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Research about Amargosa Desert Research Site

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Spatial fingerprinting of biogenic and anthropogenic volatile organic compounds in an arid unsaturated zone

Subsurface volatile organic compounds (VOCs) can pose risks to human and environmental health and mediate biological processes. VOCs have both anthropogenic and biogenic origins, but the relative importance of these sources has not been explored in subsurface environments. This study synthesizes 17 years of VOC data from the Amargosa Desert Research Site (ADRS) with the goal of improving understanding of spatial and temporal variations that distinguish sources of VOCs from a landfill and surrounding ambient sources including biogenic VOCs (bVOCs). Gas samples were collected from 1999 to 2016 from an array of shallow sample points (0.5 m and 1.5 m depth) and from vertical profiles at three deep boreholes, two (109 m deep) near the border of a waste facility (33 and 100 m distant), and one (29 m deep) in a remote area 3 km to the south. Samples were analyzed for target VOCs and a subset was analyzed for non-target VOCs to enumerate a greater variety of potential bVOCs. Principal components analysis of the target and non-target VOCs provided an assessment of spatial variability of VOCs originating from the landfill site and from ambient sources. Ambient VOCs occurred at all sample sites over a range of depths and most were consistent with biogenic origins, indicating, for the first time, presence of bVOCs in the deep unsaturated zone. Because some VOCs have both anthropogenic and biogenic sources, discrimination of sources can be important for estimating the extent and migration of anthropogenic plumes in arid unsaturated zones.

Nevada

Steady state fractionation of heavy noble gas isotopes in a deep unsaturated zone

To explore steady state fractionation processes in the unsaturated zone (UZ), we measured argon, krypton, and xenon isotope ratios throughout a ∼110 m deep UZ at the United States Geological Survey (USGS) Amargosa Desert Research Site (ADRS) in Nevada, USA. Prior work has suggested that gravitational settling should create a nearly linear increase in heavy-to-light isotope ratios toward the bottom of stagnant air columns in porous media. Our high-precision measurements revealed a binary mixture between (1) expected steady state isotopic compositions and (2) unfractionated atmospheric air. We hypothesize that the presence of an unsealed pipe connecting the surface to the water table allowed for direct inflow of surface air in response to extensive UZ gas sampling prior to our first (2015) measurements. Observed isotopic resettling in deep UZ samples collected a year later, after sealing the pipe, supports this interpretation. Data and modeling each suggest that the strong influence of gravitational settling and weaker influences of thermal diffusion and fluxes of CO 2 and water vapor accurately describe steady state isotopic fractionation of argon, krypton, and xenon within the UZ. The data confirm that heavy noble gas isotopes are sensitive indicators of UZ depth. Based on this finding, we outline a potential inverse approach to quantify past water table depths from noble gas isotope measurements in paleogroundwater, after accounting for fractionation during dissolution of UZ air and bubbles.

Nevada

Volatile organic compounds in the unsaturated zone from radioactive wastes

Volatile organic compounds (VOCs) are often comingled with low-level radioactive wastes (LLRW), but little is known about subsurface VOC emanations from LLRW landfills. The current study systematically quantified VOCs associated with LLRW over an 11-yr period at the USGS Amargosa Desert Research Site (ADRS) in southwestern Nevada. Unsaturated-zone gas samples of VOCs were collected by adsorption on resin cartridges and analyzed by thermal desorption and GC/MS. Sixty of 87 VOC method analytes were detected in the 110-m-thick unsaturated zone surrounding a LLRW disposal facility. Chlorofluorocarbons (CFCs) were detected in 100% of samples collected. Chlorofluorocarbons are powerful greenhouse gases, deplete stratospheric ozone, and are likely released from LLRW facilities worldwide. Soil-gas samples collected from a depth of 24 m and a horizontal distance 100 m south of the nearest waste-disposal trench contained >60,000 ppbv total VOCs, including >37,000 ppbv CFCs. Extensive sampling in the shallow unsaturated zone (0–2 m deep) identified areas where total VOC concentrations exceeded 5000 ppbv at the 1.5-m depth. Volatile organic compound concentrations exceeded background levels up to 300 m from the facility. Maximum vertical diffusive fluxes of total VOCs were estimated to be 1 g m -2 yr -1 . Volatile organic compound distributions were similar but not identical to those previously determined for tritium and elemental mercury. To our knowledge, this study is the first to characterize the unsaturated zone distribution of VOCs emanating from a LLRW landfill. Our results may help explain anomalous transport of radionuclides at the ADRS and elsewhere.

Nevada

Resistivity profiling for mapping gravel layers that may control contaminant migration at the Amargosa Desert Research Site, Nevada

Gaseous contaminants, including CFC 113, chloroform, and tritiated compounds, move preferentially in unsaturated subsurface gravel layers away from disposal trenches at a closed low-level radioactive waste-disposal facility in the Amargosa Desert about 17 kilometers south of Beatty, Nevada. Two distinct gravel layers are involved in contaminant transport: a thin, shallow layer between about 0.5 and 2.2 meters below the surface and a layer of variable thickness between about 15 and 30 meters below land surface. From 2003 to 2005, the U.S. Geological Survey used multielectrode DC and AC resistivity surveys to map these gravel layers. Previous core sampling indicates the fine-grained sediments generally have higher water content than the gravel layers or the sediments near the surface. The relatively higher electrical resistivity of the dry gravel layers, compared to that of the surrounding finer sediments, makes the gravel readily mappable using electrical resistivity profiling. The upper gravel layer is not easily distinguished from the very dry, fine-grained deposits at the surface. Two-dimensional resistivity models, however, clearly identify the resistive lower gravel layer, which is continuous near the facility except to the southeast. Multielectrode resistivity surveys provide a practical noninvasive method to image hydrogeologic features in the arid environment of the Amargosa Desert.

Nevada

Portable chamber measurements of evapotranspiration at the Amargosa Desert Research Site near Beatty, Nye County, Nevada, 2003-06

Portable chamber measurements of evapotranspiration (ET) were made at the U.S. Geological Survey's Amargosa Desert Research Site in southern Nevada to help quantify component- and landscape-scale contributions to ET in an arid environment. Evapotranspiration data were collected approximately every 3 months from 2003 to 2006. Chamber measurements of ET were partitioned into bare-soil evaporation and mixed-species transpiration components. The component-scale ET fluxes from native shrubs typically surpassed those from bare soil by as much as a factor of four. Component-scale ET fluxes were extrapolated to landscape-scale ET using a one-layer, multi-component canopy model. Landscape-scale ET fluxes predominantly were controlled by bare-soil evaporation. Bare soil covered 94 percent of the landscape on average and contributed about 70 percent of the landscape-scale vapor flux. Creosote bush, an evergreen shrub, accounted for about 90 percent of transpiration on average due to its dominance across the landscape (80 percent of the 6 percent shrub cover) and evergreen character.

Nevada

Selected micrometeorological, soil-moisture, and evapotranspiration data at Amargosa Desert Research Site in Nye County near Beatty, Nevada, 2001-05

Selected micrometeorological and soil-moisture data were collected at the Amargosa Desert Research Site adjacent to a low-level radio-active waste and hazardous chemical waste facility near Beatty, Nevada, 2001-05. Evapotranspiration data were collected from February 2002 through the end of December 2005. Data were col-lected in support of ongoing research to improve the understanding of hydrologic and contaminant-transport processes in arid environments. Micrometeorological data include solar radiation, net radiation, air temperature, relative humidity, saturated and ambient vapor pressure, wind speed and direction, barometric pressure, precipitation, near-surface soil temperature, soil-heat flux and soil-water content. All micrometeorological data were collected using a 10-second sampling interval by data loggers that output daily and hourly mean values. Daily maximum and minimum values are based on hourly mean values. Precipitation data output includes daily and hourly totals. Selected soil-moisture profiles at depth include periodic measurements of soil volumetric water-content measurements at nine neutron-probe access tubes to depths ranging from 5.25 to 29.25 meters. Evapotranspiration data include measurement of daily evapotranspiration and 15-minute fluxes of the four principal energy budget components of latent-heat flux, sensible-heat flux, soil-heat flux, and net radiation. Other data collected and used in equations to determine evapotranspiration include temperature and water content of soil, temperature and vapor pressure of air, and covariance values. Evapotranspiration and flux estimates during 15-minute intervals were calculated at a 0.1-second execution interval using the eddy covariance method. Data files included in this report contain the complete micrometeorological, soil-moisture, and evapotranspiration field data sets. These data files are presented in tabular Excel spreadsheet format. This report highlights selected data contained in the computer generated data files using figures, tables, and brief discussions. Instrumentation used for data collection also is described. Water-content profiles are shown to demonstrate variability of water content with depth. Time-series data are plotted to illustrate temporal variations in micrometeorological, soil-water content, and evapotranspiration data.

Nevada

Direct current resistivity profiling to study distribution of water in the unsaturated zone near the Amargosa Desert Research Site, Nevada

In order to study the distribution of water in the unsaturated zone and potential for ground-water recharge near the Amargosa Desert Research Site south of Beatty, Nevada, the U.S. Geological Survey collected direct-current resistivity measurements along three profiles in May 2003 using an eight-channel resistivity imaging system. Resistivity data were collected along profiles across the ADRS, across a poorly incised (distributary) channel system of the Amargosa River southwest of the ADRS, and across a well-incised flood plain of the Amargosa River northwest of the ADRS. This report describes results of an initial investigation to estimate the distribution of water in the unsaturated zone and to evaluate the shallow subsurface stratigraphy near the ADRS. The geophysical method of dc resistivity was employed by using automated data collection with numerous electrodes. "Cross sections" of resistivity, produced by using an inversion algorithm on the field data, at the three field sites are presented and interpreted.

Nevada

Plume-scale testing of a simplified method for detecting tritium contamination in plants and soil

Cost-effective methods are needed to detect contamination near radioactive-waste and other contaminated sites. Such methods should be capable of providing an early warning of contaminant releases and should be accurate and robust enough for assessing the long-term performance of waste-isolation facilities and remediation measures. Recently, a simplified method for detecting tritium contamination in plants and soil was developed (1). The method includes solar distillation of plant water from foliage, followed by filtration and adsorption of scintillation-interfering constituents on a graphite-based solid-phase-extraction column prior to direct-scintillation counting. The objectives of the in-progress study described here are to (i) test the simplified contamination-detection method for collection and analysis of plume-scale tritium data and (ii) gain insight into tritium migration pathways and processes.

Nevada

Monitoring radionuclide contamination in the unsaturated zone - Lessons learned at the Amargosa Desert Research Site, Nye County, Nevada

Contaminant-transport processes are being investigated at the U.S. Geological Survey’s Amargosa Desert Research Site (A DRS), adjacent to the Nation’s first commercial disposal facility for low-level radioactive waste. Gases containing tritium and radiocarbon are migrating through a 110-m thick unsaturated zone from unlined trenches that received waste from 1962 to 1992. Results relevant to long- term monitoring of radionuclides are summarized as follows. Contaminant plumes have unexpected histories and spatial configurations due to uncertainties in the: (1) geologic framework, (2) biochemical reactions involving waste components, (3) interactions between plume components and unsaturated-zone materials, (4) disposal practices, and (5) physical transport processes. Information on plume dynamics depends on ex-situ wet-chemical techniques because in-situ sensors for the radionuclides of interest do not exist. As at other radioactive-waste disposal facilities, radionuclides at the ADRS are mixed with varying amounts of volatile organic compounds (VOCs). Carbon-dioxide and VOC anomalies provide proxies for radioactive contamination. Contaminants in the unsaturated zone migrate along preferential pathways. Effective monitoring thus requires accurate geologic characterization. Direct- current electrical-resistivity imaging successfully mapped geologic units controlling preferential transport at the ADRS. Direct sampling of water from the unsaturated zone is complex and time consuming. Sampling plant water is an efficient alternative for mapping shallow tritium contamination.

Nevada

Selected micrometeorological and soil-moisture data at Amargosa Desert Research Site in Nye County near Beatty, Nevada, 1998-2000

Selected micrometeorological and soil-moisture data were collected at the Amargosa Desert Research Site adjacent to a low-level radioactive waste and hazardous chemical waste facility near Beatty, Nev., 1998-2000. Data were collected in support of ongoing research studies to improve the understanding of hydrologic and contaminant-transport processes in arid environments. Micrometeorological data include precipitation, air temperature, solar radiation, net radiation, relative humidity, ambient vapor pressure, wind speed and direction, barometric pressure, soil temperature, and soil-heat flux. All micrometeorological data were collected using a 10-second sampling interval by data loggers that output daily mean, maximum, and minimum values, and hourly mean values. For precipitation, data output consisted of daily, hourly, and 5-minute totals. Soil-moisture data included periodic measurements of soil-water content at nine neutron-probe access tubes with measurable depths ranging from 5.25 to 29.75 meters. The computer data files included in this report contain the complete micrometeorological and soil-moisture data sets. The computer data consists of seven files with about 14 megabytes of information. The seven files are in tabular format: (1) one file lists daily mean, maximum, and minimum micrometeorological data and daily total precipitation; (2) three files list hourly mean micrometeorological data and hourly precipitation for each year (1998-2000); (3) one file lists 5-minute precipitation data; (4) one file lists mean soil-water content by date and depth at four experimental sites; and (5) one file lists soil-water content by date and depth for each neutron-probe access tube. This report highlights selected data contained in the computer data files using figures, tables, and brief discussions. Instrumentation used for data collection also is described. Water-content profiles are shown to demonstrate variability of water content with depth. Time-series data are plotted to illustrate temporal variations in micrometeorological and soil-water content data. Substantial precipitation at the end of an El Ni?o cycle in early 1998 resulted in measurable water penetration to a depth of 1.25 meters at one of the four experimental soil-monitoring sites.

Nevada

Tritium and 14C concentrations in unsaturated-zone gases at test hole UZB-2, Amargosa Desert Research Site, 1994-98: A section in U.S. Geological Survey Toxic Substances Hydrology Program: Proceedings of the technical meeting, Charleston, South Carolina, March 8-12, 1999: Volume 3 (Part C) (WRI 99-4018C)>

Tritium concentrations have been determined yearly since April 1994 from water-vapor samples collected at test hole UZB-2. The hole was drilled about 100 m (meters) south of the southwest corner of a commercial burial site for low-level radioactive wastes in September 1993. UZB-2 is equipped with ten 2.5-cm (centimeters) diameter air ports permanently installed in the unsaturated zone between the depths of 5.5 and 108.8 m below land surface. Depth to ground water is about 110 m. Additional sampling ports were driven by hand to depths of 0.5, 1.0 and 1.5 m in May 1997. Initial samples of water vapor collected in April 1994 showed elevated tritium concentrations of more than 100 TU (tritium units) from all 10 air ports, with a maximum concentration of 762±10 TU from an air port at a depth of 24.1 m. Subsequent tritium concentrations increased in all air ports, although tritium concentrations at depths of less than 34.1 m have remained relatively constant since July 1995. The largest observed increase in tritium has been at a depth of 47.9 m. There, tritium concentration has increased from 198±5 TU in April 1994 to 2,570±30 TU in June 1998. Large increases also have been measured in samples collected from air ports at depths of 106.4 and 108.8 m, just above the water table. During September and October 1998, carbon dioxide samples were collected from all ten air ports in UZB-2 and at a depth of 1.5 m, and analyzed for radioactive carbon-14 ( 14 C). 14 C concentrations are highest in air ports at depths less than 6 m where they exceed 2,000 pmc (percent modern carbon). Concentrations decrease rapidly in air ports at depth and are about 20 pmc below 94.2 m. However, at 47.9 meters, the 14 C concentration is 205±1 pmc, which is 2 to 4 times higher than concentrations in air ports immediately above and below. This depth corresponds to the largest tritium increase in UZB-2. Concentrations of both tritium and 14 C are greater than what could be expected from atmospheric fallout. The distribution of tritium and 14 C likely represent a complex pattern of lateral and vertical transport through the unsaturated zone from buried wastes to UZB-2.

Nevada

Hydrogeologic studies at the USGS Amargosa Desert Research Site

In 1976, the U.S. Geological Survey (USGS) began studies of unsaturated-zone hydrology in the Amargosa Desert in support of the USGS Low-Level Radioactive Waste Program. In 1983, agreements with the Bureau of Land Management and the State of Nevada established two field study areas: a 16-ha area adjacent to a waste-burial facility 17 km south of Beatty and a 0.1-ha area about 3 km farther south (fig. 1A). The study areas are collectively known as the Amargosa Desert Research Site (ADRS). Investigations at the ADRS have provided long-term benchmark information about hydraulic characteristics and soil-water movement for undisturbed conditions and for simulated waste-site conditions in arid environments. In 1995, as a result of unexpectedly finding high concentrations of tritium and carbon-14 in the unsaturated zone beneath the ADRS, the scope of research was broadened to include the study of processes affecting radionuclide transport. The ADRS was incorporated into the USGS Toxic Substances Hydrology Program in 1997. Research at the site is a multidisciplinary, collaborative effort that involves scientists from the USGS, universities, research institutes, and national laboratories. The overall objective for research at the site is to improve understanding of and methods for characterizing mechanisms that control subsurface migration and fate of contaminants in arid environments.

Nevada

Tritium and radioactive carbon (14C) analyses of gas collected from unsaturated sediments next to a low-level radioactive-waste burial site south of Beatty, Nevada, April 1994 and July 1995

Tritium activities in water vapor and radioactive carbon ( 14 C) activities in carbon dioxide were determined in gas samples pumped from small-diameter air ports installed in a test hole within the unsaturated sediments next to a commercial burial site for low-level radioactive waste south of Beatty, Nevada. In April 1994, gas samples were collected from test hole UZB-2, which was drilled about 350 feet south of the southwest corner of the fence enclosing the burial site. The test hole is part of a study to determine the depth to which atmospheric air circulates through the unsaturated sediments at the desert site. Laboratory results completed in May 1995 show activities of tritium and 14 C were greater than expected, with measured tritium in the water vapor as high as 762 tritium units at a depth of 79 feet and measured 14 C in carbon dioxide as high as 1,700 percent modern carbon at a depth of 18 feet. In July 1995, the uppermost five air ports in test hole UZB-2 were resampled. In addition, water vapor was collected for tritium analyses at a distant test hole, and water vapor for tritium analyses and carbon dioxide for 14 C analyses were collected from three depths at the research shaft about 200 feet north of test hole UZB-2, and at two shallow probes (depth of 5.5 feet) next to the fence enclosing the burial site. Analyses of samples collected in the upper 112 feet from test hole UZB-2 in July 1995 show the same distribution of tritium and 14 C as analyses of samples collected in April 1994, except that activities were somewhat greater in July. The greatest activities of tritium and 14 C were measured from a shallow probe next to the fence with activities of 29,400 tritium units and 517,000 percent modern carbon, respectively.

Nevada