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Tidal flushing of mercury from the Bremerton Naval Complex through the PSNS015 stormwater drain system to Sinclair Inlet, Kitsap County, Washington, 2011 -12

The sediments of Sinclair Inlet, in Puget Sound, Washington, have elevated levels of contaminants including mercury. The Bremerton Naval Complex is adjacent to Sinclair Inlet, and has known areas of historical soil mercury contamination. The U.S. Geological Survey, in cooperation with the U.S. Navy, has been investigating the potential for mercury sources on the Bremerton Naval Complex to recontaminate recently remediated marine sediment. In 2011–12, the U.S. Geological Survey conducted three tidal- related sampling campaigns to characterize mercury dynamics in the largest stormwater drain system on the Bremerton Naval Complex, which passes through the soils of an area known as Site 2 that has elevated soil mercury concentrations. The sampling campaigns confirmed that the stormwater drain system, PSNS015, serves as a conduit for seawater transport more than 250 m landward of the contaminated soils that subsequently facilitates mercury transport to Sinclair Inlet. During the December 2011 reconnaissance sampling campaign, no freshwater source of mercury to PSNS015 was identified. There was heavy precipitation preceding and stormwater runoff generated during the reconnaissance survey, which suggests that the primary source of mercury in PSNS015 is not precipitation-induced. During the May 2012 spring-tide sampling campaign, the water in PSNS015 drained to Sinclair Inlet during a negative low tide, and the highest filtered total mercury concentration in the stormwater drain system (60 ng/L) was measured during the lower-low tide in the freshwater flowing into the seaward-most stormwater drain vault from either up-pipe or local groundwater intrusion. Similar conditions were not observed during the June 2012 companion neap-tide sampling campaign, when the water-level elevation of the positive low tide in Sinclair Inlet dropped only slightly below the stormwater drain vault elevation, the water in the seaward-most stormwater vault was brackish rather than fresh, and the filtered total mercury concentration never exceeded 24 ng/L. Particulate total mercury concentrations and dynamics during the spring- and neap-tide sampling campaigns were variable, with higher concentrations (as much as 133 ng/L) measured throughout the neap-tide study compared to those measured during the spring-tide study (as much as 4.34 ng/L). The highest filtered total mercury concentration of all sampling campaigns (1,140 ng/L) was measured during ebb tide in a nearshore monitoring well that represents groundwater discharging from the contaminated soils directly to Sinclair Inlet along an unwalled part of the shoreline. The results suggest that mercury extracted from Site 2 soils can be carried to Sinclair Inlet during ebb tides by at least two mechanisms: (1) through groundwater directly to Sinclair Inlet along an unwalled part of the shoreline or (2) through the stormwater drain system when the water level in Sinclair Inlet drops below the water level in the stormwater drain system. The data can be used to guide future modifications to the seawall and stormwater drain system that aim to hydraulically disconnect the stormwater drain system from the surrounding contaminated soils.

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Mercury methylation and bioaccumulation in Sinclair Inlet, Kitsap County, Washington

The U.S. Geological Survey evaluated the transformation of mercury to bioavailable methylmercury in Sinclair Inlet, Kitsap County, Washington, and assessed the effect of the transformation processes on the mercury burden in marine organisms and sediment. In August 2008, samples of sediment, water, and biota from six sites in Sinclair Inlet and three bays representative of Puget Sound embayments were collected. The extensive sediment sampling included analysis of methylmercury in sediment and porewater, estimates of methylation production potential, and analyses of ancillary constituents associated with organic carbon and reduction-oxidation (redox) conditions to assist in interpreting the mercury results. Analyses of methylmercury in water overlying incubated cores provided an estimate of the release of methylmercury to the water column. Collection of samples for mercury species in the aqueous, particulate (suspended solids), and biological phases, and for ancillary carbon and nitrogen constituents in surface water, continued, on about a monthly schedule, at four stations through August 2009. In February, June, and August 2009, seasonal sediment samples were collected at 20 stations distributed between greater Sinclair Inlet and Operable Unit B Marine of the Bremerton naval complex, Bremerton, Washington, to examine geographical and seasonal patterns of mercury biogeochemistry of sediment in Sinclair Inlet. At six of these seasonal sediment stations, porewater was collected and triplicate core incubation experiments were done. Median sediment-methylmercury concentrations were not statistically different between the representative bays and Sinclair Inlet. The percentage of sediment methylmercury (relative to total mercury) was actually lower in the Sinclair Inlet sites compared with the representative bays, reflecting the higher sediment total mercury concentration for the Sinclair Inlet stations compared with the representative bays. Likewise, median sediment methylmercury concentrations were not statistically different between the greater Sinclair Inlet stations and the Bremerton naval complex stations; whereas the percentage of sediment methylmercury to total mercury was lower in the Bremerton naval complex due to higher sediment total mercury concentrations than the greater Sinclair Inlet stations. The biogeochemical characteristics of each station, measured by redox, organic carbon, and the seasonal availability of nutrients controlled methylmercury biogeochemistry. Mercury methylation production potential was a function of temperature, concentration of total mercury in sediment, and the percentage of ferrous iron (relative to total measured iron) across all sites. Methylmercury porewater concentrations were best described by using concentrations of dissolved organic carbon and reduction-oxidation conditions. Likewise, the variable fluxes of methylmercury from incubated cores were best described using dissolved organic carbon and reduction-oxidation conditions. Sinclair Inlet exhibited the classic Puget Sound biological cycle, with spring and autumn phytoplankton blooms resulting in depletion of nitrate, orthophosphate, and silicate in the surface water. Although variable in timing between 2008 and 2009, a strong corresponding seasonal trend of increased availability, incorporation, and bioaccumulation of methylmercury into the food web of Sinclair Inlet occurred during the early spring and summer growing season.

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Eelgrass habitat near Liberty Bay: Chapter 5

Seagrasses are a widespread type of marine flowering plants that grow in nearshore intertidal and subtidal zones. Seagrass beds are ecologically important because they affect physical, biological, and chemical characteristics of nearshore habitat, and they are sensitive to changes in coastal water quality (Stevenson and others, 1993; Koch, 2001; Martinez-Crego and others, 2008). Zostera marina, commonly known as eelgrass, is protected by a no-net-loss policy in Washington State where it may be used as spawning habitat by herring, a key prey species for salmon, seabirds, and marine mammals (Bargmann, 1998). Eelgrass forms broad meadows in shallow embayments or narrow fringes on open shorelines (Berry and others, 2003). Anthropogenic activities that increase turbidity, nutrient loading, and physical disturbance at the coast can result in dramatic seagrass decline (Ralph and others, 2006).

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Improved estimates of filtered total mercury loadings and total mercury concentrations of solids from potential sources to Sinclair Inlet, Kitsap County, Washington

Previous investigations examined sources and sinks of mercury to Sinclair Inlet based on historic and new data. This included an evaluation of mercury concentrations from various sources and mercury loadings from industrial discharges and groundwater flowing from the Bremerton naval complex to Sinclair Inlet. This report provides new data from four potential sources of mercury to Sinclair Inlet: (1) filtered and particulate total mercury concentrations of creek water during the wet season, (2) filtered and particulate total mercury releases from the Navy steam plant following changes in the water softening process and discharge operations, (3) release of mercury from soils to groundwater in two landfill areas at the Bremerton naval complex, and (4) total mercury concentrations of solids in dry dock sumps that were not affected by bias from sequential sampling. The previous estimate of the loading of filtered total mercury from Sinclair Inlet creeks was based solely on dry season samples. Concentrations of filtered total mercury in creek samples collected during wet weather were significantly higher than dry weather concentrations, which increased the estimated loading of filtered total mercury from creek basins from 27.1 to 78.1 grams per year. Changes in the concentrations and loading of filtered and particulate total mercury in the effluent of the steam plant were investigated after the water softening process was changed from ion-exchange to reverse osmosis and the discharge of stack blow-down wash began to be diverted to the municipal water-treatment plant. These changes reduced the concentrations of filtered and particulate total mercury from the steam plant of the Bremerton naval complex, which resulted in reduced loadings of filtered total mercury from 5.9 to 0.15 grams per year. Previous investigations identified three fill areas on the Bremerton naval complex, of which the western fill area is thought to be the largest source of mercury on the base. Studies of groundwater in the other two fill areas were conducted under worst-case higher high tidal conditions. A December 2011 study found that concentrations of filtered total mercury in the well in the fill area on the eastern boundary of the Bremerton naval complex were less than or equal to 11 nanograms per liter, indicating that releases from the eastern area were unlikely. In addition, concentrations of total mercury of solids were low (<3 milligrams per kilogram). In contrast, data from the November 2011 study indicated that the concentrations of filtered total mercury in the well located in the central fill area had tidally influenced concentrations of up to 500 nanograms per liter and elevated concentrations of total mercury of solids (29–41 milligrams per kilogram). This suggests that releases from this area, which has not been previously studied in detail, may be substantial. Previous measurements of total mercury of suspended solids in the dry dock discharges revealed high concentration of total mercury when suspended-solids concentrations were low. However, this result could have been owing to bias from sequential sampling during changing suspended‑solids concentrations. Sampling of two dry dock systems on the complex in a manner that precluded this bias confirmed that suspended-solids concentrations and total mercury concentrations of suspended solids varied considerably during pumping cycles. These new data result in revised estimates of solids loadings from the dry docks. Although most of the solids discharged by the dry docks seem to be recycled Operable Unit B Marine sediment, a total of about 3.2 metric tons of solids per year containing high concentrations of total mercury were estimated to be discharged by the two dry dock systems. A simple calculation, in which solids (from dry docks, the steam plant, and tidal flushing of the largest stormwater drain) are widely dispersed throughout Operable Unit B Marine, suggests that Bremerton naval complex solids would likely have little effect on Operable Unit B Marine sediments because of high concentrations of mercury already present in the sediment.

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Geologic map of the Suquamish 7.5' quadrangle and part of the Seattle North 7.5' x 15' quadrangle, Kitsap County, Washington

The Suquamish 7.5' quadrangle is in the center of the Puget Lowland, Washington. The quadrangle contains the northern two-thirds of Bainbridge Island and adjacent parts of the Kitsap Peninsula. Puget Sound and contiguous waterways form 35 percent of the map area. Maximum elevation is 137 m in the northwest corner of the quadrangle, west of Suquamish; the modal elevation is 44 m. The center of the quadrangle is 20 km west-northwest of downtown Seattle. Winslow, in the southeast corner of the quadrangle, is a 35-minute ferry ride from Seattle. The Suquamish quadrangle lies within the Salish Lowland physiographic province (Haugerud, 2004), a broad region in the forearc of the Cascade Volcanic Arc that extends from south of Olympia, Washington, to north of Campbell River, British Columbia, and includes both the Puget Lowland of western Washington and the Georgia Depression of northwestern Washington and southwestern British Columbia. To the east are the Cascade Range and Coast Mountains; to the west is the outer-arc high of the Coast Ranges. The Salish Lowland is the locus of late Cenozoic subsidence: Jones (1996) indicates as much as 1 km of unconsolidated fill beneath some areas. The Lowland is crossed by east-west topographic highs formed by bedrock uplifts. A northern San Juan high divides the Lowland into Georgia Depression and Puget Lowland subprovinces. A southern high, which lies athwart the south end of Bainbridge Island immediately south of the map area, coincides with the Seattle Fault Zone along which uplift has brought Eocene rocks to elevations of 800-1,200 m, 8-10 km higher than equivalent strata in the floor of the Seattle structural basin that underlies central and northern Bainbridge Island and areas to the east (Brocher and others, 2001; Blakely and others, 2002). Deformation along the Seattle Fault appears to be driven by north-south shortening of the Cascade forearc (Wells and others, 1998). Pleistocene glacial deposits underlie most of the map area. Most extensive are the various members of the Vashon Drift, deposited in the Vashon stade of the Fraser Glaciation of Armstrong and others (1965) between about about 17,000 years ago. This study was undertaken in response to (1) awareness of the hazard posed by future earthquakes in the Seattle Fault Zone, at the south edge of the quadrangle, and the need to marshal geologic evidence for the rate and style of deformation; (2) increasing population on Bainbridge Island and consequent pressure on groundwater resources; (3) concern about landslide hazards; and (4) awareness of the role that the nearshore zone plays in supporting marine resources.

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Simulation of the ground-water flow system at Naval Submarine Base Bangor and vicinity, Kitsap County, Washington

An evaluation of the interaction between ground-water flow on Naval Submarine Base Bangor and the regional-flow system shows that for selected alternatives of future ground-water pumping on and near the base, the risk is low that significant concentrations of on-base ground-water contamination will reach off-base public-supply wells and hypothetical wells southwest of the base. The risk is low even if worst-case conditions are considered ? no containment and remediation of on-base contamination. The evaluation also shows that future saltwater encroachment of aquifers below sea level may be possible, but this determination has considerable uncertainty associated with it. The potential effects on the ground-water flow system resulting from four hypothetical ground-water pumping alternatives were considered, including no change in 1995 pumping rates, doubling the rates, and 2020 rates estimated from population projections with two different pumping distributions. All but a continuation of 1995 pumping rates demonstrate the possibility of future saltwater encroachment in the Sea-level aquifer on Naval Submarine Base Bangor. The amount of time it would take for encroachment to occur is unknown. For all pumping alternatives, future saltwater encroachment in the Sea-level aquifer also may be possible along Puget Sound east and southeast of the base. Future saltwater encroachment in the Deep aquifer also may be possible throughout large parts of the study area. Projections of saltwater encroachment are least certain outside the boundaries of Naval Submarine Base Bangor. The potential effects of the ground-water pumping alternatives were evaluated by simulating the ground-water flow system with a three-dimensional uniform-density ground-water flow model. The model was calibrated by trial-and-error by minimizing differences between simulated and measured or estimated variables. These included water levels from prior to January 17, 1977 (termed 'predevelopment'), water-level drawdowns since predevelopment until April 15, 1995, ground-water discharge to streams in water year 1995, and residence times of ground water in different parts of the flow system that were estimated in a separate but related study. Large amounts of ground water were pumped from 1977 through 1980 from the Sea-level aquifer on Naval Submarine Base Bangor to enable the construction of an off-shore drydock. Records of the flow-system responses to the applied stresses were used to help calibrate the model. Errors in the calibrated model were significant. The poor agreement between simulated and measured values could be improved by making many local changes to hydraulic parameters but these changes were not supported by other data. Model errors may have resulted in errors in the simulated effects of ground-water pumping alternatives.

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Ambient quality of ground water in the vicinity of Naval Submarine Base Bangor, Kitsap County, Washington, 1995

A study of the ambient ground-water quality in the vicinity of Naval Submarine Base (SUBASE) Bangor was conducted to provide the U.S. Navy with background levels of selected constituents. The Navy needs this information to plan and manage cleanup activities on the base. During March and April 1995, 136 water-supply wells were sampled for common ions, trace elements, and organic compounds; not all wells were sampled for all constituents. Man-made organic compounds were detected in only two of fifty wells, and the sources of these organic compounds were attributed to activities in the immediate vicinities of these off-base wells. Drinking water standards for trichloroethylene, iron, and manganese were exceeded in one of these wells, which was probably contaminated by an old local (off-base) dump. Ground water from wells open to the following hydrogeologic units (in order from shallow to deep) was investigated: the Vashon till confining unit (Qvt, three wells); the Vashon aquifer (Qva, 54 wells); the Upper confining unit (QC1, 16 wells); the Permeable interbeds within QC1 (QC1pi, 34 wells); and the Sea-level aquifer (QA1, 29 wells).The 50th and 90th percentile ambient background levels of 35 inorganic constituents were determined for each hydrogeologic unit. At least ten measurements were required for a constituent in each hydrogeologic unit for determination of ambient background levels, and data for three wells determined to be affected by localized activities were excluded from these analyses. The only drinking water standards exceeded by ambient background levels were secondary maximum contaminant levels for iron (300 micrograms per liter), in QC1 and QC1pi, and manganese (50 micrograms per liter), in all of the units. The 90th percentile values for arsenic in QC1pi, QA1, and for the entire study area are above 5 micrograms per liter, the Model Toxics Control Act Method A value for protecting drinking water, but well below the maximum contaminant level of 50 micrograms per liter for arsenic. The manganese standard was exceeded in 38 wells and the standard for iron was exceeded in 12 wells. Most of these wells were in QC1 or QC1pi and had dissolved oxygen concentrations of less than 1 milligram per liter and dissolved organic carbon concentrations greater than 1 milligram per liter. The dissolved oxygen concentration is generally lower in the deeper units, while pH increases; the recommended pH range of 6.5-8.5 standard units was exceeded in 9 wells. The common-ion chemistry was similar for all of the units.

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Availability of ground water in the area surrounding the Trident submarine construction facility, Kitsap County, Washington

This report provides general information on the water resources--with emphasis on ground-water occurrence and availability--in that part of Kitsap County (referred to as Trident Impact Area) that would be most affected by the development of the Trident submarine-construction facility at Bangor. Ground water occurs principally in a lower, confined aquifer near and below sea level and an upper, unconfined aquifer above sea level; both aquifers are extensive beneath the study area and are composed of sand and gravel layers separated by poorly permeable silt, clay, and till layers. Locally throughout the area efficiently constructed wells tapping each of the two aquifers are capable of yielding 100 to 1,300 or more gallons per minute. The estimated 1970 water use in the study area averaged about 13 million gal/day (gallons per day); of this amount about 9 million gal/day came from surface-water sources--from a large reservoir outside the study area--and about 4 million gal/day came from ground water pumped from the two aquifers. Anticipated water use soon will be about 18 to 21 million gal/day; virtually all the additional quantity required (about 5 to 8 million gal/day) above present use must come from ground-water sources. Preliminary evaluation of the aquifers suggests that an additional 1.5 million gal/day can be developed from the upper aquifer and 7 million gal/day from the lower aquifer. Existing wells tapping the lower aquifer might yield additional water and increase the total yield in the area by 3.5 million gal/day, and new wells drilled in selected areas could produce an additional 3.5 million gal/day from this aquifer. However, additional, large-scale ground-water withdrawal from the lower aquifer could induce saltwater intrusion into wells situated in coastal areas. Recommended future studies include additional data collection, monitoring of chloride concentrations in water from large-yield coastal wells, confirmation of well yields and capacities, and test-well drilling and analysis.

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