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Research about Colorado

Source-linked reports with geographic coverage including Colorado.

At least 91 records · Page 5Linked to original sources

A Colorado Front Range grassland exhibits decreasing dominance of cheatgrass (Bromus tectorum) over time

Causes, consequences, and potentials for recovery from invasions by the invasive annual grass, cheatgrass ( Bromus tectorum ), in western North America have been extensively documented. The vast majority of these studies have come from regions where yearly precipitation is dominated by “winter-wet” patterns, but this species has also demonstrated its ability to invade plant communities in “spring/summer-wet” areas as well. In grasslands of the Front Range of Colorado, a region experiencing a “spring/summer-wet” precipitation pattern, cheatgrass can exploit early-season soil moisture, but moderate rainfall continues into the growing season beyond the time of cheatgrass senescence. In this study, we measured how cheatgrass dominance changed over a 13-year interval in a disturbed meadow along the Front Range of Colorado with a “spring/summer-wet” precipitation pattern. Cheatgrass cover declined in absolute abundance by about 50% while total vegetation cover increased over this time period. The site was neither grazed nor burned during this interval. A “spring/summer-wet” precipitation pattern with high interannual variation in amounts occurred during the study, but no relationships between the seasonality or amounts of precipitation and the directional decline in cheatgrass abundance were observed. Rainout shelter manipulations showed that the seasonality of precipitation influenced cheatgrass abundance, with winter drought treatments reducing cheatgrass cover relative to plots that experienced summer drought treatments. The cheatgrass decline corresponded with a lesser decline in native grass cover and no change in native forb cover, while the abundance of non-native perennial grasses and forb species increased over the study interval. Although cheatgrass can invade communities across broad climatic gradients following disturbance, results from this study show that the persistence of cheatgrass within invaded areas may depend on the seasonality of precipitation and plant communities that vary across these gradients.

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Groundwater-level elevations in the Denver Basin bedrock aquifers and Upper Black Squirrel Creek alluvial aquifer, El Paso County, Colorado, 2021–24

El Paso County is the second-most populous county in Colorado and is projected to grow another 15 percent by 2030. Within El Paso County is the Upper Black Squirrel Creek Designated Groundwater Basin (Black Squirrel Basin), an area where surface water is scarce and water users rely primarily on groundwater from five different aquifers (the Upper Black Squirrel Creek alluvial aquifer and four bedrock aquifers within the Denver Basin aquifer system: the lower Dawson, Denver, Arapahoe, and Laramie-Fox Hills aquifers) to meet their needs. Currently (2024), land within the Upper Black Squirrel Creek Basin is primarily used for rural grazing and agriculture; however, municipal development is ongoing. In 2021, the U.S. Geological Survey, in cooperation with the Upper Black Squirrel Creek Ground Water Management District, began a study to establish a baseline dataset and assess the groundwater resources of the aquifers within the Black Squirrel Basin. A network of 39 wells was established in 2021; discrete groundwater-level measurements were made bimonthly. Nine of the 39 wells were equipped with pressure transducers to record hourly groundwater-level data. Seven wells had statistically significant seasonal trends, and trends at 3 wells were negative. For the discrete data, 16 wells had a significant trend for the study period, and 4 wells had negative trends. For the time-series data, 8 wells had significant trends, and 3 wells had negative trends. Potentiometric surface maps were created for this study using discrete, static groundwater levels measured in April 2023. These maps showed the estimated groundwater flow direction from the north-northwest to the south-southeast in the alluvial aquifer and from the northwest to the east-southeast for the lower Dawson and Denver aquifer wells. This study indicates the potential benefit of monitoring wells in the areas near municipal pumping. Additional monitoring could lead to a better understanding of connectivity between aquifers and be an important tool for assessing long-term sustainability of groundwater use.

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High-resolution multi-pollutant mapping in Denver, Colorado

Characterizing traffic-related air pollutants (TRAPs), which significantly impact health, and greenhouse gases (GHGs) can be challenging in urban environments. Mobile monitoring has the potential to capture the spatial distribution of these pollutants. We present results from a campaign using the Denver Mobile Monitoring Laboratory (DMML) in the summer of 2023 when we measured ultrafine particles (UFPs), black carbon (BC), ozone (O 3 ), methane (CH 4 ) , and carbon dioxide (CO 2 ) concentrations in Denver, CO. Despite our campaign being brief, we obtained several interesting results. We observed elevated UFP and BC concentrations on major roads. In contrast, O 3 concentrations were higher on neighborhood streets and roads and in the industrial neighborhood of Commerce City. We consistently observed elevated CH 4 concentrations (>2.5 ppm) on highway I-70, suggesting the presence of a previously unknown major source of CH 4 . The CH 4 concentrations measured in our campaign did not align with those from an overlapping aerial campaign, suggesting that mobile monitoring is crucial to capture important, potentially intermittent CH 4 hotspots in cities. We evaluated if trees mitigated pollution concentrations, as planting trees is a key policy initiative of the city of Denver. We observed significant negative associations between tree canopy coverage and UFPs, BC, and CH 4 , and a positive association with O 3 when using linear mixed-effects regression models. Our work highlights the importance of investigating the role of tree canopy coverage to mitigate TRAPs.

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Specific conductance and water type as a proxy model for salinity and total dissolved solids measurements in the Upper Colorado River Basin

Salinity levels in streams and tributaries of the Colorado River Basin have been a major concern for the United States and Mexico for over 50 years as the water is used by millions of people for domestic and industrial purposes. Recently, the United States Geological Survey expanded stream monitoring networks including the number of sites where continuous (15-min) specific conductance is measured in the Colorado River Headwaters and Gunnison River Basin located east of the Colorado-Utah state line (hereafter, UCOL). The purpose of this study is to apply a proxy method to determine salinity and total dissolved solids concentrations from specific conductance and major-ion water type that is applicable to monitoring sites in the UCOL. Within the UCOL, carbonate rich waters originate from high-elevation mountain regions in the eastern UCOL, calcium sulfate rich waters are mainly found in the western half of the UCOL including the Gunnison River Basin, and waters of variable composition are found along the lower reaches of the Colorado River and Eagle River. It was found that the chemistry of sites with variable composition changes seasonally and is impacted by both geogenic and anthropogenic processes, potentially including seasonal application of deicing road salt. The specific conductance – water type proxy can be used to reliably (±10 %) predict salinity and total dissolved solids at 66 monitoring sites in the UCOL. The method is rapid, can generate high-resolution measurements, is cost-effective, and greatly expands the utility of specific conductance measurements. Furthermore, the high-resolution estimates provide an accurate approach to determining long-term salinity loads as short-term events are accurately accounted for.

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Properties of solid bitumen formed during hydrous, anhydrous, and brine pyrolysis of oil shale: Implications for solid bitumen reflectance in source-rock reservoirs

Solid bitumen reflectance (BR o in %) is widely used as a thermal maturity proxy in source-rock reservoirs, yet solid bitumen texture and physical attributes may be affected by varying environmental constraints during its formation, e.g., water saturation, mineral catalysis, or salinity. Herein we investigated the development of solid bitumen properties during artificial maturation using three diverse (lacustrine to marine) oil shale samples containing abundant amorphous H-rich sedimentary organic matter (bituminite). The oil shales were treated via pyrolysis (320 °C, 72 h) using hydrous, anhydrous, and brine conditions, causing the development of a newly formed solid bitumen in the experiment residues from the thermal conversion of bituminite. The properties of the newly formed solid bitumen then were evaluated via geochemical screening tests, optical and electron microscopy, and infrared spectroscopy. Experimental residues also were treated via solvent extraction, allowing characterization of the effects of extraction on solid bitumen. Results showed that bituminite with higher resin and asphaltene components evolved to a solid bitumen with higher reflectance (as a percentage of the original value) when exposed to the same heat treatment, relative to bituminite with higher saturate and aromatic components. Aromatization of solid bitumen also was generally more pronounced in the presence of deionized water relative to anhydrous conditions, supporting prior observations. These results suggest the compositions of primary sedimentary organic matter, and the local concentration of water, affect the development of solid bitumen during thermal advance, potentially explaining the origin of multiple solid bitumen populations with varying reflectance in source-rock reservoir samples or in a single microscope field. Experiments using brine were inconclusive regarding enhanced/decreased aromatization, which could be attributed to the salinities of the brines used in the tests. Extraction of residues caused a consistent increase in BR o values, suggesting that migrating or expelled oils could cause an increase in BR o via natural solvation and absent an increase in temperature. This work provides insights into the development and evolution of BR o in source-rock reservoirs as a function of the composition of the original bituminite and changing environmental conditions, with potentially broad application for petroleum prospecting and resource estimation.

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Systematic approach to prioritize wells for effective groundwater monitoring and management in the Arkansas Headwaters Basin, Colorado, USA

Study region The Arkansas Headwaters Basin, an intermountain basin in the Southern Rocky Mountains of North America. Study focus Our specific focus is choosing a set of wells to support a possible future regional groundwater-surface water model that would support water management. We present a three-step process using multiple criteria to score, predict, and choose prioritized wells that capture the full distribution of data including extremes. The three-step process provides accessible visualizations, fiscally efficient well prioritization, and screening useful for subsequent groundwater modeling. The novelty of the proposed methodology is the systematic approach integrating a scoring and a predictive approach to support a selection path. The systematic approach may be broadly adapted for other basins. New hydrological insights for the region Understanding regional hydrology hinges on efficient collection of hydrologic data that captures the relevant dynamics including extremes. The present study, a case study for a particular basin in the Southern Rocky Mountains, is the first use of a scripted (R software) strategy to select an economical and representative set of monitoring wells. Our findings suggest caution when using proximity as a proxy for correlation, because proximal wells in the same geologic formation and similar depths are not always correlated. In the Arkansas Headwaters Basin, subsurface geology may be less influential on groundwater elevations than broader hydrologic influences, such as regional drought.

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Fungi, fire, and feedbacks: Grasses and wildfire interact to alter ectomycorrhizal fungal communities and decrease tree seedling growth

Wildfire and its effects, including changes to soil biota and the introduction of invasive or seeded grasses, can cause long-term shifts in ecological communities. Post-wildfire establishment of long-lived trees and shrubs is a critical bottleneck to recovering native plant communities. Ectomycorrhizal fungi (EMF) can improve plant responses to stressors and influence seedling establishment following wildfire, but little is known about how introduced grasses alter plant-fungal relationships and influence woody plant recovery. We investigated how piñon pine ( Pinus edulis ) EMF colonization and growth responded to soil wildfire history and novel grasses. Piñon seedlings were grown in soils from areas that burned in a stand-replacing fire nearly two decades prior or in soils from unburned piñon-juniper woodlands. Each piñon was grown with an invasive grass ( Bromus tectorum ), a native rhizomatous grass ( Pascopyrum smithii ) or another piñon seedling. Even ∼20 years after fire, EMF community composition in burned areas differed from that of unburned woodlands. Fire history and plant neighbor identity interacted to affect EMF abundance. Piñon seedling biomass was positively associated with EMF abundance in unburned woodland soils, but not in post-burn soils, suggesting that the EMF community in unburned woodlands is more beneficial. Importantly, the presence of either an invasive or native grass had a negative effect on seedling growth and EMF abundance, resulting in an average 61.4 % drop in EMF abundance and altered EMF community composition. Our findings suggest that plant species interactions, long-term effects of fire on soil, and EMF may determine the trajectory of woodland recovery following wildfire.

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Concentration-discharge relations and transient metal loads reveal spatiotemporal variability in solute-generation mechanisms in a mine-affected watershed

Concentration-discharge (CQ) relations are commonly used to understand geochemical and hydrologic controls on the generation of solutes in watersheds. Despite the widespread application of CQ relations, this technique has been infrequently applied to acid mine drainage (AMD) sites, but the CQ framework may allow mechanistic understanding of remedial outcomes such as impoundment of water within underground mines. Results of CQ analyses and changes in metal loads in an AMD affected watershed in Colorado, USA indicate that dissolved loads increased at many individual locations following water impoundment within mine workings. Although increased loads were observed at most individual locations, these increases were offset by a large decrease in loading from the largest mine. A loading analysis that included data from an instream monitoring location showed a statistically significant decrease in Fe and Zn after bulkhead emplacement, indicating a net positive effect of bulkheads. Streams generally displayed dilution CQ patterns whereas mines and springs showed either flushing or chemostatic patterns prior to bulkheading, which transitioned to chemostatic patterns following bulkheading, indicating a transition from dynamic to equilibrium geochemical processes. Saturation indices for sulfide and secondary minerals indicated that mines and springs were near equilibrium for phases including schwertmannite, fluorite, and gypsum. Saturation indices vary through time for mines suggesting progressive leaching of sulfide minerals as the mass of available minerals in the mine workings decreases. Together, these diverse analyses provide an integrated understanding of the variability in solute generating processes in this watershed and may inform remediation plans for similarly affected sites by indicating the nature of mineralogic controls on water quality.

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Hot stops, cool looks: Aesthetic solutions for thermal comfort at transit stops

Increased urban heat intensifies thermal discomfort, particularly in critical public spaces such as transit stops. This study investigated the predictors of transit users' thermal perceptions in Denver, Colorado—a semi-arid city. Sixty bus stops spanning a gradient of land cover compositions were selected for study. Micrometeorological data, including thermal comfort indices, were collected alongside survey responses from 77 users at 31 unique stops. Survey responses captured thermal sensation votes (TSV) and thermal comfort votes (TCV) as well as aesthetic preference votes (APV) of bus stop structure. Ordinal forest analysis revealed that for both TSV and TCV, aesthetic preferences and thermal comfort indices were the most influential predictors of transit user thermal perception. Multiple ordered logistic regression further demonstrated that, for TSV, higher APV was associated with lower odds of rating a thermal environment as hot (OR = 0.664, p < 0.002) while increased Physiological Equivalent Temperature (PET) raised these odds (OR = 1.101, p < 0.006). An interaction analysis demonstrated that APV significantly moderated the effect of PET on TCV (interaction OR = 1.040, p < 0.041), suggesting that aesthetic preferences are significantly correlated with an alleviation of thermal discomfort under high heat stress. Bivariate analyses further indicated that bus stops with greater tree canopy cover (OR = 1.032, p < 0.025) and higher visible vegetation view factors (OR = 10.350, p < 0.022) were more likely to be rated as aesthetically pleasing. These findings underscore the importance of aesthetic preferences in transit stop planning for urban heat resiliency.

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Living with wildfire in West Vail, Eagle County, Colorado: 2022 data report

Community wildfire readiness includes homeowner wildfire risk mitigation and wildfire evacuation preparedness. This report presents results from a household survey distributed to 725 households in West Vail, Colorado in 2022. Results indicate that West Vail survey respondents may not fully understand the risk of damage or property loss due to a wildfire and may benefit from further information about wildfire risk contributors - in general and specific to their property - as well as evacuation preparedness information. Among common sources of wildfire risk information, respondents rated Vail Fire & Emergency Services as the most useful source. Most residents support wildfire risk reduction strategies on nearby public lands.

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Living with wildfire in Montrose County, Colorado: 2023 Data report

During 2022–2024, the Wildfire Research (WiRē) Center partnered with the West Region Wildfire Council (WRWC) to learn more about parcel-level wildfire risk in Montrose County, Colorado. This research project was part of a larger, sustained collaboration between WiRē and the WRWC, moving the focus from areas typically characterized as fire-prone due to heavily treed and steep topography, into an area with relatively gentle topography and lighter fuels. The study area borders and includes northern portions of Ouray County that fall within the service area of Montrose County Fire Protection District. The area was of particular interest to the WRWC because it lacks some of the social infrastructure typically leveraged to build community relationships, such as Homeowners Associations, and the WRWC sought to build understanding in order to provide a foundation to foster stronger ties to pursue wildfire risk reduction. The study also presented an opportunity to help assess interest in the WRWC’s cost share program intended to facilitate risk mitigation action on private properties.

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Living with wildfire in Estes Valley Fire Protection District, Larimer County, Colorado: 2023 Data report

Homeowner wildfire risk mitigation and preparedness are critical components of community wildfire readiness. This report describes the data collected through two efforts conducted in the Estes Valley Fire Protection District of Larimer County, Colorado, study area: (1) parcel-level rapid wildfire risk assessments performed by trained assessors and (2) homeowner surveys in which respondents provided self-assessments of their parcel-level wildfire risk. This project was undertaken to support Estes Valley Fire Protection District’s desire to enhance resident wildfire risk mitigation and evacuation planning. The household surveys also explored the social dimensions of wildfire, including understanding of wildfire risk, outreach or communication preferences, mitigation and evacuation preparedness activities, and perceptions of community risk reduction strategies. The results provide evidence that despite high levels of wildfire awareness and experience, respondents underestimate the risk on their properties as compared to a trained professional and have not completed important steps in the evacuation preparedness process. However, respondents would like more information on wildfire risk reduction via newsletters (mailed or emailed), community meetings, and in-person interactions.

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Amphibian diversity of the western Colorado canyonlands including potential threats from nonnative bullfrogs and disease

Throughout the canyons of the Colorado and Uncompahgre Plateaus, water is a limited resource for wildlife, with patchy distribution and seasonal availability. Tributary creeks within these canyons drain into mainstem rivers, providing habitat and breeding sites for native amphibians. Yet, little is known about the diversity and distribution of amphibians that live in these harsh, dynamic environments. In addition, the rivers that border these canyon tributaries may serve as corridors for nonnative species and disease. The American Bullfrog ( Lithobates catesbeianus ) is a nonnative species in western Colorado known to prey on native amphibians and act as a reservoir for pathogens such as Batrachochytrium dendrobatidis ( Bd ). From 2019 to 2022, we surveyed for amphibians using visual encounter surveys (VES) and environmental DNA (eDNA) surveys throughout the McInnis Canyons National Conservation Area (MCNCA), the Dominguez–Escalante National Conservation Area (DENCA), and the Dolores River Canyon Wilderness Study Area (DRCWSA). Our primary goals were to document the diversity and distribution of native amphibians in the canyonlands and evaluate potential threats to these species from bullfrogs and Bd . We confirmed that sensitive species, such as the Great Basin Spadefoot ( Spea intermontana ) and the Northern Leopard Frog ( Lithobates pipiens ), inhabit these protected areas. In most cases, bullfrogs were not detected within ephemeral tributaries, but bullfrog DNA was detected in some tributaries at the confluence with the mainstem rivers. In Mee Canyon (MCNCA), however, bullfrogs were found within the tributary, up to 3 km from the Colorado River. A bullfrog individual removed from this canyon tested positive for Bd , and diet contents suggested that native amphibians are potential prey in this system. Nonnative predators and disease pose a threat to native amphibians, alongside environmental changes such as drought and hydrological shifts driven by ongoing climate change.

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Intra-urban variations in land surface phenology in a semi-arid environment

Urban vegetation is growing in importance as cities use 'green infrastructure' to mitigate the impacts of climate change, reduce extreme heat, and improve human health and comfort. However, due to the heterogeneity of city landscapes, urban vegetation experiences a diverse range of environmental conditions, potentially leading to differences in growing season timing and length within cities. Here, we investigate physical drivers of urban land surface phenology and timing within a semi-arid city (Denver, CO, USA) using four years (2018–2021) of remotely sensed vegetation indices, modelled air temperature, and land cover datasets. Within the metropolitan region study area, satellite-based vegetation index measurements indicate that growing season length is variable on sub-neighborhood spatial scales. This variability is largely due to differences in the timing of fall senescence, as opposed to early season growth. Areas with substantial fractions of irrigated land cover tend to remain greener for longer, while unirrigated and cooler areas are correlated with an earlier end to the growing season (up to ∼two months shorter). These findings complement those from non-arid cities where surface and air temperature are the dominant environmental control on phenological timing. Results here indicate the importance of soil moisture for phenology in semi-arid regions and suggest unique semi-arid urban growing season dynamics and temperature-vegetation feedbacks. These interactions have implications for water, heat, and vegetation management strategies to maximize ecosystem services in water-limited environments.

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Agricultural return flow dynamics on a reach of the East River, Colorado, as assessed by mass balance

The U.S. Geological Survey, in cooperation with the Upper Gunnison River Water Conservancy District, studied historical streamflow in a reach of the East River, Colorado, to gain a preliminary understanding of return flow dynamics. Return flow is agricultural irrigation water that is not consumed by evapotranspiration and instead reaches streams by surface and subsurface flow paths. The study reach had a contributing area of 50 square miles and contained 5.23 square miles of pastures irrigated with water diverted from the East River and its tributaries. By comparing upstream inflows to downstream outflows, the net water balance of the study reach from 1994 to 2023 was assessed. Two general hydrologic conditions for the study reach were identified. One hydrologic condition was characterized by a net loss or consumption of water, termed here as general deficit. This general deficit condition extended about 16 years, from 1997 to 2012. During general deficit years, there was usually a notable net loss of streamflow from April through July, and a small net gain, possibly related to return flows, occurred in August about 75 days after the minimums for losses. The second hydrologic condition was characterized by a net gain of water, termed here as general surplus. This second condition extended about 10 years, from 2014 to 2023. During general surplus years, two separate transitions from net loss to net gain commonly occurred during June through August. Losses during general surplus years were smaller than losses during general deficit years, the respective gains were larger, and times between losses and gains were about 18 and 22 days. Differences between the two hydrologic conditions could reflect interactions among irrigation water, available capacity to store additional shallow groundwater, and streamflow. However, deciphering the causes for the shifts between the two general hydrologic conditions was beyond the scope of this report.

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A genetic assessment of natural barriers for isolating a habitat network proposed for Greenback Cutthroat Trout reintroduction

Objective: Native inland trout conservation efforts rely on physical barriers to exclude nonnative salmonids from target habitats. We used genetic techniques to evaluate a series of natural waterfalls for their potential to serve as barriers to prevent nonnative salmonids from entering a proposed reintroduction area for federally threatened Greenback Cutthroat Trout Oncorhynchus virginalis stomias . Methods: Genetic samples were collected from nonnative Brook Trout Salvelinus fontinalis at 11 sampling reaches above and below natural waterfalls (height: ~1–3 m under base flow conditions) along a 33-km segment of Colorado's upper Cache la Poudre River near the outflow of the proposed reintroduction area. To evaluate whether upstream movement of Brook Trout is restricted by any of these waterfalls, we characterized longitudinal trends in genetic diversity along the river corridor and examined patterns of genetic differentiation and population structure in relation to waterfall locations using a panel of microsatellites. Result: We found no evidence that the waterfalls served as complete movement barriers for nonnative Brook Trout based on genetic clustering analyses, estimates of population differentiation, and longitudinal genetic patterns. Our multilocus assessment did not identify alleles restricted to downstream reaches, and the river segment was genetically homogenized. Conclusion: Our evaluation suggests that the existing waterfalls do not fully prevent upstream movement by nonnative Brook Trout, and thus barrier modification would be needed to establish an isolated Greenback Cutthroat Trout population in the proposed wilderness area.

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Testing tree-ring cellulose δ18O with water isotopes for Holocene lake δ18O interpretations in the central Rocky Mountains USA

Stable isotopes of water preserved in geologic archives, primarily as oxygen (δ18O), have proven critical for documenting Earth’s climatic and hydrologic systems past and present. However, timescale differences of water isotope inputs to proxy systems and the signal embedded in long paleorecords often confound translation to observed hydroclimatic metrics. Here, a unique 20-year dataset of meteorology, hydrology, and the isotopic composition of weekly meteoric and surface water samples (δ18O, δ2 H) are combined with paleoclimate δ18O data from tree-ring cellulose and lake carbonate to better understand proxy signals of Upper Colorado river basin drought. Annual tree-ring cellulose δ18O from Picea engelmannii growing within a glacier-fed creek and a spring discharge area were used to derive annual source water δ18O using a cellulose source-water isotope model. Comparisons with the monitoring record indicates that tree-ring cellulose δ18O tracks variations in wet and dry hydroclimatic extremes. Source water isotopes are shown to reflect the hydroclimate of the current year and some number of previous years as an effective moisture-discharge proxy rather than a precipitation isotope proxy. Results contextualize Holocene lake carbonate δ18O data. The contemporary-to-paleo comparison identifies changes in seasonal precipitation extremes during recent millennia and several earlier arid and monsoon-dominated Holocene periods that exceed the arid maximum of the calibration period.

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Dynamic water-quality responses to wildfire in Colorado

In 2020, Colorado experienced the most severe wildfire season in recorded history, with wildfires burning 625 357 acres across the state. Two of the largest fires burned parts of Rocky Mountain National Park (RMNP), and a study was initiated to address concerns about potential effects on drinking water quality from mobilization of ash and sediment. The study took advantage of a wealth of pre-fire data from adjacent burned and unburned basins in western RMNP. Pre- and post-fire data collection included discrete sample collection and high-frequency water-quality measurements using in-stream sensors. Kruskal–Wallis tests on discrete data indicated that specific conductance, base cations, sulphate, chloride, nitrate, and total dissolved nitrogen concentrations increased post-fire, whereas silica and dissolved organic carbon (DOC) did not ( p ≤ 0.05). In-stream sensors captured large spikes in concentrations of nutrients, turbidity, and DOC in the burned basin that were missed by discrete sampling. Sensor data indicated nitrate and turbidity increased by up to one and two orders of magnitude, respectively, from pre-event concentrations during storms, and DOC increased up to 3.5×. Empirical regression equations were developed using pre-fire data and applied to the post-fire period to estimate expected stream chemistry in the absence of fire (a ‘no-fire’ scenario). Overlays of actual post-fire chemistry showed the timing and magnitude of differences between observed and ‘estimated’ chemistry. For most solutes, observed post-fire concentrations were notably greater than expected under the ‘no-fire’ scenario, and differences were greatest during storm events. Comparison of data from the burned and unburned basins indicated DOC concentrations were affected by climate as well as fire. Results from this study demonstrate the importance of both pre-fire data and high-frequency data for characterizing dynamic hydrochemical responses in wildfire-affected areas.

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