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Groundwater & aquifers

Find USGS research on groundwater & aquifers. Use publication dates, geographic coverage, abstracts, and original report links to locate studies relevant to a particular place.

351 records · Page 5Linked to original sources

Water supply in the conterminous United States, Alaska, Hawaii, and Puerto Rico, water years 2010–20

We present an assessment of water supply across the conterminous United States (CONUS), Alaska, Hawaii, and Puerto Rico covering water years 2010–20. Our analysis drew on two national hydrologic models, the National Hydrologic Model Precipitation-Runoff Modeling System and the Weather Research and Forecasting model hydrologic modeling system. Both models produced estimates of streamflow, evapotranspiration, soil moisture, snow water equivalent, and other hydrologic states and fluxes. The models were driven by the bias-adjusted 4-kilometer-resolution, long-term regional hydroclimate simulation over the conterminous United States dataset (CONUS404). We assessed spatial and temporal error distributions by comparing monthly simulations at the 12-digit hydrologic unit code and regional scale from both models against external benchmarking datasets. Results showed that average annual rainfall across the CONUS was 857 millimeters per year for the period of analysis, with water year 2012 the driest year (729 millimeters) and water year 2019 the wettest year (995 millimeters). Key interannual variability results included the following: (1) the California–Nevada hydrologic region had the highest variability in precipitation and snow accumulation, and (2) the Texas hydrologic region was among hydrologic regions with the highest variability in precipitation. We related interannual variability in precipitation to storage volumes in soil moisture, snow water equivalent, and lakes and reservoirs to highlight areas with little storage and large year-to-year variability in precipitation. These areas included the Southern High Plains, Central High Plains, Texas, Souris–Red–Rainy, Mississippi Embayment, and Midwest regions. Our analysis of groundwater-level data showed that several of these areas overlap aquifers where groundwater levels were considerably lower than historical averages, including the Colorado Plateaus aquifers, the Rio Grande aquifer system, and the Central and Southern regions of the High Plains aquifer. Many of these lowered groundwater levels are continuations of decades-long declines from overpumping that started well before the assessment period. The resulting water budgets and their analyses provide a high-resolution foundational assessment of the mean state and variability of the terrestrial hydrologic cycle across the CONUS and Alaska, Hawaii, and Puerto Rico to support a wide range of water resource management applications.

Professional Paper

Decadal trends in the quality of groundwater used for public drinking-water supply in California, 2004–23, California Groundwater Ambient Monitoring and Assessment Program, Priority Basin Project

This study provides a comprehensive assessment of decadal changes in the quality of groundwater used for public drinking-water supply at 444 monitoring sites across California during 2004–23. We assessed decadal step trends in groundwater quality for 145 water-quality constituents and geochemical indicators statewide and across geographic and land-use based network groups. We evaluated the statistical significance of directional changes (predominant increase or decrease of constituent concentrations) and the magnitude of those changes across all network groups. Uranium showed the most widespread directional and high-magnitude increases of all constituents with regulatory benchmarks statewide, particularly in the agriculture-dominated Central Valley as well as urban-and desert-dominated regions of Southern California. Fluoride and perchlorate showed the most widespread directional and high-magnitude decreases of all constituents with regulatory benchmarks statewide, which were also most pronounced in Southern California. Although arsenic and nitrate did not often register significant directional changes across network groups, they showed widespread, high-magnitude changes in both directions (increase and decrease) at levels often exceeding 10 percent of respective regulatory benchmarks statewide. Triazine herbicides (atrazine and simazine) and the gasoline oxygenate methyl tert -butyl ether showed significant directional decreases statewide, but not at levels considered to be of high magnitude compared to respective regulatory benchmarks. We observed significant directional and high-magnitude increases of total dissolved solids statewide, which were most pronounced in agricultural areas. Analysis of explanatory geochemical indicators indicated that prevalent statewide increases of alkalinity and calcium were the predominant components of the observed statewide increases in total dissolved solids by mass. Widespread increases in groundwater alkalinity and calcium across agricultural and urban areas may be related, in part, to warm-season irrigation and other anthropogenic factors that have shifted soil weathering dynamics over the long term. Increasing alkalinity concentrations were related to increasing uranium concentrations, particularly in areas with aquifer materials derived from granitic rocks. Conversely, increasing calcium concentrations were related to decreasing fluoride concentrations, particularly in areas where fluoride occurred naturally at elevated concentrations. Decrease of perchlorate, triazine herbicides, and methyl tert -butyl ether are likely related to decreased anthropogenic source inputs over time and natural attenuation in aquifers.

California

Multiple-well monitoring site adjacent to the Midway- Sunset and Buena Vista Oil Fields, Kern County, California

Groundwater quality in and around oil fields in the Southern San Joaquin Valley is of interest to many California residents that rely heavily on groundwater for domestic, commercial, and agricultural use. To help assess the effects of historical oil-field activities and natural geologic sources on groundwater near the southwest margins of the Kern County Groundwater Subbasin, a multiple-well monitoring site was installed near the administrative boundary between the Midway-Sunset and Buena Vista Oil Fields in Kern County, California. The installation of the Midway-Sunset Buena Vista multiple-well monitoring site (MSBV) supports regional analysis of the relations of oil and gas sources to groundwater quality by providing information about the geology, hydrology, geophysical properties, and water quality of the alluvial and upper Tulare aquifers in areas where groundwater data were limited. Data collected from the site included drill cuttings, whole core samples, sidewall core samples, mud-gas analysis, borehole geophysical logs, depth to water measurements, and water quality samples. Whole cores were scanned using dual energy computed tomography. Subsamples of selected cores were analyzed for density, porosity, specific retention, and bulk minerology. Thin sections of the subsamples were prepared, photographed, and examined. Two samples were analyzed using scanning electron microscope technology to examine the microporosity of diatomite laden sediment. Instrumentation installed in the wells collect hourly depth to water measurements. Analysis of the data show there is 355 feet of alluvium overlying the Tulare Formation at the well site. The contact between the two formations is an aquitard resulting in a perched aquifer in the alluvium and unconfined aquifer in the Tulare Formation. The alluvium is more heterogenous and finer grained than the Tulare Formation resulting in markedly higher porosity in the alluvium compared to the Tulare Formation. Higher specific retention observed in the alluvium is attributed to the finer grained sediment and greater abundance of reworked diatomite (as represented by opal-CT [cristobalite-tridymite]) compared to the Tulare Formation. Total dissolved solids (TDS) approached or exceeded 10,000 milligrams per liter (mg/L) in the alluvium from approximately 176 to 242 feet below land surface and at the top of the Amnicola clay at approximately 670 feet below land surface within the Tulare Formation. Elevated TDS, chloride, and boron concentrations in the alluvium and on top of the Amnicola clay likely reflect groundwater that is mixed with oil-field water. Water chemistry and modern-aged groundwater in the alluvial monitoring well (MSBV #3) are consistent with the oil-field water in the alluvium being derived from documented historical surface disposal of oil-field water upslope (northwest) of the site. Water chemistry and pre-modern groundwater age in the deeper Tulare monitoring well (MSBV #1) on top of the Amnicola clay are consistent with oil-field fluids derived from upslope natural geologic sources or old oil wells that leak in the subsurface. Shallow groundwater in the Tulare (MSBV #2) is not affected by mixing with oil-field sources.

EarthArXiv

A joint Gaussian process model of geochemistry, geophysics, and temperature for groundwater TDS in the San Ardo Oil Field, California, USA

Decline in availability of fresh groundwater has expanded interest in brackish groundwater resources; however, the distribution of brackish groundwater is poorly understood. Water resources in sedimentary basins across the United States often overlie oil and gas development. Mapping of groundwater total dissolved solids (TDS) using data from oil well geophysical logs has become an important technique for identifying fresh and brackish groundwater. Existing geophysical log analysis methods use porosity and temperature to relate formation resistivity to TDS. Typically, natural geothermal gradients are used to estimate temperature at the location of collected resistivity. However, in thermally enhanced oil fields, steam is injected into the subsurface to mobilize high viscosity oil, creating variable temperature distributions. Furthermore, TDS derived from resistivity also depends on the fractions of dominant ions. Typically, chloride and bicarbonate fractions must be determined. It is also necessary to model TDS across many geologic units with heterogenous porosity distributions. Collectively, each quantity used to estimate TDS (resistivity, porosity, temperature, bicarbonate fraction) varies in space and time, and available data points are rarely collocated. Here, we present a new method of mapping groundwater TDS that continuously models each quantity together with a joint Gaussian process. This method enables mapping fresh and brackish water with practically available data. We apply this method to the San Ardo Oil Field in Monterey County, California, where steam injection occurs. In some areas of the aquifer system overlying the oil zone, the temperature is ∼75 °C, roughly twice the natural background value. Groundwater TDS is typically <1,500 mg/L in the aquifer and increases with depth to ∼9,000 mg/L in the oil-producing zone. A low-permeability clay layer delineates the fresh and brackish water, likely by inhibiting surface recharge from penetrating the deeper zones, allowing higher-TDS connate water to remain in place. Weaker lateral TDS trends may be controlled by recharge patterns associated with the Salinas River. Our model reveals with high certainty that groundwater has freshened in one localized part of the oil-producing zone and suggests with less certainty that more widespread freshening has also occurred. The lowering of TDS was possibly from decades of low-TDS steam injection and the associated fluid production and disposal operations.

California

Multi-lithofacies alluvial characterization via airborne electromagnetic-borehole fusion using ordinary interval kriging and geologic constraints

Airborne electromagnetic (AEM) survey provides extensive spatial coverage and detailed resolution at the near surface and can be used to develop hydrogeological models. However, utilization of AEM data is not straightforward because AEM resistivity is an indirect measurement for inferring sediment types. This study develops an ordinary interval kriging (OIK) algorithm and a resistivity-to-multi-lithofacies (R2ML) data fusion workflow for multi-lithofacies alluvial characterization. OIK utilizes irregular interval data to construct three-dimensional (3D) resistivity fields from one-dimensional inverted AEM resistivity models. The R2ML workflow maps the resistivity field generated from OIK into a multi-facies lithological model, incorporating geologic constraints derived from well logs and geological observations. The numerical and real-world cases demonstrate that OIK is computationally efficient, accounts for 3D anisotropy, and minimizes the smoothing effect, thereby preserving resistivity contrasts and reducing interpolation uncertainty. The methodology is applied to lithologic characterization of the Mississippi River Valley alluvial aquifer (MRVA) in the Shellmound area, Mississippi, U.S. A frequency-domain AEM survey was conducted to support groundwater studies for the managed aquifer recharge (MAR) to the MRVA. The resulting lithological model, including four types of lithofacies—clay, very fine sand, fine-medium sands, and graveliferous sands, illustrates the geomorphological processes of the MRVA and implies potential MAR. The alignment between the lithological model and existing geological and hydrogeological investigations demonstrates that OIK and R2ML workflow effectively capture the subsurface architecture of the MRVA. The methods have broad applicability for characterizing alluvial aquifers through AEM-borehole data fusion, supporting sustainable groundwater management.

Mississippi

“Leaky weirs” capture alluvial deposition and enhance seasonal mountain-front recharge in dryland streams

“Leaky weirs” are rock structures installed in dryland streams, which are anchored into exposed bedrock, loosely cemented, and designed to allow water to slowly pass through. They are being tested at a ranch in southeastern Arizona, USA, to restore and conserve the historic range and desert wetlands. Data are collected to assess how leaky weirs impact surface water, subsurface water, and groundwater recharge—including stream discharge, timing, and depth of infiltration, and groundwater elevations. Three adjacent watersheds, two with outlets just below leaky weirs and one with leaky weirs farther upstream, were instrumented with water-level loggers, wildlife cameras, and crest stage instruments with temperature sensors in the soil. As most groundwater recharge is assumed to be focused along the mountain fronts in this region, mountain-block recharge is also evaluated to differentiate between the two using isotope analyses. Finally, a single, late-season flood event is scrutinized to consider the leaky weir effect on all monitored components in the water budget. Results indicated groundwater flow is primarily from the mountains to the east via older, regional mountain-block recharge. However, the development of shallow alluvial aquifers is supported by the leaky weirs, that slow flows, capture permeable sediments, and allow infiltration, thus enhancing mountain-front recharge. In turn, these new pockets of water help support the restoration of historic wetlands. Sediment accumulates where leaky weirs are installed, reducing flashy peak flows, and resulting in a series of infiltration ponds along the channel that support vegetation during growing seasons and recharge the shallow aquifer during non-growing seasons.

Arizona

The saline groundwater legacy of a large buried coastal paleo-estuary

Elevated groundwater salinity in coastal regions threatens the beneficial use of fresh groundwater. Coastal groundwater management typically focuses on preventing intrusion from modern sources of seawater; however, past geological processes can also leave a legacy of saline groundwater now hidden in the subsurface. Here, multiple extensive airborne electromagnetic surveys provide detailed evidence of residual salinity from a paleo-estuary filling a late Pleistocene incised valley impacting more than 10,000 km 2 that is now hidden beneath coastal Louisiana’s deltaic plain. Our results show that the three-dimensional pattern of saline groundwater beneath Louisiana mimics that of near-surface aquifers surrounding the modern Delaware Bay estuary, fingerprinting the signature of the past drowning of a large, incised valley of the Mississippi River following post-glacial sea-level rise. These findings demonstrate a new framework for understanding legacy sources of saltwater critical for managing stressed water resources along global coastlines.

Louisiana

Treatability study to evaluate bioremediation of trichloroethene at Site K, former Twin Cities Army Ammunition Plant, Arden Hills, Minnesota, 2020–22

Executive Summary Chlorinated solvents, including trichloroethene (TCE) and other chlorinated volatile organic compounds (cVOCs), are widespread contaminants that can be treated by bioremediation approaches that enhance anaerobic reductive dechlorination. Reductive dechlorination can be enhanced either through the addition of an electron donor (biostimulation) or the addition of a known dechlorinating culture (bioaugmentation) along with an electron donor. Although bioremediation has been applied at many TCE-contaminated groundwater sites, application in source zones at sites where residual dense nonaqueous phase liquid (DNAPL) is present is more limited. In this study, laboratory and field treatability tests were completed to evaluate the potential application of anaerobic bioremediation for a shallow groundwater plume containing TCE in a perched alluvial aquifer at Site K, former Twin Cities Army Ammunition Plant, Arden Hills, Minnesota, which was on the National Priorities List as the New Brighton/Arden Hills Superfund site until 2019. In addition to the presence of residual DNAPL at the site, temporal variability in groundwater flow directions and input of oxygenated recharge were possible complicating factors for the application of enhanced anaerobic biodegradation in the shallow plume. The Site K plume extends beneath the footprint of Building 103, which was demolished in 2006, and soil excavations to a maximum depth of 6 feet (ft) below ground surface in 2014 were known to leave some deeper contaminated soil in place in the TCE source area. Groundwater treatment at the site, formalized as part of the 1997 Record of Decision, has been in operation since 1986 and consists of an extraction trench at the downgradient edge of the plume to collect groundwater, which is then pumped to an on-site air stripper. Groundwater concentrations in the plume have been relatively stable since treatment began, indicating a continued source of TCE in the aquifer. The desire for a destructive remedy that would enhance the removal of cVOCs in the aquifer at Site K and shorten the remediation timeframe led the U.S. Army to request that the U.S. Geological Survey conduct a groundwater treatability study to assess bioremediation. This report describes the U.S. Geological Survey bioremediation treatability study conducted during 2020–22, including pre-design site characterization to assist in formulating the bioremediation approach, laboratory experiments to support the design of the field pilot test, and implementation and 1-year performance monitoring results for the pilot test. Pre-design site characterization included the collection of soil cores for cVOC analysis and lithologic descriptions and the re-installment of three wells to obtain hydrologic measurements and initial groundwater chemistry. Relatively flat head gradients were measured at the site, and substantial decreases in water-level elevations occurred from spring to summer (May–July 2021). Continuous water-level monitoring indicated a rapid response to precipitation. Groundwater flow velocities were consistently less than 0.5 foot per day, and the pilot bioremediation test was therefore designed with short lateral distances (about 5 ft) between injection and individual monitoring points. Soil analyses confirmed that high volatile organic compound contamination was left in place in the source area. The highest concentrations were near or in clay at the base of the perched aquifer. Concentrations of cVOCs measured in the replaced wells were consistent with historical data and had a maximum TCE concentration of 57,700 micrograms per liter (μg/L), indicative of nearby residual DNAPL based on the general rule of observed concentrations exceeding 1 percent of solubility. The primary TCE daughter product detected was 1,2-cis-dichloroethene (cisDCE), which indicated limited reductive dechlorination in the plume. Groundwater in both the source and downgradient areas was relatively reducing during the pre-design characterization, particularly in the source area where methane concentrations greater than 400 μg/L were measured. Initial laboratory tests conducted using native aquifer microorganisms from the three replacement wells showed that anaerobic TCE biodegradation rates were low when biostimulated with the addition of sodium lactate as an electron donor, also known as a carbon donor, and resulted in the production of only cisDCE. Addition of a known dechlorinating culture, WBC-2, however, resulted in rapid biodegradation and production of ethene, verifying complete reductive dechlorination of TCE. Microcosms constructed with aquifer soil collected from the site were used to evaluate other electron donors besides lactate to support reductive dechlorination by WBC-2, including corn syrup as an alternative fast-release compound and whey, soy-based vegetable oil, and 3-D Microemulsion (Regenesis, San Clemente, California) as slow-release compounds. First-order rate constants for total organic chlorine removal in these WBC-2 amended microcosms were greatest with either lactate or vegetable oil as the donor, ranging between 0.061 and 0.047 per day or corresponding half-lives of 11–15 days. Testing of commercial products in other WBC-2-bioaugmented microcosms led to selection for the field pilot test of an emulsified vegetable oil product that also contained some sodium lactate as a fast-release donor. Delaying the addition of WBC-2 relative to the donor in the microcosms resulted in the most rapid overall biodegradation rates. The selected design for the pilot test utilized three separate test plots, each about 30-ft wide and 60-ft long: plots GS1 and GS2 in the source area of the plume and plot GS3 in the downgradient area of the plume near the excavation trench. Each test plot had one injection well, one monitoring well upgradient from the injection point, and 12 surrounding monitoring wells in a grid to capture variable groundwater flow directions. Donor injections, which included a bromide tracer, were completed in October 2021, immediately following baseline sampling, and the WBC-2 culture was injected about 40 days later, between November 30 and December 2, 2021. Performance monitoring conducted until December 2022 included hydrologic measurements and analyses of cVOCs, redox-sensitive constituents, dissolved organic carbon, bromide, volatile fatty acids, compound-specific carbon isotopes, and microbial communities. The biogeochemical data collected during the pilot tests in the three treatment plots showed that enhanced, complete reductive dechlorination of cVOCs in the groundwater was achieved in the GS1 and GS3 plots. In contrast, evidence of distribution of the injected amendments and subsequent biodegradation was limited in GS2, which was in an area of more heterogeneous soil lithology and low water table elevations. The molar composition of volatile organic compounds in the GS1 and GS3 plots was dominated by ethene in wells that were reached by the injected amendments by the end of the monitoring period. In the GS1 and GS3 plots, similar patterns were observed of cVOC concentrations decreasing to near detection levels, or below, at some wells sampled in July and October 2022, whereas ethene became dominant and indicated sustained complete reductive dechlorination. Baseline cVOC concentrations were more than a factor of 10 higher in the groundwater in the GS1 plot than in GS3, but no apparent inhibition of complete dechlorination occurred. As expected from the initial pre-design site data and the laboratory experiments, enhanced dissolution of residual DNAPL coupled to biodegradation was evident in the GS1 plot, where a marked increase in dichloroethene (DCE) above the initial baseline and upgradient TCE and DCE concentrations occurred. DCE concentrations subsequently declined where DNAPL dissolution was evident, concurrent with production of vinyl chloride and then predominantly ethene. Thus, overall biodegradation rates outpaced the DNAPL dissolution and desorption and DCE production in the source area. This success in complete degradation to predominantly ethene was achieved even in areas where the DCE concentrations reached a maximum of about 30,000 μg/L. Compound specific isotope analysis of carbon in TCE, cisDCE, trans-1,2-dichloroethene, and vinyl chloride was conducted to provide another line of evidence of the occurrence and extent of anaerobic biodegradation. Along a flow path in each plot that was affected by the injected amendments, carbon isotopes in the TCE and daughter cVOCs in the groundwater became isotopically heavier, indicating biodegradation. Enhanced biodegradation rates calculated from the field tests in GS1 and GS3 showed half-lives of 36.9–75.3 days for DCE degradation and 9.48–38.5 days for ethene production. Notably, these ethene production rates calculated from the field tests are consistent with the results of WBC-2-bioaugmented microcosms amended with either lactate or vegetable oil, which had half-lives for total organic chlorine removal that ranged from 11 to 15 days. These rates indicated rapid enhanced biodegradation, which is promising for application of a full-scale bioremediation remedy. Ultimately, however, the mass of residual or sorbed TCE in the aquifer that remains accessible for dissolution and biodegradation would likely control the time required for a full-scale bioremediation effort to achieve performance goals for TCE and cisDCE specified in the Record of Decision for Site K. The field pilot tests showed that the relatively low hydraulic head gradients and temporal changes in groundwater flow directions in the shallow aquifer would add complexity to a full-scale bioremediation effort. The radius of influence (ROI) at GS1 and GS3 (16.3 ft and 12.7 ft, respectively) were close to the design ROI of 15 ft. The estimated ROI at GS2 was about four times the design ROI, but may be less reliable at this location owing to groundwater flow direction. In addition, the low temperatures following WBC-2 injection in late November to early December 2021, in combination with the low hydraulic head gradients, were probably major factors in the delay observed before the onset of enhanced biodegradation following injection of the culture. Additional test injections could be beneficial to optimize the timing of donor and culture injections with the variable temperatures and hydraulic head in the shallow aquifer.

Minnesota

Evidence of mineral alteration in a salt marsh subterranean estuary: Implications for carbon and trace element cycling

Subterranean estuaries (STE) in salt marshes are biogeochemically active zones where interactions between terrestrial groundwater and seawater drive complex cycling of carbon and trace elements, influenced by mineral dissolution. These systems, characterized by fine-grained organic-rich peat overlying permeable coastal aquifers, play a crucial role as a blue carbon sink, yet their geochemical dynamics remain poorly understood. We investigated dissolved trace elements, carbon, silica, and radium isotopes in a salt marsh STE (Sage Lot Pond, Waquoit Bay, MA) over seasonal and annual cycles. Our results reveal that groundwater and estuarine water circulation through marsh peat and aquifer sediments leads to enrichments of dissolved organic and inorganic carbon (DOC and DIC), Si, Ba, and Mn, with variable source/sink behavior of Fe and net removal of U. Submarine groundwater discharge dominated Ba fluxes, whereas pore water drainage from marsh peat acted as the main sink for U and source of Si. Fe cycling was variable, with terrestrial Fe largely removed as groundwater passed through the STE, consistent with Fe-sulfide and amorphous phase formation. Radium isotope ratios identified two distinct subsurface flow pathways, influenced by metal-oxide cycling and organic matter breakdown. Si production was decoupled from DIC, suggesting Si originates from mineral alteration, whereas DIC results from both mineral weathering and microbial respiration. Silicate mineral alteration, coupled with marsh pore water drainage, accounts for up to 16% of annual DIC exports (66 g C m −2 y −1 ), highlighting the importance of STEs in coastal carbon and trace element cycling, especially as marshes face environmental change.

Massachusetts

Water use permits as of July 2024 and reported water use near the North Unit of Theodore Roosevelt National Park, North Dakota, 1980–2023

Starting in the early 2000s, increasing oil and gas development in western North Dakota created a need for additional water resources from surface-water and groundwater sources near the North Unit of Theodore Roosevelt National Park. To summarize the use of water in that area, the U.S. Geological Survey, in cooperation with the National Park Service, developed a map of surface-water and groundwater resources, aquifers, and water-use diversions, and plotted water-use trends from 1980 to 2023. Reported water used from permits in the map area has more than doubled since 2020, increasing from about 750 acre-feet in 2020 to about 2,300 acre-feet in 2022 and 2,000 acre-feet in 2023. Surface water provided the primary source of reported water used for the study period with an average of about 410 acre-feet per year from 1980 through 2017 and about 1,330 acre-feet per year from 2018 through 2023. After 2011, groundwater sourced from the Little Missouri River, Tobacco Garden Creek, Fox Hills, Fort Union, and Dakota aquifers became a larger portion of total annual reported water use from permits in the map area. From 1980 through 2015, water use for irrigation averaged 86 percent of the total annual reported surface-water and groundwater use in the map area. Starting in 2011, however, industrial uses became a proportionally larger total use of water, and in 2015, became the highest reported volume of water use in the map area. From 2011 to 2023, industrial use designated for water depots increased from 50 acre-feet to about 1,370 acre-feet, accounting for about 70 percent of total reported water use in the map area in 2023.

North Dakota

Groundwater tracing used to delineate recharge areas and map karst groundwater pathways for subterranean streams at Oregon Caves National Monument and Preserve

Oregon Caves National Monument and Preserve in southwestern Oregon is a 4,554-​acre area managed by the National Park Service that is home to several cave systems, including Oregon Caves, which is the longest cave in Oregon, with 3.03 miles of mapped passages. Because of the interconnected nature of karst hydrologic systems, it is critical to understand the areas that can influence water quality and quantity in karst environments. Toward this goal, dye tracing was conducted by the U.S. Geological Survey from 2021 to 2024 to better understand the pathways that karst groundwater follows at Oregon Caves National Monument and Preserve and to delineate recharge areas for two caves, Oregon Caves and Cave Next Door. During the project, eight dye injections were conducted, delineating a 0.51-​square-​mile recharge area for Oregon Caves and a 0.69-​square-​mile recharge area for Cave Next Door. Additionally, the study helped to identify three resurgences associated with Oregon Caves that were previously unknown and showed that the recharge areas for the two caves were distinct from one another. The dye traces also illuminated some unique recharge characteristics of the karst at Oregon Caves, including a high variance in karst groundwater velocities, retention within the karst aquifers, and a significant diffuse-​flow component.

Oregon

Decadal trends and occurrence of geogenic constituents and mixtures in groundwater across the continental United States

Worldwide, about 50% of the population is served by groundwater-sourced drinking water. Numerous groundwater quality assessments have found that geogenic constituents are among the most common contaminants in drinking-water aquifers. Documenting changing groundwater quality is a crucial aspect of water availability assessments. We assess trends and occurrence of geogenic constituent concentrations in groundwater across the continental United States using 3 decades of data from the U.S. Geological Survey’s National Water Quality Network. Thousands of groundwater wells were grouped into agricultural, urban, or domestic supply network types. Although most networks and constituents had no statistically significant change in concentration, many had increasing concentration trends, elevated concentrations, or both. Lithium, sodium, radium, sulfate, and uranium had increasing trends in more than 10% of the study networks. Urban and domestic well networks had increasing lithium and sodium trends more often than agricultural networks. Manganese most commonly increased in domestic well networks; uranium more commonly increased in agricultural and urban networks. Elevated concentration mixtures were widespread, and mixture complexities appeared to increase over time. Our results indicate that more than 2.3 million domestic-well users may be affected by elevated concentrations of one or more geogenic constituents.

continental United States

Controls on water quality below a reclaimed surface coal mine, southeastern Montana

Coal mining and reclamation can have a profound influence on hydrogeologic systems, with clear consequences for groundwater quality, yet their long-term influence on downgradient water quality over time following reclamation is less well documented. Geochemical trends were evaluated in water quality downgradient of a fully reclaimed landscape at the former Big Sky Mine in the Rosebud Creek watershed (southeastern Montana, USA), over a 3-year period (2020–2022), including bond release in 2022. Within 6 km downgradient from the reclaimed area, sulfate concentrations decreased from approximately 3500 to 1800 mg l −1 within the Miller Coulee alluvial aquifer. Major ions, δ 34 S SO4 values, and residence time tracers suggest that the observed decreases in sulfate concentration result from a combination of dilution by mixed-age inflows and incomplete transit of the high salinity plume from the mine boundary. Both bedrock and alluvial aquifers of the Rosebud Creek corridor contained contributions of millennia-old regional groundwater, which may serve to mitigate mine-derived high salinity waters. Rosebud Creek, which traverses the outflow zone of Miller Coulee in the study area, exhibited high sulfate concentrations during low flows and consistent downgradient increases in sulfate concentration. The possibility of plume dynamics in Miller Coulee suggests that the greatest water quality impacts may not yet have reached Rosebud Creek.

Montana

Data gap analysis for estimation of agricultural return flows in the Upper Gunnison River Basin, Colorado

The Gunnison River and many tributaries in the Upper Gunnison River Basin provide water to irrigate agricultural crops. The application of irrigation water can recharge some aquifers locally by water percolating below the root zone and eventually flowing back to the stream or river through the subsurface. Diverting surface water for irrigation reduces streamflow during the irrigation season but can provide temporary storage of water and supplement streamflow after the snowmelt runoff season. Understanding the timing and quantity of agricultural return flows could help resource managers make informed decisions and adapt to potential changes in water management and availability that could affect irrigation practices. In 2024, the U.S. Geological Survey, in cooperation with the Upper Gunnison River Water Conservancy District, began a study to characterize agricultural return flows in the Upper Gunnison River Basin by using endmember mixing analysis and developing a groundwater model. Both approaches require data from multiple sources, but data gaps exist in the East River study reach and other reaches of interest (Ohio Creek, Tomichi Creek, and Cochetopa Creek). The East River Basin, which is the initial focus of the study, has fewer data gaps than the other basins. Data gaps could be addressed by installing additional surface water and groundwater monitoring sites, making regular streamflow measurements on tributaries, and completing tests to characterize local aquifer properties.

Colorado

Multidecadal change in pesticide concentrations relative to human health benchmarks in the Nation’s groundwater

Groundwater-quality trend assessments identify aquifers that are responding to changes in pesticide use and the compounds that may pose a threat to water availability. The U.S. Geological Survey has been monitoring pesticide concentrations in groundwater for 25 principal aquifers across the conterminous United States since 1993. The groundwater well locations represent a range of soils, climate, and landforms. The wells are used to monitor groundwater underlying selected agricultural and urban settings and groundwater used for domestic supply. This study examined changes in relative concentrations, defined here as the percentage of wells with pesticide concentrations exceeding a human health benchmark (HHB). HHBs used in this report are legally enforceable drinking-water standards and nonenforceable drinking water levels. Relative pesticide concentration increases may lead to decreased water availability, as restrictions may be put in place for groundwater used as a drinking-water source. This study focused on concentration changes in 22 pesticides that were included in laboratory analysis from 1993 to 2023. The analysis and interpretation of these pesticide concentrations in groundwater have been separated into approximate decadal intervals (decade 1 (1993–2001), decade 2 (2002–12), and decade 3 (2013–22). For one pesticide, 1,2-dibromo-3-chloropropane (DBCP), concentration data were also collected in decade 4 (2023–onward). Atrazine, deethylatrazine, alachlor, prometon, and simazine were 5 pesticides detected at moderate concentrations (greater than 10 percent of the HHB but less than or equal to the HHB). The percentage of wells that had groundwater pesticide concentrations in the moderate concentration category decreased from 7 percent in decade 1 to 2 percent in decade 3. The agricultural networks had the highest percentages of wells with moderate concentrations, and these percentages decreased from 13 percent in decade 1 to 4 percent in decade 3. Moderate concentrations in the urban networks decreased between decades 1 and 2 from 4 percent to 0 percent. No moderate concentrations occurred in the urban networks in decade 3. The percentage of wells with moderate concentrations in the domestic supply networks (1 percent) was the lowest of all the network types and did not change across the three decades. Moderate atrazine or deethylatrazine concentrations occurred across all three decades in aggregated ecoregions representing similar soils, climate, and landforms in the Semiarid West, Midcontinent, and Northeastern United States. Moderate concentrations of prometon, alachlor, and simazine also occurred in the Midcontinent, Arid West, Northeast, South Atlantic Gulf, and Semiarid West regions, but the moderate concentrations did not persist across all three decades. DBCP was the only pesticide that exceeded its respective HHB, and the exceedances occurred across all four decades. In this report, the DBCP analysis was limited to one well network in the Central Valley, California. Agricultural use of DBCP was suspended in 1977. Forty-five years after being banned, DBCP concentrations were greater than the maximum contaminant level of 2 micrograms per liter (μg/L), but the number of exceedances decreased from 50 percent to 15 percent of the samples between 1993 and 2023. This assessment of decadal groundwater pesticide concentrations provides a characterization of changes in water availability because of pesticide contamination in areas where groundwater is used as a drinking-water source. The results highlight the importance of continued long-term monitoring and assessment of groundwater pesticides to identify locations and specific compounds that may pose a potential risk to human health.

continental United States

Modeling future groundwater depletion to evaluate sustainability goals set under the Sustainable Groundwater Management Act in the critically overdrafted basins of the Central Valley, California, USA (2020–2070)

In 2014, California's Sustainable Groundwater Management Act (SGMA) mandated local agencies to devise and implement groundwater sustainability plans to address critically overdrafted conditions throughout the state's aquifers. However, the feasibility of these agencies' sustainability goals has not previously been assessed through a regional-scale, integrative lens. Here, we develop and analyze a novel, basin-wide database of 936 sustainability indicator wells located within Central Valley subbasins designated as critically overdrafted, most of which lie in the San Joaquin Valley. Our database shows 2040 groundwater elevation goals vary widely from 60 m above to 80 m below 2020 levels, with variability within and between adjacent subbasins. To evaluate the feasibility of achieving these goals, we coupled the database with a regional hydrologic model (Central Valley Hydrologic Model version 2) and simulated multiple future pumping scenarios. Results show that under increased groundwater demand, 60%–70% of indicator wells may fail to meet their 2040 goals. Even a 50% reduction from 2020 demand levels leaves nearly 40% of wells failing to meet their sustainability thresholds by 2040. Baseline models show that by 2070, up to 70% of wells could fail to meet their goals due to large-scale, spatially connected regions of groundwater depletion. This integrated framework, linking the first region-wide compilation of SGMA indicator wells with a regional groundwater model, demonstrates that many local sustainability goals may be unattainable with substantial (up to 50%) reductions in pumping. Additional management interventions, such as expanded recharge or coordinated demand reductions, may help achieve sustainability goals.

California

Hypothetical CO2 leakage into, and hydrological plume management within, an underground source of drinking water at a proposed CO2 storage facility, Kemper County, Mississippi, USA

A large Geologic Carbon Sequestration (GCS) hub has been proposed in Kemper County, Mississippi. The target injection interval consists of numerous Cretaceous-aged deep saline aquifers overlain by a competent and extensive regional sealing layer. Above the seal, the deepest Underground Source of Drinking Water (USDW) at the site is the Eutaw aquifer of the Eutaw Group and McShan Formation, undifferentiated. To assess potential risks of leakage from the deep sequestration reservoir, a model of a portion of the Cretaceous Eutaw Group was constructed in this study. Simulations tested various permeabilities, hypothetical leakage rates, and plume mitigation strategies utilizing existing wells. Results suggest that, under the influence of regional groundwater flow fields, leaking CO 2 would effectively bypass the existing wells, and to influence this migration would require very large water extraction rates. Therefore, to ensure plume detection, monitoring for leakage at the injection wells themselves is very important.

Mississippi

Simulation of groundwater flow to evaluate hydrogeologic controls on a PFAS plume, Coakley Landfill Superfund Site, Rockingham County, New Hampshire

Per- and polyfluoroalkyl substances (PFAS), including perfluorooctanoic acid (PFOA) and perfluorooctanesulfonic acid (PFOS), have been detected at combined concentrations above 2,000 nanograms per liter (ng/L) at groundwater seep locations near the Coakley Landfill Superfund site, in North Hampton, New Hampshire. The landfill was active from 1972 to 1985. An impermeable cap was placed on the landfill in 1998. The adjacent area to the Coakley Landfill has many water supply wells, and transport of PFAS compounds to the wells is a concern. Fracture anisotropy in the underlying bedrock aquifer complicates the understanding of PFAS transport because groundwater preferentially travels along fractures that may not align with the prevailing groundwater flow direction. In 2018, the U.S Environmental Protection Agency and the U.S. Geological Survey began an investigation of the groundwater flow from the Coakley Landfill site. This report describes the modification of a numerical groundwater-flow model for the local area around the Coakley Landfill and summarizes findings of the investigation. In addition, this report includes a brief description of PFOA and PFOS occurrence, a discussion of model construction, evaluation of model performance through calibration, and discussion of simulation results for two periods (before and after capping). Limitations are also discussed. Results show that simulated groundwater flow moves from the Coakley Landfill to the west and north. Advective transport modeling using particle tracking shows that groundwater from the landfill discharges primarily to streams to the west and north, and a small amount is transported to distal wells. Dilution of contaminants through advection and dispersion likely plays a role in whether PFAS compounds from the landfill will be detected above laboratory reporting levels at distal wells.

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