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The contributions and influence of two Americans, Henry S. Washington and Frank A. Perret, to the study of Italian volcanism with emphasis on volcanoes in the Naples area

A century ago, two Americans, Henry Stephens Washington and Frank Alvord Perret, made significant contributions to the geology, petrology, and volcanology of Italy, in particular to those volcanoes in the Naples area, Vesuvius, Campi Flegrei (Phlegraean Fields), and the Island of Ischia. Both were from the eastern United States, both were born in 1867, and both studied physics as undergraduates. However, each man followed a different scientific path and approach in his volcanological studies. Washington was classically trained and more interested in rock chemistry, mineralogy, and petrogenesis. Perret was a gifted inventor, worked in Edison's laboratory, established his own company, and was a keen observer of volcanic phenomena and processes; today he would be called a “physical volcanologist” Each man published classic works on Italian volcanoes, The Roman Comagmatic Region (Washington, 1906) and The Vesuvius Eruption of 1906 (Perret, 1924); both were published by the Carnegie Institution of Washington. However, both men had cosmopolitan tastes for other volcanoes, and they traveled widely and made significant contributions to the knowledge of other volcanic areas. The following two sections present, albeit briefly, their work, significance, and influence to Italian volcanism with emphasis on those volcanoes in the Naples area.

Naples↗

Natural attenuation can lead to environmental resilience in mine environment

Four streams flowing in the Iglesiente and Arburese mine districts (SW Sardinia, Italy), exploited for zinc (Zn) and lead (Pb) extraction from sulphides and secondary non-sulphide mineralization (calamine ores), have been studied combining investigations from the macroscale (hydrologic tracer techniques) to the microscale (X-ray powder diffraction, scanning electron microscopy, X-ray absorption spectroscopy). In the investigated area, concerns arise from release of metals to water during weathering of ore minerals and mine-waste. Specifically, Zn is observed at extremely high concentrations (10s of mg/L or more) in waters in some of the investigated catchments. The results from synoptic sampling campaigns showed marked differences of Zn loads, from 6.3 kg/day (Rio San Giorgio) to 2000 kg/day (Rio Irvi). Moreover, natural attenuation of metals was found to occur i) through precipitation of Fe compounds (Fe oxy/hydroxides and “green rust”), ii) by means of the authigenic formation of metal sulphides promoted by microbial sulphate reduction, iii) by metal intake in roots and stems of plants ( Phragmites australis and Juncus acutus ) and by immobilization in the rhizosphere, and iv) by cyanobacterial biomineralization processes that lead to formation of Zn-rich phases (hydrozincite and amorphous Zn-silicate) The biologically mediated natural processes that lead to significant abatement and/or reduction of metal loads, are the response of environmental systems to perturbations caused from mine activities, and can be considered part of the resilience of the system itself. The aim of this study is to understand the effect of these processes on the evolution of the studied systems towards more stable and, likely, resilient conditions, e.g. by limiting metal mobility and favoring the improvement of the overall quality of water. The understanding of how ecosystems adapt and respond to contamination, and which chemical and physical factors control these natural biogeochemical barriers, can help to plan effective remediation actions.

Sardinia↗

Assessing mercury distribution using isotopic fractionation of mercury processes and sources adjacent and downstream of a legacy mine district in Tuscany, Italy

Mercury (Hg) concentrations and isotopic compositions in a range of sample types collected from the legacy Abbadia San Salvatore Mine (ASSM) area were used to evaluate the distribution of Hg in the region. The district generated more than 100,000 metric tons of Hg releasing extensive amounts of gaseous Hg emissions and producing large amounts of mine waste calcine from which Hg can be mobilized into the local and regional environments. Direct and indirect impact from cinnabar ore mining and processing resulted in elevated Hg concentrations in the calcine, soils, lake and stream sediments, and fish samples collected at and downstream of ASSM. The contribution of Hg from the different sources and processes resulted in a wide range of 202Hg and 199Hg isotopic compositions (-2.25 to 0.96‰, -0.12 to 0.72‰ respectively). Fish samples resulted in negative values for 202Hg (-0.53 to -1.21‰) and positive Hg (0.12 to 0.73‰). Primary cinnabar ore and present-day geothermal water and precipitate showed distinctly negative 202Hg (-0.96 to -2.25‰), whereas waste calcine were enriched in 202Hg (202Hg from about -1 to +1‰); soils and sediments show intermediate compositions, reflecting different extents of contributions from the various Hg sources and processes. These sources and processes of Hg include weathering cinnabar, gaseous Hg emissions from ore processing, and geothermal activity to a lesser extent. Hg speciation in concert with Hg isotope ratios can better ascertain source attribution and assist in identifying Hg pathways into the environment to distinguish the more bioavailable forms of Hg entering the ecosystem.

Tuscany↗

Trace and rare earth elements determination in milk whey from the Veneto region, Italy

Multi-element analyses determine the content of 17 trace elements (Al, V, Cr, Mn, Fe, Co, Ni, Cu, Zn, As, Se, Sr, Cd, Cs, Ba, Pb, U) and 14 rare earth elements (La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Yb, Lu, Y) in whey samples from cow and goat milk by inductively coupled plasma mass spectrometry and inductively coupled plasma-sector field mass spectrometry. A total of 261 milk whey samples were collected from four locations in the Veneto region of northeastern (NE) Italy. These samples contain a wide range concentration of 17 trace elements (0.06–1530 μg kg −1 ) and 14 rare earth elements (0.16–28.2 ng kg −1 ) in whey samples, but do not reach toxic concentrations. Elemental fingerprinting of trace and rare earth elements in cow and goat milk whey provide information on the dairy quality and, as they reflect the local environmental conditions, result in an excellent indicator of their geographical origin.

Veneto region↗

Could a freshwater fish be at the root of dystrophic crises in a coastal lagoon?

Eutrophication has a profound impact on ecosystems worldwide. Grass carp Ctenopharyngodon idella , an herbivorous fish, has been introduced to control aquatic plant overgrowth caused by eutrophication, but could have other, potentially detrimental, effects. We used the Po di Volano basin (south of the Po River delta, northern Italy) as a test case to explore whether grass carp effects on canal aquatic vegetation could be at the root of historical changes in N loads exported from the basin to the Goro Lagoon. We modeled the aquatic vegetation production and standing crop, its denitrification potential, and its consumption by introduced grass carp. We then examined whether changes in historical nitrogen loads matched the modeled losses of the drainage network denitrification function or other changes in agricultural practices. Our results indicate that introduced grass carp could completely remove submerged vegetation in the Po di Volano canal network, which could – in turn – lead to substantial loss of the denitrification function of the system, causing in an increase in downstream nitrogen loads. A corresponding increase, matching both timing and magnitude, was detected in historical nitrogen loads to the Goro Lagoon, which were significantly different before and after the time of modeled collapse of the denitrification function. This increase was not clearly linked to watershed use or agricultural practices, which implies that the loss of the denitrification function through grass carp overgrazing could be a likely explanation of the increase in downstream nitrogen loads. Perhaps for the first time, we provide evidence that a freshwater fish introduction could have caused long-lasting changes in nutrient dynamics that are exported downstream to areas where the fish is not present.

Po River basin↗

High-resolution and accurate topography reconstruction of Mount Etna from Pleiades satellite data

The areas characterized by dynamic and rapid morphological changes need accurate topography information with frequent updates, especially if these are populated and involve infrastructures. This is particularly true in active volcanic areas such as Mount (Mt.) Etna, located in the northeastern portion of Sicily, Italy. The Mt. Etna volcano is periodically characterized by explosive and effusive eruptions and represents a potential hazard for several thousands of local people and hundreds of tourists present on the volcano itself. In this work, a high-resolution, high vertical accuracy digital surface model (DSM) of Mt. Etna was derived from Pleiades satellite data using the National Aeronautics and Space Administration (NASA) Ames Stereo Pipeline (ASP) tool set. We believe that this is the first time that the ASP using Pleiades imagery has been applied to Mt. Etna with sub-meter vertical root mean square error (RMSE) results. The model covers an area of about 400 km 2 with a spatial resolution of 2 m and centers on the summit portion of the volcano. The model was validated by using a set of reference ground control points (GCP) obtaining a vertical RMSE of 0.78 m. The described procedure provides an avenue to obtain DSMs at high spatial resolution and elevation accuracy in a relatively short amount of processing time, making the procedure itself suitable to reproduce topographies often indispensable during the emergency management case of volcanic eruptions.

Mount Etna↗

Physically based estimation of rainfall thresholds triggering shallow landslides in volcanic slopes of southern Italy

On the 4th and 5th of March 2005, about 100 rainfall-induced landslides occurred along volcanic slopes of Camaldoli Hill in Naples, Italy. These started as soil slips in the upper substratum of incoherent and welded volcaniclastic deposits, then evolved downslope according to debris avalanche and debris flow mechanisms. This specific case of slope instability on complex volcaniclastic deposits remains poorly characterized and understood, although similar shallow landsliding phenomena have largely been studied in other peri-volcanic areas of the Campania region underlain by carbonate bedrock. Considering the landslide hazard in this urbanized area, this study focused on quantitatively advancing the understanding of the predisposing factors and hydrological conditions contributing to the initial landslide triggering. Borehole drilling, trial pits, dynamic penetrometer tests, topographic surveys, and infiltration tests were conducted on a slope sector of Camaldoli Hill to develop a geological framework model. Undisturbed soil samples were collected for laboratory testing to further characterize hydraulic and geotechnical properties of the soil units identified. In situ soil pressure head monitoring probes were also installed. A numerical model of two-dimensional variably saturated subsurface water flow was parameterized for the monitored hillslope using field and laboratory data. Based on the observed soil pressure head dynamics, the model was calibrated by adjusting the evapotranspiration parameters. This physically based hydrologic model was combined with an infinite-slope stability analysis to reconstruct the critical unsaturated/saturated conditions leading to slope failure. This coupled hydromechanical numerical model was then used to determine intensity–duration (I-D) thresholds for landslide initiation over a range of plausible rainfall intensities and topographic slope angles for the region. The proposed approach can be conceived as a practicable method for defining a warning criterion in urbanized areas threatened by rainfall-induced shallow landslides, given the unavailability of a consistent inventory of past landslide events that prevents a rigorous empirical analysis.

Water↗

Lakes as paleoseismic records in a seismically-active, low-relief area (Rieti Basin, central Italy)

Small lakes in low relief areas are atypical candidates for studies on paleoseismicity, but their sediments can contain seismically induced event layers (seismites) generated through strong ground shaking, sediment transport, hydrological reorganization and/or changes in groundwater chemistry and flow. Lakes Lungo and Ripasottile are shallow lakes (<10m deep) located in the tectonically active Rieti Basin in the central Apennines, Italy, where strong normal faulting earthquakes (Mw 6.5 to 7.0) regularly occur. Sediment cores from these lakes provide paleoseismic indicators for the past ~1000 years. Sedimentological and geochemical analysis reveals four event layers identified in both lakes that correspond with documented large-scale earthquakes in 1298, 1349, 1639, and 1703 AD. Chronological correlation between earthquakes and possible seismites is reliable because of the unusually high resolution of sediment dating available for the studied cores. The common physical structure is a physically homogenous bed (homogenite) of re-suspended sediment consisting of a denser, high magnetic susceptibility (MS) clastic base, with organic matter concentrated above. Chemical signatures are associated with some event layers and may represent abrupt or transient shifts to a groundwater-dominated system, or permanent changes in groundwater flow and/or spring discharge. Excursions in δ13Corg may represent disruptions or changes in carbon source. Not all event layers show the same features, a result attributed to differences in seismic processes as well as the lake attributes, and anthropogenic modification. The observations made here may provide a new means of detecting paleoseismicity and may be applied to other low relief lakes in seismically active areas.

Rieti Basin↗

Multiproxy Cretaceous-Paleogene boundary event stratigraphy: An Umbria-Marche basin-wide perspective

The complete and well-studied pelagic carbonate successions from the Umbria-Marche Basin (Italy) permit the study of the event-rich stratigraphical interval around the Cretaceous-Paleogene (K-Pg) boundary (e.g., Deccan volcanism, boundary impact, Paleocene recovery and climate). To test the robustness of various proxy records (bulk carbonate δ13C, δ18O, 87Sr/86Sr and Ca, Fe, Sr and Mn concentrations) inside the Umbria-Marche basin, several stratigraphically equivalent sections were investigated (Bottaccione Gorge, Contessa Highway, Fornaci East quarry, Frontale, Morello and Petriccio Core). Besides the classical Gubbio sections of Bottaccione and Contessa, the new Morello section is put forward as an alternative location for this stratigraphical interval as it is less altered by burial diagenesis. Elemental profiles (Ca, Fe, Sr, Mn) acquired by handheld X-Ray Fluorescence (pXRF) efficiently provide regional chemostratigraphical and paleoenvironmental information. The Deccan volcanism, the K-Pg boundary, the characteristic pattern of the Sr/Ca profile across the boundary driven by the extinction and recovery of coccolithophores, and the Dan-C2 hyperthermal event are examples of such recorded paleoenvironmental events. Moreover, cyclostratigraphic analyses of proxies of detrital input (magnetic susceptibility and Fe concentrations) show the imprint in the sedimentary record of a 2.4 Myr eccentricity minimum around 66.45-66.25 Ma and suggest that the occurrence of the Dan-C2 hyperthermal event was astronomically paced.

Umbria-Marche basin↗

Microclimatic gradients provide evidence for a glacial refugium for temperate trees in a sheltered hilly landscape of Northern Italy

Aim Refugia play a key role in conserving biodiversity during periods of unfavourable and highly variable regional climate. However, refugial populations are often small and fragmented, which makes their identification difficult. In this study, we investigate whether an area of complex topography in the southern foreland of the Alps could have provided a suitable microclimate to serve as a glacial refugium for temperate trees during the last glacial. Location The Euganean Hills in Northern Italy (Veneto). Methods We assessed the current microclimatic variability in the ecologically diverse region on a fine scale by recording half‐hourly near‐surface temperatures over a period of 11 months. After comparing our measurements with today's vegetation distribution, broad‐scale synoptic patterns, and topoclimatic factors, we estimated refugial suitability based on extreme temperatures, climatic stability, and difference from the regional average. Results Present‐day temperature gradients within the Euganean Hills are large enough to explain the presence of the temperate tree species Fagus sylvatica as well as Mediterranean Quercus ilex , two species that are absent elsewhere in the adjacent Po Plain. During winter, anticyclonic weather patterns resulted in strong atmospheric inversions, with temperatures increasing by +1°C/100 m in the hills relative to the surrounding Po Plain. Main conclusions Our high‐resolution climate data support multi‐proxy palaeoecological records identifying the Euganean Hills as a refugium for temperate trees. Temperature anomalies of 2–4°C relative to the surrounding Po Plain are sufficient to allow several temperate tree species to survive the Last Glacial Maximum (LGM) in the Euganean Hills under a harsh continental climate. Specifically, elevations >200 m a.s.l. in the central parts of the hills may have provided suitable conditions for local LGM refugia. Regions of complex topography such as the Euganean Hills conserved past and present biodiversity and provide high‐priority areas for conservation under future climate warming.

Journal of Biogeography↗

Mechanisms of earthquake‐induced chemical and fluid transport to carbonate groundwater springs after earthquakes

Mechanisms by which hydrochemical changes occur after earthquakes are not well documented. We use the 2016–2017 central Italy seismic sequence, which caused notable hydrochemical transient variations in groundwater springs to address this topic, with special reference to effects on fractured carbonate aquifers. Hydrochemistry measured before and after the earthquakes at four springs at varying distances from the epicenters all showed immediate postmainshock peaks in trace element concentrations but little change in major elements. Most parameters returned to preearthquake values before the last events of the seismic sequence. The source of solutes, particularly trace elements, is longer residence time pore water stored in slow‐moving fractures or abandoned karstic flow paths. These fluids were expelled into the main flow paths after an increase in pore pressure, hydraulic conductivity, and shaking from coseismic aquifer stress. The weak response to the later earthquakes is explained by progressive depletion of high solute fluids as earlier shocks flushed out the stored fluids in the fractures. Spring δ 13 C DIC values closest to a deep magma source to the west became enriched relative to preearthquake values following the 24 August event. This enrichment indicates input from deeply sourced dissolved CO 2 gas after dilation of specific fault conduits. Differences in carbon isotopic responses between springs are attributed to proximity to the deep gaseous CO 2 source. Most of the transient chemical changes seen in the three fractured carbonate aquifers are attributed to local shaking and emptying of isolated pores and fractures and are not from rapid upward movement of deep fluids.

Water Resources Research↗

Ensemble smoothed seismicity models for the new Italian Probabilistic Seismic Hazard Map

We develop a long‐term (a few decades or longer) earthquake rate forecast for Italy based on smoothed seismicity for incorporation in the 2017–2018 Italian Probabilistic Seismic Hazard Maps (IPSHM). Because the earthquake rate models from previous IPSHM were computed using source zones that were drawn around seismicity and tectonic provinces, the present model will be the first introduction of the smoothed seismicity method into the IPSHM. Smoothed seismicity models are constructed from both historical CPTI15 (Catalogo Parametrico dei Terremoti Italiani, 1000–2014) and instrumental (1981–2016) earthquake catalogs and use both fixed and adaptive smoothing methods. We compute spatial likelihood values comparing the spatial distribution of observed earthquakes with a suite of trial earthquake rate models to optimize smoothing parameters and catalogs. Then we produce an ensemble model using two different smoothing models (adaptive and fixed) and two earthquake catalogs (historical and instrumental), which are weighted equally through a logic‐tree approach to improve the forecast capability. We also compare our optimized smoothed seismicity models with the best two models of the Italian Collaboratory for the Study of Earthquake Predictability (CSEP) experiment and retrospectively test them with the CSEP methodology. We observed that the ensemble model performs slightly better than the optimized fixed and the adaptive smoothing seismicity models obtained in this study and the best time‐independent model of the CSEP Italian experiment. The preferred ensemble model forecasts an annual rate of 1.47 M &#x2265; 5.0 "> M ≥ 5.0 earthquakes, with higher rates mainly concentrating along the Apennines chain, eastern Alps, Calabria, and northeast Sicily. Finally, six ensemble models are created from the different smoothing methods using different weights through a logic‐tree approach to estimate the uncertainty associated with the model.

Seismological Research Letters↗

Application of hydrologic-tracer techniques to the Casargiu adit and Rio Irvi (SW-Sardinia, Italy): Using enhanced natural attenuation to reduce extreme metal loads

Hydrologic tracer techniques were applied to Rio Irvi (SW Sardinia), a stream affected by mine drainage, allowing the calculation of stream discharge and metal loads and comparison to other streams. The calculated discharge showed a continuous increase from near 21.2 L/s to 29.1 L/s. Cumulative loads of mine-related constituents, including the Casargiu adit inflow, were large, with more than 9900 kg/day of SO 4 2− , 2370 kg/day of Zn, 550 kg/day of Fe and 172 kg/day of Mn. The greatest measurable inflow source of metals, other than the Casargiu adit, was an acidic tributary (L4), but most sources of instream metal load were related to dispersed groundwater inflows. Some of those groundwater inflows were related to non-flowing tributaries. Calculations of the cumulative instream metal load, excluding the Casargiu adit inflow, indicated increases of 1250 kg/day for SO 4 2 , 858 kg/day for Zn - , 137 kg/day gain for Fe and 60 kg/day for Mn. Rio Irvi Zn load was extreme for a stream of this size and discharge. A comparison with two other mine-affected rivers in Sardinia indicated the loading in Rio Irvi was two to three orders of magnitude greater. This difference was attributed to different geochemical conditions, but also to a lack of a biogeochemical barrier like that seen to be acting along and below the riverbed in Rio San Giorgio. Several years of intense vegetation growth in the river bed of Rio San Giorgio created a biogeochemical barrier to metal loading, and the cumulative Zn load there was near 8 kg/day, despite being a drainage with a greater mass of mine wastes to contribute to the load.

Sardinia↗

Geochemical and Pb isotopic characterization of soil, groundwater, human hair, and corn samples from the Domizio Flegreo and Agro Aversano area (Campania region, Italy)

A geochemical survey was carried out to investigate metal contamination in the Domizio Littoral and Agro Aversano area (Southern Italy) by means of soil, groundwater, human hair and corn samples. Pb isotope ratios were also determined to identify the sources of metals. Specifically, the investigation focused on topsoils ( n = 1064), groundwater ( n = 26), 25 human hair ( n = 24) and corn samples ( n = 13). Topsoils have been sampled and analysed in a previous study for 53 elements (including potentially harmful ones), and determined by ICP-MS after dissolving with aqua regia. Groundwater was analysed for 72 elements by ICP-MS and by ICP-ES. Samples of human hair were prepared and analysed for 16 elements by ICP-MS. Dried corn collected at several farms were also analysed for 53 elements by ICP-MS. The isotopic ratios of 206 Pb/ 207 Pb and 208 Pb/ 207 Pb in selected topsoil ( n = 24), groundwater ( n = 9), human hair ( n = 9) and corn ( n = 4) samples were analysed from both eluates and residues to investigate possible anthropogenic contamination and geogenic contributions. All data were processed and mapped by ArcGis software to produce interpolated maps and contamination factor maps of potentially harmful elements, in accordance with Italian Environmental Law (Legislative Decree 152/06). Results show that soil sampling sites are characterized by As, Cd, Co, Cr, Cu, Hg, Pb, Se, and Zn contents exceeding the action limits established for residential land use (RAL) and, in some cases, also the action limits for industrial land use (IAL) as established by Legislative Decree 152/06. A map of contamination factors and a map showing the degrees of contamination indicate that the areas in the municipalities of Acerra, Casoria and Giugliano have been affected by considerable anthropogenic-related pollution. To interpret the isotopic data and roughly estimate proportion of Pb from an anthropogenic source we broadly defined possible natural and anthropogenic Pb end-member fields based on literature data. For example, we summarized data for Vesuvius and Campi Flegrei volcanic rocks, gasoline, and aerosol deposits. Lead isotope data show mixing between geogenic and anthropogenic sources. Topsoil, groundwater, human hair and corn samples show a greater contribution from geogenic sources like the Yellow Tuff (from Campi Flegrei) and volcanic rocks from Mt. Vesuvius. Aerosols, fly ash and gasoline (anthropogenic sources) have also been contributors. In detail, 46% of the topsoil residues, 96% of topsoil leachates, 88% of groundwater, 90% of human hair, and 25% of corn samples indicate that > 50% percent of the lead in this area can be ascribed to anthropogenic activity.

Campania region↗

Inflation leading to a Slow Slip Event and volcanic unrest at Mt. Etna in 2016: Insights from CGPS data

Global Positioning System (CGPS) data from Mount Etna between May 2015 and September 2016 show intense inflation and a concurrent Slow Slip Event (SSE) from 11 December 2015 to 17 May 2016. In May 2016, an eruptive phase started from the summit craters, temporarily stopping the ongoing inflation. The CGPS data presented here give us the opportunity to determine (1) the source of the inflating body, (2) the strain rate parameters highlighting shear strain rate accumulating along NE Rift and S Rift, (3) the magnitude of the SSE, and (4) possible interaction between modeled sources and other flank structures through stress calculations. By analytical inversion, we find an inflating source 5.5 km under the summit (4.4 km below sea level) and flank slip in a fragmented shallow structure accommodating displacements equivalent to a magnitude M w 6.1 earthquake. These large displacements reflect a complex mechanism of rotations indicated by the inversion of CGPS data for strain rate parameters. At the scale of the volcano, these processes can be considered precursors of seismic activity in the eastern flank of the volcano but concentrated mainly on the northern boundary of the mobile eastern flank along the Pernicana Fault and in the area of the Timpe Fault System.

Mt. Etna↗

Fate of antimony and arsenic in contaminated waters at the abandoned Su Suergiu mine (Sardinia, Italy)

We investigated the fate of Sb and As downstream of the abandoned Su Suergiu mine (Sardinia, Italy) and surrounding areas. The mined area is a priority in the Sardinian remediation plan for contaminated sites due to the high concentrations of Sb and As in the mining-related wastes, which may impact the Flumendosa River that supplies water for agriculture and domestic uses. Hydrogeochemical surveys conducted from 2005 to 2015 produced time-series data and downstream profiles of water chemistry at 46 sites. Water was sampled at: springs and streams unaffected by mining; adits and streams in the mine area; drainage from the slag heaps; stream water downstream of the slag drainages; and the Flumendosa River downstream from the confluence of the contaminated waters. At specific sites, water sampling was repeated under different flow conditions, resulting in a total of 99 samples. The water samples were neutral to slightly alkaline. Elevated Sb (up to 30 mg L −1 ) and As (up to 16 mg L −1 ) concentrations were observed in water flowing from the slag materials from where the Sb ore was processed. These slag materials were the main Sb and As source at Su Suergiu. A strong base, Na-carbonate, from the foundry wastes, had a major influence on mobilizing Sb and As. Downstream contamination can be explained by considering that: (1) the predominant aqueous species, Sb(OH) 6 − and HAsO 4 −2 , are not favored in sorption processes at the observed pH conditions; (2) precipitation of Sb- and As-bearing solid phases was not observed, which is consistent with modeling results indicating undersaturation; and (3) the main decrease in dissolved Sb and As concentrations was by dilution. Dissolved As concentrations in the Flumendosa River did not generally exceed the EU limit of 10 µg L −1 , whereas dissolved Sb in the river downstream of the contamination source always exceeded the EU limit of 5 µg L −1 . Recent actions aimed at retaining runoff from the slag heaps are apparently not sufficiently mitigating contamination in the Flumendosa River.

Sardinia↗

A physics-based earthquake simulator and its application to seismic hazard assessment in Calabria (Southern Italy) region

The use of a newly developed earthquake simulator has allowed the production of catalogs lasting 100 kyr and containing more than 100,000 events of magnitudes ≥4.5. The model of the fault system upon which we applied the simulator code was obtained from the DISS 3.2.0 database, selecting all the faults that are recognized on the Calabria region, for a total of 22 fault segments. The application of our simulation algorithm provides typical features in time, space and magnitude behavior of the seismicity, which can be compared with those of the real observations. The results of the physics-based simulator algorithm were compared with those obtained by an alternative method using a slip-rate balanced technique. Finally, as an example of a possible use of synthetic catalogs, an attenuation law has been applied to all the events reported in the synthetic catalog for the production of maps showing the exceedance probability of given values of PGA on the territory under investigation.

Calabria region↗

Hydrochemical determination of source water contributions to Lake Lungo and Lake Ripasottile (central Italy)

Lake Lungo and Lake Ripasottile are two shallow (4-5 m) lakes located in the Rieti Basin, central Italy, that have been described previously as surface outcroppings of the groundwater table. In this work, the two lakes as well as springs and rivers that represent their potential source waters are characterized physio-chemically and isotopically, using a combination of environmental tracers. Temperature and pH were measured and water samples were analyzed for alkalinity, major ion concentration, and stable isotope (δ2H, δ18O, δ13C of dissolved inorganic carbon, and δ34S and δ18O of sulfate) composition. Chemical data were also investigated in terms of local meteorological data (air temperature, precipitation) to determine the sensitivity of lake parameters to changes in the surrounding environment. Groundwater represented by samples taken from Santa Susanna Spring was shown to be distinct with SO42- and Mg2+ content of 270 and 29 mg/L, respectively, and heavy sulfate isotopic composition(δ34S=15.2 ‰ and δ18O=10‰). Outflow from the Santa Susanna Spring enters Lake Ripasottile via a canal and both spring and lake water exhibits the same chemical distinctions and comparatively low seasonal variability. Major ion concentrations in Lake Lungo are similar to the Vicenna Riara Spring and are interpreted to represent the groundwater locally recharged within the plain. The δ13CDIC exhibit the same groupings as the other chemical parameters, providing supporting evidence of the source relationships. Lake Lungo exhibited exceptional ranges of δ13CDIC (±5 ‰) and δ2H, δ18O (±5 ‰ and ±7 ‰, respectively), attributed to sensitivity to seasonal changes. The hydrochemistry results, particularly major ion data, highlight how the two lakes, though geographically and morphologically similar, represent distinct hydrochemical facies. These data also show a different response in each lake to temperature and precipitation patterns in the basin that may be attributed to lake water retention time. The sensitivity of each lake to meteorological patterns can be used to understand the potential effects from long-term climate variability.

Lake Lungo, Lake Ripasottile↗