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Chemical compositions of rock types as factors in our environment

The types of rocks that form geologic units in the Earth’s crust supply most of the raw materials from which soils are formed and from which water derives its inorganic constituents. The compositions of what we eat and drink thus depend in part upon the compositions of the source rocks. Igneous rocks are formed by crystallization and solidification of a rock melt. Metamorphic rocks are formed by recrystallization of both igneous and sedimentary rocks caused by heat and pressure within the Earth’s crust. Sedimentary rocks are formed chiefly by the deposition in water of weathering and erosion products of pre-existing igneous, metamorphic, or other sedimentary rocks. The compositions of metamorphic rocks are generally similar to the compositions of the rocks that were metamorphosed, and only igneous and sedimentary rock compositions are considered here. Igneous rocks range in SiO 2 content from about 40 to nearly 80 percent, and other constituents increase in amount as SiO 2 decreases. The changes in the other constituents are not large, however, except for the quantitatively unimportant least silicic rocks; these contain conspicuously more magnesium and less aluminum than the other kinds of igneous rocks. Sedimentary rocks range in SiO 2 content from nearly zero for the carbonate rocks to almost 100 percent for quartzite and pure sandstone. Shale and clay contain intermediate amounts of SiO 2 and as much as 25 percent AI 2 O 3 , more than any of the igneous rocks. Carbonate rocks are composed mostly of calcium and magnesium carbonates. The contents of individual trace elements vary widely with rock type. Chromium, titanium, nickel, and cobalt are conspicuously concentrated in low-silica igneous rocks that are quantitatively unimportant. Arsenic, iodine, molybdenum, and selenium are conspicuously concentrated in shale and clay. In addition, most other elements occur in largest amounts in shale and clay compared to other sedimentary rocks, and in amounts nearly equal to those in igneous rocks. Soils derived from different kinds of igneous rocks do not differ from each other as much as do soils derived from different kinds of sedimentary rocks. This is partly because igneous rocks generally are more resistant to weathering than sedimentary rocks that were deposited in water. Some of the important constituents of sedimentary rocks have been precipitated from solution, which makes them more susceptible to weathering and re-solution. Similarly, sedimentary rocks have a greater effect than igneous rocks on the composition of ground water. Determination of areal variations in composition should be more detailed than normal petrologic investigations if the results are to be usable for environmental studies. Statistical principles should be used in planning the sampling, analysis, and interpretation of results.

Book chapter↗

The geochemist’s involvement with the pollution problem

The geochemist can contribute much information of value toward assessing the effect of environment, including inorganic pollution, on health. The average composition of rocks, soils, plants, and water and also the increments of inorganic substances that can be expected in geologic environments of high-metal content are essential for comparison with metal contents of these components of the environment in areas contaminated by various types of inorganic air and water pollution. Background levels of lead, zinc, nickel, chromium, copper, and manganese in soils and in four classes of vegetation have been estimated from collections that were made in remote areas presumed to be free from inorganic contamination. The trace-metal content of soils and plants varies widely in different geologic provinces of the United States; in those areas of high natural mineralization, additions of metals from man-made pollution may compound a possible hazard. Results of sampling in urban areas show that contamination of vegetation by gasoline lead can be expected for at least 1000 ft back from transportation lanes, and that the lead burden is increasing greatly with time. Ore-treatment plants can also be a source of air contamination for several miles downwind and several thousand feet in other directions. Soils of naturally high metal content in a mining district may be further contaminated with both major and minor elements from smelting operations. Recent studies show that volatile elements are released directly to the air from ore deposits in place. Concentrations of mercury, for instance, may be as much as 20 times background for several hundred feet in altitude over ore deposits in which mercury occurs as a relatively minor constituent. The source of inorganic pollution in surface drainage and also in ground water is commonly geologic, as rivers may be contaminated from coal and metal deposits in place and also from mining and smelting operations. More information of the type illustrated should be accumulated and made available to scientists who are working in environmental health, and, in particular, to those involved in the pollution problem. Only by these means can we provide a scientific basis for the enactment of realistic and effective legislation for pollution control.

Book chapter↗

Latitude dependence of the angular dispersion of the geomagnetic field

Changes in the direction of the Earth's magnetic field at a given site are produced in part by wobble of the main geomagnetic dipole, in part by fluctuations in the intensity and direction of the non-dipole field, and in part by changes in the intensity of the main dipole field. These three processes combine to produce an angular variance that is strongly latitude dependent. A method is presented for isolating the contribution due to variation with latitude of the average intensity of the non-dipole field.

Geophysical Journal International↗

Paleomagnetism

This chapter highlights the ways in which rocks become magnetized. It also interprets paleomagnetic results in terms of the theories of polar wandering, continental drift, and an expanding Earth. The chapter describes the salient characteristics and trends of the geomagnetic field during the period of direct observation. Several questions are posed concerning the extension of these properties back to earlier times. Some of these questions can now be answered from the results of paleomagnetic research. The intensity of the main dipole component of the geomagnetic field appears to have been decreasing since well before the period of direct observation. Furthermore, two important properties of the geomagnetic field have been established by spherical harmonic analysis. First, the field is derivable from a potential and, hence, contributions to the total field from currents flowing across the Earth–air interface are negligibly small. Secondly, 2–5% of the field is of external origin and is because of movements of charged particles in the space around the Earth.

Advances in Geophysics↗

Paper A: Terrestrial features of impact origin

Craters made by meteorites striking the earth are discussed, with attention given to geological evidence for discriminating them from craters formed by other structural processes. The major known meteorite craters are briefly described, as well as other features that are considered probable or possible meteorite craters on the basis of less conclusive evidence. Separate tabulations are given of (1) topographic features either known to be meteorite craters, or considered as possible meteorite craters through lack of conclusive evidence to the contrary, and (2) topographic features once considered to be possible meteorite impact craters, but which are now believed to be of other origin.

Conference Paper↗