Consideration of grid cell size to represent stream network geometry for the conterminous United States
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Nitrogen dynamics in intertidal and nearshore subtidal groundwater (subterranean estuary) adjacent to the Seacoast Shores peninsula, Falmouth, Massachusetts, were investigated during 2015–16 by the U.S. Geological Survey. The peninsula is a densely populated residential area with septic systems and cesspools that are substantial sources of nitrogen to groundwater. The study area is in the Eel River, an estuarine saltwater embayment connected to the ocean adjacent to the western shore of the peninsula, that was the subject of an earlier study by Colman and others (2018, https://doi.org/10.3133/sir20185095 ) on nitrogen transport and transformations in groundwater between onshore and offshore locations. The previous study documented the distribution of nitrate concentrations and nitrate attenuation reactions in fresh groundwater beneath the peninsula and the estuary. The current study extended those observations with more detailed sampling and analysis of shallow groundwater from wells near discharge sites beneath the estuary. The current field investigation included sampling of existing wells and installation and sampling of clusters of wells and temporary sampling points in the subterranean estuary, including (1) shallow transects 0.3 to 1.2 meters (m) deep extending from 1 to 13.5 m offshore and (2) deeper wells (from 1.83 to 4.88 m deep) extending from 4.3 to 14.3 m offshore. Measurements of hydraulic-head gradients 2–5 m below the sediment/water interface in the intertidal and nearshore subtidal zones indicated that groundwater flow generally was upwards (towards the estuary) under all tide conditions in October 2016. The magnitude of the gradient was greatest during low tide conditions, indicating that groundwater discharge likely decreased during high tides. Measurements of specific conductance in shallow groundwater in the subterranean estuary in three transects perpendicular to shore were consistent with the existence of saltwater flow cells (infiltration of overlying saline water, mixing with fresh groundwater, and discharge to the overlying saline water) in the intertidal and nearshore subtidal regions. The size of these flow cells was variable in space and time and dependent on the elevation of the tide (spring or neap). At this location in the Eel River subterranean estuary, and offshore to at least 13.5 m, offshore flow of fresh groundwater apparently prevented a deeper saltwater wedge from discharging to the surface. Nitrate concentrations in shallow groundwater (30 to 122 centimeters [cm] depth) were variable in space and time, ranging from not detectable to 600 micromoles per liter (μmol/L) (8.4 milligrams per liter as N), and were highest in June 2016 at depths from 61 to 122 cm below the sediment/water interface and from 4 to 9 m offshore. Nitrate generally was not detectable in saline shallow groundwater at 30-cm depth or at any depth from 30 to 122 cm from 10 to 13.5 m offshore. Dissolved oxygen concentrations were suboxic (less than 16 μmol/L) in 60 percent of the sampled subterranean groundwater beneath the intertidal and subtidal zones. In the remaining sites, the range of dissolved oxygen concentrations was from 18 to 272 μmol/L and the median concentration was 43 μmol/L. Evidence for microbial nitrate reduction (denitrification and possibly anammox) was provided by the distribution of the reaction product nitrogen gas (excess N 2 , or N 2MIC ), as determined from analysis of the dissolved nitrogen gas and argon gas (Ar) concentrations in groundwater samples. Excess nitrogen gas provided evidence for nitrate reduction in shallow groundwater below the subtidal and, to a lesser extent, intertidal zones adjacent to the Seacoast Shores peninsula. These zones, where evidence for nitrate reduction was detected, were in fresh and brackish groundwater near subtidal or intertidal saltwater cells where discharging fresh groundwater mixed with infiltrating saline water. Infiltrating seawater may have supplied organic carbon, one of several potential electron donors that are required for denitrification. Other potential electron donors, such as organic carbon, iron, manganese, hydrogen, methane, ammonium, elemental sulfur, or sulfide phases, may have been supplied by the estuarine sediments. Drainage from surface runoff near the shore also may have supplied organic carbon to fresh groundwater near the intertidal saltwater cell. The highest amounts of nitrate converted to excess nitrogen gas were estimated to be in the range of 230 to 430 μmol/L in nearly fresh groundwater near the subtidal saltwater cell at depths of 61 to 122 cm below the sediment/water interface and from 10 to 13.5 m offshore. Evidence of denitrification within 10 m of the shore was sparse (generally limited to less than 50 μmol/L of N 2 -N) despite the presence of high nitrate concentrations. The spatial distribution of estimated nitrate reduction in the intertidal and nearshore subtidal fresh and brackish groundwater may be related to local variability in the distribution of reactive electron donors in those zones. Variations in the amount of nitrate reduction to nitrogen gas were not clearly related to potential aqueous electron donors such as dissolved organic carbon, nor to potential reaction products such as alkalinity, but may have been controlled by combinations of aqueous and solid-phase reactants. The distribution of relatively shallow fresh groundwater containing nitrate could indicate potential nitrate discharge areas in the lower intertidal zone and uncertain locations farther offshore; however, the data did not extend all the way to the sediment/water interface or to the offshore freshwater limit. This study confirmed substantial loss of nitrate from some of the fresh and brackish groundwater in shallow subestuarine sediments prior to discharge but did not quantify how much nitrate eventually discharged to the estuary.
Groundwater flow in the active model area (AMA) was simulated using a groundwater-flow model. A steady-state model version of the model simulates equilibrium conditions, and a transient model version simulates monthly variability. The model corresponds to the physical and temporal dimensions of the conceptual model and groundwater budget. The steady-state model version represents average conditions for an 11-year period (January 1, 2005–December 31, 2015), and the transient model represents monthly hydrologic variability within that period. The 13-layer model was constructed using MODFLOW-NWT with a uniformly spaced grid consisting of 416 rows, 433 columns, and cells with a horizontal dimension of 500 feet (ft) on a side. The model was calibrated to measured values of water levels in wells and lakes and estimated base flow for selected streamflow measurement stations, commonly referred to as streamgages. Model calibration was accomplished using a combination of manual and automatic methods, including the Model-Independent Parameter Estimation (PEST) program that adjusted model input parameters with the aim of minimizing the difference between estimated and model-simulated values of hydraulic head and base flow. Model boundary conditions consist of all simulated groundwater inflow to and outflow from the AMA. For example, a stream reach that simulates a gain from or loss to groundwater is a boundary condition that allows water to exit or enter, respectively, the groundwater system. Other boundary conditions include springs, seeps, precipitation recharge, groundwater exchange with lakes and Puget Sound, and groundwater pumping. A comparison of the estimated groundwater budget to that simulated by the steady-state model version indicates that the relative percentages of total inflow or total outflow for six major categories of boundary conditions are similar for the two budgets. The model was used to simulate three suites of scenarios of potential drought and water-use changes. Scenario 1 suite consisted of the steady-state model version that was run with 0, 15, 20, and 25 percent reduction of precipitation recharge to assess the corresponding reductions in base flow with decreasing recharge. The last simulation for the scenario 1 suite consisted of the transient model version simulating 3 years of consecutive seasonal drought, defined by the months of May through September, to assess the corresponding base-flow reductions. Scenario 2 suite consisted of the steady-state model version with all simulated groundwater use removed, compared with a simulation that includes current groundwater use to evaluate changes to potentiometric surfaces and base flows. Scenario 3 suite consisted of a transient model version of the model that simulated pumping increases for four different categories of water-supply wells (compared to no pumping increases) to evaluate resulting reductions in base flow. Although, these scenarios provide examples of model applications and useful insights, many other scenarios could be simulated. A description of how to download the model is described in the body of this report. Uncertainty is associated with most model inputs. Groundwater levels, lake levels, and land-surface altitudes are relatively certain; other model inputs are far less certain, including precipitation recharge, base flow, hydraulic properties, water use, and the three-dimensional structure of subsurface hydrogeologic units. Models are useful not because of high levels of accuracy of all model inputs, but because they combine the best information and estimates available, thereby providing the best predictions available related to physical processes. The model described in this report simulates groundwater flow on a regional scale, which has inherent limitations for simulating hydrologic scenarios at local scales. Model structures and inputs were generalized to be consistent with this regional scale. For example, the actual groundwater system has much greater heterogeneity of hydraulic conductivity than is possible within the model’s degrees of freedom. Variations in hydraulic gradients over distances less than 500 ft cannot be simulated. The distances between model features, such as a pumping well and a stream, must be placed at 500-ft intervals and are co-located if both features are within the same model cell.
Evaluating stream water chemistry patterns provides insight into catchment ecosystem and hydrologic processes. Spatially distributed patterns and controls of stream solutes are well-established for high-relief catchments where solute flow paths align with surface topography. However, the controls on solute patterns are poorly constrained for low-relief catchments where hydrogeologic heterogeneities and river corridor features, like wetlands, may influence water and solute transport. Here, we provide a data set of solute patterns from 58 synoptic surveys across 28 sites and over 32 months in a low-relief wetland-rich catchment to determine the major surface and subsurface controls along with wetland influence across the catchment. In this low-relief catchment, the expected wetland storage, processing, and transport of solutes is only apparent in solute patterns of the smallest subcatchments. Meanwhile, downstream seasonal and wetland influence on observed chemistry can be masked by large groundwater contributions to the main stream channel. These findings highlight the importance of incorporating variable groundwater contributions into catchment-scale studies for low-relief catchments, and that understanding the overall influence of wetlands on stream chemistry requires sampling across various spatial and temporal scales. Therefore, in low-relief wetland-rich catchments, given the mosaic of above and below ground controls on stream solutes, modeling efforts may need to include both surface and subsurface hydrological data and processes.
The Santa Ana River drains about 2,670 square miles of the densely populated coastal area of southern California, near Los Angeles. Almost all the flow in the river, more than 200,000 acre-feet annually, is diverted into ponds where it infiltrates and recharges underlying aquifers. About 2 million people are dependent on these aquifers for water supply. Stormflow in the Santa Ana River is considered a source of "high-quality" water suitable for use as a source of ground-water recharge. To test this assumption, stormflow samples were collected at two locations--below Prado Dam and at the diversion point downstream from Imperial Highway--for 12 winter storms between 1995 and 1998. Nitrate concentrations decreased during stormflow from a median concentration of 7.8 milligrams per liter in base flow to concentrations less than 1 milligram per liter in some large storms. Concentrations of chemically reduced forms of nitrogen (nitrite, ammonia, and organic nitrogen) increased during stormflow and are the predominant forms of nitrogen in large stormflows. Dissolved organic carbon (DOC) concentrations increased from a median concentration of 4.6 milligrams per liter in base flow to more than 20 milligrams per liter in some stormflows. Concentrations of DOC were especially high during the first storm of the rainy season, and large increases in DOC concentrations were measured even as a result of small early season storms that did not cause large increases in streamflow. DOC present during early season stormflow had less ultraviolet absorbance at 254 nanometers (UV 254 ) per unit of carbon than did DOC from late season stormflows. DOC in water held in storage behind Prado Dam had the highest UV 254 absorbance per unit of carbon. Maximum pesticide concentrations in stormflow did not exceed U.S. Environmental Protection Agency Maximum Contaminant Levels. Most pesticide concentrations were less than 1 microgram per liter and less than the detection limits obtained using standard drinking water analyses. Increases in concentrations of pesticides such as diazinon, malathion, and chlorpyrifos in stormflow result from runoff from urban areas downstream from Prado Dam. In general, large late season stormflows have the most pesticide detections of all stormflows sampled. Concentrations of methyl tert-butyl ether (MTBE), a gasoline additive, during base flow were as high as 0.9 microgram per liter and concentrations decreased during stormflow. Like pesticides, the concentrations did not exceed the U.S. Environmental Protection Agency Maximum Contaminant Levels for MTBE.
Climate change in California is expected to alter future water availability, impacting water supplies needed to support future housing growth and agriculture demand. In groundwater-dependent regions like California's Central Coast, new land-use related water demand and decreasing recharge is already stressing depleted groundwater basins. We developed a spatially explicit state-and-transition simulation model that integrates climate, land-use change, water demand, and groundwater gain-loss to examine the impact of future climate and land use change on groundwater balance and water demand in five counties along the Central Coast from 2010 to 2060. The model incorporated downscaled groundwater recharge projections based on a Warm/Wet and a Hot/Dry climate future from a spatially explicit hydrological process-based model. Two urbanization projections from a parcel-based, regional urban growth model representing 1) recent historical and 2) state-mandated housing growth projections were used as alternative spatial targets for future urban growth. Agricultural projections were based on recent historical trends from remote sensing data. Annual projected changes in groundwater balance were calculated as the difference between land-use related water demand, based on historical estimates, and climate-driven recharge plus agriculture return flows. Results indicate that future changes in climate-driven groundwater recharge, coupled with cumulative increases in agricultural water demand, result in overall declines in future groundwater balance, with a Hot/Dry future resulting in cumulative groundwater decline in all but Santa Cruz County. Cumulative declines by 2060 are especially prominent in San Luis Obispo (−2.9 to −5.1 Bm 3 ) and Monterey counties (−6.5 to −8.7 Bm 3 ), despite limited changes in agricultural water demand over the model period. These two counties show declining groundwater reserves in a Warm/Wet future as well, while San Benito and Santa Barbara County barely reach equilibrium. These results suggest future groundwater supplies may not be able to keep pace with regional demand and declining climate-driven recharge, resulting in a potential reduction in water security in the region. However, our county-scale projections showed new housing and associated water demand does not conflict with California's groundwater sustainability goals. Rather, future climate coupled with increasing agricultural groundwater demand may reduce water security in some counties, potentially limiting available groundwater supplies for new housing.
Across the United States, rural residents rely on unregulated and generally unmonitored private wells for drinking water, which may pose serious health risks due to unrecognized contaminants. We assessed the nature, degree, and spatial distribution of cumulative health risks from inorganic contaminants in groundwater. Our analysis included nearly 84,000 data points from 6500+ wells, across 51 of Montana's 98 watersheds, using a public groundwater database. We compared a drinking water screening level cumulative risk assessment (CRA) for inorganics based on the U.S. Environmental Protection Agency (EPA) protective health thresholds (Maximum Contaminant Level Goals, Health Advisories [MCLG-HAs]) to a CRA based on EPA public supply enforceable Maximum Contaminant Levels (MCLs). Based on median concentrations of 19 inorganics (antimony, arsenic, barium, beryllium, boron, cadmium, chromium, copper, fluoride, manganese, molybdenum, nickel, nitrate, lead, selenium, strontium, thallium, uranium, zinc), 75% of watersheds had MCLG-HA-based cumulative risk values > 1.0; arsenic and uranium contributed the most risk, followed by strontium, fluoride, manganese and boron. Hence, this screening level (Tier I) CRA indicated widespread potential for unrecognized human health risk to private well users from inorganic contaminants considering both carcinogenic and non-carcinogenic risks. Sensitivity analysis showed that benchmarks applied (MCLG-HAs versus MCLs) exerted the largest control on results. Our findings identify priority regions for Tier 2 risk assessments to elucidate local sources and distributions of geogenic versus anthropomorphic contaminants. Our study is the first statewide assessment of cumulative health risk from groundwater that we are aware of, and results support increased statewide drinking water education and testing to reduce human health risks from contaminated private well water.
Freshwater salinization impacts the availability of water for human use and ecosystem needs worldwide. It has been estimated that total dissolved solids (TDS) in the Colorado River Basin cause $350 million/year in damages and substantial resources are devoted to reducing TDS loading to streams. This study describes the development and application of coupled watershed models that enable TDS source tracking through the subsurface and across the landscape at a seasonal timestep for 35 years in the Upper Colorado River Basin. Results indicate that, on average, 75% of TDS loading to streams originates as baseflow, and 50% of loading is lagged in delivery by longer than one season. Snowmelt was identified as a dominant process controlling the transport of lagged TDS to streams. This approach informs when and where TDS mitigation efforts may be effective in a watershed that serves as a critical water supply for the southwestern United States.
Headwater stream temperature often exhibits spatial variation at the kilometer-scale, but the relative importance of the underlying hydrogeological processes and riverine perturbations remains poorly understood. In this study, we investigated the relative importance of groundwater (GW) and other processes on downstream annual stream temperature signal characteristics using deterministic heat budget model (HFLUX) scenarios within an idealized stream reach representative of mountainous forested conditions. We summarized annual stream thermal regimes from the relationship of paired sinusoidal air and water temperature signals (amplitude ratio, phase lag, and mean ratio). Results showed that downstream changes in annual temperature depended on the thermal gradient between water and the hypothetical equilibrium temperature (where all heat fluxes sum to zero). GW inflow, riparian shading, and the boundary input signal were the most significant factors affecting downstream annual water temperature signals, while flow volume and channel dimensions impacted how quickly annual temperature signals changed. Effects of GW were dominated by advective rather than conductive heat exchange processes, but conduction played a larger role when GW input was more spatially diffuse. Our results indicated several mechanisms by which local processes may affect stream thermal resilience to disturbances and can help guide management of wildfire and climate change.
Letterkenny Army Depot in Chambersburg, Pennsylvania, built an Ammonium Perchlorate Rocket Motor Destruction (ARMD) Facility in 2016 to centralize rocket motor destruction and contain all waste during the destruction process. The U.S. Geological Survey has collected environmental samples from groundwater, surface water, and soils at ARMD since 2016. During 2021, samples were collected from four groundwater wells in September, one surface-water site in October, and five soil sites in November near the facility. Samples were analyzed for nutrients, trace metals, major ions, total volatile organic compounds, and perchlorate. Perchlorate was not detected in any 2021 samples. Groundwater results showed no constituents exceeded any U.S. Environmental Protection Agency (EPA) maximum contaminant level (MCL). Dissolved arsenic (As) was detected in one well above the reporting detection level (RDL) of 3 micrograms per liter (μg/L) at 5.4 μg/L but below its MCL of 10 μg/L. Dissolved iron (Fe) was the only inorganic constituent measured above an EPA secondary maximum contaminant level (SMCL). All groundwater samples collected in 2021 exceeded the Fe SMCL of 300 μg/L, with concentrations ranging from 390 μg/L to 3,500 μg/L. Surface-water data collected during 2021 showed no measured constituents in the surface-water sample that exceeded any EPA MCL or SMCL. Soil samples collected from 2016 through 2021 showed all concentrations of As exceeded the EPA soil screening levels of 3 milligrams per kilogram (mg/kg) but did not exceed the Pennsylvania medium-specific concentrations for As of 61 mg/kg. Arsenic concentrations in 2021 ranged from 9.1 mg/kg to 12.9 mg/kg. The 2021 results for the ARMD Facility indicate no increases in concentrations of reported compounds compared to data from 2016 to 2020. The contained burn treatment facility for demilitarization of rocket motors during 2021 appears to have operated without elevating concentrations of target compounds compared to previous years.
Hydrologic models for the Wards Brook valley near Fryeburg, Maine were developed for historical (2016 – 2021) and hypothetical future conditions (2046 – 2065 and 2080 – 2099) to understand the effects of groundwater withdrawals for bottled water and municipal use on hydrologic conditions (stream base flows and groundwater levels). Analyses showed that the simulated base flows in Wards Brook were reduced because of pumping for both municipal water supplies and for water bottling, and about half of the total pumping impact on the base flows in Wards Brook was from the bottled water extraction. Simulated flows were greater than the minimum recommended streamflow of 2,180 cubic meters per day (400 gallons per minute) throughout the historical period. Simulated groundwater levels at two of three nearby ponds (Round Pond and Davis Pond) were minimally affected by pumping conditions, and effects were primarily from the municipal well closest to the ponds. Several estimates of future projected recharge were used to understand the potential effects of groundwater withdrawals on hydrologic conditions under multiple hypothetical climate conditions. Annual projected recharge rates in the mid- and late-21st century from two climate scenarios (stabilized greenhouse-gas emissions and high greenhouse-gas emissions) were similar to rates for 2016 – 2021. However, monthly recharge patterns for the future periods shifted toward more recharge in the winter months (December, January, and February) and less recharge in April, May, and October relative to 2016 – 2021. The lowest mean monthly base flows from the future emission scenarios all remain larger than the minimum recommended streamflow and indicate no long-term declines in flow relative to historical conditions. However, simulated base flows during hypothetical 3-year drought scenarios declined below minimum recommended streamflow during the summer months in the stabilized- and high-emission scenarios in the mid-21st century. Although water is generally plentiful in the Wards Brook valley, reduced pumping may be needed to maintain streamflows in Wards Brook under future climate conditions similar to modeled drought scenarios.
Historical, future, and potential stream capture from groundwater pumping in the middle Humboldt River Basin (MHRB), Nevada, is estimated using a calibrated numerical groundwater flow model. The model was developed to estimate (1) stream capture, which is the change in flux between the groundwater system and the Humboldt River and tributaries, and (2) change in streamflow, which is the change in streamflow estimated for the Imlay gage on the Humboldt River (U.S. Geological Survey streamgage 10333000). Historical stream capture for water years (WYs) 1961–2015 is estimated using recorded and estimated groundwater pumping during that period. Future (predictive) stream capture was based on historical stresses (WYs 1961–2015) using a scenario that simulated non-mine pumping from WY 2015 at a uniform rate for 100 years into the future. Potential stream capture throughout the middle Humboldt River Basin from groundwater pumping during varying durations of time are presented in a series of capture maps. Maps also are presented that show the potential to capture from groundwater evapotranspiration, as well as the storage changes for pumping duration of 100 years. Estimates of historical stream capture from the mainstem Humboldt River during the early 1960s are less than 400 acre-feet per year (acre-ft/yr) when groundwater withdrawals and pumping rates were relatively small compared to more recent times. In the late 1980s and early 1990s, groundwater withdrawals increased and estimated historical stream capture also increased from about 4,000 acre-ft/yr in the late 1980s and early 1990s to as much as 18,800 acre-feet (acre-ft) in WY 1998. In WY 2015, estimated historical stream capture declined to about 13,000 acre-ft because of decreasing groundwater withdrawals and lower streamflow during the drought of WYs 2012–15, resulting in less stream water available for capture. Stream capture was estimated for 100 years into the future based on WY 2015 non-mine pumping rates and mine-dewatering activity through WY 2015. Stream capture is forecast to increase to about 23,000 acre-ft/yr, and streamflow in the Humboldt River could decrease by as much as 19,000 acre-ft/yr. Pumping for mine-dewatering and the associated discharge of that water affects streamflow in the Humboldt River at Imlay, Nevada (U.S. Geological Survey streamgage 10333000). Historically, from WYs 1991 to 2015, streamflow was greater at Imlay gage during active mine-dewatering from mine-water discharge operations and increased by as much as 105,000 acre-ft in WY 1998. The increase was attributed mostly to the discharge of groundwater from mine-related dewatering operations directly into the mainstem Humboldt River or its tributaries, with some of this increase associated with return flows from discharge to rapid infiltration basins. Results indicate that streamflow at Imlay gage is expected to decrease by as much as 1,600 acre-ft/yr 30 years after mine-related pumping and discharge are discontinued. The streamflow reductions at the Imlay gage are expected to then decrease to around 500 acre-ft/yr, 100 years after mine-related pumping and discharge are discontinued. Potential capture maps were produced for pumping durations of 10, 25, 50, and 100 years. Capture map results indicate that areas of greater potential stream capture occur adjacent to the Humboldt River and for upstream tributaries areas north of the Humboldt River.
Direct measurements of groundwater velocity made with borehole flowmeters in screened wells must be compensated for the effects of flow-field distortion (also known as borehole acceleration). A theoretical equation developed by Drost et al. (1968) and simple inputs describing hydraulic properties of well construction and geologic formation were programmed into an Excel workbook to facilitate computation by groundwater-flowmeter users. Tables describing the physical and hydraulic properties for well constructions and gravel pack media are provided with an example to facilitate use of the workbook. Groundwater flowlines converge or diverge as they pass from a geologic formation, through a gravel pack and well screen. The extent of flowline convergence or divergence and the value of the flow-field distortion coefficient is related to the relative changes in hydraulic conductivity of the well screen, gravel pack, and geologic formation. Convergence or divergence is accompanied by acceleration or deceleration of groundwater. Direct measurements of groundwater velocity at the center of the monitoring well can be adjusted to provide a more accurate estimate of velocity in the formation by applying a correction for flow-field distortion. Variables required to compute the flow-field distortion coefficient include the hydraulic conductivity of the gravel pack, well screen, and the geologic formation surrounding the well screen; the borehole radius, and the inside radius and outside radius of the well screen.
Groundwater seepage from underlying permeable glacial sedimentary structures, such as eskers, has been hypothesized to directly feed pools in northern peat bogs. These hypotheses directly contradict classical peat bog models for ombrogenous systems, wherein meteoric water is the sole water input to these systems. Variations in the underlying mineral sediment in contact with the peat imply that unrecognized hydrogeologic connectivity may exist with pools in northern peat bogs, particularly where high permeability materials are in contact with the peat. Seepage dynamics originating from these structural variations were investigated using a suite of thermal and hydrogeophysical methods deployed around pools in a peat bog of northeastern Maine, USA. Thermal characterization methods mapped anomalies that were confirmed as matrix seepage or preferential flow pathways (PFPs). Geochemical methods were employed at identified thermal anomalies to confirm upwelling of solute-rich groundwater. Conduits around pools were associated with surficial terminations of suspected peat pipes, based on the inference of pathways extending down into the peat, that focus flow through PFPs in the peat matrix. Discharge also occurred through the peat matrix adjacent to suspected pipe structures and matrix seepage rates were quantified using analysis of diurnal temperature signals recorded at multiple depths. Seepage rates, with a maximum of nearly 0.4 m/d, were measured at localized points around pools. Periods of synchronized temperatures paired with highly muted diurnal temperature signals, recorded in diurnal temperature with depth data, were interpreted qualitatively as activation of strong upward discharge rates through suspected peat pipes. These time periods correlated strongly with local precipitation events around the peatland. Ground-penetrating radar surveys revealed discontinuities in the low permeability glacio-marine clay at the mineral sediment-peat interface, interpreted to be regional glacial esker deposits, which were located beneath and around pools. Heat tracing, specific conductance contrasts, seepage rates, and trace metal concentrations all imply groundwater seepage originating from underlying permeable glacial esker deposits and directly sourcing pools. Preferential groundwater inputs into northern peat bogs may play a key role in developing and maintaining pool systems, with enhanced solute transport impacting peatland ecology, water resources, and carbon cycling.
The groundwater below the Red Hill Bulk Fuel Storage Facility (the facility) in Oʻahu, Hawaiʻi, contains fuel compounds from past spills. This study used carbon-14 analyses to distinguish fuel-derived carbon from background carbon, along with other biodegradation indicators, to address two goals: (1) determine the extent and migration direction of groundwater affected by residual fuel below the facility and (2) determine if residual fuel locations in the subsurface could be identified by analyzing soil gas at the surface above the facility. Groundwater from 19 wells was sampled between September 2022 and April 2023. Nonvolatile dissolved organic carbon (NVDOC) from a well presumed to be unaffected by past spills contained 38 percent ancient carbon indicating a natural source of ancient carbon in the subsurface. The NVDOC concentrations and ancient carbon percentages indicate fuel biodegradation products are likely present on the north and south of Red Hill with the greatest effects at well RHMW02 near the 2014 spill site. The NVDOC concentrations are almost three times higher than diesel range organic (DRO) concentrations in groundwater from the same sites. Major ion data indicate that iron reduction is an important biodegradation process. Soil probe samples and soil carbon traps were used to determine the carbon-14 content of soil carbon dioxide. Ancient carbon from fuel biodegradation was not detected at any soil probe or carbon trap site in contrast to a 2017 study which reported ancient carbon detections. A reanalysis of the 2017 results using a range of local values for background carbon-14 indicates that ancient carbon from fuel biodegradation was probably only detected in lower tunnel exhaust system samples and not in any soil carbon trap samples. Measurements of carbon dioxide efflux with a dynamic closed chamber were highly variable. The soil gas results indicate that soil gas measurements at land surface were not useful for detecting residual fuel at the facility.
The Little Sequatchie River and Pryor Cove Branch, in southern Tennessee, drain the eastern escarpment of the Cumberland Plateau to the Sequatchie River near the southern end of the Sequatchie Valley. The Little Sequatchie River is the largest tributary to the Sequatchie River by drainage area, covering over 120 square miles. The hydrology of the two drainage areas has been largely altered by karst processes, which has caused the majority of the streams to sink at the contact between the Mississippian Pennington Formation and the underlying Mississippian Bangor Limestone. The U.S. Geological Survey, in cooperation with the U.S. Fish and Wildlife Service and Tennessee Department of Environment and Conservation, initiated a study in 2021 to map the karst groundwater pathways in both watersheds in order to delineate recharge areas for several springs. One of these springs, Sequatchie Cave, represents a significant habitat for two Species of Greatest Conservation Need, the Glyphopsyche sequatchie (Sequatchie caddisfly) and the federally endangered Marstonia ogmorhaphe (royal marstonia). Springs and springflow-dominated streams in the Little Sequatchie River valley and Pryor Cove also provide water for agricultural practices and serve as a drinking water source for nearby communities. During the study, a total of 25 dye injections were conducted over eight rounds from January 2022 through March 2023. Dye traces from these injections helped to delineate recharge areas for six major springs, ranging from 7.3 to 65.2 square miles in area. The majority of the dye traces remained subsurface (from sinkpoint to recovery site) for long distances, with karst groundwater travelling nearly 8 miles before resurfacing. The dye traces also had rapid traveltimes, often travelling hundreds to thousands of feet per hour. The goal of this project was to provide scientific data related to karst groundwater pathways and spring recharge areas to aid State and Federal agencies in making informed decisions to protect and preserve this unique and vulnerable karst system.
A 1,026-foot well was drilled into the Floridan aquifer on St. George Island in search of a supply of water for residential development in 1971. This is the only well on the island on record to have been drilled below 200 feet for water. The well was abandoned; water flowing from the well was saline. It had a specific conductance of 7,500 micromhos per centimeter at 25° Celsius. The specific conductances of samples taken at drilling depths 217-1,026 feet ranged from 3,140 to 39,600, with the maximum value at 470 ft. A composite geophysical and lithologic log of the well shows spontaneous potential, single-point resistance, gamma-ray, neutron, gamma-gamma, and caliper logs. Well-site notes, a written description of cuttings samples, a graph showing the relation of specific conductance of water samples to the depth of the well at time of sampling, and four chemical analyses of the water are included in the report.
This report includes the results and interpretation of geophysical investigations to aid in the location, identification, and conceptual site model (CSM) development of the near surface groundwater and surface water hydrology of the Upper Cement Creek and California Gulch of the Animas Rivers within the Bonita Peak Mining Districts (BPMD). Mine influenced water (MIW) from numerous mine adits within the BPMD has altered the geochemistry and ecology of these ground and surface waters. Many studies of varying scales have investigated the geology, hydrogeology, geochemistry, and aqueous chemistry of these adits and impacted areas. Field investigations using non-invasive geophysical methods were conducted in the summer of 2019 to aid in identifying potential groundwater inputs to these streams and further the CSM of the near surface within and along these streams. Two field deployments were completed in August and September of 2019. In August 2019, Phase 1 was completed using multifrequency electromagnetic induction (EMI) and thermal infrared imaging (TIR) to measure the bulk electrical conductivity, magnetic susceptibility, and the temperature response at known and suspected groundwater seeps into the Upper Cement Creek and California Gulch stretches of these alpine streams. Results and interpretation from Phase 1 were used to co-locate stretches of these streams for further detailed fiber optic distributed temperature system (FODTS) monitoring of the temperature dynamics for submeter identification of potential groundwater seeps during Phase 2. Phase 2 included additional EMI measurements, FODTS measurements, and repeated some Phase 1 measurements for improved data quality. All these data were used for the combined qualitative interpretation identifying seep locations. The data from both Phase 1 and Phase 2 are available in the USGS data release at: https://www.sciencebase.gov/catalog/item/5f18a30082cef313ed84879b. These data include detailed near-surface electrical conductivity and magnetic susceptibility mapping, discrete TIR imaging, and several kilometers of FODTS data. These data were georeferenced and used to identify potential groundwater seeps into these streams. The results indicate a complex near surface geophysical and hydrogeologic regime. Seeps are classified and spatially correlated to the EMI, TIR, and geochemical sampling results. This report is a thorough compilation of the geophysical field efforts in the summer of 2019, the data processing, and interpretations of these data. These data alone should not be used for final interpretations of the complex hydrogeology within these alpine systems. Rather, these data should be combined with other known data from various investigations to further refine the CSM and guide decisions for future investigations, watershed protective measures, and other site decisions. Geographical information system (GIS) layers of these results are available to project managers for such integration and combined interpretations.