Geology Reports⌕ Search

Geology topics

Minerals & deposits

Find USGS publications on mineral resources and deposits. Search commodities and geographic names, then check source reports for geology and assessment methods.

Follow this topic with RSS
272 records · Page 15Linked to original sources
USGS2026

Stream sediment sources in Medicine Creek, northern Missouri and southern Iowa

This report presents the results of a cooperative study by the U.S. Geological Survey and Missouri Department of Natural Resources to quantify sediment transport source contributions in the Medicine Creek drainage basin. Understanding relative source contributions provides valuable information for selecting the conservation practices that may be most effective in reducing sediment and sediment-associated nutrient transport in the Medicine Creek drainage basin and similar areas of the Lower Grand River drainage basin. Sediment samples were collected from potential contributing areas (source samples) and from fluvial-transported samples (target samples). Source sample types included streambanks, row crop fields, and a combined pastures and forests category. Samples were analyzed for particle size and quantity of carbon, nitrogen, stable isotopes of carbon and nitrogen, and 49 mineral elements as potential tracers. Results for the carbon stable isotope ratio of carbon-13/carbon-12 (δ 13 C) and concentrations of total carbon, total nitrogen, calcium, potassium, and copper were selected by discriminant function analysis as the best combination of multiple tracers to differentiate each source type. The discriminant function analysis poorly differentiated pastures and forests, so these source types were combined. The sources defined by the discriminant function analysis were then used in an unmixing model to apportion sources for each target sample. In the study area, transported sediment was predominantly bank sediment, with an overall average of 86.9 percent of suspended-sediment samples and depositional streambed samples attributed to bank material. Suspended-sediment samples from the mainstem of Medicine Creek were dominated by bank sediments (average of 95.8 percent), and depositional streambed samples from throughout the drainage basin had more variable source contributions with an average of 71.1 percent attributed to bank material. The relative importance of upland sources (row crop fields and the combined pastures and forests category) varied seasonally and with streamflow but was not related to land use or drainage basin size. Relative contributions from upland sources were greater in the summer through winter rather than spring and during lower streamflow, though this may be driven by the seasonality of streamflow. These results indicate management practices that reduce bank erosion could be effective strategies for managing the dominant source of sediment and sediment-associated phosphorus.

Iowa, Missouri↗
USGS2025

Properties of solid bitumen formed during hydrous, anhydrous, and brine pyrolysis of oil shale: Implications for solid bitumen reflectance in source-rock reservoirs

Solid bitumen reflectance (BR o in %) is widely used as a thermal maturity proxy in source-rock reservoirs, yet solid bitumen texture and physical attributes may be affected by varying environmental constraints during its formation, e.g., water saturation, mineral catalysis, or salinity. Herein we investigated the development of solid bitumen properties during artificial maturation using three diverse (lacustrine to marine) oil shale samples containing abundant amorphous H-rich sedimentary organic matter (bituminite). The oil shales were treated via pyrolysis (320 °C, 72 h) using hydrous, anhydrous, and brine conditions, causing the development of a newly formed solid bitumen in the experiment residues from the thermal conversion of bituminite. The properties of the newly formed solid bitumen then were evaluated via geochemical screening tests, optical and electron microscopy, and infrared spectroscopy. Experimental residues also were treated via solvent extraction, allowing characterization of the effects of extraction on solid bitumen. Results showed that bituminite with higher resin and asphaltene components evolved to a solid bitumen with higher reflectance (as a percentage of the original value) when exposed to the same heat treatment, relative to bituminite with higher saturate and aromatic components. Aromatization of solid bitumen also was generally more pronounced in the presence of deionized water relative to anhydrous conditions, supporting prior observations. These results suggest the compositions of primary sedimentary organic matter, and the local concentration of water, affect the development of solid bitumen during thermal advance, potentially explaining the origin of multiple solid bitumen populations with varying reflectance in source-rock reservoir samples or in a single microscope field. Experiments using brine were inconclusive regarding enhanced/decreased aromatization, which could be attributed to the salinities of the brines used in the tests. Extraction of residues caused a consistent increase in BR o values, suggesting that migrating or expelled oils could cause an increase in BR o via natural solvation and absent an increase in temperature. This work provides insights into the development and evolution of BR o in source-rock reservoirs as a function of the composition of the original bituminite and changing environmental conditions, with potentially broad application for petroleum prospecting and resource estimation.

Colorado↗
USGS2026

Tephra from Kīlauea’s 2008–2018 lava lake eruption—Proximal deposits and dispersal characteristics

A network of ten buckets was established early in the 2008–2018 summit eruption at Kīlauea to collect proximal tephra ejected from the new, informally named the “Overlook crater”; the buckets were emptied on most days of the eruption thereafter. This report summarizes the results of more than 2,400 different sampling intervals (most 1–3 days long) during the eruption, focusing on the physical and dispersal characteristics of the tephra deposits. The network was within about 300 meters south of the vent to capture tephra dispersed by the dominant northeast trade wind. The juvenile tephra mainly reflected spattering at the southeast (SE) sink, a downwelling area in the southeastern part of the lava lake in the Overlook crater that remained in the same area throughout the eruption, with admixtures of solid rock and secondary minerals derived from the wall of the crater. The proportion of juvenile material to lithic material ranged widely early in the eruption but was generally greater than 90 percent for the last 6 years of the eruption as lake level rose and the crater walls decreased in height and became more stable. The accumulation rate of tephra at each bucket was strongly dependent on the location of the bucket and reflects the interplay between lava lake level and wind direction and speed. The mass per unit area (m/a) of collected tephra was a maximum of about 97 kilograms per square meter for the entire eruption, equivalent to a thickness of about 75 millimeters. Thirty-two explosive events with a volcanic explosivity index of −2 to −4 deposited much of the tephra in the network. Fifteen of these rock-fall-induced events occurred within 6 days of one another. Pele’s hair, a volcanic glass predominantly associated with quieter activity at the vent in the final half of the eruption, was dispersed more than 60 kilometers downwind from the lava lake and formed a nearly continuous deposit near the Overlook crater. This eruption was probably the most frequently sampled long-lasting eruption in history, but most of the deposits are ephemeral. The collected samples, although generally of small mass, are retained by the Hawaiian Volcano Observatory and are available for detailed study.

Hawaii↗
USGS2026

Geochemical geodatabase of sedimentary strata (coal, coal-adjacent rocks, tuffaceous oil shale, phosphate-rich rocks) and produced water in the Uinta region, Utah and Colorado

The Geochemical Geodatabase of Sedimentary Strata (Coal, Coal-adjacent Rocks, Tuffaceous Oil Shale, Phosphate-rich Rocks) and Produced Water in the Uinta Region, Utah and Colorado, consists of compiled datasets acquired as part of the Carbon Ore, Rare Earth, and Critical Mineral (CORE-CM) Uinta Region assessment funded by the U.S. Department of Energy (DEFE0032046, 2021–2024; Birgenheier et al., 2024). The CORE-CM assessment focused on providing comprehensive geological and geochemical characterization of current and prospective sedimentary-hosted resources including coal, oil shale, phosphatic limestone, and produced water from oil and gas targets present in eastern Utah and northwestern Colorado (Figure 1). This Data Series includes a geodatabase that consists of analytical geochemical data collected September 2021 through December 2024 via portable X-ray fluorescence (pXRF), and laboratory measured analyses produced by inductively coupled plasma mass spectrometry (ICP-MS) and inductively coupled plasma optical emission spectroscopy (ICP-OES). The coal-related geochemical data are derived primarily from the Cretaceous Blackhawk Formation and Ferron Sandstone of Utah, and the Mesaverde Group of Colorado. Additional non-coal resources assessed include oil shale-bearing strata of the Eocene upper Green River Formation (Utah and Colorado), phosphate-rich limestone of the Permian Park City Formation (Utah) and produced water from oil and gas-bearing strata of the Eocene Green River and Wasatch Formations (Uinta Basin) and the Pennsylvanian Paradox Formation (Paradox Basin) (Table 1). The CORE-CM assessment included a wide range of lithologies present in the coal, oil shale, and phosphate geologic resource systems whether or not the specific lithology has current economic value. Geochemical analyses of produced water from oil and gas wells focused on current and emerging hydrocarbon targets in the central Uinta Basin and northern Paradox Basin. A total of 13,092 geochemical analyses from these geologic systems is provided in the included geodatabase. A series of coal quality data (e.g., composition and maceral analyses) is also included in the database and was digitized from archived coal samples from the Utah Geological Survey (Appendix A).

Colorado, Utah↗
USGS2025

Igneous differentiation in arcs

This chapter assesses crystallization-differentiation of convergent-margin magmas both from the standpoints of natural rock suites and from laboratory phase-equilibrium experiments. Crystallization-differentiation of dry subalkaline and alkaline basalts are summarized at the beginning for reference and context. Experiments crystallizing arc basalts through andesites at middle to upper crustal pressures (100–400 MPa), saturated either with H 2 O or mixed H 2 O-CO 2 , produce liquid lines of descent similar to arc igneous suites, with higher f O 2 s giving results closer to calc-alkaline magma series. Early enrichment of melts in SiO 2 with little or no enrichment in FeO* (total Fe as FeO) comes about by the combined effects of H 2 O suppressing crystallization of plagioclase relative to olivine, shifting plagioclase to more calcic – therefore lower SiO 2 – compositions, and suppressing silicate minerals to greater extents than Fe-rich spinel. Also contributing to SiO 2 enrichment is crystallization near the liquidus of higher proportions of olivine relative to calcic clinopyroxene, compared with MORB, but it is unclear if this is brought about by H 2 O or elevated pressure. Exhumed arc terranes, however, generally fail to expose evidence for primitive liquids having reached and differentiated at middle to upper crustal depths, at least in any abundance. Instead, most differentiation in arcs appears to take place in the lower crust or near the crust-mantle transition, and although hydrous experiments at such pressures produce liquids broadly similar to arc suites in their SiO 2 enrichment, the experimental liquids differ in becoming peraluminous at early stages of differentiation while melts have basaltic, basaltic andesitic, or andesitic SiO 2 concentrations. Crystallization of abundant calcic clinopyroxene close to the liquidus causes the high-pressure experimental liquids to become peraluminous with only small increases in SiO 2 concentration. In contrast, natural arc volcanic and plutonic suites become gradually less metaluminous with increasing SiO 2 , crossing to peraluminous at dacitic to rhyolitic SiO 2 concentrations. Hybridism, encompassing magma-mixing, assimilation of old crust, and incorporation of near-solidus melts from only shortly older deep, antecedent arc intrusions may accompany natural crystallization-differentiation, preventing melts from attaining peraluminous compositions at low-SiO 2 concentrations. If so, then nearly all arc suites are to substantial extents composites, rather than preserving simple, progressive liquid lines of descent. Some comments and assessments are also made on the participation of garnet in arc differentiation and on the production of arc batholiths.

Book chapter↗
USGS2025

Geologic map of the Buckner 7.5-Minute quadrangle, Louisa County, Virginia

The Buckner 7.5-minute quadrangle straddles three terrane boundaries in the Piedmont Physiographic Province in central Virginia: the Chopawamsic terrane, the Elk Hill Complex, and the Goochland terrane. In much of the map area, the Elk Hill Complex separates the Chopawamsic and Goochland terranes. Rocks of the Chopawamsic terrane include Ordovician metavolcanic and metasedimentary rocks of the Chopawamsic Formation, Ordovician to Silurian granodiorite sheet intrusions, and Paleozoic mafic intrusions. Silurian to Devonian rocks of the Quantico Formation, mostly garnet-mica schist, crop out in the northwesternmost part of the map area, and are in unconformable contact with rocks of the Chopawamsic Formation on the southeastern limb of the Quantico synclinorium. The main map unit in the Elk Hill Complex is Neoproterozoic mica gneiss, which is in pre-metamorphic fault contact with rocks of the Chopawamsic Formation to the west. The main map unit of the Goochland terrane is the Maidens Gneiss. Except for Jurassic diabase dikes, all rocks on the Buckner 7.5-minute quadrangle were metamorphosed to amphibolite facies during the Alleghanian orogeny and preserve multiple compositional and phyllosilicate penetrative foliations. Evidence of amphibolite-facies metamorphism during the Taconic orogeny is preserved in rocks of the Elk Hill Complex. The entire width of the Maidens Gneiss on the Buckner 7.5-minute quadrangle is within the Spotsylvania high-strain zone and amphibolite-facies mylonitic textures are pervasive. Quartz veins and Jurassic diabase dikes crosscut all older rocks of the quadrangle. Multiple levels of terrace deposits are present along and near the major streams of the quadrangle. The lower terrace deposits are likely remnants of former positions of the Little River on the landscape, whereas higher deposits may be remnants of former deposits of the Atlantic Coastal Plain that covered this portion of the Piedmont Province. A linear cluster of aftershocks from the magnitude 5.8 earthquake that occurred near Mineral, Virginia, in 2011 defines the Fredericks Hall fault, which is at depth on the Buckner quadrangle. Most of the aftershocks occurred in the core of the Elk Creek antiform and have no relation to faults mapped at the surface. Several abandoned crushed stone and building stone quarries, as well as a mica prospect, exist in the quadrangle.

Virginia↗
USGS2024

Bedrock geologic map of the Woodstock quadrangle, Grafton County, New Hampshire

The bedrock geology of the Woodstock 7.5-minute quadrangle consists of highly deformed metasedimentary rocks of the Central Maine trough, including the Silurian Rangeley and Perry Mountain Formations and the Devonian Littleton Formation. The central, northern, and eastern parts of the quadrangle are underlain by the oldest rocks in the area, the Rangeley Formation. In the southwest and south-central part of the quadrangle, metaturbidites of the Perry Mountain Formation and subsequent Littleton Formation overly the Rangeley Formation in a deformed F 1 synform, herein informally called the Bagley Brook basin. The metasedimentary rocks were intruded by widespread syn- to post-tectonic granitoids of the Devonian New Hampshire Plutonic Suite and minor post-metamorphic Jurassic-Cretaceous mafic dikes of the White Mountain Plutonic-Volcanic Suite. The metasedimentary rocks were affected by at least two episodes of deformation in the Devonian Acadian orogeny. The dominant regional foliation is second-generation (S 2 /D 2 ) and formed during the development of sillimanite-muscovite mineral assemblages. Large bodies of the Early Devonian Kinsman Granodiorite intruded the metasedimentary rocks semi-concordantly during D 2 deformation. Dikes of the Late Devonian Concord Granite cut the Kinsman Granodiorite and the metasedimentary rocks and were emplaced either syn- or post-D 2 . The map pattern in the Rangeley Formation is dominated by northeast to northwest trending, moderately to steeply north-dipping F 2 and F 3 folds. Map-scale F 1 folds are defined by the Bagley Brook basin. Previous division of Rangeley Formation stratigraphy in this region into “upper” and “lower” parts was not corroborated by 1:24,000-scale mapping of lithodemic units, and rocks previously mapped as part of the Smalls Falls and Madrid Formations are here reassigned to the Rangeley Formation. Some rocks previously mapped as the lower part of the Littleton Formation are now assigned to the Perry Mountain Formation. The Littleton Formation on this map is approximately equivalent to rocks previously mapped as the upper part of the same formation. Steeply dipping fractures in the quadrangle show a preferred northeast orientation, consistent with subsurface fracture orientations in the well fields near Mirror Lake. Jurassic-Cretaceous mafic dikes and normal faults show preferred northeast orientations, similar to the fractures, suggesting that the extensional stress field that controlled dike orientation during the Mesozoic also produced the dominant brittle fabrics in the area.

New Hampshire↗
USGS2024

Editorial: From cold seeps to hydrothermal vents: Geology, chemistry, microbiology, and ecology in marine and coastal environments

This Research Topic compiles contemporary studies on cold seeps, hydrothermal vents, mud volcanoes, and related seafloor features that are associated with focused fluid emissions and the transfer of carbon, other chemical species, and sometimes heat from the geosphere to the ocean. Because these features sometimes tap fluids and gas originating kilometers below the seafloor, they provide an important window into deep processes that are otherwise inaccessible to scientists. At the shallow portion of their journey, migrating fluids nearing the seafloor contribute to a range of unique biological, physical, and chemical processes within the sediments themselves and at the sediment-water interface. Seafloor fluid emissions play a critical role in global biogeochemical cycles, ocean chemistry, and possibly even climate change. Seafloor leakage points often emit hydrocarbon gases (especially methane and CO 2 ) and are sometimes the loci for deposition of seafloor minerals that have economic value. A burgeoning area of research focuses on natural products generated at these features, seeking compounds with potential pharmaceutical or other applications. Multidisciplinary studies have become routine for characterization of seafloor fluid emission sites, attesting to the inseparability of geologic, physical, chemical, and biological processes in these settings. It is increasingly common for researchers to combine in a single research cruise: subbottom imaging and seafloor mapping; porewater and water column geochemistry and gas sampling; sediment retrieval for lithologic, biostratigraphic, and solid phase analyses; and studies of benthic and subseafloor communities at the microbial to macrofaunal scales. This multidisciplinary approach has the advantage of ensuring the spatial and temporal coincidence of surveys and samples, an important factor at highly dynamic seafloor fluid emission sites. In addition, researchers often use remotely operated vehicles (ROVs), autonomous underwater vehicles (AUVs), or human-occupied vehicles (HOVs) to record video of the seafloor, compile photomosaics, collect targeted samples, and survey with high-resolution geophysical near-seafloor systems, providing a degree of detail about seafloor fluid emission sites that is unprecedented compared to most areas of the deep ocean. While rarer, long-term cabled observatories or shorter-term deployments of portable observatories are also used at some loci for seafloor fluid flux and are particularly helpful for capturing temporal variations at these dynamic features. Here we summarize the Research Topic’s contribution to multidisciplinary seafloor emission studies in the categories of cold seeps, mud volcanoes, and hydrothermal vents. Figure 1 shows the geographic distribution of the studies in this Research Topic and key features referred to in this Introduction.

Frontiers in Earth Science↗
USGS2025

The Hardscrabble Creek complex: A newly discovered, mostly buried, Mesoproterozoic mafic-ultramafic pluton in the Wet Mountains, Colorado, USA

The origin of prolific ca. 1.4 Ga ferroan magmatism between the southwestern USA and eastern Canada is enigmatic and has been explained by various models, including extensional, mantle plume, and convergent plate-margin models. Rare mafic plutons are associated with the ferroan plutons, which may help constrain their mantle source and tectonic setting. In the southwestern USA, only two such mafic plutons are known to exist. We present the first evidence for a third, mostly buried, potentially layered, mafic-ultramafic Mesoproterozoic pluton, informally referred to as the Hardscrabble Creek complex, in the central Wet Mountains of Colorado, USA. Recent geophysical data show an elliptical magnetic and gravity high spatially coincident with local gabbroic outcrops. New field and petrographic analyses of these exposed rocks reveal that they consist of ultramafic to mafic cumulates, including orthopyroxenite, olivine norite, norite, and anorthosite. High-precision U-Pb dating of zircon from orthopyroxenite and norite yield weighted mean 206 Pb/ 238 U dates of 1352.36 ± 1.60 Ma and 1352.37 ± 1.71 Ma, respectively. These dates indicate that the complex formed over a narrow timeframe, after the adjacent 1362 ± 7 Ma ferroan San Isabel Granite, and during the waning stages of the regional ca. 1.4 Ga ferroan magmatism. Whole-rock geochemistry and Nd-Sr-Pb isotope compositions of samples from the Hardscrabble Creek complex are similar to those of the San Isabel Granite, suggesting that they were derived from the same or a similar mantle source. The mineral chemistry of the samples is comparable to Proterozoic massif-type anorthosites and related mafic intrusions, indicating that the Hardscrabble Creek complex and San Isabel Granite together represent a rare anorthosite-mangerite-charnockite-granite (AMCG) suite in the southwestern USA. The Hardscrabble Creek complex is unique because it formed ~80 m.y. after the other few mafic plutons in the southwestern USA, and it contains an ultramafic section that is absent from these plutons and rare to the AMCG suite in general. A combination of arc-like whole-rock geochemistry, chondrite uniform reservoir-like Nd-Sr-Pb isotopes, and ocean island basalt (OIB)-like zircon trace element chemistry suggests that the complex was derived from a partial melt of OIB-like mantle and interacted with metasomatically enriched lithospheric mantle. The enriched lithospheric mantle signature, combined with the long ~160 m.y. duration of magmatism in the region, is consistent with a period of protracted convergent tectonism.

Colorado↗
USGS2025

Gravity and magnetic surveys of the Skaergaard intrusion, East Greenland

Aeromagnetic and gravity surveys of the Skaergaard intrusion in East Greenland were carried out in July–August 1971 as part of a grant to the University of Oregon Center for Volcanology to refine the models of crystallization and differentiation of the intrusion, specifically to test whether the intrusion is underlain by dense rocks of a reservoir 20 kilometers (km) thick (referred to as a “hidden zone”). The Skaergaard intrusion is a source of platinum group elements that are critical mineral resources for many technologies, and because no new data have been collected these legacy datasets remain a valuable asset. The total-intensity aeromagnetic survey was flown in early July 1971 with a proton precession magnetometer at a constant barometric altitude of 1.5 km (5,000 feet) with a nominal line spacing of 1 km. Two gravimeters were used to acquire 168 stations of which 86 were at known altitudes (mainly sea level) and 82 had altitudes measured by altimetry in late July–August 1971. Finally, a north-south ground vertical-intensity magnetic traverse was completed across the intrusion together with collection of oriented hand specimens. The hand specimens were measured for remnant magnetization and density, along with density measurements of more specimens collected by expedition geologists for other purposes. The intrusion is composed of layered gabbro with extensive crystal fractionation that is dense and strongly reversely polarized. After terrain correction and standard Bouguer gravity reduction, the gravity anomaly dataset was corrected for all rock above sea level using the density measurements of the various zones of the intrusion and the topographic and geologic maps (variable density Bouguer gravity reduction). A large regional gradient in the gravity anomaly data was removed using orthogonal polynomial fitting to the gridded data. The zonal volumes of rock below sea level were calculated from the dipping polygonal layer gravity model of the intrusion below sea level and combined with elliptic cross–section cylinders for the various zones above sea level to approximate the original zonal volumes of the intrusion. The residual gravity anomaly of 18–20 milligals (mGal) was only about half of the expected anomaly if a large hidden zone proposed from petrologic considerations were present, and both two-dimensional and three-dimensional models imply that the exposed series of intrusion zones explain the gravity anomaly by their down-dip extension below sea level together with a small hidden-zone volume. A three-dimensional model of the exposed rocks and their down-dip extension below sea level also can account for the aeromagnetic anomaly with little or no requirement for hidden-zone rock. The middle and upper zone units of the intrusion contain the most magnetite and account for most of the aeromagnetic anomaly.

Skaergaard intrusion↗
USGS2026

The Sedimentary Geochemistry and Paleoenvironments Project Phase 2 data release: An open data resource for the study of Earth's environmental history

Geochemical data from sedimentary rocks are the primary source of information regarding Earth's surface evolution through time, including its air and water envelopes and interactions with life and deep Earth processes. The Sedimentary Geochemistry and Paleoenvironments Project (SGP) is a scientific consortium centered around open data and community-driven development of cyberinfrastructure tools and resources for sedimentary geochemistry and Earth history. Here we describe the SGP Phase 2 data release, which focused on incorporating Paleoproterozoic and Mesoproterozoic (2500–1000 million years ago) data and better accommodating carbonate data. This data release was built through the involvement of >200 researchers worldwide in academia, government, and industry, and provides the largest available public data resource for our user community in the academic fields of geochemistry, sedimentology, tectonics, paleontology, Earth history, and paleoclimate, as well as the petroleum and minerals industries. The dataset now encompasses 126,006 samples and 4,132,371 geochemical analyses. In addition to direct entry by SGP Team Members, we have ingested and incorporated datasets from the Geoscience Australia OZCHEM database, the Alberta Geological Survey, and the Deep-Time Marine Sedimentary Element Database (DM-SED) compilation. This paper details sampling in the Phase 2 dataset with respect to age, geography, lithology, and other geological characteristics, documents access via our search website and API, discusses possible issues and/or biases in the dataset that could impact analyses, describes plans for governance and stewardship of data from Indigenous lands, and serves as the citable reference paper for the data release.

Chemical Geology↗
USGS2025

Rapid emplacement of the Keaiwa Lava Flow of 1823 from the Great Crack in the Southwest Rift Zone of Kilauea volcano

The Keaīwa Lava Flow of 1823 in the Southwest Rift Zone of Kīlauea volcano is unusual for its expansive pāhoehoe sheet flow morphology and lack of constructive vent topography, despite having a similar tholeiitic basalt composition to other lavas erupted from Kīlauea. This lava flow issued from a ∼10-km-long continuous fissure now known as the Great Crack, and has an unusually thin sheet flow morphology with margin thicknesses of ∼15–110 cm (average of 42 cm). Based on field observations of the lava flow at its fissure vent (e.g., drain-back features), we propose that the Great Crack formed, or at least significantly widened, just prior to and syn-eruptively with this 1823 eruption. The absence of pyroclastic cones or spatter ramparts indicates that the eruption consisted of a rapid outpouring of relatively degassed lava as the fissure unzipped. The rapidly moving lava flow overtopped pre-existing tumuli and scoria cones (e.g., Lava Plastered Cones) up to ∼10 m tall. Glass and whole-rock chemistry yield homogeneous compositions for the lavas erupted from the Great Crack, with glass compositions of 6.40 ± 0.10 wt% MgO and whole-rock compositions of 7.39 ± 0.07 wt% MgO. Lava pads erupted from a short western fissure system are richer in mafic minerals (e.g., olivine and clinopyroxene), and show slightly more MgO-rich whole-rock compositions (7.79 ± 0.05 wt%). MgO-in-glass thermometry on juvenile spatter yield eruption temperatures of 1153 ± 13°C that are typical of Kīlauea lavas. Thus, the extensive sheet-like lava flow morphology is not a direct consequence of unusual magmatic or rheological conditions (i.e., low viscosity). Instead, the flow morphology is associated with high effusion rates caused by sudden drainage of uprift magma as it erupted from the Great Crack. Lava flow modeling on a 2-m-resolution digital elevation model indicates that a minimum bulk effusion rate of ∼5800 m 3 /s (∼3500 m 3 /s dense rock equivalent) and a minimum flow velocity of ∼11 m/s are required for the lava flow to overcome the topography of the Lava Plastered Cones. This effusion rate is among the highest inferred for eruptions in Hawaiʻi and around the world. This study highlights a less frequent eruption style at Hawaiian volcanoes characterized by a sudden outpouring of lava from an unusual fissure system. Local eyewitness accounts indicate that the 1823 eruption was preceded by seismicity. Given the complex magmatic-volcanic-tectonic relations across Kīlauea, we speculate that the south flank could have slipped over one or more events that ultimately triggered unzipping of the Great Crack and passive release of briefly stored uprift magma. An eruption similar to 1823 at Kīlauea or Mauna Loa, with an eruptive timeframe that could be as short as an hour, with high effusion rates and rapid flow front velocities, would not easily allow for a timely response.

Hawaii↗
USGS2000

Natural attenuation of chlorinated volatile organic compounds in ground water at Area 6, Naval Air Station Whidbey Island, Washington

Natural attenuation is a viable alternative to pump and treat for meeting remediation objectives in the vicinity of the southern contaminant plume. The combination of historically low contaminant concentrations in ground water, a landfill cap that limits source area contributions, favorable conditions for degradation of VC, and a relatively long downgradient distance to potential receptors are all favorable for natural attenuation as a remediation alternative. Natural attenuation could effectively meet all but one remediation goal that extraction wells PW- 2, PW-4, PW-6, PW-7, PW-8 and PW-9 are currently being employed to meet. The goal of preventing migration of all VC across the site boundary could not be met by natural attenuation. Some VC would migrate south of the Navy boundary, but the potential for subsequent VC mineralization downgradient of the base and the existing institutional controls would result in minimal additional risk from using natural attenuation. In the western contaminant plume natural attenuation is not currently a viable alternative to pump and treat for meeting remediation objectives. There is a possibility that rates for reductive dechlorination of TCE and TCA could increase substantially if the plume was allowed to migrate beneath the Oak Harbor landfill, but there are not enough data to be certain of such an increase. TCA and TCE concentrations at the leading edge of the western plume need to be reduced to at least 25 and 40 µg/L, respectively, to be protective of potential downgradient receptors. Source area TCA and TCE concentrations have decreased substantially over the past ten years, and the extraction wells PW-3 and PW-5 in particular are removing a significant mass of contaminants from ground water, so natural attenuation may be a viable alternative for the western plume in the future. There would be some possible side benefits of using natural attenuation as an alternative to pump and treat in the southern contaminant plume. The first would be that the resulting decrease in the amount of treated water that would need to be recharged in the swale north of the landfill would result in less off-base migration of contamination across the western site boundary. The second benefit would be a substantial reduction in the amount of dissolved iron and manganese being extracted from the shallow aquifer and run through the treatment system. Removing that source of operation and maintenance problems would result in more effective containment and removal of contamination in the western contaminant plume. The most critical data gap identified in this evaluation is the paucity of contaminant chemistry information downgradient of the Navy boundary in the vicinity of the southern contaminant plume. Without such data, the behavior of the plume and the protectiveness of natural attenuation to downgradient receptors cannot be verified, and field attenuation rates for VC cannot be determined directly. The existing long-term monitoring plan would need to be reviewed and revised if natural attenuation is selected as a remedy for the contamination in the southern plume. In particular, additional performance monitoring wells may be required downgradient of the property.

Washington↗
USGS2026

Understanding the resource potential of natural hydrogen on Earth: Scientific gaps, uncertainties and recommendations

A comprehensive scientific research roadmap is essential to bridge knowledge gaps and deepen the understanding of key geological, geochemical, and geophysical aspects of natural hydrogen (H 2 ) as a potential new energy resource. This paper reviews major scientific uncertainties on natural H 2 , suggesting research priorities, as a guide for defining exploration strategies, techniques, and data interpretation. The uncertainties concern all phases of the natural H 2 cycle, from generation (source rocks) through migration (advection and diffusion) and accumulation (reservoir and cap rocks) to the application and interpretation of subsurface and surface geochemical and geophysical exploration techniques. Understanding H 2 sources and generation rates (the amount of H 2 generated by a given volume of rock over time) is crucial for determining whether a geological H 2 system operates as a short-term dynamic system with rapid H 2 production and release, or as a conventional gas system with long-term accumulations, analogous to petroleum reservoirs. Preliminary estimates for serpentinisation, radiolysis, and organic matter degradation suggest that H 2 generation is not inherently fast, especially for non-hydrothermal continental systems (crystalline basement of shields, ophiolites, peridotite massifs, sedimentary basins), and long-term accumulations, like those of fossil natural gas systems, represent the most likely scenario. The mechanisms of H 2 migration through geological formations require application of fundamental principles of fluid-flow physics, distinguishing advection and diffusion, as well as their forms (from gas-phase, bubble flows to aqueous solutions). Additional studies of H 2 accumulation and retention in subsurface reservoirs could improve understanding of mechanisms of H 2 migration by focusing on the rock fluid-bearing properties and the factors affecting H 2 preservation, such as the presence of cap rocks impermeable to H 2 , pressure conditions, residence times, and microbial or abiotic consumption. Advanced techniques, including reservoir modelling, flow simulations, 3D imaging (micro-CT) of H 2 -bearing rocks, and extraction and analysis of gas occluded in rocks, can provide insights into the stability and potential recoverability of H 2 accumulations. The interpretation of surface exploration techniques, including gas geochemistry, geophysics, and remote sensing, long employed in mineral and energy resource exploration, is now being adapted for natural H 2 studies, but challenges remain in the data interpretation. Distinguishing H 2 seepage due to geological degassing from H 2 produced near the surface by modern microbial processes or artificial sources, such as hammering or drilling for soil-gas sampling, drilling into aquifers, and corrosion in boreholes, is an essential step in exploration. The simple detection of H 2 in soils, even in morphological structures like sub-circular depressions or “fairy circles”, cannot be cursorily interpreted as a signal of natural H 2 seepage from a deep source. A holistic geochemical approach, including isotopic analyses of gases associated with H 2 , is recommended to distinguish among the variety of possible H 2 origins. Observations of H 2 in wells should be interrogated to rule out possible artifacts such as corrosion and drill bit metamorphism. The integration of multiple geophysical methods, including seismic, gravimetric, magnetic, and electro-magnetic surveys, is recommended to mitigate interpretation ambiguities regarding the structure of a subsurface H 2 system (source and reservoir rocks, including fluid and gas storage), due to the non-uniqueness of rock-specific physical properties.

Earth-Science Reviews↗
USGS2024

Geologic map and structure sections along the southern part of the Bartlett Springs Fault Zone and adjacent areas from Cache Creek to Lake Berryessa, northern Coast Ranges, California

Introduction Located in the Coast Ranges of northern California, the Bartlett Springs Fault Zone is the easternmost fault in the San Andreas Fault system in northern California. The fault is a right-lateral, strike-slip structure considered capable of producing an earthquake of moment magnitude 7. The purpose of this mapping is to better characterize the geology and earthquake hazards associated with the southern part of the Bartlett Springs Fault Zone and to help identify any evidence of active uplift on the faults bounding the Coast Ranges. Although the area immediately surrounding the Bartlett Springs Fault Zone is sparsely populated, its southern segment presents a potential seismic hazard to northern California communities as far away as the San Francisco Bay region and Sacramento. There are also nearby water resources, mineral resources, and public lands used for public recreation. The Coast Ranges of northern California are a series of northwest-southeast-oriented mountain ranges and valleys located north of the San Francisco Bay region, between the Pacific Ocean to the west and the Sacramento Valley to the east. The region has rugged terrain, high mountain peaks that reach more than 2,400 meters above sea level, isolated and narrow valley bottoms on which most human settlements are located, and large drainage systems that tend to follow the northwest-southeast-oriented topographic grain. The physiographic character of the region is shaped by its bedrock geology, deformational history, and active faulting. The basement rocks of the northern Coast Ranges consist of the Franciscan Complex and the Great Valley complex, the latter of which consists of two informal units, the Coast Range ophiolite and the Great Valley sequence. The Franciscan Complex and the Great Valley complex are in structural contact along the Coast Range Fault, a regional-scale structure and fundamental crustal boundary. The Franciscan Complex and the Great Valley complex are superposed by active, northwest-southeast-striking strike-slip faults that are associated with seismicity swarms. These active strike-slip faults can produce moderate to large earthquakes that have moment magnitudes of 7–8. In places, these active structures bound large ranges and valleys, suggesting that much of the modern topographic expression is the result of active deformation processes. This report contains new 1:24,000-scale geologic mapping along the southern part of the Bartlett Springs Fault Zone between Clear Lake and Lake Berryessa. The map area spans 738 square kilometers in northern Napa County, southern Lake County, and parts of Yolo and Colusa Counties. The south and east borders of the map are 90 kilometers north of San Francisco and 70 kilometers west of Sacramento, respectively. The map area is within the Knoxville mining district, which has a history of mercury and gold mining dating back to the mid-19th century. The two main towns in the region, Lower Lake and Clearlake, California, are west-northwest of the map area. Approximately 71,000 people live in the cities and rural communities located within a 40-kilometer radius of the center of the map area. The bedrock geology, cross sections, and structural data presented herein are critical for evaluating the long-term evolution of the Bartlett Springs Fault Zone. This work will supplement studies on local seismic hazards, liquefaction potential, landslide hazards, earthquake geology, natural resources, groundwater resources, engineering geology, and tectonic history by providing the background information for site-specific investigations on these subjects.

California↗
USGS2025

Melt generation sources and conditions in the wake of a migrating slab window: Geochemistry and petrology of the million-year history of primitive volcanism at Clear Lake volcanic field, California

Clear Lake volcanic field (CLVF) is the northernmost and youngest (~2.2 Ma to 8 ka) of the volcanic centers distributed along the San Andreas transform fault in western California. The initial phase of CLVF volcanism (interval one) occurred between ~2.2 and 1.3 Ma and extends ~35 km southeast of Clear Lake, forming a semi-continuous upland plateau capped by lava flows, with isolated volcanic remnants on the periphery. This volcanism is broadly characterized by geochemically primitive compositions that reflect three source compositions and conditions of melt generation. (1) Partial melting of upwelling asthenospheric mantle lherzolite at moderate pressures (1.2–1.4 GPa) and temperatures (1297–1329 °C) produced high-CaO (9.8–11.3 wt %) basalts with high Al 2 O 3 (16.8–17.6 wt %), Mg#s (66–70), MgO (8–10 wt %), Ni (103–262 μg/g), and Cr (284–609 μg/g). These high-CaO basalts contain olivine (Fo 87–91 ) phenocrysts with Cr-spinel inclusions ± subordinate plagioclase and crop out only in the southern part of the CLVF. (2) Partial melting of depleted sub-continental lithospheric mantle harzburgite at variable pressures (0.7–1.5 GPa) and temperatures (1097–1299 °C) produced a compositional continuum of med-K 2 O, calc-alkaline, high-MgO basalts through high-MgO andesites with high Mg#s (67–77), MgO (8–14 wt %) and high Ni and Cr abundances (154–439 and 340–1124 μg/g, respectively). Mineral assemblages are olivine (Fo 88–93 ) with Cr-spinel inclusions ± subordinate clinopyroxene, orthopyroxene and plagioclase. Small (<2.5 cm) mantle harzburgite xenoliths and mantle olivine xenocrysts are also found in several of these samples. These high-MgO basalts through andesites represent the largest volume of primitive compositions and have erupted predominantly along the main, fault-controlled northwest-southeast trending axis of volcanism with peripheral outcrops to the north, west, and east. (3) Partial melting of the Gorda eclogite slab edge produced adakitic silicic slab melts with strong depletion in the heavy rare earth elements (Yb = 0.6 μg/g). Subsequent reaction of those melts with depleted ultramafic rocks during ascent imprinted the adakitic dacites with high Mg#s (65–78) and elevated Ni (117–210 μg/g) and Cr (191–283 μg/g). Phenocrysts of orthopyroxene (En 87–94 ) with spinel inclusions (Cr# = 80–88) and extremely Ni-rich (9483 μg/g) olivine cores (Fo 84–93 ) record those reactions. Small-volume outcrops of the adakites on the eastern periphery of the CLVF track the passing slab edge. The trio of melting sources recorded by early CLVF magmatism reflect the tectonically complex environment and the hot (1097–1329 °C), shallow (0.7–1.5 GPa) melting conditions for these primitive compositions and provide estimates of the heat delivered to the crust. Over time, this flux led to maturation of the CLVF magmatic system toward the more voluminous and silicic volcanism that characterizes the balance of its subsequent volcanic history and maintains the present-day anomalously high heat flow in the region. The current interval (interval four) of volcanic activity at CLVF is characterized by low-volume, fault-controlled eruptions of basaltic andesite and andesite suggestive of mantle magma and heat delivery to the crust, similar to interval one. This analogous activity provides motivation for the current study and begs the question of whether the system is undergoing thermal priming for renewed silicic volcanism.

California↗
USGS1999

Episodic sediment-discharge events in Cascade Springs, southern Black Hills, South Dakota

Cascade Springs is a group of artesian springs in the southern Black Hills, South Dakota, with collective flow of about 19.6 cubic feet per second. Beginning on February 28, 1992, a large discharge of red suspended sediment was observed from two of the six known discharge points. Similar events during 1906-07 and 1969 were documented by local residents and newspaper accounts. Mineralogic and grain-size analyses were performed to identify probable subsurface sources of the sediment. Geochemical modeling was performed to evaluate the geochemical evolution of water discharged from Cascade Springs. Interpretations of results provide a perspective on the role of artesian springs in the regional geohydrologic framework. X-ray diffraction mineralogic analyses of the clay fraction of the suspended sediment were compared to analyses of clay-fraction samples taken from nine geologic units at and stratigraphically below the spring-discharge points. Ongoing development of a subsurface breccia pipe(s) in the upper Minnelusa Formation and/or Opeche Shale was identified as a likely source of the suspended sediment; thus, exposed breccia pipes in lower Hell Canyon were examined. Upper Minnelusa Formation breccia pipes in lower Hell Canyon occur in clusters similar to the discrete discharge points of Cascade Springs. Grain-size analyses showed that breccia masses lack clay fractions and have coarser distributions than the wall rocks, which indicates that the red, fine-grained fractions have been carried out as suspended sediment. These findings support the hypothesis that many breccia pipes were formed as throats of abandoned artesian springs. Geochemical modeling was used to test whether geochemical evolution of ground water is consistent with this hypothesis. The evolution of water at Cascade Springs could not be suitably simulated using only upgradient water from the Minnelusa aquifer. A suitable model involved dissolution of anhydrite accompanied by dedolomitization in the upper Minnelusa Formation, which is caused by upward leakage of relatively fresh water from the Madison aquifer. The anhydrite dissolution and dedolomitization account for the net removal of minerals that would lead to breccia pipe formation by gravitational collapse. Breccia pipes in the lower Minnelusa Formation are uncommon; however, networks of interconnected breccia layers and breccia dikes are common. These networks, along with vertical fractures and faults, are likely pathways for transmitting upward leakage from the Madison aquifer. It is concluded that suspended sediment discharged at Cascade Springs probably results from episodic collapse brecciation that is caused by subsurface dissolution of anhydrite beds and cements of the upper Minnelusa Formation, accompanied by replacement of dolomite by calcite. It is further concluded that many breccia pipes probably are the throats of artesian springs that have been abandoned and exposed by erosion. The locations of artesian spring-discharge points probably have been shifting outwards from the center of the Black Hills uplift, essentially keeping pace with regional erosion over geologic time. Thus, artesian springflow probably is a factor in controlling water levels in the Madison and Minnelusa aquifers, with hydraulic head declining over geologic time, in response to development of new discharge points. Development of breccia pipes as throats of artesian springs would greatly enhance vertical hydraulic conductivity in the immediate vicinity of spring-discharge points. Horizontal hydraulic conductivity in the Minnelusa Formation also may be enhanced by dissolution processes related to upward leakage from the Madison aquifer. Potential processes could include dissolution resulting from leakage in the vicinity of breccia pipes that are abandoned spring throats, active spring discharge, development of subsurface breccias with no visible surface expression or spring discharge, as well as general areal leakage from the Madison aquifer into the Minnelusa Formation.

South Dakota↗
USGS2025

Origin and evolution of mafic volcanism associated with 3 m.y. of andesite production at the Goat Rocks volcanic cluster, southern Washington Cascade Range

More than 3 m.y. of mafic volcanism near the Goat Rocks volcanic cluster in the southern Washington Cascade Range, USA, lends insight into the evolution of basalts and the subarc mantle at a long-lived, major arc volcanic locus. We contribute field observations, 40 Ar/ 39 Ar dates, paleomagnetic directions, and bulk rock and mineral compositions to characterize nine mafic units that erupted in association with the Goat Rocks volcanic cluster. The time frame of mafic volcanism, ca. 3.6 Ma to 60 ka, encompasses the lifespan of the central volcanic cluster (3.1 Ma to 115 ka), with a lull from ca. 2.7 Ma to 1.4 Ma. A climactic period of voluminous mafic activity and far-traveled lava flows, including construction of the Hogback Mountain shield volcano, coincided with voluminous andesite eruptions from the central volcanic cluster. The basaltic rocks in the Goat Rocks area are calc-alkaline to barely tholeiitic and have high field strength element depletion relative to large-ion lithophile elements characteristic of calc-alkaline basalts (CAB) of the Cascade volcanic arc. Unlike at neighboring andesitic volcanic centers (Mounts Adams, St. Helens, and Rainier), no other mafic end members such as high-aluminum olivine tholeiite (HAOT) or intraplate-type basalt (IPB) are present at or near the Goat Rocks volcanic cluster, although some of the calc-alkaline basalts in this study have IPB-like affinities. The Goat Rocks mafic units exhibit two main temporal trends in composition: (1) the most primitive basalts erupted earlier, compared to less primitive and more evolved compositions later, and (2) high field strength element concentrations are higher in the younger basalt units relative to the oldest two. In contrast to these temporal trends, the mafic units define two compositional groups that recur through time, a low-Sr and a high-Sr group, each with distinct trace element and Sr and Nd isotope ratios. Although radiogenic isotope ratios are generally aligned with High Cascades CAB and HAOT, some extend toward IPB of Mount Adams and Simcoe Mountains volcanic field. Olivine-dominated crystal fractionation at shallow pressure from a small range of parent magma compositions accounts for much of the variation among the basalts and basaltic andesites. A high-pressure fractionation model is plausible for only one of the youngest basalt units (basalt of Walupt Lake volcano). Mafic recharge and crustal assimilation accounts for the incompatible-element enriched composition of basaltic andesites erupted during construction of the largest andesitic centers, further supporting sustained basalt mass flux and thermal energy driving andesite genesis. We model the most primitive members of the Goat Rocks mafic units as partial melts of successively less depleted mantle in time. Variable degrees of fluxing with fluids and melts from subduction explain the distinction between high-Sr and low-Sr groups. We propose that mantle metasomatism by ancestral subduction and fluid-flux melting is heterogeneously distributed through the local subarc mantle and played a greater role in the genesis of the high-Sr basalt group. The limited range of primitive basalt types around the Goat Rocks volcanic cluster contrasts with the much greater diversity of basalts throughout the southern Washington to northern Oregon Cascade arc. On the other hand, the central volcanic cluster encompasses nearly the entire diversity observed at neighboring composite volcanoes. In the case of the Goat Rocks area at least, and perhaps attributable to the entire region, this means that the genesis of diverse intermediate magmas is independent from and does not require vastly different parental basalt compositions.

California, Oregon, Washington↗