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Research about Argentina, Chile

Source-linked reports with geographic coverage including Argentina, Chile.

9 recordsLinked to original sources

Multi-proxy thermal history of basin heating during Cordilleran orogenesis in the Magallanes-Austral retroarc foreland basin, Patagonian Andes

Resolving thermal histories in sedimentary basins is crucial for interpreting orogenic growth, basin burial, and tectonic processes during Cordilleran orogenesis. In the Magallanes–Austral Basin, Patagonian Andes, we integrate new (U-Th)/He thermochronology, vitrinite reflectance (%R o ), calcite-cement clumped isotope data and thermal history modelling to resolve the origin of the regionally extensive Paleogene unconformity (51°S–50°S). Thermal history modelling results require post-depositional heating of Palaeocene (Danian–Selandian) strata below the unconformity and suggest maximum burial temperatures of 87°C–101°C (55–52 Ma) and 89°C–92°C (18–16 Ma). For lower Eocene strata above the unconformity, Miocene burial temperatures (89°C–92°C) are consistent with calcite cement formation temperatures (~62°C–92°C) from carbonate clumped isotopes. Our results indicate that basin burial and heating between ca. 60 and 52 Ma were likely driven by shallowing of the subducting Farallon plate and enhanced plate coupling preceding arrival of the Farallon–Phoenix mid-ocean ridge. Subsequent basin inversion and cooling from ca. 52 to 44 Ma correspond with subduction of this mid-ocean ridge. Refined thermal models, constrained by expanded thermochronometric and organic maturation datasets, indicate that up to ~1.7–2.0 km of proximal foreland basin strata were removed during uplift and erosion across the Paleogene basin margin. A return to basin subsidence beginning ca. 44 Ma may reflect dynamic subsidence after passage of the mid-ocean ridge and renewed coupling between the fold-thrust belt and foreland basin system. Neogene thermal histories document continued subsidence, localized hot orogenic fluid flow along stratigraphic boundaries, followed by a final phase of basin inversion and cooling at ca. 18–16 Ma, which we attribute to regional uplift associated with Chile ridge subduction. Altogether, this study demonstrates that multiple thermal indices when analysed and modelled can provide clarity for tectonic and stratigraphic events that affect foreland basins.

Patagonian Andes↗

Postglacial eruptive history of Laguna del Maule volcanic field and constraints on its magmatic system

The Laguna del Maule (LdM) volcanic field has produced >100 explosive and extrusive events over the past 17 ka. More than two-thirds of these have been silicic, with most being postglacial rhyolites (72–78 % SiO 2 ) concentrated near the eponymous lake (LdM), an extraordinary anomaly in the Quaternary Andes and unprecedented in this 1.5–Ma-old volcanic field as a whole. The postglacial field includes >70 separate vents distributed over ∼360 km 2 that together produced the many distinct eruptive events, of which 55 are rhyolitic (73 %−77 % SiO 2 ), 18 are rhyodacitic (68 %−72 % SiO 2 ), 4 are dacitic (63 %–66 % SiO 2 ), 26 are intermediate (54–62 % SiO 2 ), and 2 are true basalts (50 %–53 % SiO 2 ). Of these, most originated from single-vent domes, cones, or craters that erupted effusive and/or explosive products, each with relatively short lifespans. Some originated from multi-vent centers, the largest one being the Barrancas complex southeast of the lake, which has as many as 18 vents that erupted over as much as 10 kyr. The LdM basin itself is ringed by 13 separate silicic centers, many of which are also multi-vent and built over time by multiple explosive and extrusive events. These surround the lake, near the middle of which is the vent for the high-silica rhyolite Plinian eruption that produced the “ Rhyolite of Laguna del Maule ”, which was the first and largest silicic event from the postglacial field. Explosive and effusive products from all these events have been put in a time-stratigraphic framework supported by radiocarbon dating and chemical analyses to reconstruct the postglacial eruptive history. Correlations of pyroclastics to eruptive vents have provided a spatial-temporal framework that helps characterize the magmatic system beneath the LdM field. Distribution of both silicic and mafic vents support the likelihood that two separate magmatic systems produced the postglacial eruptions in the volcanic field—one in the Laguna del Maule basin and the other at the Barrancas complex—with a cluster of silicic vents at each and mafic vents situated between the two. Vent distributions, compositions of eruptive products, and temporal and spatial trends of eruptive units suggest that the abundant rhyodacitic and mafic units in the LdM basin have no common magma reservoir, but instead each had its own evolutionary trend. In contrast, there is enough affinity among some of the rhyolitic units in the Basin to imply magmatic connections and/or continuity that span both time and space, although neither geographic proximity nor temporal similarity have singular control on LdM-basin rhyolite compositions. Compositional trends through time at the Barrancas center suggest the rhyolitic eruptions at West and East Barrancas were derived from separate, zoned reservoirs that were tapped in batches, not permitting development of a large high-silica reservoir such as that beneath the LdM basin.

Laguna del Maule lake basin↗

Tectonic subsidence modeling of diachronous transition from backarc to retroarc basin development and uplift during Cordilleran orogenesis, Patagonian-Fuegian Andes

Backstripped tectonic basin subsidence histories are critical for interpreting phases of lithospheric deformation and paleoenvironmental change from the stratigraphic record. This study presents new subsidence modeling of the Rocas Verdes Backarc Basin (RVB) and Magallanes-Austral retroarc foreland basin (MAB) of southernmost South America to evaluate along-strike changes in tectonic subsidence related to the Late Jurassic through Miocene history of the Southern Andes. We compiled composite stratigraphic sections for seven basin localities that span 47°–54°S from published sedimentological records of paleoenvironment, paleobathymetry, and geochronology. Modeling results resolve regional trends in basin tectonic subsidence, uplift, and sedimentation rate that influenced the depositional environment during five broad phases of RVB-MAB development: (a) Late Jurassic tectonic subsidence and basin deepening associated with rift-related backarc extension that postdated regional diachronous rift-related magmatism. (b) Southward younging of Early to Late Cretaceous pronounced acceleration in tectonic subsidence interpreted as the initiation of flexural loading and development of the MAB foreland basin system. (c) Late Cretaceous (ca. 85–70 Ma) tectonic uplift within the central foredeep ∼49° to 52°S, coeval with a shift from slope to shelf deposition at these latitudes. (d) A protracted period of low-magnitude basin uplift and relative tectonic quiescence during the Paleogene, with the exception of southernmost localities; and (e) Synchronous latest Oligocene-early Miocene tectonic subsidence linked to basin deepening and transgression across the northern and central basin sectors. Backstripped tectonic subsidence analysis corroborates existing interpretations for orogenic development in the RVB-MAB and sheds new light on complex polyphase basin histories where extension precedes convergence.

Andes Mountains, Magallanes-Austral retroarc forel↗

Detrital record of the late Oligocene – Early Miocene mafic volcanic arc in the southern Patagonian Andes (~51 °S) from single-clast geochronology and trace element geochemistry

Retroarc foreland basins are important archives of continental arc magmatism and upper plate deformational processes that control the evolution of continental lithosphere. However, resolving source areas in foreland basin infill dominated from mixed mafic and recycled sediment using conventional methods such as detrital zircon geochronology poses a challenge to thorough analysis due to lower zircon fertility and the higher susceptibility to weathering of mafic lithologies. Here, we integrate whole rock 40 Ar/ 39 Ar geochronology and major and trace element geochemistry data from volcanic clasts from the lower Miocene infill of the Magallanes-Austral Basin and local Sierra Baguales intrusive rocks to understand the distribution of mafic sources and Neogene changes in arc magmatism in between multiple ridge subduction events in the southern Patagonian Andes. Potential source areas for the coarse-grained mafic detritus include the Eocene plateau lavas, the Late Jurassic-Miocene Southern Patagonian batholith, and the Late Jurassic Sarmiento Ophiolitic Complex. Published detrital zircon U-Pb age spectra suggest that all three sources are viable contributors to the basin, though the paucity of Jurassic and Eocene zircons preclude these as major sources. Here, new 40 Ar/ 39 Ar dating of the volcanic clasts from the early Miocene Río Guillermo Formation reveals latest Oligocene to early Miocene eruptive ages (∼25-22 Ma), indicating syndepositional eruption with the ancestral Río Guillermo fluvial sedimentation. A single dated clast yields a Late Cretaceous age (∼102 Ma). The clasts are dominantly basaltic andesite with Ba/Ta ∼500-1000, La/Ta >20, and Ba/La >15, indicating an arc-derived melt source. We propose that the clasts record a Miocene mafic continental arc source area in the Patagonian Andes, which has since been removed by erosion and is thus sparsely represented in the batholith. Furthermore, we suggest that this early Miocene phase of arc volcanism, which postdates Eocene and Oligocene backarc magmatism and pre-dates middle Miocene to recent Chile Ridge backarc magmatism, reflects a return to normal arc volcanism along the Patagonian margin following a cessation due to ridge subduction and subsequent slab window migration. New geochemistry and 40 Ar/ 39 Ar data from a basaltic dike in the Sierra Baguales, which crosscuts the Cenozoic stratigraphic section, records plateau magmatism ∼16 Ma associated with incipient Chile Ridge slab window volcanism.

Patagonian Andes↗

Volcanic lightning and plume behavior reveal evolving hazards during the April 2015 eruption of Calbuco volcano, Chile

Soon after the onset of an eruption, model forecasts of ash dispersal are used to mitigate the hazards to aircraft, infrastructure and communities downwind. However, it is a significant challenge to constrain the model inputs during an evolving eruption. Here we demonstrate that volcanic lightning may be used in tandem with satellite detection to recognize and quantify changes in eruption style and intensity. Using the eruption of Calbuco volcano in southern Chile on 22-23 April 2015, we investigate rates of umbrella cloud expansion from satellite observations, occurrence of lightning, and mapped characteristics of the fall deposits. Our remote-sensing analysis gives a total erupted volume that is within uncertainty of the mapped volume (0.56 ±0.28 km3 bulk). Observations and volcanic plume modeling further suggest that electrical activity was enhanced both by ice formation in the ash clouds >10 km asl and development of a low-level charge layer from ground-hugging currents.

Calbuco volcano↗

Copahue volcano and its regional magmatic setting

Copahue volcano (Province of Neuquen, Argentina) has produced lavas and strombolian deposits over several 100,000s of years, building a rounded volcano with a 3 km elevation. The products are mainly basaltic andesites, with the 2000–2012 eruptive products the most mafic. The geochemistry of Copahue products is compared with those of the main Andes arc (Llaima, Callaqui, Tolhuaca), the older Caviahue volcano directly east of Copahue, and the back arc volcanics of the Loncopue graben. The Caviahue rocks resemble the main Andes arc suite, whereas the Copahue rocks are characterized by lower Fe and Ti contents and higher incompatible element concentrations. The rocks have negative Nb-Ta anomalies, modest enrichments in radiogenic Sr and Pb isotope ratios and slightly depleted Nd isotope ratios. The combined trace element and isotopic data indicate that Copahue magmas formed in a relatively dry mantle environment, with melting of a subducted sediment residue. The back arc basalts show a wide variation in isotopic composition, have similar water contents as the Copahue magmas and show evidence for a subducted sedimentary component in their source regions. The low 206 Pb/ 204 Pb of some backarc lava flows suggests the presence of a second endmember with an EM1 flavor in its source. The overall magma genesis is explained within the context of a subducted slab with sediment that gradually looses water, water-mobile elements, and then switches to sediment melt extracts deeper down in the subduction zone. With the change in element extraction mechanism with depth comes a depletion and fractionation of the subducted complex that is reflected in the isotope and trace element signatures of the products from the main arc to Copahue to the back arc basalts.

Copahue volcano↗

Alunite in the Pascua-Lama high-sulfidation deposit: Constraints on alteration and ore deposition using stable isotope geochemistry

The Pascua-Lama high-sulfidation system, located in the El Indio-Pascua belt of Chile and Argentina, contains over 16 million ounces (Moz) Au and 585 Moz Ag. The deposit is hosted primarily in granite rocks of Triassic age with mineralization occurring in several discrete Miocene-age phreatomagmatic breccias and related fracture networks. The largest of these areas is Brecha Central, which is dominated by a mineralizing assemblage of alunite-pyrite-enargite and precious metals. Several stages of hydrothermal alteration related to mineralization are recognized, including all types of alunite-bearing advanced argillic assemblages (magmatic-hydrothermal, steam-heated, magmatic steam, and supergene). The occurrence of alunite throughout the paragenesis of this epithermal system is unusual and detailed radiometric, mineralogical, and stable isotope studies provide constraints on the timing and nature of alteration and mineralization of the alunite-pyrite-enargite assemblage in the deposit. Early (preore) alteration occurred prior to ca. 9 Ma and consists of intense silicic and advanced argillic assemblages with peripheral argillic and widespread propylitic zones. Alunite of this stage occurs as fine intergrowths of alunite-quartz ± kaolinite, dickite, and pyrophyllite that selectively replaced feldspars in the host rock. Stable isotope systematics suggest a magmatic-hydrothermal origin with a dominantly magmatic fluid source. Alunite is coeval with the main stage of Au-Ag-Cu mineralization (alunite-pyrite-enargite assemblage ore), which has been dated at approximately 8.8 Ma. Ore-stage alunite has an isotopic signature similar to preore alunite, and Δ 34 S alun-py data indicate depositional temperatures of 245° to 305°C. The δ D and δ 18 O data exclude significant involvement of meteoric water during mineralization and indicate that the assemblage formed from H 2 S-dominated magmatic fluids. Thick steam-heated alteration zones are preserved at the highest elevations in the deposit and probably formed from oxidation of H 2 S during boiling of the magmatic ore fluids. Coarsely crystalline magmatic steam alunite (8.4 Ma) is restricted to the near-surface portion of Brecha Central. Postmineral alunite ± jarosite were previously interpreted to be supergene crosscutting veins and overgrowths, although stable isotope data suggest a mixed magmatic-meteoric origin for this late-stage alteration. Only late jarosite veinlets (8.0 Ma) associated with fine-grained pseudocubic alunite have a supergene isotopic signature. The predominance of magmatic fluids recorded throughout the paragenesis of the Pascua system is atypical for high-sulfidation deposits, which typically involve significant meteoric water in near-surface and peripheral alteration and, in some systems, even ore deposition. At Pascua, the strong magmatic signature of both alteration and main-stage (alunite-pyrite-enargite assemblage) ore is attributed to limited availability of meteoric fluids. This is in agreement with published data for the El Indio-Pascua belt, indicating an event of uplift and subsequent pediment incision, as well as a transition from semiarid to arid climatic conditions, during the formation of the deposit in the mid to late Miocene.

Economic Geology↗

Nitrogen loss from nonpolluted South American forests mainly via dissolved organic compounds

Conceptual 1 , 2 , 3 , 4 and numerical 5 , 6 , 7 , 8 models of nitrogen cycling in temperate forests assume that nitrogen is lost from these ecosystems predominantly by way of inorganic forms, such as nitrate and ammonium ions. Of these, nitrate is thought to be particularly mobile, being responsible for nitrogen loss to deep soil and stream waters. But human activities—such as fossil fuel combustion, fertilizer production and land-use change—have substantially altered the nitrogen cycle over large regions 9 , making it difficult to separate natural aspects of nitrogen cycling from those induced by human perturbations 10 . Here we report stream chemistry data from 100 unpolluted primary forests in temperate South America. Although the sites exhibit a broad range of environmental factors that influence ecosystem nutrient cycles 11 , 12 , 13 (such as climate, parent material, time of ecosystem development, topography and biotic diversity), we observed a remarkably consistent pattern of nitrogen loss across all forests. In contrast to findings from forests in polluted regions, streamwater nitrate concentrations are exceedingly low, such that nitrate to ammonium ratios were less than unity, and dissolved organic nitrogen is responsible for the majority of nitrogen losses from these forests. We therefore suggest that organic nitrogen losses should be considered in models of forest nutrient cycling, which could help to explain observations of nutrient limitation in temperate forest ecosystems.

South America↗

Hydrothermal element fluxes from Copahue, Argentina: A "beehive" volcano in turmoil

Copahue volcano erupted altered rock debris, siliceous dust, pyroclastic sulfur, and rare juvenile fragments between 1992 and 1995, and magmatic eruptions occurred in July– October 2000. Prior to 2000, the Copahue crater lake, acid hot springs, and rivers carried acid brines with compositions that reflected close to congruent rock dissolution. The ratio between rock-forming elements and chloride in the central zone of the volcano-hydrothermal system has diminished over the past few years, reflecting increased water/rock ratios as a result of progressive rock dissolution. Magmatic activity in 2000 provided fresh rocks for the acid fluids, resulting in higher ratios between rock-forming elements and chloride in the fluids and enhanced Mg fluxes. The higher Mg fluxes started several weeks prior to the eruption. Model data on the crater lake and river element flux determinations indicate that Copahue volcano was hollowed out at a rate of about 20 000–25 000 m 3 /yr, but that void space was filled with about equal amounts of silica and liquid elemental sulfur. The extensive rock dissolution has weakened the internal volcanic structure, making flank collapse a volcanic hazard at Copahue.

Copahue↗