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Research about Alabama, Florida, Louisiana, Mississippi, Texas

Source-linked reports with geographic coverage including Alabama, Florida, Louisiana, Mississippi, Texas.

At least 37 records · Page 2Linked to original sources
USGS2020

Data-driven, multi-model workflow suggests strong influence from hurricanes on the generation of turbidity currents in the Gulf of Mexico

Turbidity currents deliver sediment rapidly from the continental shelf to the slope and beyond; and can be triggered by processes such as shelf resuspension during oceanic storms; mass failure of slope deposits due to sediment- and wave-pressure loadings; and localized events that grow into sustained currents via self-amplifying ignition. Because these operate over multiple spatial and temporal scales, ranging from the eddy-scale to continental-scale; coupled numerical models that represent the full transport pathway have proved elusive though individual models have been developed to describe each of these processes. Toward a more holistic tool, a numerical workflow was developed to address pathways for sediment routing from terrestrial and coastal sources, across the continental shelf and ultimately down continental slope canyons of the northern Gulf of Mexico, where offshore infrastructure is susceptible to damage by turbidity currents. Workflow components included: 1) a calibrated simulator for fluvial discharge (Water Balance Model - Sediment; WBMsed ); 2) domain grids for seabed sediment textures ( dbSEABED ); bathymetry, and channelization; 3) a simulator for ocean dynamics and resuspension (the Regional Ocean Modeling System; ROMS ); 4) A simulator ( HurriSlip ) of seafloor failure and flow ignition; and 5) A Reynolds-averaged Navier–Stokes ( RANS ) turbidity current model ( TURBINS ). Model simulations explored physical oceanic conditions that might generate turbidity currents, and allowed the workflow to be tested for a year that included two hurricanes. Results showed that extreme storms were especially effective at delivering sediment from coastal source areas to the deep sea, at timescales that ranged from individual wave events (~hours), to the settling lag of fine sediment (~days).

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2020

Detection probabilities of bird carcasses along sandy beaches and marsh edges in the northern Gulf of Mexico

We estimated detection probabilities of bird carcasses along sandy beaches and in marsh edge habitats in the northern Gulf of Mexico to help inform models of bird mortality associated with the Deepwater Horizon oil spill. We also explored factors that may influence detection probability, such as carcass size, amount of scavenging, location on the beach, habitat type, and distance into the marsh. Detection probability for medium-sized carcasses (200–500 g) ranged from 0.82 (SE = 0.09) to 0.93 (SE = 0.04) along sandy beaches. Within sandy beaches, we found that intact/slightly scavenged carcasses were easier to detect than heavily scavenged ones and did not find strong effects of location on the beach on detection probability. We estimated detection rate for each combination of scavenging state, carcass size, and position along sandy beaches. In marsh edge habitats, detection ranged from 0.04 (SE = 0.04) to 0.86 (SE = 0.10), with detection rates rapidly increasing from small (< 200 g) to medium carcass sizes and leveling off between medium and extra-large (> 1000 g) carcasses regardless of vegetation type ( Spartina or Phragmites ). Carcasses of all sizes were generally harder to locate in Spartina -dominated marshes than in Phragmites -dominated ones. A subset of the data for which we could adequately assess the effect of distance into the marsh indicated that detection rates generally declined the farther a carcass was into marsh vegetation. Based on power analyses, our ability to identify predictors that influence detection rates would be higher with larger numbers of carcasses, greater numbers of search trials per carcass, or more balanced sampling distributions across predictor values.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2020

Final project memorandum: Southeast Climate Adaptation Science Center Project

Low-lying public lands along the northern Gulf of Mexico coast are vulnerable to sea-level rise. Coastal planners and resource managers in the region have requested customized information that can be used to concisely communicate local sea-level rise scenarios and identify potential impacts to the missions of management agencies. In this project, researchers worked with the Northern Gulf of Mexico Sentinel Site Cooperative to develop information sheets outlining potential sea-level rise scenarios for the region through 2100 including their potential impact on the missions of federally-managed lands. Researchers drew from existing information on regional and global sea-level rise scenarios to develop customized information sheets for 54 federally-managed lands in the region (e.g., National Wildlife Refuges, National Park Service lands, National Estuarine Research Reserves) (Chivoiu et al. 2020). This project was developed in response to a request for customized sea-level rise scenario products from partners at the Northern Gulf of Mexico Sentinel Site Cooperative and the U.S. Fish and Wildlife Service’s Gulf Restoration Program. The results of this project support the conservation stewardship missions of the U.S. Fish and Wildlife Service and National Park Service by providing science to inform management of their lands along the Gulf of Mexico.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2020

Malaclemys terrapin (Diamondback terrapin) Lepadomorph epibionts

Diamondback terrapins (Malaclemys terrapin) are distributed along the Atlantic and Gulf of Mexico (GoM) coasts of the U.S.A. (Hart et al. 2014. Conserv. Genet. DOI 10.1007/s10592-014-0563-6). Under consideration for listing in Florida and proposed for Appendix II listing by the U.S. at CoP16 (CITES), terrapin populations are declining in many parts of their range due to drowning in crab pots, road mortality, exploitation by the pet trade and habitat loss. The species has been divided into seven subspecies based on morphometric and geographic variations: M.t. terrapin, M.t. centrata, M.t. tequesta, M.t. rhizophorarum, M.t. macrospilota, M.t. pileata, and M.t. littoralis. (Ernst and Lovich 2009). Terrapins in the northern GoM are comprised primarily of the Mississippi (M.t. pileata) and ornate subspecies (M.t. macrospilota) which inhabit salt marshes across the region from approximately the Texas/Louisiana border to Naples, Florida.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2019

Seasonal variation in environmental and behavioural drivers of annual-cycle habitat selection in a nearshore seabird

Aim Conservation of highly mobile species often requires identifying locations or time periods of elevated vulnerability. Since both extrinsic habitat conditions and intrinsic behavioural and energetic requirements contribute to habitat use at the landscape scale, identifying spatial or temporal foci for conservation intervention requires understanding how habitat needs and distributions vary across the annual cycle. Nearshore marine birds inhabit highly dynamic systems and have widely varying habitat needs among breeding, moult and non-breeding seasons, making them a useful case study for testing the relative contributions of individual resource requirements and environmental conditions in driving annual variation in distribution patterns. Location Northern Gulf of Mexico (USA). Methods We tracked Brown Pelicans using bird-borne GPS transmitters and used a combination of Hidden Markov Models and multivariate selectivity analysis to compare the characteristics of preferred resident habitats used throughout the annual cycle. Results Habitat selection was driven by dynamic oceanographic variables during all stages of the annual cycle. Key habitat characteristics varied between seasons, with particularly strong selection on high productivity, low temperature and low salinity during the breeding and post-breeding moult periods. The post-breeding moult also corresponded to a time of limited availability of preferred habitats, resulting in extensive overlap between breeding populations from different administrative planning areas. Main conclusions By incorporating seasonal variation in individual behaviour and resource requirements into our habitat models, we were able to identify the post-breeding moult as a period of high selectivity and restricted availability of preferred habitats for Brown Pelicans. Locations meeting preferred habitat criteria during the post-breeding period, particularly estuarine habitats with high productivity and low salinity, would therefore be high-value targets for management and restoration. Our analysis demonstrates the importance of accounting for both intrinsic and extrinsic temporal variation in evaluating habitat selection.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2019

Oyster reefs in northern Gulf of Mexico estuaries harbor diverse fish and decapod crustacean assemblages: A meta-synthesis

Oyster reefs provide habitat for numerous fish and decapod crustacean species that mediate ecosystem functioning and support vibrant fisheries. Recent focus on the restoration of eastern oyster ( Crassostrea virginica) reefs stems from this role as a critical ecosystem engineer. Within the shallow estuaries of the northern Gulf of Mexico (nGoM), the eastern oyster is the dominant reef building organism. This study synthesizes data on fish and decapod crustacean occupancy of oyster reefs across nGoM with the goal of providing management and restoration benchmarks, something that is currently lacking for the region. Relevant data from 23 studies were identified, representing data from all five U.S. nGoM states over the last 28 years. Cumulatively, these studies documented over 120,000 individuals from 115 fish and 41 decapod crustacean species. Densities as high as 2,800 ind m −2 were reported, with individual reef assemblages composed of as many as 52 species. Small, cryptic organisms that occupy interstitial spaces within the reefs, and sampled using trays, were found at an average density of 647 and 20 ind m −2 for decapod crustaceans and fishes, respectively. Both groups of organisms were comprised, on average, of 8 species. Larger-bodied fishes captured adjacent to the reef using gill nets were found at an average density of 6 ind m −2 , which came from 23 species. Decapod crustaceans sampled with gill nets had a much lower average density, <1 ind m −2 , and only contained 2 species. On average, seines captured the greatest number of fish species ( n = 33), which were made up of both facultative residents and transients. These data provide general gear-specific benchmarks, based on values currently found in the region, to assist managers in assessing nekton occupancy of oyster reefs, and assessing trends or changes in status of oyster reef associated nekton support. More explicit reef descriptions (e.g., rugosity, height, area, adjacent habitat) would allow for more precise benchmarks as these factors are important in determining nekton assemblages, and sampling efficiency.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2019

Loggerhead sea turtle (Caretta caretta) diving changes with productivity, behavioral mode, and sea surface temperature

The relationship between dive behavior and oceanographic conditions is not well understood for marine predators, especially sea turtles. We tagged loggerhead turtles ( Caretta caretta ) with satellite-linked depth loggers in the Gulf of Mexico, where there is a minimal amount of dive data for this species. We tested for associations between four measurements of dive behavior (total daily dive frequency, frequency of dives to the bottom, frequency of long dives and time-at-depth) and both oceanographic conditions (sea surface temperature [SST], net primary productivity [NPP]) and behavioral mode (inter-nesting, migration, or foraging). From 2011–2013 we obtained 26 tracks from 25 adult female loggerheads tagged after nesting in the Gulf of Mexico. All turtles remained in the Gulf of Mexico and spent about 10% of their time at the surface (10% during inter-nesting, 14% during migration, 9% during foraging). Mean total dive frequency was 41.9 times per day. Most dives were ≤ 25 m and between 30–40 min. During inter-nesting and foraging, turtles dived to the bottom 95% of days. SST was an important explanatory variable for all dive patterns; higher SST was associated with more dives per day, more long dives and more dives to the seafloor. Increases in NPP were associated with more long dives and more dives to the bottom, while lower NPP resulted in an increased frequency of overall diving. Longer dives occurred more frequently during migration and a higher proportion of dives reached the seafloor during foraging when SST and NPP were higher. Our study stresses the importance of the interplay between SST and foraging resources for influencing dive behavior.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2019

Analysis for agreement of the Northern Gulf of Mexico topobathymetric digital elevation model with 3-Dimensional Elevation Program 1/3 arc-second digital elevation models

Topographical differencing and edge-matching analyses were used to evaluate agreement of the Coastal National Elevation Database Applications Project’s Northern Gulf of Mexico topobathymetric digital elevation model (TBDEM) with The National Map 3-Dimensional Elevation Program (3DEP) 1/3 arc-second digital elevation models (DEMs). In addition to topographic map products provided through the National Geospatial Program, the model integrates bathymetric and topobathymetric datasets for three-dimensional (3D) mapping of rivers, lakes, and bays in the upland and intertidal wetlands to offshore environments in coastal zones from the border between Texas and Louisiana to east of Mobile Bay, Alabama. Contoured elevation differences between the Northern Gulf of Mexico TBDEM and the 3DEP 1/3 arc-second DEMs indicate that 85 percent of elevation data in the Northern Gulf of Mexico TBDEM agree (no difference for contoured elevations) between 95 and 100 percent with 3DEP 1/3 arc-second DEMs. Edge matching differences between adjacent Northern Gulf of Mexico TBDEM source projects or between the TBDEM and 3DEP DEMs indicate most seams between integrated and 3DEP DEMs are smooth. Where seams did not match, most differences were in the range of tenths to hundredths of a meter. Valid differences that are greater than plus or minus 2 meters in areas of bathymetric data are found in the Mississippi River, Atchafalaya River, Lower Atchafalaya River, Wax Lake Pass channel, the Vermilion Bay bathymetric datasets, and where topobathymetric datasets are integrated in the model. Areas with positive or negative outlier difference elevations seem to be a result of site conditions that affect light detection and ranging (lidar) waveform return signals, misclassification of surface features, or possibly because of interpolation required to develop a smooth elevation surface. Results of this analysis provide information to help understand model parameters and agreement of the Northern Gulf of Mexico TBDEM developed using different data types from different sources with The National Map 3DEP DEMs. Inclusion of bathymetric and topobathymetric data types in the 3DEP aligns with the mission to respond to growing needs for a wide range of three-dimensional representations of the Nation and supports the U.S. Geological Survey strategy for developing a National Terrain Model to provide hydrographic and elevation data that extend the elevation surface below water bodies. The 3D Nation Requirements and Benefits Study sponsored by the U.S. Geological Survey and National Oceanic and Atmospheric Administration to assess local to regional Tribal, State, and Federal technical requirements, needs, and benefits for using topographic and bathymetric 3DEP elevation data will be used to help develop and refine future program alternatives for 3D elevation data that include a category for bathymetry and topobathymetry. At the time of this report (2019), 3DEP acquisition is specific to topographic lidar that meets lidar DEM specifications and which requires surface-water feature areas to be hydroflattened. Cataloging bathymetric and topobathymetric DEMs as part of the 3DEP will require new specifications for acoustic, lidar, merged acoustic and lidar, and possibly other bathymetric and topobathymetric survey data types.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2018

Landscape conservation design for enhancing the adaptive capacity of coastal wetlands in the face of sea-level rise and coastal development

Coastal wetlands provide many valuable benefits to people and wildlife, including critical habitat, improved water quality, reduced flooding impacts, and protected coastlines. However, in the 21st century, accelerated sea-level rise and coastal development are expected to greatly alter coastal landscapes across the globe. The future of coastal wetlands is uncertain, challenging coastal environmental managers to develop conservation strategies that will increase the resilience of these valuable ecosystems to change and preserve the benefits they provide. One strategy for preparing for the effects of sea-level rise is to ensure that there is space available for coastal wetlands to migrate inland. In a recent study, we identified areas where coastal wetlands may move inland along the northern Gulf of Mexico coast, one of the most wetland-rich and sea-level rise sensitive regions of the world. Building on these findings, this project produced customized landscape conservation-design products focused on identifying landward migration routes for coastal wetlands. The resulting products provide environmental managers with information to make decisions to enhance the capacity of coastal wetlands to adapt to sea-level rise and coastal development, protecting these ecosystems and the critical economic and ecological benefits that they provide.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2017

Assessing coastal wetland vulnerability to sea-level rise along the northern Gulf of Mexico coast: Gaps and opportunities for developing a coordinated regional sampling network

Coastal wetland responses to sea-level rise are greatly influenced by biogeomorphic processes that affect wetland surface elevation. Small changes in elevation relative to sea level can lead to comparatively large changes in ecosystem structure, function, and stability. The surface elevation table-marker horizon (SET-MH) approach is being used globally to quantify the relative contributions of processes affecting wetland elevation change. Historically, SET-MH measurements have been obtained at local scales to address site-specific research questions. However, in the face of accelerated sea-level rise, there is an increasing need for elevation change network data that can be incorporated into regional ecological models and vulnerability assessments. In particular, there is a need for long-term, high-temporal resolution data that are strategically distributed across ecologically-relevant abiotic gradients. Here, we quantify the distribution of SET-MH stations along the northern Gulf of Mexico coast (USA) across political boundaries (states), wetland habitats, and ecologically-relevant abiotic gradients (i.e., gradients in temperature, precipitation, elevation, and relative sea-level rise). Our analyses identify areas with high SET-MH station densities as well as areas with notable gaps. Salt marshes, intermediate elevations, and colder areas with high rainfall have a high number of stations, while salt flat ecosystems, certain elevation zones, the mangrove-marsh ecotone, and hypersaline coastal areas with low rainfall have fewer stations. Due to rapid rates of wetland loss and relative sea-level rise, the state of Louisiana has the most extensive SET-MH station network in the region, and we provide several recent examples where data from Louisiana’s network have been used to assess and compare wetland vulnerability to sea-level rise. Our findings represent the first attempt to examine spatial gaps in SET-MH coverage across abiotic gradients. Our analyses can be used to transform a broadly disseminated and unplanned collection of SET-MH stations into a coordinated and strategic regional network. This regional network would provide data for predicting and preparing for the responses of coastal wetlands to accelerated sea-level rise and other aspects of global change.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2017

Groundwater quality in the Coastal Lowlands aquifer system, south-central United States

Groundwater provides nearly 50 percent of the Nation’s drinking water. To help protect this vital resource, the U.S. Geological Survey (USGS) National Water-Quality Assessment (NAWQA) Project assesses groundwater quality in aquifers that are important sources of drinking water. The Coastal Lowlands aquifer system constitutes one of the important areas being evaluated. One or more inorganic constituents with human-health benchmarks were detected at high concentrations in about 12 percent of the study area and at moderate concentrations in about 18 percent. Organic constituents were not detected at high or moderate concentrations in the study area.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2017

Gulf Coast vulnerability assessment: Mangrove, tidal emergent marsh, barrier islands and oyster reef

Climate, sea level rise, and urbanization are undergoing unprecedented levels of combined change and are expected to have large effects on natural resources—particularly along the Gulf of Mexico coastline (Gulf Coast). Management decisions to address these effects (i.e., adaptation) require an understanding of the relative vulnerability of various resources to these stressors. To meet this need, the four Landscape Conservation Cooperatives along the Gulf partnered with the Gulf of Mexico Alliance to conduct this Gulf Coast Vulnerability Assessment (GCVA). Vulnerability in this context incorporates exposure and sensitivity to threats (potential impact), coupled with the adaptive capacity to mitigate those threats. Potential impact and adaptive capacity reflect natural history features of target species and ecosystems. The GCVA used an expert opinion approach to qualitatively assess the vulnerability of four ecosystems: mangrove, oyster reef, tidal emergent marsh, and barrier islands, and a suite of wildlife species that depend on them. More than 50 individuals participated in the completion of the GCVA, facilitated via Ecosystem and Species Expert Teams. Of the species assessed, Kemp’s ridley sea turtle was identified as the most vulnerable species across the Gulf Coast. Experts identified the main threats as loss of nesting habitat to sea level rise, erosion, and urbanization. Kemp’s ridley also had an overall low adaptive capacity score due to their low genetic diversity, and higher nest site fidelity as compared to other assessed species. Tidal emergent marsh was the most vulnerable ecosystem, due in part to sea level rise and erosion. In general, avian species were more vulnerable than fish because of nesting habitat loss to sea level rise, erosion, and potential increases in storm surge. Assessors commonly indicated a lack of information regarding impacts due to projected changes in the disturbance regime, biotic interactions, and synergistic effects in both the species and habitat assessments. Many of the assessors who focused on species also identified data gaps regarding genetic information, phenotypic plasticity, life history, and species responses to past climate change and sea level rise. Regardless of information gaps, the results from the GCVA can be used to inform Gulf-wide adaptation plans. Given the scale of climatic impacts, coordinated efforts to address Gulf-wide threats to species and ecosystems will enhance the effectiveness of management actions and also have the potential to maximize the efficacy of limited funding.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2015

Incorporating future change into current conservation planning: Evaluating tidal saline wetland migration along the U.S. Gulf of Mexico coast under alternative sea-level rise and urbanization scenarios

In this study, the U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service, quantified the potential for landward migration of tidal saline wetlands along the U.S. Gulf of Mexico coast under alternative future sea-level rise and urbanization scenarios. Our analyses focused exclusively on tidal saline wetlands (that is, mangrove forests, salt marshes, and salt flats), and we combined these diverse tidal saline wetland ecosystems into a single grouping, &ldquo;tidal saline wetland.&rdquo; Collectively, our approach and findings can provide useful information for scientists and environmental planners working to develop future-focused adaptation strategies for conserving coastal landscapes and the ecosystem goods and services provided by tidal saline wetlands. The primary product of this work is a public dataset that identifies locations where landward migration of tidal saline wetlands is expected to occur under alternative future sea-level rise and urbanization scenarios. In addition to identifying areas where landward migration of tidal saline wetlands is possible because of the absence of barriers, these data also identify locations where landward migration of these wetlands could be prevented by barriers associated with current urbanization, future urbanization, and levees.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2014

Oyster reef restoration in the northern Gulf of Mexico: extent, methods and outcomes

Shellfish reef restoration to support ecological services has become more common in recent decades, driven by increasing awareness of the functional decline of shellfish systems. Maximizing restoration benefits and increasing efficiency of shellfish restoration activities would greatly benefit from understanding and measurement of system responses to management activities. This project (1) compiles a database of northern Gulf of Mexico inshore artificial oyster reefs created for restoration purposes, and (2) quantitatively assesses a subset of reefs to determine project outcomes. We documented 259 artificial inshore reefs created for ecological restoration. Information on reef material, reef design and monitoring was located for 94, 43 and 20% of the reefs identified. To quantify restoration success, we used diver surveys to quantitatively sample oyster density and substrate volume of 11 created reefs across the coast (7 with rock; 4 with shell), paired with 7 historic reefs. Reefs were defined as fully successful if there were live oysters, and partially successful if there was hard substrate. Of these created reefs, 73% were fully successful, while 82% were partially successful. These data highlight that critical information related to reef design, cost, and success remain difficult to find and are generally inaccessible or lost, ultimately hindering efforts to maximize restoration success rates. Maintenance of reef creation information data, development of standard reef performance measures, and inclusion of material and reef design testing within reef creation projects would be highly beneficial in implementing adaptive management. Adaptive management protocols seek specifically to maximize short and long-term restoration success, but are critically dependent on tracking and measuring system responses to management activities.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2013

Oyster reef restoration in the Northern Gulf of Mexico: effect of artificial substrate and sge on nekton and benthic macroinvertebrate assemblage use

In the northern Gulf of Mexico (GOM), reefs built by eastern oysters, Crassostrea virginica, provide critical habitat within shallow estuaries, and recent efforts have focused on restoring reefs to benefit nekton and benthic macroinvertebrates. We compared nekton and benthic macroinvertebrate assemblages at historic, newly created (<5years) and old (>6years) shell and rock substrate reefs. Using crab traps, gill-nets, otter trawls, cast nets, and benthic macroinvertebrate collectors, 20 shallow reefs (<5m) in the northern GOM were sampled throughout the summer of 2011. We compared nekton and benthic assemblage abundance, diversity and composition across reef types. Except for benthic macroinvertebrate abundance, which was significantly higher on old rock reefs as compared to historic reefs, all reefs were similar to historic reefs, suggesting created reefs provide similar support of nekton and benthic assemblages as historic reefs. To determine refuge value of oyster structure for benthic macroinvertebrates compared to bare bottom, we tested preferences of juvenile crabs across depth and refuge complexity in the presence and absence of adult blue crabs (Callinectes sapidus). Juveniles were more likely to use deep water with predators present only when provided oyster structure. Provision of structural material to support and sustain development of benthic and mobile reef communities may be the most important factor in determining reef value to these assemblages, with biophysical characteristics related to reef location influencing assemblage patterns in areas with structure; if so, appropriately locating created reefs is critical.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2012

Science in support of the Deepwater Horizon response

This introduction to the Special Feature presents the context for science during the Deepwater Horizon oil spill response, summarizes how scientific knowledge was integrated across disciplines and statutory responsibilities, identifies areas where scientific information was accurate and where it was not, and considers lessons learned and recommendations for future research and response. Scientific information was integrated within and across federal and state agencies, with input from nongovernmental scientists, across a diverse portfolio of needs—stopping the flow of oil, estimating the amount of oil, capturing and recovering the oil, tracking and forecasting surface oil, protecting coastal and oceanic wildlife and habitat, managing fisheries, and protecting the safety of seafood. Disciplines involved included atmospheric, oceanographic, biogeochemical, ecological, health, biological, and chemical sciences, physics, geology, and mechanical and chemical engineering. Platforms ranged from satellites and planes to ships, buoys, gliders, and remotely operated vehicles to laboratories and computer simulations. The unprecedented response effort depended directly on intense and extensive scientific and engineering data, information, and advice. Many valuable lessons were learned that should be applied to future events.

Alabama, Florida, Louisiana, Mississippi, Texas↗
USGS2011

Determination of the anionic surfactant di(ethylhexyl) sodium sulfosuccinate in water samples collected from Gulf of Mexico coastal waters before and after landfall of oil from the Deepwater Horizon oil spill, May to October, 2010

On April 22, 2010, the explosion on and subsequent sinking of the Deepwater Horizon oil drilling platform resulted in the release of crude oil into the Gulf of Mexico. At least 4.4 million barrels had been released into the Gulf of Mexico through July 15, 2010, 10 to 29 percent of which was chemically dispersed, primarily using two dispersant formulations. Initially, the dispersant Corexit 9527 was used, and when existing stocks of that formulation were exhausted, Corexit 9500 was used. Over 1.8 million gallons of the two dispersants were applied in the first 3 months after the spill. This report presents the development of an analytical method to analyze one of the primary surfactant components of both Corexit formulations, di(ethylhexyl) sodium sulfosuccinate (DOSS), the preliminary results, and the associated quality assurance/quality control (QA/QC) from samples collected from various points on the Gulf Coast between Texas and Florida. Seventy water samples and 8 field QC samples were collected before the predicted landfall of oil (pre-landfall) on the Gulf Coast, and 51 water samples and 10 field QC samples after the oil made landfall (post-landfall). Samples were collected in Teflon(Registered) bottles and stored at -20(degrees)C until analysis. Extraction of whole-water samples used sorption onto a polytetrafluoroethylene (PTFE) filter to isolate DOSS, with subsequent 50 percent methanol/water elution of the combined dissolved and particulate DOSS fractions. High-performance liquid chromatography/tandem mass spectrometry (LC/MS/MS) was used to identify and quantify DOSS by the isotope dilution method, using a custom-synthesized 13C4-DOSS labeled standard. Because of the ubiquitous presence of DOSS in laboratory reagent water, a chromatographic column was installed in the LC/MS/MS between the system pumps and the sample injector that separated this ambient background DOSS contamination from the sample DOSS, minimizing one source of blank contamination. Laboratory and field QA/QC for pre-landfall samples included laboratory reagent spike and blank samples, a total of 34 replicate analyses for the 78 environmental and field blank samples, and 11 randomly chosen laboratory matrix spike samples. Laboratory and field QA/QC for post-landfall samples included laboratory reagent spike and blank samples, a laboratory 'in-bottle' duplicate for each sample, and analysis of 24 randomly chosen laboratory matrix spike samples. Average DOSS recovery of 89(+/-)9.5 percent in all native (non-13C4-DOSS ) spikes was observed, with a mean relative percent difference between sample duplicates of 36 percent. The reporting limit for this analysis was 0.25 micrograms per liter due to blank limitations; DOSS was not detected in any samples collected in October (after oil landfall at certain study sites) above that concentration. It was detected prior to oil landfall above 0.25 micrograms per liter in 3 samples, but none exceeded the Environmental Protection Agency aquatic life criteria of 40 micrograms per liter.

Alabama, Florida, Louisiana, Mississippi, Texas↗