Data collected at the Fixed Sites described the range in water-quality characteristics (stream-flow and concentrations of nutrients and suspended sediment) in the WMIC Study Unit and, in general, represented the water quality from the Relatively Homogeneous Units from which they were chosen. The result from the eight Fixed Sites agreed with those found for all of the sites; namely, that these water-quality characteristics in streams throughout the WMIC Study Unit during base-flow conditions are influenced primarily by the land use and surficial deposits in their drainage basins. General basin characteristics (bedrock information, topographic gradient, and basin size) were not important factors in explaining the variability in these water-quality characteristics during base-flow conditions, but may be important factors for other characteristics measured at Fixed Sites, such as major ions, and may be important during higher flow. In general, streams in agricultural areas had the poorest water quality; that is, they contained the highest concentrations of total phosphorus, total Kjeldahl nitrogen, and suspended sediment. Streams in urban and mixed agriculture/forested areas had moderate water quality, exhibiting the highest concentrations of total phosphorus, total Kjeldahl nitrogen, and suspended sediment, and the lowest base flow. In general, water quality in streams in areas with sandy/sand and gravel deposits and loamy deposits were very similar. Within the forested areas, streams in areas with a higher percentage of forested wetlands had lower base flow, higher concentrations of total Kjeldahl nitrogen, and lower concentrations of dissolved nitrite plus nitrate than streams in areas with a lower percentage of forested wetlands. The variability in water quality throughout the WMIC Study Unit during base-flow conditions could be described very well by subdividing the area into Relatively Homogeneous Units and sampling a few streams with drainage basins completely within these homogeneous units. This subdivision and sampling scheme enabled the differences in water quality to be directly related to the differences in the environmental characteristics that exist throughout the Study Unit.

Michigan, Wisconsin↗

USGS1998

Flow and geochemistry along shallow ground-water flowpaths in an agricultural area in southeastern Wisconsin

Water-quality and geohydrologic data were collected from 19 monitor wells and a stream in an agricultural area in southeastern Wisconsin. These sites were located along a 2,700-ft transect from a local ground-water high to the stream. The transect is approximately parallel to the horizontal direction of ground-water flow at the water table. Most of the wells were installed in unconsolidated deposits at five locations along the transect and include an upgradient well nest, a midgradient well nest, a downgradient well nest, wells in the lowland area near the stream, and wells installed in the stream bottom. The data collected from this study site were used to describe the water quality and geohydrology of the area and to explain and model the variations in water chemistry along selected ground-water flowpaths. Water samples from most wells and the stream were analyzed for major ions, nutrients, pesticides, dissolved organic carbon, aluminum, tritium, CFCs, 15N, 18O, and dissolved gases. Measurements of temperature, pH, specific conductance, and dissolved oxygen were made in the field. Concentrations of all dissolved constituents were below Wisconsin ground-water quality enforcement standards. The concentrations of both nitrate and ammonium in precipitation concentrated by evapotranspiration are roughly equal to the concentrations of either in the shallow ground waters. The nitrogen and oxygen isotope data, however, indicate that soil ammonium, ammonium fertilizer, and animal waste are possible nitrate sources. Concentrated precipitation can also supply dissolved sulfate to the shallow ground waters and may be a principal source of pesticides to the ground water. However, some input of dissolved chloride to the ground water from mineral or anthropogenic sources is necessary. X-ray diffraction analyses of samples from 2 cores show the most abundant mineral to be dolomite, with subordinate quartz, microclme, and plagioclase, and minor amounts of mica, hornblende, and chlorite. Hydraulic conductivities determined from slug tests at selected wells range from 0.006 to 55 feet per day, with most values between 0.4 and 12 feet per day. A cross-sectional ground-water flow model, representing the water-table flow system, was developed for the site and was used to identify possible ground-water flowpaths for geocli^mical modeling. The model was calibrated against measured water levels and was most sensitive to variation in recharge and hydraulic conductivity. The calibrated model shows that downward flow from shallow to deeper wells within a nest may occur at the upgradient and midgradient well nests, but that flow from each well nest travels beneath downgradient nests to the stream. Pathline and travel-time analysis performed on the calibrated flow-model output yielded travel times to well screens that range from 5.8 to 59 years with a recharge of 4 inches per yr. Recharge dates based on tritium and CFC concentrations range from pre-1955 to 1986 and are consistent with flowpaths1 and travel times in the calibrated flow model. Changes in water quality along ground-water flowpaths were evaluated using the geochemical model PHREEQC. Geochemical mole balance models of shallow ground-water formation show that the principal reaction, by an order of magnitude, is dissolution of dolomite with CO2 . Concentration factors in the mole-balance models range from 1 to 11, with most values between 5 and 10, which provides independent support for the concentration factor of 8 based on recharge estimates used in the flow model. Ground water recharging at mid- and downgradient wells is oxic and contains dissolved nitrate, whereas the ground water discharging to the stream is anoxic and contains dissolved ammonium. Redox environments were defined at each well on the basis of relative concentrations of various dissolved redox-active species. Chemically permissible flowpaths inferred from the observed sequence of redox environments at well sites are consistent with flowpaths in the ground-water flow model. The transition from nitrate in recharging ground water to ammonium in ground water discharging to the stream suggests the possibility of nitrate reduction along the flowpath. None of the techniques employed in this study, however, were able to prove the occurrence of this reaction.

Michigan, Wisconsin↗

USGS1997

Rift-wide correlation of 1.1 Ga Midcontinent rift system basalts: Implications for multiple mantle sources during rift development

Magmatism that accompanied the 1.1 Ga Midcontinent rift system (MRS) is attributed to the upwelling and decompression melting of a mantle plume beneath North America. Five distinctive flood-basalt compositions are recognized in the rift-related basalt succession along the south shore of western Lake Superior, based on stratigraphically correlated major element, trace element, and Nd isotopic analyses. These distinctive compositions can be correlated with equivalent basalt types in comparable stratigraphic positions in other MRS localities around western Lake Superior. Four of these compositions are also recognized at Mamainse Point more than 200 km away in eastern Lake Superior. These regionally correlative basalt compositions provide the basis for determining the sequential contribution of various mantle sources to flood-basalt magmatism during rift development, extending a model originally developed for eastern Lake Superior. In this refined model, the earliest basalts were derived from small degrees of partial melting at great depth of an enriched, ocean-island-type plume mantle source (ε Nd(1100) value of about 0), followed by magmas representing melts from this plume source and interaction with another mantle source, most likely continental lithospheric mantle (ε Nd(1100 ) < 0). The relative contribution of this second mantle source diminished with time as larger degree partial melts of the plume became the dominant source for the voluminous younger basalts (ε Nd(1100) value of about 0). Towards the end of magmatism, mixtures of melts from the plume and a depleted asthenospheric mantle source became dominant (ε Nd(1100) = 0 to +3).

Michigan, Wisconsin↗

USGS1997

U-Th-Pb zircon ages of some Keweenawan Supergroup rocks from the south shore of Lake Superior

New single-crystal zircon U–Th–Pb ages for plutonic and rhyolitic Keweenawan Supergroup rocks from the south shore of Lake Superior provide geochronological constraints on magmatic evolution associated with the 1.1 Ga Midcontinent rift. Analyses of a granophyric phase of the Mineral Lake intrusion and the Mellen granite, both parts of the Mellen Intrusive Complex, and a laterally extensive rhyolite from the top of the Kallander Creek Volcanics have weighted average 207 Pb/ 206 Pb ages of 1102.0 ± 2.8 Ma ( N = 2), 1100.9 ± 1.4 Ma ( N = 5), and 1098.8 ± 1.9 Ma ( N = 4), respectively. Analyses of a pyroclastic rhyolite flow at the top of the Porcupine Volcanics result in variable 207 Pb/ 206 Pb ages that range from 1080 to 1137 Ma. This rhyolite exhibits a continuum between morphologically complex and simpler prismatic zircon crystals, the latter yielding concordant analyses having a weighted average 207 Pb/ 206 Pb age of 1093.6 ± 1.8 Ma ( N = 2). Four prismatic zircons from an aphyric rhyolite of the Chengwatana Volcanics in the Ashland syncline form a linear array intersecting concordia at 1094.6 ± 2.1 Ma (MSWD = 1.3). Another presumed Chengwatana rhyolite recovered from drill core intersecting the Hudson–Afton horst in southeast Minnesota yielded only ~20 morphologically indistinguishable zircons. Six analyses give 207 Pb/ 206 Pb ages ranging from 1112 to 1136 Ma, including one analysis with a virtually concordant age of 1130 Ma. This age, however, is considerably older than that obtained for the Chengwatana Volcanics in the Ashland syncline or any other precisely dated rock from the Midcontinent rift.

Michigan, Wisconsin↗

USGS1997

Pesticides in ground water in the Western Lake Michigan Drainages, Wisconsin and Michigan, 1983-1995

In 1991, the U.S. Geological Survey (USGS) began implementation of the National Water-Quality Assessment (NAWQA) Program. The long-term goals of the NAWQA Program are to describe the status and trends in the quality of a large, representative part of the Nation's surface- and ground- water resources, and to identify, describe, and explain, if possible, the major factors that affect the observed water quality (Hirsch and others, 1988). The program consists of study-unit investigations that include parts of most major river basins and aquifer systems in the country. The Western Lake Michigan Drainages study unit encompasses a 20,000-square-mile area in eastern Wisconsin and the Upper Peninsula of Michigan that drains to Lake Michigan and Green Bay (figure 1).

Michigan, Wisconsin↗

USGS1997

Stream habitat characteristics of fixed sites in the western Lake Michigan drainages, Wisconsin and Michigan, 1993-95

Habitat characteristics of 11 fixed sites in the Western Lake Michigan Drainages were examined by the U.S. Geological Survey from 1993 through 1995 as part of the ecological assessment of the National Water-Quality Assessment Program. Evaluation of habitat consisted of more than 75 measurements at three spatial levels: drainage basin, stream segment between major tributaries (length from 1 to 14 kilometers), and stream reach (approximately 150 meters). The 11 fixed sites consisted of 8 "indicator" sites with drainage basins that differ in bedrock type, surficial deposits, and land use; and 3 "integrator" sites with drainage basins that contain a mixture of bedrock type, surficial deposits, and land use. Spatial and temporal variations in habitat characteristics are described and compared. Comparisons are limited to indicator sites except for comparisons amongbasin characteristics, which include all fixed sites. Two habitat classification schemes used in Wisconsin and Michigan were used to rank the quality of habitat in indicator streams. Reach-level data were collected at two additional reaches at three of the indicator sites to assess the representativeness of the reach for overall stream conditions. Although the number of sites is small, statistical analyses indicate that spatial distribution of several characteristics can be related to land use, geology, topography, and width of the riparian zone. Land use and geology, in combination, appeared to be important factors in controlling flood magnitudes. Annual mean flow was correlated with basin shape and drainage density and low flow was correlated with permeability of soils in the basin. At the reach level, a wide variety of characteristics were observed at the eight indicator sites, with many of the characteristics significantly different between sites. Spatial differences in some reach characteristics can be attributed to the percentage of agriculture in the drainage basin, type of surficial deposits, and width of the riparian zone. Temporal variability in width, depth, and velocity can be attributed to variable flow conditions; whereas temporal variability in streambank measurements are attributed to problematic identification of the boundary between the flood plain and streambanks. Data from multiple-reach sites indicate that the primary reach adequately represented the variability found within the stream segment for depth, streambank stability index, and canopy angle. However, velocity, dominant substrate type, embeddedness, streambank height, streambank angle, and streambank vegetative stability differed among the multiple reaches at one or more of the three sites. Correlation analyses of habitat characteristics with median concentrations of four nutrients, pH, and specific conductance indicates that dissolved nitrate plus nitrite concentrations are related to percentage of agriculture in the basin and fine-grained sediment deposition in the reach. Geology and land use appear to be major influences on pH, but their influence on specific conductance, although expected, was not confirmed in this study. Habitat evaluation scores at the eight indicator sites ranged from poor to good. Scores were correlated to the percentage of agricultural or urban land in the drainage basins, width of the riparian zone, and streambank stability index. Results from this study illustrate the need for collection of habitat data at multiple scales along with water-chemistry data for determining major influences on distribution of aquatic communities. These results also indicate the importance of collecting land use, geological, and geomorphic information at the drainage-basin level to adequately describe how natural and human factors influence local aquatic habitat conditions.

Michigan, Wisconsin↗

USGS1997

Fish communities of fixed sites in the Western Lake Michigan Drainages, Wisconsin and Michigan, 1993-95

Fish communities were surveyed at 20 wadable stream sites during 1993-95 as part of the U.S. Geological Survey's (USGS) National Water- Quality Assessment (NAWQA) Program's assessment of the Western Lake Michigan Drainages. Part of the NAWQA design is to incorporate ecological data into an overall environmental assessment. Collection of fish-community data was part of this ecological assessment. The Western Lake Michigan Drainages study area is located in eastern Wisconsin and parts of the Upper Peninsula of Michigan. To isolate the effects of individual factors on stream quality, the study area was subdivided into 28 environmental settings, or relatively homogeneous units (RHUs), on the basis of land use/land cover, texture of surficial deposits, and bedrock geology. A fixed monitoring site was established on a wadable stream within 8 of these RHUs to determine the status and trends of water quality in a representative stream. Water-quality characteristics, ecological- community data, and stream-habitat factors were measured at these sites during 1993- 95. Fish communities were sampled at the 8 wadable fixed sites once a year during 1993-95. At three of these sites, multiple-reach samples were collected in 1994 to determine within-site variation. Fish communities also were sampled at an additional 12 sites, 11 in 1993 and one in 1995, within the 6 largest RHUs. The sites, 1-3 per each of the 6 RHUs, were located on streams with drainage basins of similar size as the fixed sites within the same RHUs. A total of 44 fish species from 12 families were collected at the 20 sites. The family with the most species represented were the minnows. The number of species per site ranged from one at a small urban site (Lincoln Creek) in 1995 to 21 at an agricultural site (North Branch Milwaukee River) in 1995. The number of individuals collected in one sampling pass ranged from 21 at a stream in the forested northwest part of the study area (Peshekee River) in 1995 to 498 at an agricultural site (East River) in 1995. White sucker (Catostomus commersoni) were collected at 17 sites, the most of any species. Species that are indicative of a coldwater environment were collected at 12 sites. Detrended correspondence analysis (DCA) of multiple-reach and multiple-year data indicated that species composition at each of these sites were fairly consistent between reaches and years. Thus, for simplicity, most analyses were done using 1993 data only. Index of Biotic Integrity (IBI) scores on 1993 data ranged from very poor at a channelized urban site to excellent at 3 sites; 2 in primarily agricultural areas and 1 in a forested area. Seven sites each scored good or fair, and two sites scored poor. Sites with multiple-year or multiple-reach data did not vary significantly within the error factor of the IBI. DCA of fish-community data from 19 sites indicated that coldwater sites were tightly grouped, whereas warmwater sites showed a larger gradient. This was expected, given the potential for greater diversity among warmwater sites. Fixed sites were shown to be representative of the study area as a whole, while specific fish communities could not be attributed to particular RHUs. Cluster analysis revealed two major groups of sites and two outlier sites. The two groups represented coldwater and warmwater streams, while the outlier sites were the urban site and a species- rich site with high biotic integrity that drains primarily agricultural land. Canonical correspondence analysis (CCA) revealed that soil credibility was a significant predictor of species composition. Though not statistically significant, land use, soil permeability, and bedrock permeability also were indicated as predictors of fish-species composition by CCA.

Michigan, Wisconsin↗

USGS1997

Effects of land use and geohydrology on the quality of shallow ground water in two agricultural areas in the western Lake Michigan drainages, Wisconsin

Water-quality and geohydrologic data were collected between September 1993 and September 1994, from 56 wells and 2 springs, in two agricultural areas in the Western Lake Michigan Drainages study unit of the National-Water Quality Assessment Program. These data were used to study the effects of land use and geohydrology on shallow ground-water quality. Water samples from each well and spring were analyzed for major ions, nutrients, dissolved organic carbon, pesticides, volatile organic compounds, oxygen and hydrogen isotopes, and uranium; measurements of temperature, pH, specific conductance, and dissolved oxygen were made in the field. Ground-water samples were also analyzed for tritium or chlorofluorocarbons, or both, to estimate the recharge date of the ground water. Slug tests were performed on most of the wells to estimate the hydraulic conductivity of the surficial deposits in the vicinity of the well. The two areas chosen for study had similar agricultural land uses but different geohydrologic characteristics. Sampled monitor wells and springs were located down gradient from farm fields having similar crop rotation patterns, mainly corn and alfalfa. Area l is characterized by sand and clay surficial deposits overlying carbonate bedrock, and area 2 is characterized by sand and gravel surficial deposits overlying sandstone or crystalline bedrock. The depth to water was significantly deeper and the hydraulic conductivity of the surficial deposits was significantly higher in area 2. Water-quality analyses indicate that agricultural land use has affected the ground-water quality of both of the study areas, however, Wisconsin ground-water-quality enforcement standards were exceeded in only 22 percent (13 of 58) of samples for dissolved nitrate and 2 percent (l of 58) of samples for dissolved atrazine plus deethyl atrazine. There was a significant difference between the two areas in the concentrations of dissolved nitrate and atrazine plus deethyl atrazine in the shallow ground water. Although the amount of nitrogen fertilizer and manure applied to the land surface was similar or slightly higher in area 2, as compared to area 1, and atrazine application rates may have been slightly higher in area l, area 2 had significantly higher concentrations of both dis solved nitrate and atrazine plus deethyl atrazine in shallow ground water. The areal difference in nitrate and atrazine concentrations was likely due to the relatively higher permeability and lower organic matter content of the surficial deposits in area 2. The more permeable surficial deposits in area 2 allowed nitrate and atrazine (and its metabolites) to readily move from the land surface to ground water. Additionally, the lower organic matter content in area 2 helped to maintain higher dis solved oxygen concentrations in recharging water and throughout the saturated zone, thus reducing the possibility of denitrification or assimilative uptake. Estimated recharge dates showed that historic patterns of atrazine plus deethyl atrazine concentrations in ground water mimic historic patterns of atrazine use on corn. Concentrations in ground water that recharged prior to the early 1960s, when atrazine started to become widely used on corn in Wisconsin, were very low or not detectable. As atrazine use on corn steadily increased from the late 1960s to the late 1970s and early 1980s, detectable concentrations of atrazine plus deethyl atrazine in ground water became more common. The recharge dates of some of the highest measured concentrations of atrazine plus ethyl atrazine in ground water from both study areas correspond to the period of highest atrazine use on corn within the State.

Michigan, Wisconsin↗

USGS1997

Results of quality-control sampling of water, bed sediment, and tissue in the Western Lake Michigan Drainages study unit of the National Water-Quality Assessment Program

This report contains the quality control results of the Western Lake Michigan Drainages study unit of the National Water Quality Assessment Program. Quality control samples were collected in the same manner and contemporaneously with environmental samples during the first highintensity study phase in the unit (1992 through 1995) and amounted to approximately 15 percent of all samples collected. The accuracy and precision of hundreds of chemical analyses of surface and ground-water, bed sediment, and tissue was determined through the collection and analysis of field blanks, field replicates and splits, matrix spikes, and surrogates. Despite the several detections of analytes in the field blanks, the concentrations of most constituents in the environmental samples will likely be an order of magnitude or higher than those in the blanks. However, frequent detections, and high concentrations, of dissolved organic carbon (DOC) in several surface and ground-water blanks are probably significant with respect to commonly measured environmental concentrations, and the environmental data will have to be qualified accordingly. The precision of sampling of water on a percent basis, as determined from replicates and splits, was generally proportional to the concentration of the constituents, with constituents present in relatively high concentrations generally having less sampling variability than those with relatively low concentrations. In general, analytes with relatively high variability between replicates were present at concentrations near the reporting limit or were associated with relatively small absolute concentration differences, or both. Precision of replicates compared to that for splits in bed sediment samples was similar, thus eliminating sampling as a major source of variability in analyte concentrations. In the case the phthalates in bed sediment, contamination in either the field or laboratory could have caused the relatively large variability between replicate samples and between split samples.Variability of analyte concentrations in tissue samples was relatively low, being 29 percent or less for all constituents. Recoveries of most laboratory schedule 2001/2010 pesticide spike compounds in surfacewater samples were reasonably good. Low intrinsic method recovery resulted in relatively low recovery forp,p'-DDE, metribuzin, and propargite. In the case of propargite, decomposition with the environmental sample matrices was also indicated. Recoveries of two compounds, cyanazine and thiobencarb, might have been biased high due to interferences. The one laboratory schedule 2050/2051 field matrix pesticide spike indicated numerous operational problems with this method that biased recoveries either low or high. Recoveries of pesticides from both pesticide schedules in field spikes of ground-water samples generally were similar to those of field matrix spikes of surface- water samples. High maximum recoveries were noted for tebuthiuron, disulfoton, DCPA, and permethrin, which indicates the possible presence of interferents in the matrices for these compounds. Problems in the recoveries of pesticides on schedule 2050/2051 from ground-water samples generally were the same as those for surfacewater samples. Recoveries of VOCs in field matrix spikes were reasonable when consideration was given for the use of the micropipettor that delivered only about 80 percent on average of the nominal mass of spiked analytes. Finally, the recoveries of most surrogate compounds in surface and ground-water samples were reasonable. Problems in sample handling (for example, spillage) were likely not the cause of any of the low recoveries of spiked compounds.

Michigan, Wisconsin↗

USGS1997

Trace elements and synthetic organic compounds in biota and streambed sediment of the Western Lake Michigan Drainages, 1992-1995

Sampling was conducted in 1992,1994, and 1995 to determine the occurrence of a broad suite of trace elements and synthetic organic compounds in biota and streambed sediment in selected streams in the Western Lake Michigan Drainages a study unit of the National Water- Quality Assessment (NAWQA) Program of the U.S. Geological Survey. Sediment was sampled at 31 sites for trace elements and 23 sites for synthetic organic compounds; biota were collected at a subset of sites. Some of the variability in trace elements and synthetic organic compounds was related to land use, and many differences in trace element concentration by land use category were statistically significant. The spatial distribution of some trace elements was related to a combination of land use and surficial deposits and (or) bedrock type. Urban land use was likely the dominant factor influencing high sediment concentrations of Cd, Cu, Hg, and Pb. Forested land use was related to high concentrations of As in sediment and biota and high Se in sediment; however, bedrock type was an additional factor for As and surficial deposits type was a factor for Se. Land use, surficial deposits, and bedrock type appeared to influence Ni and Zn concentrations, and Cr concentrations did not directly reflect any of these factors. Most occurrences of organochlorine compounds in sediment and biota were related to urban land use. DDT and related compounds were detected at sites spanning all land uses. PCBs were detected in sediment at large-river sites and at one urban site in the Milwaukee area; the highest concentrations of PCBs in fish were found at two of four large river sites. A larger number of SVOCs were detected at urban sites and large river sites compared to agricultural and forested sites.

Michigan, Wisconsin↗

USGS1996

Pesticides in streams of the western Lake Michigan drainages, Wisconsin and Michigan, 1993-95

During 1993-95, water samples were collected at nine sites on eight streams in the Western Lake Michigan Drainages to attempt to determine pesticide concentrations. The sampling effort was part of the U.S. Geological Survey's National Water- Quality Assessment (NAWQA) Program. Pesticides analyzed for were 58 herbicides and 30 insecticides. Pesticides are used extensively in the study area; application of herbicides to corn and soybeans accounts for most of the use. Herbicides were detected more frequently and generally at higher concentrations than insecticides. The herbicide atrazine is applied to more acreage in Wisconsin than all other pesticides and was detected in 142 of 143 samples. The herbicides simazine, metolachlor, cyanazine, prometon, and alachlor were detected in more than half of the samples. The presence of these compounds in the sampled streams, is related to agricultural use. Two streams in forested basins in the northern part of the study area were sampled and found to contain low concentrations of atrazine. Atmospheric deposition is the likely source; atrazine has been detected in rain fall in northeastern Wisconsin. Herbicide concentrations in agricultural basins were highest in samples collected during storm runoff following application. Concentrations decreased over the growing season as herbicides broke down and increased ground cover reduced runoff. The U.S. Environmental Protection Agency (USEPA) drinking-water standard for atrazine was exceeded in eight samples, and the standard for alachlor was exceeded in two samples. All exceedances occurred during brief periods of high streamflow in June and July at two streams that drain primarily agricultural basins. Herbicide data for the Western Lake Drainages and other NAWQA study units indicate that concentrations in streams are as much as two orders of magnitude higher in areas where agricultural land contains a high percentage of row crops especially corn and soybeans than in areas where grazing, hay production, and other less herbicide-intensive crops are raised.

Michigan, Wisconsin↗

USGS1996

Sources and transport of phosphorus in the Western Lake Michigan Drainages

In 1991, the U.S. Geological Survey (USGS) began full implementation of the National Water-Quality Assessment (NAWQA) Program. The goals of the NAWQA program are to (1) provide a nationally consistent descrip- tion of water-quality conditions for a large part of the Nation's water resources, (2) define long-term trends (or lack of trends) in water quality, and (3) identify, describe, and explain, as possible, the major factors that affect the observed water-quality conditions and trends (Hirsch and others, 1988). To fulfill the goals of the NAWQA program, the USGS plans to examine 60 areas (study units) across the United States on a rotational cycle. The first 20 of these study units began intensive investigations in 1991. One of these study units is the Western Lake Michigan Drainages (WMIC) (fig. 1).

Michigan, Wisconsin↗

USGS1996

Water-quality assessment of the western Lake Michigan drainages: Analysis of available information on nutrients and suspended sediment, water years 1971-90

In 1986, Congress appropriated funds for the U.S. Geological Survey (USGS) to develop the pilot phase of the National Water-Quality Assessment (NAWQA) Program. The long-term goals of this program are to (1) provide a nationally consistent description of current water-quality conditions for a large part of the Nation's water resources; (2) define. long-term trends (or lack of trends) in water quality; and (3) identify, describe, and explain, as possible, the major factors that affect the observed water-quality conditions and trends. To fulfill the goals of the NAWQA program, the USGS plans to examine 60 areas (study units) across the United States during full implementation of the program. In 1991, the NAWQA program went into full implementation with the intensive investigation of 20 of these study units; one of these study units is the Western Lake Michigan Drainages (WMIC) study unit.

Michigan, Wisconsin↗

USGS1996

Use of frequency-volume analyses to estimate regionalized yields and loads of sediment, phosphorus, and polychlorinated biphenyls to lakes Michigan and Superior

In most rivers, transport of various constituents occurs largely during short-term, high-intensity events. A method is described to make regionalized estimates of the long-term average loads of selected streamwater constituents, as well as loads occurring during high-flow events with specified recurrence intervals. This method is used to estimate the load of suspended sediment, total phosphorus, and sediment-borne constituents, such as poly chlorinated biphenyls (PCB's), from all the rivers in the United States that drain into Lake Michigan and Lake Superior whose drainage basins are greater than 325 square kilometers. Statistical comparisons of estimated loads and environmental factors indicate that suspendedsediment loads were primarily affected by river gradient and secondarily affected by the texture of surficial deposits, whereas total phosphorus loadings were primarily affected by the texture of surficial deposits and secondarily affected by river gradient. Total phosphorus loads were highest in rivers entering into the middle to southern part of Lake Michigan, especially rivers in areas draining clay surficial deposits and agricultural areas. During high flow, inputs of phosphorus and suspended sediment from rivers entering the southwestern part of Lake Superior become very important to the total input of these constituents; these rivers have steep gradients and drain surficial deposits with high clay content. The single largest contributor of PCB's during the entire period and during each type of high-flow event was the Fox River, which supplied 46 to 64 percent of the total PCB load to both lakes.

Michigan, Wisconsin↗

USGS1996

Summary of biological investigations relating to water quality in the Western Lake Michigan Drainages, Wisconsin and Michigan

This report summarizes aquatic biological studies relevant to water-quality assessment that have been done in the Western Lake Michigan Drainages from 1891 to 1996. The objective of the summary was to compile sources of biological data for the U.S. Geological Survey's National Water-Quality Assessment Program. The studies are divided into four categories: (1) populations and community structure of aquatic biota, (2) health of aquatic biota, (3) chemical concentrations in tissues of aquatic biota, and (4) toxicity tests by use of aquatic biota. Studies are further categorized by subbasin, spatial scale (regional or local), types of biota, and, if applicable, effect or contaminant investigated. For the purposes of this report, the study area is divided into five subbasins. The subbasins, from north to south, are (1) the Ford/Escanaba Subbasin in Michigan's Upper Peninsula, and in Wisconsin, (2) the Menominee/ Oconto/Peshtigo Subbasin, (3) the Fox/Wolf Subbasin, (4) the Sheboygan/Manitowoc/Twin Subbasin, and (5) the Milwaukee Subbasin. Most biological studies related to waterquality conditions in the Western Lake Michigan Drainages have focused on populations and community structure of aquatic biota. Chemical concentrations in tissues of aquatic biota have been the next most common area of research. Our review suggests a paucity of data related to the health of all types of aquatic biota, especially amphibians, invertebrates, and reptiles; toxicity studies also were relatively uncommon. Overall, organisms primarily studied have been fish and invertebrates, although birds are most frequently examined in studies of organism health. The Fox/ Wolf Subbasin has been the focus of many more studies than the other subbasins, most likely because of the greater extent and severity of known water-quality problems in the Lower Fox River/Green Bay area over the past several decades and because it is the largest subbasin. Studies in the other subbasins are needed to adequately assess the water quality of these areas.

Michigan, Wisconsin↗

USGS1995

Environmental factors used to subdivide the western Lake Michigan drainages into relatively homogeneous units for water-quality site selection

In 1991, the National Water-Quality Assessment (NAWQA) Program was fully implemented by the U.S. Geological Survey (USGS). The goals of the NAWQA program are to (1) provide a nationally consistent description of water-quality conditions for a large part of the Nation’s water resources; (2) define long-term trends (or lack of trends) in water quality; and (3) identify, describe, and explain, as possible, the major factors that affect the observed water-quality conditions and trends (Hirsch and others, 1988).

Michigan, Wisconsin↗

USGS1995

National Water-Quality Assessment Program, western Lake Michigan drainages: Summaries of liaison committee meeting, Green Bay, Wisconsin, March 28-29, 1995

The Western Lake Michigan Drainages (WMIC) study unit, under investigation since 1991, drains 20,000 square miles (mi2) in eastern Wisconsin and Upper Michigan (fig. 1). The major water-quality issues in the WMIC study unit are: (1) nonpoint-source contamination of surface and ground water by agricultural chemicals, (2) contamination in bottom sediments of rivers and harbors by toxic substances, including polychlorinated biphenyls (PCB's), other synthetic organic compounds, and trace elements, (3) nutrient enrichment of rivers and lakes resulting from nonpoint- and point-source discharges, and (4) acidification and mercury contamination of lakes in poorly buffered watersheds in the northwestern part of the study unit. A study-unit liaison committee, which includes representatives of Federal, State, university, and private and citizen organizations, has met annually since 1991 to review plans and results and guide the investigators toward policy-relevant efforts. The results of research conducted in the WMIC study unit by U.S. Geological Survey (USGS) and non-USGS researchers were presented at the liaison committee meeting held in Green Bay, Wis., on March 28-29, 1995. This report contains summaries of the oral presentations given at the WMIC 1995 liaison committee meeting.

Michigan, Wisconsin↗

USGS1994

Nitrate in ground water in the western Lake Michigan drainage basin, Wisconsin and Michigan

In 1991, the U.S. Geological Survey began the nationwide implementation of the National Water-Quality Assessment (NAWQA) Program. The long-term goals of the NAWQA Program are to describe the status and trends in the quality of a large, representative part of the Nation's surface- and ground-water resources and to provide a sound, scientific understanding of the primary natural and human factors that affect the quality of these resources. The program (as currently planned) consists of 60 study-unit investigations that include parts of most major river basins and aquifer systems in the country. The Western Lake Michigan Drainage Basin encompasses a 20,000-square-mile area in eastern Wisconsin and the Upper Peninsula of Michigan that drains to Lake Michigan and Green Bay (fig. 1).

Michigan, Wisconsin↗