Geology topics
Source-linked reports with geographic coverage including Delaware.
Using 3D Elevation Program data, a modern illustration of each State's landscape showcases its elevation differences in vivid detail. Each State has been consistently adjusted and colorized according to its highest and lowest elevations, accentuating differences even in States with low relief. To further emphasize landforms, shaded relief has been added on top of the elevation colors.
Dinoflagellate cyst palynology and lithostratigraphy from three continuously cored boreholes (Blackbird, Smyrna, and Woodland Beach), supplemented by calcareous nannofossil biostratigraphic data, were used to refine the age and correlation of three Paleocene-Eocene formations in northern Delaware: the Vincentown, Manasquan, and Shark River. Lithologic logs reveal significant facies changes in the upper Paleocene Vincentown Formation over a short distance (*9 km) southeastward, transitioning from very permeable glauconite-quartz-shell-rich sands that form the regionally important Rancocas/Aquia aquifer to much less permeable muddy sands and sandy muds. These lithologic changes represent a shift from nearshore, clear, warm-water, carbonate-rich sand shoals to mud-dominated deeper-water, offshore shelfal environments. Dinocyst assemblages including Areoligera gippingensis, Cribroperidinium giuseppei, and Stenodinium meckelfeldensis confirm the Paleogene ages and track these paleoceanographic changes from shallow coastal settings updip to neritic or outer marine settings downdip. The Vincentown Formation is unconformably overlain by the lower Eocene Manasquan Formation, which consists predominantly of silt and clay with relatively consistent lithology across the study area, representing general neritic or open marine conditions. Lithology, dinoflagellate cyst assemblages, and calcareous nannofossil data indicate that the Marlboro Clay and its record of the onset of the Paleocene-Eocene Thermal Maximum (PETM) global warming event is absent from the Paleocene-Eocene transition at these sites, with an unconformity marking the boundary between the Vincentown and Manasquan formations. The youngest unit examined, the Eocene Shark River Formation, unconformably overlies the Manasquan Formation and consists of interbedded clayey silts and sands, with dinoflagellate assemblages suggesting a return to coastal or inner neritic settings. Calcareous nannofossil zones recognized from the Woodland Beach core corroborate the depositional ages determined using dinoflagellates throughout the sequence, confirming the chronostratigraphic framework for these important coastal plain units.
The State of Delaware has encouraged agricultural conservation practices to improve nutrient uptake by crops and mitigate nutrient transport to groundwater in the surficial aquifer. To study recent changes in groundwater quality, the U.S. Geological Survey and the Delaware Department of Agriculture (DDA) developed a network of shallow wells near agricultural areas throughout the Delaware Coastal Plain. This network was designed to characterize water quality related to agricultural practices and to detect any recent changes in shallow groundwater quality, in particular groundwater nitrate concentrations. The shallow well network was first sampled in 2014 and resampled in 2019. In 2019, field parameters (including dissolved oxygen, pH, specific conductance, and temperature), major ions, nutrients, stable isotopes of water, and isotopes of nitrate were measured in groundwater samples collected between October and December. Wells were organized into three groups based on their geochemical characteristics measured in 2014: the Agricultural, Urban, and Mixed Groups. Results from the 2019 sampling showed little change in water quality from the 2014 sampling. Land-use factors continued to be the driving influence between groups. Groundwater moves slowly and changes in groundwater quality are likely to respond slowly to changes in conservation practices. Continued sampling of both groundwater quality in this network and monitoring land management practices can help detect groundwater quality trends in the future.
Saltwater intrusion (SWI) is a well-studied phenomenon that threatens the freshwater supplies of coastal communities around the world. The development and advancement of numerical models has led to improved assessment of the risk of salinization. However, these studies often fail to include the impact of surface waters as potential sources of aquifer salinity and how they may impact SWI. Based on field-collected data, we developed a regional, variable-density groundwater model using SEAWAT for east Dover, Delaware. In this location, major users of groundwater from the surficial aquifer are the City of Dover and irrigation for agriculture. Our model includes salinized marshland and tidal streams, along with irrigation and municipal pumping wells. Model scenarios were run for 100 years and included changes in pumping rates and sea-level rise (SLR). We examined how these drivers of SWI affect the extent and location of salinization in the surficial aquifer by evaluating differences in chloride concentration near surface waters and the subsurface freshwater-saltwater interface. We found the presence of the marsh inverts the typical freshwater-saltwater wedge interface and that the edge of the interface did not migrate farther inland. Additionally, we found that tidal streams are the dominant pathways of SWI at our site with salinization from streams being exacerbated by SLR. Our results also show that spatial distribution of pumping affects both the magnitude and extent of salinization, with an increase in concentrated pumping leading to more intensive salinization than a more widely distributed increase of the same total pumping volume.
We present an annotated checklist of fleas (Siphonaptera) known to occur in the state of Delaware based on an examination of Siphonaptera collections at the University of Delaware and the Carnegie Museum of Natural History, as well as new specimens of fleas we collected from wildlife, other hosts, and tick flags. We review published records and compile them herein with our new records, which include 3 species previously unreported from Delaware. With these additions, there are now 18 flea species from 19 avian and mammalian hosts documented from Delaware.
Background Monitoring movement across an organism’s ontogeny is often challenging, particularly for long-lived or wide-ranging species. When empirical data are unavailable, general knowledge about species’ ecology may be used to make assumptions about habitat use across space or time. However, inferences about habitat use based on population-level ecology may overlook important eco-evolutionary contributions from individuals with heterogenous ethologies and could diminish the efficacy of conservation and management. Methods We analyzed over a decade of acoustic telemetry data to understand individual differences in habitat use of federally endangered adult Atlantic sturgeon ( Acipenser o. oxyrinchus ) in the Delaware and Hudson rivers during spawning season. In particular, we sought to understand whether sex or natal origin could predict patterns in habitat use, as there is a long-held assumption that adult Atlantic sturgeon seldom stray into non-natal rivers. Results In both rivers, migration timing, spawning habitat occupancy, and maximum upstream migration distance were similar between natal and non-natal individuals. While non-natal individuals represented only 13% of fish detected in the Hudson River, nearly half of all tagged fish detected in the Delaware River were non-natal and generally occupied freshwater habitats longer than natal individuals. In both systems males had more heterogenous patterns of habitat use and longer duration of occupancy than did females. Conclusions This study demonstrates the importance of non-natal rivers for fulfilling ontogenetic habitat requirements in Atlantic sturgeon. Our results may also highlight an opportunity to improve conservation and management by extending habitat designations to account for more heterogenous patterns in individual habitat use in non-natal freshwater environments.
Delaware’s status as the first State to ratify the U.S. Constitution is a well-known point of pride. “The First State” is among Delaware’s nicknames, alongside “the Blue Hen State,” “the Diamond State,” and “the Small Wonder,” the last of which relates to Delaware’s diminutive land area—larger only than Rhode Island. Less well known, perhaps, is Delaware’s geographic distinction as the State with the lowest average elevation. Most of its land area rises no more than 80 feet above sea level. In fact, about 32,000 acres of Cypress Swamp, sometimes called the Great Cypress Swamp, stretch across its southern border. These low elevations put Delaware at particular risk of sea level rise. Sea levels are rising more quickly than average for the Mid-Atlantic region, which includes Delaware. The State has seen its coastal waters rise more than 1 foot over the past century. The Landsat Program’s 50-year archive of repeat Earth observations offers an indispensable record of land change along the Nation’s coastlines. Imagery collected by Landsat satellites can inform studies of coastline losses, flooding extents, and land cover conversions. Landsat data also can support plans to mitigate those effects.
Reliable estimates of the magnitude of peak flows in streams are required for the economical and safe design of transportation and water conveyance structures. In addition, reliable estimates of the magnitude of low flows at defined frequencies and durations are needed for meeting regulatory requirements, quantifying base flows in streams and rivers, and evaluating time of travel and dilution of toxic spills. This report, in cooperation with the Delaware Department of Transportation and the Delaware Geological Survey, presents methods for estimating the magnitude of peak flows and low flows at defined frequencies and durations on nontidal streams in Delaware, at locations both monitored by streamflow-gage sites and ungaged. Methods are presented for estimating (1) the magnitude of peak flows for return periods ranging from 2 to 500 years (50-percent to 0.2-percent annual-exceedance probability), and (2) the magnitude of low flows as applied to 7-, 14-, and 30-consecutive day low-flow periods with recurrence intervals of 2, 10, and 20 years (50-, 10-, and 5-percent annual non-exceedance probabilities). These methods are applicable to watersheds that exhibit a full range of development conditions in Delaware. The report also describes StreamStats, a web application that allows users to easily obtain peak-flow and low-flow magnitude estimates for user-selected locations in Delaware. Peak-flow and low-flow magnitude estimates for ungaged sites are obtained using statistical regression analysis through a process known as regionalization, where information from a group of streamflow-gage sites within a region forms the basis for estimates for ungaged sites within the same region. Ninety-four streamflow-gage sites in and near Delaware with at least 10 years of nonregulated annual peak-flow data were used for the peak-flow regression analysis, a subset of the 121 sites for which peak-flow estimates were computed. These sites included both continuous-record streamflow-gage sites as well as partial record sites. Forty-five streamflow-gage sites with at least 10 years of nonregulated low-flow data available were used for the low-flow regression analyses, a subset of the 68 sites for which low-flow estimates were computed. Estimates for gaged sites are obtained by combining (1) the station peak-flow statistics (mean, standard deviation, and skew) and peak-flow estimates using the recent Bulletin 17C guidelines that incorporate the Expected Moments Algorithm with (2) regional estimates of peak-flow magnitude derived from regional regression equations and regional skew derived from sites with records greater than or equal to 35 years. Example peak-flow estimate calculations using the methods presented in the report are given for (1) ungaged sites, (2) gaged sites, (3) sites upstream or downstream from a gaged location, and (4) sites between gaged locations. Estimates for low-flow gaged sites are obtained by combining (1) the station low-flow statistics (mean, standard deviation, and skew) and low-flow estimates with (2) regional estimates of low-flow magnitude derived from regional regression equations. Example low-flow estimate calculations using the methods presented in the report are given for (1) ungaged sites, (2) gaged sites, (3) sites upstream or downstream from a gaged location, and (4) sites between gaged locations. A total of 54 sites in the Coastal Plain region were used to develop peak-flow regressions for the region and 40 sites were used for the Piedmont region. Similarly, 24 sites were used for low-flow regression equation development in the Coastal Plain, with 21 in the Piedmont. Peak and low-flow site inclusion in the Coastal Plain tended to be more restricted with tidal influence and ranges of basin characteristics, including drainage area, limiting regression equation development and application. Regional regression equations for peak flows and low flows, as applicable to ungaged sites in the Piedmont and Coastal Plain Physiographic Provinces in Delaware, are presented. Peak-flow regression equations used variables that quantified drainage area, basin slope, percent area with well-drained soils, percent area with poorly drained soils, impervious area, and percent area of surface water storage in estimating peak-flow estimates, whereas low-flow regression equations used only drainage area and percent poorly drained soils in the estimation of low flows. Average standard errors for peak-flow regressions tended to be lower than those for low- flow regressions, with lower errors in the Piedmont region for both peak- and low-flow regressions. For peak-flow estimates, a sensitivity analysis of Piedmont regression equation estimates to changes in impervious area is also presented. Additional topics associated with the analyses performed during the study are discussed, including (1) the availability and description of 32 basin and climatic characteristics considered during the development of the regional regression equations; (2) the treatment of increasing trends in the annual peak-flow series identified at 18 gaged sites and inclusion in or exclusion from the regional analysis; (3) regional skew analysis and determination of regression regions; (4) sample adjustments and removal of sites owing to regulation and redundancy; and (5) a brief comparison of peak- and low-flow estimates at gages used in previous studies.
The U.S. Geological Survey, in cooperation with the Delaware Department of Natural Resources and Environmental Control and the Delaware Geological Survey, conducted a groundwater-quality investigation to (1) describe the occurrence and distribution of PFAS, and (2) document any changes in groundwater quality in the Columbia aquifer public water-supply wells in the Delaware Coastal Plain between 2000 and 2008 and between 2008 and 2018. Thirty public water-supply wells located throughout the Columbia aquifer of the Delaware Coastal Plain were sampled from August through November 2018. Groundwater collected from the wells was analyzed for the occurrence and distribution of 18 per- and polyfluorinated alkyl substances (PFAS) as well as groundwater age. Descriptive statistical analyses were performed to assess PFAS analytical results within the well network and the combined perfluorooctanoic acid (PFOA) and perfluorooctane sulfonate (PFOS) concentrations were compared to the U.S. Environmental Protection Agency’s (EPA) health advisory level (HAL) for informational purposes only and not for evidence of compliance or noncompliance with Federal regulations. The EPA’s HAL is a health-based reference level for public drinking water as supplied to customers and is not applied to source (raw) water. Groundwater-age data were compared for sites sampled in 2000, 2008, and 2018 to document any changes. All samples were analyzed for 18 PFAS using EPA Method 537 (modified). Forty-four percent of the analyzed PFAS were detected in the study well network. Sixteen of the sampled wells have one or more PFAS detections, and as many as eight different PFAS were found in a single sample. Wells with a higher number of PFAS detected (five or more) were in New Castle and Sussex Counties. The PFAS most frequently detected were PFOA, with 47 percent detection; perfluorohexanoic acid (PFHxA), with 33 percent detection; and PFOS and perfluorohexane sulfonate (PFHxS), with 27 percent detection each. PFAS concentrations were below 1,000 parts per trillion (ppt). Two wells exceeded the EPA’s lifetime-drinking water health advisory level of 70 ppt for combined concentrations of PFOA and PFOS. The average age of groundwater entering the screens of the supply wells sampled in 2018 ranged from 8.2 to 45.8 years, with a median groundwater age of 25.7 years. Groundwater age was positively correlated with well depth and negatively correlated with dissolved oxygen. Groundwater age and PFAS concentrations were negatively correlated in the Columbia aquifer. Data from the 23 resampled wells indicate a significant positive difference in the average modeled groundwater-sample-age results. The average groundwater age from samples collected in 2018 was generally 5 years older than the average groundwater age from samples collected in 2008. The same pattern was found during cycle two (2008) of this study, where the 2008 groundwater age was on average 7 years older than the samples collected in 2000. The distribution of groundwater sample ages among the 17 trend wells and during the three study cycles (2000, 2008, and 2018) indicates that sample-age medians were statistically different from zero; well-water sample-age data show a slight increase in groundwater sample age.
Impacts of ecological mismatches should be most pronounced at points of the annual cycle when populations depend on a predictable, abundant, and aggregated food resource that changes in timing or distribution. The degree to which species specialize on a key prey item, therefore, should determine their sensitivity to mismatches. We evaluated the hypothesis that the effects of ecological mismatch during migratory stopover are mediated by a species’ foraging ecology by comparing two similar long‐distance migratory species that differ in their foraging strategies during stopover. We predicted that a specialist foraging strategy would make species more sensitive to effects of mismatch with a historically abundant prey, while an active, generalist foraging strategy should help buffer against changing local conditions. We estimated arrival times, start of mass gain, and rate of mass gain during spring stopover in Delaware Bay, USA. At this site, shorebirds feed on a temporally aggregated food resource (horseshoe crab Limulus polyphemus eggs), the timing of which is linked to water temperature; red knot ( Calidris canutus rufa ) specializes on these while the ruddy turnstone ( Arenaria interpres ) feeds more generally. We used a hierarchical nonlinear model to estimate the effect of mismatch between shorebird arrivals and timing of crab spawning on the timing and rate of mass gain over 22 yr. In years with cooler water temperature, crabs spawned later, which was associated with later and faster mass gain for the knots. Turnstones exhibited less inter‐annual variation in the timing and rate of mass gain than knots, and we found no relationship between mass gain dynamics and the availability of horseshoe crab eggs for this generalist species. Long‐distance migrants rely on predictable resources en route and even when these linkages are simple and predictable, populations can be vulnerable to change; these results suggest that generalist foraging strategies may buffer migratory species against phenological mismatch. We provide a framework to evaluate population responses to changes in prey phenology at sites vulnerable to climatic change.
Personnel at Beebe Healthcare in Lewes, Delaware, collected surf zone injury (SZI) data for eight summer seasons from 2010 through 2017. Data include, but are not limited to, time of injury, gender, age, and activity. More than 2000 SZI events, including 196 spinal injuries and 6 fatalities, occurred at the five most populated beaches along the 25 miles of Atlantic-fronting coast. SZI are predominantly wave related incidents associated with wading (50.1%), body surfing (18.4%), and body boarding (13.3%). The episodic nature of SZI indicate the importance of linking the environmental conditions and human behavior in the surf zone to predict days with high injury rates. Higher order statistics are necessary to effectively consider all associated factors related to SZI. Two Bayesian networks (BN) were constructed to model SZI and predict changes in injury rate (proportion of injuries to bathers) and injury likelihood (probability of at least one injury occurrence) on an hourly basis. The models incorporate environmental data collected by weather stations, wave gauges, and researcher personnel on the beach. The models include prior (e.g., historic) information to infer relationships between provided parameters. Sensitivity analysis determined the most influential parameters related to injury rates were significant wave height, foreshore slope, and water temperature. Exposure parameters (e.g., air temperature) influenced the number of people in the water, resulting in strong correlation between injury likelihood and the related meteorological conditions (variance reduction > 0.4%). Log likelihood ratio (LLR) scores indicate the network predicts SZI likelihood during any specified hour with more skill than prior predictions with the best performing model improving prediction 69.1% of the time (LLR = 69.1%). An alternative BN predicting injury rate performed worse with the prior probability model out predicting the injury rate network (positive LLR = 36.7%). Issues persist with predicting SZI that have an LLR ≪ -1 (< 5% of 2017 injuries) and occur in conditions different than when most other SZI occur. Better understanding of SZI will improve awareness techniques to both educate beachgoers and assist beach patrol decision making during high risk conditions.
All ecological measurements are subject to error; the effects of missed detection (false negatives) are well known, but the effects of mistaken detection (false positives) are less understood. Long-term capture–recapture datasets provide valuable ecological insights and baselines for conservation and management, but where such studies rely on noninvasive re-encounters, such as field-readable color bands, there is the potential to accumulate detection errors as the length of the study and number of tags deployed increases. We investigated the prevalence and effects of misreads in a 10-yr dataset of Red Knots ( Calidris canutus rufa ) marked with field-readable leg flags in Delaware, USA. We quantified the effects of misreads on survival estimation via a simulation study and evaluated whether removal of individuals only reported once in a year (potential misreads) influenced survival estimation from both simulated datasets and our case study data. We found overall apparent error rates of 0.31% (minimum) to 6.6% (maximum). Observer-specific error rates and the variation among observers both decreased with the number of flags an observer recorded. Our simulation study showed that misreads lead to spurious negative trends in survival over time, particularly for long-term studies. Removing all records in which a flag was only recorded once in a sampling occasion reduced bias and eliminated spurious negative trends in survival but also reduced precision in survival estimates. Without data filtering, we found a slight decrease in Red Knot annual survival probability from 2008 to 2018 (β = −0.043 ± 0.03), but removing all single-observation records resulted in no apparent trend (β = −0.0074 ± 0.02). Spurious trends in demographic rates could influence inference about population trajectories and resultant conservation decision-making. Data filtering could eliminate errors, but researchers should carefully consider the tradeoff between precision obtained by larger sample sizes and potential bias due to misreads in their data.
To determine the impacts of groundwater-borne nutrients on phytoplankton biomass and community structure, we conducted a series of mesocosm experiments in the Inland Bays of Delaware. Four treatments were tested, including mesocosms coupled directly to submarine groundwater seepage, mesocosms with the addition of pumped submarine groundwater, mesocosms with the addition of phosphate, and control mesocosms with no nutrient addition. We measured chlorophyll a concentrations as a proxy for overall biomass and used genetic sequencing techniques to characterize the phytoplankton community structure. Groundwater carried a high N load to the estuary with NO 3 - up to 295 µmol l -1 and NH 4 + up to 55 µmol l -1 . As a result, treatment mesocosms had elevated NO 3 - and NH 4 + , while control mesocosms were relatively low in nutrients. In June, the highest chlorophyll a concentrations occurred in mesocosms attached to seepage meters after 3.5 d, with significant differences across all treatments. In August, groundwater-amended mesocosms reached the highest biomass concentrations, which peaked after 3 d. There were significant differences across all treatments, except control and phosphate-amended mesocosms which remained unchanged. Community sequence data showed that species assemblage was also impacted by availability of nutrients, with significant differences in community structure for mesocosms receiving nutrients vs. control mesocosms in both June and August experiments. Harmful algal species proliferated in high nutrient treatments, including Cylindrotheca closterium , Karlodinium veneficum , Nitzschia spp., and Heterocapsa spp. While the general relationship between nutrient supply and biomass production is well known, we demonstrate the role groundwater-borne nutrients and sediment processes play in shaping community structure in estuarine primary producers and in promoting harmful algal blooms.
Structured decision making is a systematic, transparent process for improving the quality of complex decisions by identifying measurable management objectives and feasible management actions; predicting the potential consequences of management actions relative to the stated objectives; and selecting a course of action that maximizes the total benefit achieved and balances tradeoffs among objectives. The U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service, applied an existing, regional framework for structured decision making to develop a prototype tool for optimizing salt marsh management decisions at the Bombay Hook National Wildlife Refuge in Delaware. Refuge biologists, refuge managers, and research scientists identified multiple potential management actions to improve the ecological integrity of eight salt marsh management units within the refuge and estimated the outcomes of each action in terms of performance metrics associated with each management objective. Value functions previously developed at the regional level were used to transform metric scores to a common utility scale, and utilities were summed to produce a single score representing the total management benefit that would be accrued from each potential management action. Constrained optimization was used to identify the set of management actions, one per salt marsh management unit, that would maximize total management benefits at different cost constraints at the refuge scale. Results indicated that for the objectives and actions considered here, total management benefits would increase consistently up to approximately \$300,000, but that further expenditures would yield diminishing return on investment. Management actions selected within optimal portfolios at total costs less than \$300,000 included hydrologic restoration, recontouring adjacent uplands to facilitate marsh migration, and burning the marsh. The prototype presented here provides a framework for decision making at the Bombay Hook National Wildlife Refuge that can be updated as new data and information become available. Insights from this process may also be useful to inform future habitat management planning at the refuge.
The 30 November 2017 Delaware earthquake with magnitude MW 4.2 occurred beneath the northeastern tip of the Delmarva Peninsula near Dover, Delaware. The earthquake and its aftershocks provide an opportunity to evaluate seismicity in a passive margin setting using much improved coverage by high-quality permanent broadband seismometers at regional distance ranges in the central and eastern United States. This is the largest instrumentally recorded earthquake in Delaware and triggered a collaborative rapid-response effort by seismologists at five institutions along the mid-Atlantic. As a result of this effort, eighteen portable seismographs were deployed in the epicentral region within 24 hours of the mainshock. High-quality seismic recordings at over 380 permanent regional broadband seismographic stations in the eastern United States show a remarkably small decrease in amplitude with distance between 800-2000 km. The mainshock focal mechanism shows predominantly strike-slip motion with a significant thrust component. The orientation of the subhorizontal P-axis is consistent with that of earthquakes in the nearby Reading-Lancaster seismic zone in Pennsylvania, but are rotated counter-clockwise about 45º from that of the MW 5.8 Mineral, Virginia earthquake. We detected small aftershocks below the normal event detection threshold by using a waveform cross-correlation detection method. This demonstrated the effectiveness of this approach for earthquake studies and hazard evaluation in the eastern United States. Based on their waveform similarities, repeating earthquakes with magnitudes greater than 1.5 are detected in 2010, 2015, and 2017. While there is a large time interval between events, 5 years and 2.2 years respectively, the events occur within a spatially tight cluster located near the 2017 Dover DE earthquake mainshock.
The purpose of this study was to evaluate the effects of irrigation and cover crops as conservation practices on water quality in groundwater and streams. Bucks Branch, a stream in the Nanticoke River watershed in southwestern Delaware, was identified as having one of the highest concentrations of nitrate in all surface-water sites sampled by the Delaware Department of Natural Resources and Environmental Control (DNREC). The study site is on two adjacent fields bordering Bucks Branch, one that has used irrigation since 2000 and one with dryland farming; both under conservation tillage and long-term rotation of corn, soybean, and small grain crops. A streamgage was installed near the study site fields to measure streamflow and water quality. The study area is typical of farming practices and environmental conditions throughout much of the intensively farmed agricultural land of the Coastal Plain of Delaware and surrounding parts of Maryland. Monitoring was conducted from January 2014 through June 2016. Corn was grown on both fields during the two growing seasons of the study period, and cover crops were planted before or shortly after harvest on both fields. During the second year of data collection, the effects of radish and rye grass cover crops on nutrient transport were studied. The combined results from data collected for this study show that water and nitrate moved below the root zone year round when soil moisture was high, especially after significant rainfall and frequently after irrigation. Soil water sampled 2 to 3 weeks after nutrients were applied had nitrate concentrations greater than 50 milligrams per liter as nitrogen (mg/L as N) and may be a significant source of nitrate to groundwater. Whereas recharge containing elevated nitrate concentrations also occurred under the dryland field, it was less frequent and of lower concentration than recharge under the irrigated field. Nitrate was present in all groundwater samples from these sites. Groundwater estimated to have recharged within 10 years or less had higher median concentrations of nitrate than in older water samples. The oldest groundwater encountered was over 30 years old, and had traveled along the longest, deep flowpaths from upland fields to the stream. The median nitrate concentration was 18 mg/L as N in younger water (less than 10 years old) beneath the irrigated field, compared to about 10 mg/L as N in younger water beneath the dryland field. Samples from the shallow upland wells in both study fields showed little, if any, evidence of denitrification. Several samples from deeper wells and from wells near forested riparian zone wetlands that border both fields did show partial denitrification. A mixing model estimated that between 12 and 22 percent of the nitrate discharging to the stream was lost through uptake and denitrification upstream of the streamgage on Bucks Branch. Continuous data collected at this site and evidence of denitrification in the surface-water samples showed a greater potential for loss of nitrate during the warmer months than the colder months. This pattern was similar to that seen below the streamgage at the most downstream site in the watershed. A mixed cover crop of radishes and rye was planted prior to removal (radishes) and just after harvest (rye) of the corn crop on the irrigated field. Rye grass was planted shortly after crop harvest on the dryland field. Cover crop biomass samples collected while radishes were growing and after they were killed by freezing temperatures indicates that the early planted radish crop effectively scavenged available nitrogen from the soil. Whereas radish biomass initially held more nitrogen than rye, at 55 to 8 pounds per acre, respectively, leaching of inorganic nitrate following radish die-off was minimal. Soil-water nitrate concentrations during the cover-crop growing period were lower than during the growing season prior to planting of the cover crop. There also was an increase in soil fertility and dissolved organic nitrate in samples of soil water that was likely related to increased soil microbial metabolism. Results indicate that cover crops stored plant nutrients over the winter and did not increase shallow groundwater concentrations of nitrate. Although conservation practices such as cover crops and nutrient management have been applied to these fields, there was still significant leaching of nitrate to groundwater, especially under the irrigated field. This will likely continue to be a challenge in this area and other parts of the Coastal Plain where soil moisture capacity is relatively low and managing irrigation around rainfall is difficult. Cover crops, when planted in standing corn, are one practice that can effectively pull nitrate from below the root zone to the top layer of soil, thus limiting the amount of potential nitrate leaching to groundwater. Irrigation management that would lower average soil moisture conditions during the growing season also could potentially limit nitrogen transport.
The U.S. Geological Survey, in cooperation with the Delaware Department of Agriculture, developed a network of wells to monitor groundwater quality in the surficial aquifer of the Delaware Coastal Plain. Well-drained soils, a flat landscape, and accessible water in the Delaware Coastal Plain make for a productive agricultural setting. As such, agriculture is one of the largest industries in the State of Delaware. This setting enables the transport of chemicals from agriculture and other land uses to shallow groundwater. Efforts to mitigate nutrient transport to groundwater by the implementation of agricultural best management practices (BMPs) have been ongoing for several decades. To measure the effectiveness of BMPs on a regional scale, a network of 48 wells was designed to measure shallow groundwater quality (particularly nitrate) over time near agricultural land in the Delaware Coastal Plain. Water characteristics, major ions, nutrients, and dissolved gases were measured in groundwater samples collected from network wells during fall 2014. Wells were organized into three groups based on their geochemical similarity and these groups were used to describe nitrate and chloride concentrations and factors that affect the variability among the groups. The results from this study are intended to establish waterquality conditions in 2014 to enable comparison of future conditions and evaluate the effectiveness of agricultural BMPs on a regional scale.
Water samples were collected and analyzed for arsenic and radon from 36 private, mostly domestic wells that tap the Rancocas aquifer in southern New Castle and northern Kent Counties, Delaware, during the summer of 2015. Both arsenic and radon are from natural mineral sources, in particular glauconitic and other marine-derived sediments, which are important components of the geologic formations comprising the Rancocas aquifer. Routine testing of domestic wells is not required in Delaware; as a result, many homeowners are not aware of potential water-quality problems with these chemicals in their well water. Arsenic has previously been detected at levels of potential concern for human health in this aquifer in adjacent parts of Maryland where it is referred to as the Aquia aquifer. Arsenic and radon also have previously been detected in several Rancocas aquifer wells in Delaware. The Delaware Department of Natural Resources and Environmental Control intends to use the data from this project to better identify areas with potential for levels of concern for domestic well owners. This report includes chemical results and maps showing the distribution of sampled wells and concentrations of arsenic and radon. All data collected for this study also are available in the U.S. Geological Survey’s National Water Information System database. Arsenic was detected above the minimum reporting limit of 0.1 micrograms per liter (µg/L) in 34 of the 36 wells sampled with concentrations ranging from about 0.11 to 27 µg/L. In 15 of the samples, arsenic concentrations were at or above the U.S. Environmental Protection Agency (EPA) Maximum Contaminant Level (MCL) of 10 µg/L for public wells. Most of the higher concentrations are clustered along a band running from the southwest to northeast in the southern part of the study area. Radon, which is an inert gas derived from radium, was detected in all water samples with concentrations ranging from 85 to 1,870 picocuries per liter (pCi/L). Currently, the EPA has not set a MCL for radon in public water systems. There were no samples where radon was detected at a concentration exceeding the proposed alternative MCL of 4,000 pCi/L. Samples from 16 of 36 wells were above the lower proposed MCL of 300 pCi/L. Most of these samples were from wells greater than 200 feet deep located in a similar part of the aquifer as the higher concentrations of arsenic along an east-northeasterly line in the southern part of the study area.