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Source-linked reports with geographic coverage including England.

7 recordsLinked to original sources
USGS2022

Characterization of bituminite in Kimmeridge Clay by confocal laser scanning and atomic force microscopy

This work investigates bituminite (amorphous sedimentary organic matter) in Upper Jurassic Kimmeridge Clay source rock via confocal laser scanning microscopy (CLSM) and atomic force microscopy (AFM). These petrographic tools were used to provide better understanding of the nature of bituminite, which has been historically difficult to identify and differentiate from similar organic matter types in source rocks. As part of an International Committee for Coal and Organic Petrology (ICCP) working group, an immature (0.42% vitrinite reflectance), organic-rich (44.1 wt% total organic carbon content) sample of Kimmeridge Clay was distributed to multiple laboratories for CLSM characterization. The primary observations from CLSM imaging and spectroscopy include: 1) the interpreted presence of Botryococcus algae as a contributor to bituminite precursors; 2) color red-shift of sulfide reflectance and bituminite auto-fluorescence from below the sample surface; 3) positive alteration of bituminite from laser-induced photo-oxidation of the sample surface, including fluorescence blue-shift; 4) fluorescence blue-shift associated to higher fluorescence intensity regions in bituminite indicative of compositional (fluorophore) differences; 5) the need for fluorescence spectroscopy standardization as applied via CLSM; and 6) the suitability of CLSM fluorescence spectroscopy to predict solid bitumen reflectance from bituminite spectral emission via calibration to an extant dataset. Secondary CLSM observations include detection of reflected laser light from highly reflective inclusions in bituminite, including sulfides and fusinite, and radiolytic alteration of bituminite caused by substitution of U for Fe in sulfides. Findings from AFM include the observation that surface roughening or surface flattening of bituminite are induced by differential broad ion beam (BIB) milling and are dependent on the location and scale of AFM topology measurement. This result highlights our still limited understanding of the effects of BIB milling on sedimentary organic matter and indicates the need for further research before this technique can be advanced as a standard practice in petrographic sample preparation. Collectively, the results of this study illustrate the general applicability and versatility of AFM and CLSM as tools for organic petrology research, specifically for better understanding of the nature and properties of the bituminite maceral.

Kimmeridge↗
USGS2020

Critical shifts in trace metal transport and remediation performance under future low river flows

Exceptionally low river flows are predicted to become more frequent and more severe across many global regions as a consequence of climate change. Investigations of trace metal transport dynamics across streamflows reveal stark changes in water chemistry, metal transformation processes, and remediation effectiveness under exceptionally low-flow conditions. High spatial resolution hydrological and water quality datasets indicate that metal-rich groundwater will exert a greater control on stream water chemistry and metal concentrations because of climate change. This is because the proportion of stream water sourced from mined areas and mineralized strata will increase under predicted future low-flow scenarios (from 25% under Q45 flow to 66% under Q99 flow in this study). However, mineral speciation modelling indicates that changes in stream pH and hydraulic conditions at low flow will decrease aqueous metal transport and increase sediment metal concentrations by enhancing metal sorption directly to streambed sediments. Solute transport modelling further demonstrates how increases in the importance of metal-rich diffuse groundwater sources at low flow could minimize the benefits of point source metal contamination treatment. Understanding metal transport dynamics under exceptionally low flows, as well as under high flows, is crucial to evaluate ecosystem service provision and remediation effectiveness in watersheds under future climate change scenarios.

Environmental Science & Technology↗
USGS2019

U-Pb geochronology of tin deposits associated with the Cornubian Batholith of southwest England: Direct dating of cassiterite by in situ LA-ICPMS

The Cornwall and Devon vein- and greisen-type copper and tin deposits of southwest England are spatially and genetically related to shallow-seated granitic intrusions. These late Variscan intrusions, collectively known as the Cornubian Batholith, extend over 200 km and form a continuous granitic spine from the Isles of Scilly Granite in the west to the Dartmoor Granite in the east. The granitic plutons of the Cornubian Batholith were intruded from ~ 295 to 270 Ma without a major hiatus. Twelve samples of cassiterite (SnO 2 ) were obtained from tin deposits associated with seven different plutons within the Cornubian Batholith for in situ LA-ICPMS U–Pb dating. This study of cassiterite was undertaken to obtain the first results of direct dating of ore mineral to refine the geochronology of tin mineralization in this region. Of the cassiterite samples analyzed, the oldest ages were determined within the Kit Hill and Hingston–Gunnislake Granites in the central part of the Cornubian Batholith. The Hingston–Gunnislake cassiterite, from Drakewalls Mine, was the oldest sample dated at 291.8 ± 3.4 Ma. The next oldest dates, 290.5 ± 2.8 and 288.5 ± 2.9 Ma, were from two cassiterite samples extracted from the adjacent Kit Hill Consolidated Mines within the Kit Hill Granite. At the eastern end of the study area, two cassiterite samples within the Dartmoor Granite produced ages of 286.0 ± 1.8 and 284.1 ± 1.3 Ma. The youngest sample from this study, 275.4 ± 1.6 Ma, is from the Balleswidden Mine within the westernmost Land’s End Granite. The cassiterite dates do not reveal any readily observable relationship between ore ages and geographic relationship from west to east throughout the Cornubian Batholith. Incorporating the associated errors, the geochronology does indicate continuous mineralization within the granites for ~ 21 million years, from ca. 295 to 274 Ma. This span falls within the established period of granitic magmatism of ca. 295 to 270 Ma for the Cornubian Batholith and further confirms the reliability of in situ LA-ICPMS U–Pb dating of cassiterite.

Mineralium Deposita↗
USGS1979

The flow mechanism in the Chalk based on radio-isotope analyses of groundwater in the London Basin

14 C analyses of groundwaters from the Chalk of the London Basin are re-interpreted and the age of the groundwater is revised. Radio-isotope analyses are used to examine the flow mechanism in the aquifer. The evidence supports the view that a network of micro-fissures and larger intergranular pores in the matrix provides a significant part of the water pumped from Chalk wells and the major fissures distribute the water to the wells. Most of the matrix is fine-grained and contains a very old water. This diffuses into the micro-fissures and larger pores and is carried to the wells by the major fissures.

southeast England↗
USGS1977

The age of groundwater in the Lincolnshire Limestone, England and its relevance to the flow mechanism

Groundwater samples from the Lincolnshire Limestone have been analysed for tritium, radiocarbon, and the stable-isotope ratios 13 C 12 C "> 13 C 12 C , 18 O 16 O "> 18 O 16 O and D/H. The age of the water increases in a downgradient direction below overlying confining deposits and reaches a maximum age greater than 25,000 years within 15 km of the outcrop. The δ 13 C ratio ultimately attains the unusually low negative values of −2‰ in a downgradient direction; this is approaching that of the aquifer matrix which is +2.35‰. The reason is believed to be exchange of carbon between the groundwater and the matrix by a continuous process of precipitation and further solution of calcium carbonate. The δ 18 O and δ D ratios imply that recharge of the aquifer during the late Pleistocene took place in the spring and autumn rather than the winter as at present. The data are interpreted by assuming that movement of water through the saturated zone is a combination of flow in fissures and “piston flow” through the micro-fissures and pores of the rock. The mechanism of water movement in the saturated zone is dominated by relatively rapid flow in fissures, but the fissure flow includes a contribution of much older water from “intergranular” storage which enters the fissures from the rock matrix by pressure differentials in the fissure distribution system and by diffusion. The distribution of water of different ages in the aquifer is closely related to recent groundwater abstraction patterns.

Journal of Hydrology↗
USGS1969

Peridotite-gabbro complexes as keys to petrology of mid-oceanic ridges

Two suites of olivine-rich ultramafic and feldspathic rocks appear to be present in the Mid-Atlantic Ridge: one which seems to have alkalic affinities, and one similar to the chromitite- bearing alpine peridotite-gabbro complexes. The similarities of rocks in the two environments—continental and oceanic—imply that much about the petrology of mid-oceanic ridges may be learned from studies of continental complexes, and that silicic rocks have been formed in the mantle. Although gabbros in St. Paul Rocks and similar rocks at Tinaquillo, Venezuela, and Lizard, England, have been interpreted as not comagmatic with intimately associated peridotite by some petrologists, evidence to the contrary at Lizard is discussed. Association of fresh gneissic gabbro, some containing quartz, with talcose serpentinite, amphibole schist, quartz diorite and epidotic but unsheared basalts along the Mid-Atlantic Ridge is believed to indicate presence of alpine-type rocks that occur normally in eugeosynclinal belts. Gabbro, described as partly interlayered with peridotite by gravitational differentiation, forms major parts of three widely separated ultramafic complexes which have been interpreted as slices of oceanic crust and upper mantle: the Troodos massif in Cyprus, the Bowutu Mountains in Papua, and the Camagiiey complex in central Cuba. If, as Dietz has suggested, peridotite and related rocks in eugeosynclines represent fragments of ocean rind formed along mid-oceanic ridges and moved laterally by ocean-floor spreading, gabbro must be an essential constituent of the upper mantle. This could account for many geophysical anomalies, but would complicate some postulated mechanisms involved in ocean-floor spreading.

England↗