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William J. Andrews

Publications and source records attributed to William J. Andrews.

At least 37 records · Page 2Linked to original sources

Description of landscape features, summary of existing hydrologic data, and identification of data gaps for the Osage Nation, northeastern Oklahoma, 1890-2012

The Osage Nation of northeastern Oklahoma, conterminous with Osage County, is characterized by gently rolling uplands and incised stream valleys that have downcut into underlying sedimentary rock units of Pennsylvanian through Permian age. Cattle ranching and petroleum and natural-gas extraction are the principal land uses in this rural area. Freshwater resources in the Osage Nation include water flowing in the Arkansas River and several smaller streams, water stored in several lakes, and groundwater contained in unconsolidated alluvial aquifers and bedrock aquifers. The Vamoosa-Ada aquifer is the primary source of fresh groundwater in this area. Fresh groundwater is underlain by saline groundwater in aquifers underlying the Osage Nation. Because of the potential for future population increases, demands for water from neighboring areas such as the Tulsa metropolitan area, and expansion of petroleum and natural-gas extraction on water resources of this area, the U.S. Geological Survey, in cooperation with the Osage Nation, summarized existing hydrologic data and identified data gaps to provide information for planning of future development of water resources in the Osage Nation. Streamflows in the Osage Nation are substantially affected by precipitation. During the relatively wet periods from the 1970s to 2000, the annual streamflows in the Osage Nation increased by as much as a factor of 2 relative to preceding decades, with subsequent decreases in streamflow of as much as 50 percent being recorded during intermittent drier years of the early 2000s. This report summarizes hydrologic data from 3 surface-water sites and 91 wells distributed across the Osage Nation. Data collected at those sites indicate that surface water in the Osage Nation generally has sufficient dissolved oxygen for survival of both coldwater and warmwater aquatic biota. Total dissolved solids concentration exceeded the secondary drinking-water standard of 500 milligrams per liter (mg/L) in up to 75 percent of the surface-water samples, indicating limited availability of potable water at some sites. Some surface-water samples collected in the Osage Nation contained dissolved chloride concentrations exceeding the secondary drinking-water standard of 250 mg/L, with greater chloride concentrations in selected basins appearing to be associated with greater densities of petroleum well locations. Several lakes sampled in the Osage Nation from 2011–12 contained sufficient chlorophyll-a concentrations to be ranked as mesotrophic to eutrophic, indicating impairment by nutrients. Relatively large dissolved phosphorus concentrations in many surface-water samples, compared to water-quality standards, indicate that eutrophication can occur in local streams and lakes. The amount of fresh groundwater stored in alluvial aquifers and the Vamoosa-Ada bedrock aquifer is adequate for domestic and other purposes in the Osage Nation at the current rate of usage. In areas where these aquifers are absent, groundwater must be pumped from minor bedrock aquifers that produce smaller volumes of water. About 30 and 60 percent of 32 and 54 water samples collected from the alluvial and Vamoosa-Ada aquifers, respectively, contained total dissolved solids concentrations larger than the secondary drinking-water standard of 500 mg/L. Local factors, such as natural seepage of brines or leakage from petroleum and natural-gas extraction activities, may cause substantial variations in dissolved chloride concentration in groundwater in the Osage Nation. Total phosphorus concentrations measured in groundwater samples were similar to dissolved phosphorus concentrations measured in the base flow of several streams. Total fresh surface-water withdrawals (use) and fresh groundwater withdrawals in the Osage Nation were estimated to have increased from 0.75 to 16.19 million gallons per day and from 0.13 to 2.39 million gallons per day, respectively, over the period from 1890 through 2010. Estimated saline-groundwater reinjection volumes at the heavily developed Burbank Oil Field in the Osage Nation from 1950 through 2012 were many times larger than the total amounts of freshwater withdrawn in this area, with estimated increases in saline-groundwater reinjection in the 2000s probably being related to increased petroleum extraction. Estimates of freshwater resources in local streams, lakes, and freshwater aquifers and of net annual precipitation indicate that less than 1 percent of freshwater resources and net annual precipitation currently is being withdrawn annually in the Osage Nation. In addition to freshwater resources, the Osage Nation may be underlain by 45,000,000 million gallons of brines, a small portion of which are withdrawn and reinjected during petroleum and natural-gas extraction. Ongoing development of desalinization technology may lead to the ability to expand use of these saline waters in the future. Several additional studies could improve understanding of the hydrologic resources of the Osage Nation. Development of computer models (simulations) of groundwater and surface-water flow for this area could enable testing of scenarios of localized and widespread effects of future climate variations and water-use changes on streamflows, lake-water levels, and groundwater levels in the Osage Nation. Installation of additional long-term streamflow and water-quality sampling stations, some with continuous water-quality monitors, could expand and improve understanding of surface-water quality. Periodic measurement of groundwater levels and sampling of water from a network of wells could provide better information about trends of groundwater quantity and quality with time. Measurement of water withdrawals at selected sites could enable more accurate estimates of water use. Lastly, better understanding of aquifer properties and spatial distribution of saline groundwater provided by geophysical surveys could improve understanding of fresh and saline groundwater resources underlying the Osage Nation.

Oklahoma↗

Analysis of environmental setting, surface-water and groundwater data, and data gaps for the Citizen Potawatomi Nation Tribal Jurisdictional Area, Oklahoma, through 2011

The Citizen Potawatomi Nation Tribal Jurisdictional Area, consisting of approximately 960 square miles in parts of three counties in central Oklahoma, has an abundance of water resources, being underlain by three principal aquifers (alluvial/terrace, Central Oklahoma, and Vamoosa-Ada), bordered by two major rivers (North Canadian and Canadian), and has several smaller drainages. The Central Oklahoma aquifer (also referred to as the Garber-Wellington aquifer) underlies approximately 3,000 square miles in central Oklahoma in parts of Cleveland, Logan, Lincoln, Oklahoma, and Pottawatomie Counties and much of the tribal jurisdictional area. Water from these aquifers is used for municipal, industrial, commercial, agricultural, and domestic supplies. The approximately 115,000 people living in this area used an estimated 4.41 million gallons of fresh groundwater, 12.12 million gallons of fresh surface water, and 8.15 million gallons of saline groundwater per day in 2005. Approximately 8.48, 2.65, 2.24, 1.55, 0.83, and 0.81 million gallons per day of that water were used for domestic, livestock, commercial, industrial, crop irrigation, and thermoelectric purposes, respectively. Approximately one-third of the water used in 2005 was saline water produced during petroleum production. Future changes in use of freshwater in this area will be affected primarily by changes in population and agricultural practices. Future changes in saline water use will be affected substantially by changes in petroleum production. Parts of the area periodically are subject to flooding and severe droughts that can limit available water resources, particularly during summers, when water use increases and streamflows substantially decrease. Most of the area is characterized by rural types of land cover such as grassland, pasture/hay fields, and deciduous forest, which may limit negative effects on water quality by human activities because of lesser emissions of man-made chemicals on such areas than in more urbanized areas. Much of the water in the area is of good quality, though some parts of this area have water quality impaired by very hard surface water and groundwater; large chloride concentrations in some smaller streams; relatively large concentrations of nutrients and counts of fecal-indicator bacteria in the North Canadian River; and chloride, iron, manganese, and uranium concentrations that exceed primary or secondary drinking-water standards in water samples collected from small numbers of wells. Substantial amounts of hydrologic and water-quality data have been collected in much of this area, but there are gaps in those data caused by relatively few streamflow-gaging stations, uneven distribution of surface-water quality sampling sites, lack of surface-water quality sampling at high-flow and low-flow conditions, and lack of a regularly measured and sampled groundwater network. This report summarizes existing water-use, climatic, geographic, hydrologic, and water-quality data and describes several means of filling gaps in hydrologic data for this area.

Oklahoma↗

Hydrologic drought of water year 2011 compared to four major drought periods of the 20th century in Oklahoma

Water year 2011 (October 1, 2010, through September 30, 2011) was a year of hydrologic drought (based on streamflow) in Oklahoma and the second-driest year to date (based on precipitation) since 1925. Drought conditions worsened substantially in the summer, with the highest monthly average temperature record for all States being broken by Oklahoma in July (89.1 degrees Fahrenheit), June being the second hottest and August being the hottest on record for those months for the State since 1895. Drought conditions continued into the fall, with all of the State continuing to be in severe to exceptional drought through the end of September. In addition to effects on streamflow and reservoirs, the 2011 drought increased damage from wildfires, led to declarations of states of emergency, water-use restrictions, and outdoor burning bans; caused at least $2 billion of losses in the agricultural sector and higher prices for food and other agricultural products; caused losses of tourism and wildlife; reduced hydropower generation; and lowered groundwater levels in State aquifers. The U.S. Geological Survey, in cooperation with the Oklahoma Water Resources Board, conducted an investigation to compare the severity of the 2011 drought with four previous major hydrologic drought periods during the 20th century – water years 1929–41, 1952–56, 1961–72, and 1976–81. The period of water years 1925–2011 was selected as the period of record because few continuous record streamflow-gaging stations existed before 1925, and gaps in time existed where no streamflow-gaging stations were operated before 1925. In water year 2011, statewide annual precipitation was the 2d lowest, statewide annual streamflow was 16th lowest, and statewide annual runoff was 42d lowest of those 87 years of record. Annual area-averaged precipitation totals by the nine National Weather Service climate divisions from water year 2011 were compared to those during four previous major hydrologic drought periods to show how precipitation deficits in Oklahoma varied by region. The nine climate divisions in Oklahoma had precipitation in water year 2011 ranging from 43 to 76 percent of normal annual precipitation, with the Northeast Climate Division having the closest to normal precipitation and the Southwest Climate Division having the greatest percentage of annual deficit. Based on precipitation amounts, water year 2011 ranked as the second driest of the 1925–2011 period, being exceeded only in one year of the 1952 to 1956 drought period. Regional streamflow patterns for water year 2011 indicate that streamflow in the Arkansas-White-Red water resources region, which includes all of Oklahoma, was relatively large, being only the 26th lowest since 1930, primarily because of normal or above-normal streamflow in the northern part of the region. Twelve long-term streamflow-gaging stations with periods of record ranging from 67 to 83 years were selected to show how streamflow deficits varied by region in Oklahoma. Statewide, streamflow in water year 2011 was greater than streamflows measured in years during the drought periods of 1929–41, 1952–56, 1961–72, and 1976–81. The hydrologic drought worsened going from the northeast toward the southwest in Oklahoma, ranging from 140 percent (above normal streamflow) in the northeast, to 13 percent of normal streamflow in southwestern Oklahoma. The relatively low streamflow in 2011 resulted in 83.3 percent of the statewide conservation storage being available at the end of the water year in major reservoirs, similar to conservation storage in the preceding severe drought year of 2006. The ranking of streamflow as the 16th smallest for the 1925–2011 period, despite precipitation being ranked the 2d smallest, may have been caused, in part, by the relatively large streamflow in northeastern Oklahoma during water year 2011.

Oklahoma↗

Pilot study of natural attenuation of arsenic in well water discharged to the Little River above Lake Thunderbird, Norman, Oklahoma, 2012

The City of Norman, Oklahoma, wanted to augment its water supplies to meet the needs of an increasing population. Among the city’s potential water sources are city wells that produce water that exceeds the 10 micrograms per liter primary drinking-water standard for arsenic. The City of Norman was interested in investigating low-cost means of using natural attenuation to remove arsenic from well water and augment the water supply of Lake Thunderbird, the primary water source for the city. The U.S. Geological Survey, in cooperation with the City of Norman, conducted a preliminary investigation (pilot study) to determine if discharge of water from those wells into the Little River over a 12-day period would reduce arsenic concentrations through natural-attenuation processes. Water in the Little River flows into Lake Thunderbird, the principal water source for the city, so the discharged well water would improve the water balance of that reservoir. During this pilot study, 150–250 gallons per minute from each of six city wells were discharged to the Little River over a 12-day period. Water-quality samples were collected from the wells during discharge and from the river before, during, and after well discharges. Streambed-sediment samples were collected at nine sites in the river before and after the well-discharge period. Water discharge from the six wells added 0.3 kilogram per day of arsenic to the river at the nearest downstream streamflow-gaging station. Dissolved arsenic concentration in the Little River at the closest downstream sampling site from the wells increased from about 4 micrograms per liter to as much as 24 micrograms per liter. Base flow in the river increased by about 1.7 cubic feet per second at the nearest downstream streamflow-gaging station. Streamflow in the river was two-thirds of that expected from the amount of water discharged from the wells because of seepage to soils and evapotranspiration of well water along drainage ways to the river. Arsenic concentrations at the nearest downstream streamflow-gaging station were less than arsenic concentrations measured in many of the well-water samples during the well-pumping period. Arsenic concentrations, loads, and yields in the Little River generally decreased downstream from the closest streamflow-gaging station to the wells by 50 percent or more, indicating removal of about 0.25 kilogram or 0.53 pound per day of arsenic during base-flow conditions. Measured river-water arsenic concentrations near the confluence of the Little River with Lake Thunderbird were in compliance with the primary drinking-water standard. Arsenic concentrations measured at four downstream stations in the Little River also were less than established criteria set for protection of aquatic biota. After well discharges to the Little River were stopped, arsenic concentrations, loads, and yields in the river gradually decreased over 14 days to concentrations measured prior to the well-water discharges. Cumulative loads of arsenic discharged at the wells and the closest and farthest downstream streamflow-gaging stations indicated removal of about 2.5 kilograms of arsenic as well-water flowed to and down the river. Arsenic concentrations in streambed-sediment samples collected before and after the well-water discharges were not significantly different. Results of this pilot study indicate that using natural-attenuation processes to remove arsenic from water and supplement city water supplies may be a viable, relatively low-cost method for attenuating arsenic in well water and for augmenting the water supply of Lake Thunderbird.

Oklahoma↗

Emerging contaminants at a closed and an operating landfill in Oklahoma

Landfills are the final depositories for a wide range of solid waste from both residential and commercial sources, and therefore have the potential to produce leachate containing many organic compounds found in consumer products such as pharmaceuticals, plasticizers, disinfectants, cleaning agents, fire retardants, flavorings, and preservatives, known as emerging contaminants (ECs). Landfill leachate was sampled from landfill cells of three different age ranges from two landfills in Central Oklahoma. Samples were collected from an old cell containing solid waste greater than 25 years old, an intermediate age cell with solid waste between 16 and 3 years old, and operating cell with solid waste less than 5 years old to investigate the chemical variability and persistence of selected ECs in landfill leachate of differing age sources. Twenty-eight of 69 analyzed ECs were detected in one or more samples from the three leachate sources. Detected ECs ranged in concentration from 0.11 to 114 μg/L and included 4 fecal and plant sterols, 13 household\industrial, 7 hydrocarbon, and 4 pesticide compounds. Four ECs were solely detected in the oldest leachate sample, two ECs were solely detected in the intermediate leachate sample, and no ECs were solely detected in the youngest leachate sample. Eleven ECs were commonly detected in all three leachate samples and are an indication of the contents of solid waste deposited over several decades and the relative resistance of some ECs to natural attenuation processes in and near landfills.

Oklahoma↗

Changes in Selected Metals Concentrations from the Mid-1980s to the Mid-2000s in a Stream Draining the Picher Mining District of Oklahoma

After abandonment in the late 1960s, the Picher mining district of Oklahoma, once the largest source of lead and zinc in the world, continued to be affected by severe environmental degradation, with scattered subsidence and abundant toxic metals such as cadmium and lead seeping from flooded underground mine workings and seeping and running off from as much as 60 million tons of mine tailings remaining at the land surface. Water-quality data collected during the mid-1980s and the mid-2000s at the Tar Creek at 22nd Street Bridge in Miami, Oklahoma streamflow-gaging station (USGS number 07185095), located downstream from much of the district, indicate that total concentrations of iron, manganese, and zinc significantly decreased between the two sampling periods. Those water-quality improvements probably are due to a combination of reclamation activities and natural attenuation processes such as stabilization of exposed minerals in flooded underground mine workings, progressive wind and water erosion of the most readily erodible metalliferous particles from tailings, and colonization of volunteer plants that reduce physical erosion of soils and tailings.

Kansas, Missouri, Oklahoma↗

Relations among land cover, streamflow, and water quality in the North Canadian River Basin near Oklahoma City, Oklahoma: 1968-2009

The U.S. Geological Survey, in cooperation with the city of Oklahoma City, has collected water-quality samples at the North Canadian River near Harrah, Oklahoma (the Harrah station), since 1968, and the North Canadian River at Britton Road at Oklahoma City, Oklahoma (the Britton Road station), since 1988. The North Canadian municipal wastewater-treatment plant, managed by the city of Oklahoma City, is the largest wastewater-treatment plant in the North Canadian River Basin and discharges effluent between the Britton Road and Harrah stations. Water-quality constituent concentrations were summarized, and trends in concentrations and frequencies of detection of selected constituents with time were evaluated to determine if changes in land cover, streamflow, and other potential sources of constituents in water had significant effects on water quality in the North Canadian River downstream from Oklahoma City.

Oklahoma↗

Evaluation and trends of land cover, streamflow, and water quality in the North Canadian River Basin near Oklahoma City, Oklahoma, 1968-2009

The U.S. Geological Survey, in cooperation with the city of Oklahoma City, collected water-quality samples from the North Canadian River at the streamflow-gaging station near Harrah, Oklahoma (Harrah station), since 1968, and at an upstream streamflow-gaging station at Britton Road at Oklahoma City, Oklahoma (Britton Road station), since 1988. Statistical summaries and frequencies of detection of water-quality constituent data from water samples, and summaries of water-quality constituent data from continuous water-quality monitors are described from the start of monitoring at those stations through 2009. Differences in concentrations between stations and time trends for selected constituents were evaluated to determine the effects of: (1) wastewater effluent discharges, (2) changes in land-cover, (3) changes in streamflow, (4) increases in urban development, and (5) other anthropogenic sources of contamination on water quality in the North Canadian River downstream from Oklahoma City. Land-cover changes between 1992 and 2001 in the basin between the Harrah station and Lake Overholser upstream included an increase in developed/barren land-cover and a decrease in pasture/hay land cover. There were no significant trends in median and greater streamflows at either streamflow-gaging station, but there were significant downward trends in lesser streamflows, especially after 1999, which may have been associated with decreases in precipitation between 1999 and 2009 or construction of low-water dams on the river upstream from Oklahoma City in 1999. Concentrations of dissolved chloride, lead, cadmium, and chlordane most frequently exceeded the Criterion Continuous Concentration (a water-quality standard for protection of aquatic life) in water-quality samples collected at both streamflow-gaging stations. Visual trends in annual frequencies of detection were investigated for selected pesticides with frequencies of detection greater than 10 percent in all water samples collected at both streamflow-gaging stations. Annual frequencies of detection of 2,4-dichlorophenoxyacetic acid and bromacil increased with time. Annual frequencies of detection of atrazine, chlorpyrifos, diazinon, dichlorprop, and lindane decreased with time. Dissolved nitrogen and phosphorus concentrations were significantly greater in water samples collected at the Harrah station than at the Britton Road station, whereas specific conductance was greater at the Britton Road station. Concentrations of dissolved oxygen, biochemical oxygen demand, and fecal coliform bacteria were not significantly different between stations. Daily minimum, mean, and maximum specific conductance collected from continuous water-quality monitors were significantly greater at the Britton Road station than in water samples collected at the Harrah station. Daily minimum, maximum, and diurnal fluctuations of water temperature collected from continuous water-quality monitors were significantly greater at the Harrah station than at the Britton Road station. The daily maximums and diurnal range of dissolved oxygen concentrations were significantly greater in water samples collected at the Britton Road station than at the Harrah station, but daily mean dissolved oxygen concentrations in water at those streamflow-gaging stations were not significantly different. Daily mean and diurnal water temperature ranges increased with time at the Britton Road and Harrah streamflow-gaging stations, whereas daily mean and diurnal specific conductance ranges decreased with time at both streamflow-gaging stations from 1988–2009. Daily minimum dissolved oxygen concentrations collected from continuous water-quality monitors more frequently indicated hypoxic conditions at the Harrah station than at the Britton Road station after 1999. Fecal coliform bacteria counts in water decreased slightly from 1988–2009 at the Britton Road station.

Oklahoma↗

Comparison of load estimation techniques and trend analysis for nitrogen, phosphorus, and suspended sediment in the Eucha-Spavinaw Basin, northwestern Arkansas and northeastern Oklahoma, 2002-10

The City of Tulsa, Oklahoma, uses water from Lake Eucha and Spavinaw Lake in the Eucha-Spavinaw basin of northwestern Arkansas and northeastern Oklahoma for public water supply. Increases in algal biomass, which cause taste and odor problems in drinking water produced from the lakes, may be attributable to increases in nitrogen and phosphorus concentrations in the lakes and in streams discharging to the lakes. To evaluate transport of nitrogen, phosphorus, and suspended sediment in this basin, loads and temporal trends were evaluated for five streamflow-gaging stations in the Spavinaw and Beaty Creek basins. Two approaches were used to develop regression equations for estimation of loads and yields of nitrogen, phosphorus, and sediment. The first approach used regression equations referred to as daily mean load (DM L ) regressions, developed from water-quality samples and daily mean streamflow data collected from 2002 through 2010 at five streamflow-gaging stations in the basin. This approach was updated to compare loading results with those used in previous investigations. The second approach used regression equations, referred to as instantaneous continuous (INST C ) regressions, developed from continuous measurements of physical water-quality constituents (specific conductance, temperature, and turbidity, and streamflow data) obtained from 2004 through 2010 to estimate loads of nitrogen, phosphorus, and sediment at two of the streamflow-gaging stations, Spavinaw Creek near Colcord, Okla., and Beaty Creek near Jay, Okla. Daily, annual, and mean annual loads estimated from these two regression methods were compared for the period 2005–10. Based on estimates obtained using DM L regressions, mean annual loads of 1,640,000 pounds of nitrogen, 99,900 pounds of phosphorus, and 116,000,000 pounds of sediment were transported into Lake Eucha from the Spavinaw and Beaty Creek basins. Estimated annual loads of nitrogen and phosphorus delivered to Lake Eucha from the Spavinaw and Beaty Creek basins during 2002–10 were 2.5 to 7.8 percent less, respectively, than the loads of those constituents discharged to Lake Eucha from 2002–09, indicating that nitrogen and phosphorus loads in 2010 were less than loads typical for the period 2002–09. Daily, annual, and mean annual load estimates varied substantially, depending on streamflow conditions and the independent variables used to develop regressions. Daily and annual loads estimated from INST C regressions that included turbidity, streamflow, temperature, specific conductance, and seasonality fit better with the field data than loads estimated from DM L regressions that included streamflow, seasonality, and time. Loads estimated from the INST C regression generally were greater than those estimated from the DM L regression. Relative percent differences in the mean annual total nitrogen load estimated by the INST C and DM L regressions were within 2 percent for Spavinaw Creek near Colcord, and Beaty Creek near Jay, Okla. The relative percent difference between the two types of regressions for estimates of mean annual total phosphorus loads at the two streamflow-gaging stations was 27.7 for Spavinaw Creek near Colcord, Okla., and only -2.6 percent for Beaty Creek near Jay, Okla. The relative percent difference between mean annual suspended-sediment loads at the streamflow-gaging stations was -38.6 percent for Spavinaw Creek near Colcord, Okla., and -122.7 percent for Beaty Creek near Jay, Okla. The DM L regression may have substantially underestimated phosphorus load at the Spavinaw Creek near Colcord, Okla., streamflow-gaging station in wet years and overestimated sediment load at both streamflow-gaging stations in wet years. Temporal trends in flow-adjusted nitrate-nitrogen, nitrogen, phosphorus, and suspended-sediment concentrations were analyzed for the five streamflow-gaging stations for the period 2001–10. No significant trends were observed for nitrate plus nitrite-nitrogen or total nitrogen concentrations at any streamflow-gaging station. There were significant upward trends in phosphorus concentrations in water samples collected during base-flow conditions at the Spavinaw Creek near Maysville, Okla., streamflow-gaging station and during runoff conditions for the Beaty Creek near Jay, Okla., streamflow-gaging station (3.5 to 4.2 percent per year). There were significant downward trends in phosphorus concentrations in base-flow and runoff samples collected at the Spavinaw Creek near Cherokee City, Sycamore, and Colcord, Okla., streamflow-gaging stations (-4.9 to -12.9 percent per year). There were significant downward trends in suspended-sediment concentration at the Spavinaw Creek near Maysville, and Sycamore, Okla., and the Beaty Creek near Jay, Okla., streamflow-gaging stations (-1.5 to -1.8 percent per year). No significant trends were detected in suspended-sediment concentration for the Spavinaw Creek near Cherokee City, and Colcord, Okla., streamflow-gaging stations. Possible causes for downward trends in phosphorus concentrations include decreases in phosphorus discharges from a wastewater-treatment plant upstream from the Spavinaw Creek near Cherokee City, Okla., streamflow-gaging station, and implementation of best management practices in the basin. Downward trends in sediment concentrations may be related to effects of best management practices in the basin.

Arkansas, Oklahoma↗

Selected metals in sediments and streams in the Oklahoma Part of the Tri-State Mining District, 2000-2006

The abandoned Tri-State mining district includes 1,188 square miles in northeastern Oklahoma, southeastern Kansas, and southwestern Missouri. The most productive part of the Tri-State mining district was the 40-square mile part in Oklahoma, commonly referred to as 'the Picher mining district' in north-central Ottawa County, Oklahoma. The Oklahoma part of the Tri-State mining district was a primary producing area of lead and zinc in the United States during the first half of the 20th century. Sulfide minerals of cadmium, iron, lead, and zinc that remained in flooded underground mine workings and in mine tailings on the land surface oxidized and dissolved with time, forming a variety of oxide, hydroxide, and hydroxycarbonate metallic minerals on the land surface and in streams that drain the district. Metals in water and sediments in streams draining the mining district can potentially impair the habitat and health of many forms of aquatic and terrestrial life. Lakebed, streambed and floodplain sediments and/or stream water were sampled at 30 sites in the Oklahoma part of the Tri-State mining district by the U.S. Geological Survey and the Oklahoma Department of Environmental Quality from 2000 to 2006 in cooperation with the U.S. Environmental Protection Agency, and the Quapaw and Seneca-Cayuga Tribes of Oklahoma. Aluminum and iron concentrations of several thousand milligrams per kilogram were measured in sediments collected from the upstream end of Grand Lake O' the Cherokees. Manganese and zinc concentrations in those sediments were several hundred milligrams per kilogram. Lead and cadmium concentrations in those sediments were about 10 percent and 0.1 percent of zinc concentrations, respectively. Sediment cores collected in a transect across the floodplain of Tar Creek near Miami, Oklahoma, in 2004 had similar or greater concentrations of those metals than sediment cores collected at the upstream end of Grand Lake O' the Cherokees. The greatest concentrations of cadmium, iron, lead, and zinc were detected in sediments beneath an intermittent tributary to Tar Creek, a slough which drains mined areas near Commerce, Oklahoma. In surface water, aluminum and iron concentrations were greatest in the Neosho River, perhaps a result of runoff from areas underlain by shales. The greatest aqueous concentrations of cadmium, lead, manganese, and zinc were measured in water from Tar Creek, the primary small stream draining the Picher mining district with the largest proportion of mined area. Water from the Spring River had greater zinc concentrations than water from the Neosho River, perhaps as a result of a greater proportion of mined area in the Spring River Basin. Dissolved metals concentrations were generally much less than total metals concentrations, except for manganese and zinc at sites on Tar Creek, where seepage of ground water from the mine workings, saturated mine tailings, and/or metalliferous streambed sediments may be sources of these dissolved metals. Iron and lead concentrations generally decreased with increasing streamflow in upstream reaches of Tar Creek, indicating dilution of metals-rich ground water by runoff. Farther downstream in Tar Creek, and in the Neosho and Spring Rivers, metals concentrations tended to increase with increasing streamflow, indicating that most metals in these parts of these streams were associated with runoff and re-suspension of metals precipitated as oxide, hydroxide, and hydroxycarbonate minerals on land surface and streambeds. Estimated total aluminum, cadmium, iron, manganese, and zinc loads generally were greatest in water from the Neosho and Spring Rivers, primarily because of comparatively large streamflows in those rivers. Slight increases in metal loads in the downstream directions on those rivers indicated contributions of metals from inflows of small tributaries such as Tar Creek and from runoff.

Kansas, Missouri, Oklahoma↗

Summary of surface-water quality data from the Illinois River Basin in Northeast Oklahoma, 1970-2007

The quality of streams in the Illinois River Basin of northeastern Oklahoma is potentially threatened by increased quantities of wastes discharged from increasing human populations, grazing of about 160,000 cattle, and confined animal feeding operations raising about 20 million chickens. Increasing numbers of humans and livestock in the basin contribute nutrients and bacteria to surface water and groundwater, causing greater than the typical concentrations of those constituents for this region. Consequences of increasing contributions of these substances can include increased algal growth (eutrophication) in streams and lakes; impairment of habitat for native aquatic animals, including desirable game fish species; impairment of drinking-water quality by sediments, turbidity, taste-and-odor causing chemicals, toxic algal compounds, and bacteria; and reduction in the aesthetic quality of the streams. The U.S. Geological Survey, in cooperation with the Oklahoma Scenic Rivers Commission, prepared this report to summarize the surface-water-quality data collected by the U.S. Geological Survey at five long-term surface-water-quality monitoring sites. The data summarized include major ions, nutrients, sediment, and fecal-indicator bacteria from the Illinois River Basin in Oklahoma for 1970 through 2007. General water chemistry, concentrations of nitrogen and phosphorus compounds, chlorophyll-a (an indicator of algal biomass), fecal-indicator bacteria counts, and sediment concentrations were similar among the five long-term monitoring sites in the Illinois River Basin in northeast Oklahoma. Most water samples were phosphorus-limited, meaning that they contained a smaller proportion of phosphorus, relative to nitrogen, than typically occurs in algal tissues. Greater degrees of nitrogen limitation occurred at three of the five sites which were sampled back to the 1970s, probably due to use of detergents containing greater concentrations of phosphorus than in subsequent periods. Concentrations of nitrogen, phosphorus, and sediment, and counts of bacteria generally increased with streamflow at the five sites, probably due to runoff from the land surface and re-suspension of streambed sediments. Phosphorus concentrations typically exceeded the Oklahoma standard of 0.037 milligrams per liter for Scenic Rivers. Concentrations of chlorophyll-a in phytoplankton in water samples collected at the five sites were not well correlated with streamflow, nor to concentrations of the nutrients nitrogen and phosphorus, probably because much of the algae growing in these streams are periphyton attached to streambed cobbles and other debris, rather than phytoplankton in the water column. Sediment concentrations correlated with phosphorus concentrations in water samples collected at the sites, probably due to sorption of phosphorus to soil particles and streambed sediments and runoff of soils and animal wastes at the land surface and resuspension of streambed sediments and phosphorus during wet, high-flow periods. Fecal coliform bacteria counts at the five sites sometimes exceeded the Oklahoma Primary Body Contact Standard of 400 colonies per 100 milliliters when streamflows were greater than 1000 cubic feet per second. Ultimately, Lake Tenkiller, an important ecological and economic resource for the region, receives the compounds that runoff the land surface or seep to local streams from groundwater in the basin. Because of eutrophication from increased nutrient loading, Lake Tenkiller is listed for impairment by diminished dissolved oxygen concentrations, phosphorus, and chlorophyll-a by the State of Oklahoma in evaluation of surface-water quality required by section 303d of the Clean Water Act. Stored phosphorus in soils and streambed and lakebed sediments may continue to provide phosphorus to local streams and lakes for decades to come. Steps are being made to reduce local sources of phosphorus, including upgrades in capacity and effective

Arkansas, Oklahoma↗

Preliminary analysis of the hydrologic and geochemical controls on acid‐neutralizing capacity in two acidic seepage lakes in Florida

In late 1988, parallel studies of Lake Five‐O ( p H 5.14) in the Florida panhandle and Lake Barco ( p H 4.50) in north central Florida were initiated to develop hydrologic and major ion budgets of these lakes as part of an overall effort to improve understanding of the hydrologic, depositional, and biogeochemical factors that control acid‐neutralizing capacity (ANC) in seepage lakes. Preliminary findings from these studies indicate that earlier perceptions of lake hydrology and mechanisms of ANC regulation in Florida seepage lakes may have to be revised. The traditional perspective of seepage lakes in the Florida panhandle views these systems as dominated by precipitation inputs and that ANC regulation is due largely to in‐lake processes. Our results for Lake Five‐O show modest to steep hydraulic gradients almost entirely around the lake. In addition, the horizontal hydraulic conductivity of the surficial aquifer is high (8–74 m day −1 ), indicating that large quantities of groundwater flow into Lake Five‐O. Calculations of net groundwater flow from hydrologic budgets also indicate that groundwater may comprise at least 38 to 46% of the total inflow. For Lake Barco, net flow estimates of the minimum groundwater inflow range from 5 to 14% of total inflow. Enrichment factor and ion flux calculations for Lake Five‐O and Lake Barco indicate that terrestrial as well as in‐lake processes contribute significantly to ANC regulation. The extent that terrestrial processes contribute to ANC generation is directly related to the magnitude of groundwater inflow as well as the degree of ion enrichment or depletion that occurs in the surficial aquifer. Net ANC generation in both study lakes was dominated by anion retention (NO 3 − and SO 4 2− ). Where previous studies concluded that in‐lake reduction was the primary sink for SO 4 2− , our preliminary calculations show that adsorption of SO 4 2− within the watershed is perhaps twice as important as in‐lake reduction as a source of ANC. Net base cation enrichment in both lakes was negligible.

Florida↗

Streamflow, water quality, and metal loads from chat leachate and mine outflow into Tar Creek, Ottawa County, Oklahoma, 2005

Picher mining district is an abandoned lead and zinc mining area located in Ottawa County, northeastern Oklahoma. During the first half of the 20th century, the area was a primary producer of lead and zinc in the United States. Large accumulations of mine tailings, locally referred to as chat, produce leachate containing cadmium, iron, lead, and zinc that enter drainages within the mining area. Metals also seep to local ground water and streams from unplugged shafts, vent holes, seeps, and abandoned mine dewatering wells. Streamflow measurements were made and water-quality samples were collected and analyzed from two locations in Picher mining district from August 16 to August 29 following a rain event beginning on August 14, 2005, to determine likely concentrations and loads of metals from tailings and mine outflows in the part of Picher mining district near Tar Creek. Locations selected for sampling included a tailings pile with an adjacent mill pond, referred to as the Western location, and a segment of Tar Creek from above the confluence with Lytle Creek to below Douthat bridge, referred to as Tar Creek Study Segment. Measured streamflow was less than 0.01 cubic foot per second at the Western location, with streamflow only being measurable at that site on August 16, 2005. Measured streamflows ranged from <0.01 to 2.62 cubic feet per second at Tar Creek Study Segment. One water-quality sample was collected from runoff at the Western location. Total metals concentrations in that sample were 95.3 micrograms per liter cadmium, 182 micrograms per liter iron, 170 micrograms per liter lead, 1,760 micrograms per liter zinc. Total mean metals concentrations in 29 water-quality samples collected from Tar Creek Study Segment from August 16-29, 2005, were 21.8 micrograms per liter cadmium, 7,924 micrograms per liter iron, 7.68 micrograms per liter lead, and 14,548 micrograms per liter zinc. No metals loading values were calculated for the Western location. Metals loading to Tar Creek Study Segment were calculated based on instantaneous streamflow and metals concentrations. Total metals loading to Tar Creek from chat leachate ranged from 0.062 to 0.212 pound per day of cadmium, <0.001 to 0.814 pound per day of iron, 0.003 to 0.036 pound per day of lead, and 10.6 to 47.9 pounds per day of zinc. Metals loading to Tar Creek Study Segment from chat leachate and mine outflow was determined by subtracting values at appropriate upstream and downstream stations. Four sources of calculated metal loads are from Tar Creek and Lytle Creek entering the study segment, from chat pile leachate, and from old Lytle Creek mine outflow. Less than 1 percent of total and dissolved iron loading came from chat leachate, while about 99 percent of total iron loading came from mine outflow. Total and dissolved lead loading percentages from chat leachate were greater than total and dissolved lead loading percentages from mine outflow. About 19 percent of total zinc loading came from chat leachate, about 29 percent of total zinc loading came from mine outflow, and about 52 percent of total zinc loading came from Lytle Creek.

Oklahoma↗

Water-quality assessment of part of the Upper Mississippi River Basin, Minnesota and Wisconsin — Ground-water quality along a flow system in the Twin Cities metropolitan area, Minnesota, 1997-98

As part of a national analysis of the effects of land use on ground-water quality for the National Water-Quality Assessment Program, the U.S. Geological Survey sampled wells along a flow system in surficial glacial aquifers in the northwestern part of the Twin Cities metropolitan area during 1997 and 1998. In addition, a reconnaissance steady-state ground-water model was developed to estimate flowpaths and dates of ground-water recharge using a particle-tracking routine. Sediment samples collected during drilling had high horizontal hydraulic conductivities (ranging from about 3.1 to about 190 feet per day, based on sediment-size analysis of well cuttings), small organic carbon concentrations (ranging from less than 0.2 to 160 grams per kilogram), and pH values that were mostly alkaline (ranging from 4.9 to 8.2). Water samples were analyzed for physical properties, major ions, iron, manganese, nutrients, organic carbon, radon, pesticides, volatile organic compounds (VOCs), chlorofluorocarbons, tritium, and isotopes of nitrogen, hydrogen, and oxygen. Most of the water samples had small dissolved-oxygen concentrations (less than 1 milligram per liter). Calcium, magnesium, sodium, bicarbonate, sulfate, and chloride were the primary dissolved constituents in water samples. Nitrite plus nitrate as nitrogen (nitrate) concentrations were less than the U.S. Environmental Protection Agency (USEPA) Maximum Contaminant Level of 10 mg/L. Nitrogen isotope ratios indicated that the sources of nitrate primarily were soils, animal waste, or denitrification that increased nitrogen isotope ratios in nitrate. Small concentrations of pesticides were detected in the shallow parts of the aquifer. The herbicide prometon was the most frequently detected pesticide. Herbicides applied to control grasses and weeds in corn (atrazine, simazine, and metolachlor) also were frequently detected in water samples. All pesticide and VOCs detected were below USEPA Maximum Contaminant Levels or Health Advisory Limits. Chlorofluorocarbon compounds and tritium concentrations were used to estimate dates of recharge of ground-water samples. In general, shallower ground-water samples were more recently recharged although most water sampled from the aquifer was recharged after 1955. Although land use had substantial effects on ground-water quality, the distribution of contaminants in the aquifer also is affected by complex combinations of factors and processes that include sources of natural and anthropogenic contaminants, three-dimensional advective flow, physical and hydrologic settings, age and evolution of ground water, and transformation of chemical compounds along the flow system. Compounds such as nitrate and dissolved oxygen were greatest in water samples from the upgradient end of the flow system and near the water table. Specific conductance and dissolved solids increased along the flow system and with depth due to increase in residence time in the flow system and dissolution of aquifer materials.

Minnesota↗

Hydrology and ground-water quality in the mine workings within the Picher Mining District, Northeastern Oklahoma, 2002-03

The Picher mining district of northeastern Ottawa County, Oklahoma, was a major site of mining for lead and zinc ores in the first half of the 20th century. The primary source of lead and zinc were sulfide minerals disseminated in the cherty limestones and dolomites of the Boone Formation of Mississippian age, which comprises the Boone aquifer. Ground water in the aquifer and seeping to surface water in the district has been contaminated by sulfate, iron, lead, zinc, and several other metals. The U.S. Geological Survey, in cooperation with the Oklahoma Department of Environmental Quality, investigated hydrology and ground-water quality in the mine workings in the mining district, as part of the process to aid water managers and planners in designing remediation measures that may restore the environmental quality of the district to pre-mining conditions. Most ground-water levels underlying the mining district had similar altitudes, indicating a large degree of hydraulic connection in the mine workings and overlying aquifer materials. Recharge-age dates derived from concentrations of chlorofluorocarbons and other dissolved gases indicated that water in the Boone aquifer may flow slowly from the northeast and southeast portions of the mining district. However, recharge-age dates may have been affected by the types of sites sampled, with more recent recharge-age dates being associated with mine-shafts, which are more prone to atmospheric interactions and surface runoff than the sampled airshafts. Water levels in streams upstream from the confluence of Tar and Lytle Creeks were several feet higher than those in adjacent portions of the Boone aquifer, perhaps due to low-permeability streambed sediments and indicating the streams may be losing water to the aquifer in this area. From just upstream to downstream from the confluence of Tar and Lytle Creeks, surface-water elevations in these streams were less than those in the surrounding Boone aquifer, indicating that seepage from the aquifer to downstream portions of Tar Creek was much more likely. Water properties and major-ion concentrations indicate that water in the mining area was very hard, with large concentrations of dissolved solids that increased from areas of presumed recharge toward areas with older ground water. Most of the ground-water samples, particularly those from the airshafts, had dissolved-oxygen concentrations less than 1.0 milligram per liter. Small concentrations of dissolved oxygen may have been introduced during the sampling process. The small dissolved-oxygen concentrations were associated with samples containing large iron concentrations that indicates possible anoxic conditions in much of the aquifer. Ground water in the mining district was dominated by calcium, magnesium, and sulfate. Sodium concentrations tended to increase relative to calcium and magnesium concentrations. Ground-water samples collected in 2002-03 had large concentrations of many trace elements. Larger concentrations of metals and sulfate occurred in ground water with smaller pHs and dissolved-oxygen concentrations. Iron was the metal with the largest concentrations in the ground-water samples, occurring at concentrations up to 115,000 micrograms per liter. Cadmium, lead, manganese, zinc, and the other analyzed metals occurred in smaller concentrations in ground water than iron. However, larger cadmium concentrations appeared to be associated with sites that have small iron concentrations and more oxygenated waters. This is noteworthy because the small sulfate and iron concentrations in these waters could lead to conclusions that the waters are less contaminated than waters with large sulfate and iron concentrations. Ground-water quality in the mining district was compared with subsets of samples collected in 1983-85 and in 2002.

Oklahoma↗

Phosphorus concentrations, loads, and yields in the Illinois River Basin, Arkansas and Oklahoma, 1997-2001

The Illinois River and tributaries, Flint Creek and the Baron Fork, are designated scenic rivers in Oklahoma. Recent phosphorus increases in streams in the basin have resulted in the growth of excess algae, which have limited the aesthetic benefits of water bodies in the basin, especially the Illinois River and Lake Tenkiller. The Oklahoma Water Resources Board has established a standard for total phosphorus not to exceed the 30- day geometric mean concentration of 0.037 milligram per liter in Oklahoma Scenic Rivers. Data from water-quality samples from 1997 to 2001 were used to summarize phosphorus concentrations and estimate phosphorus loads, yields, and flowweighted concentrations in the Illinois River basin. Phosphorus concentrations in the Illinois River basin generally were significantly greater in runoff-event samples than in base-flow samples. Phosphorus concentrations generally decreased with increasing base flow, from dilution, and increased with runoff, possibly because of phosphorus resuspension, stream bank erosion, and the addition of phosphorus from nonpoint sources. Estimated mean annual phosphorus loads were greater at the Illinois River stations than at Flint Creek and the Baron Fork. Loads appeared to generally increase with time during 1997-2001 at all stations, but this increase might be partly attributable to the beginning of runoff-event sampling in the basin in July 1999. Base-flow loads at stations on the Illinois River were about 10 times greater than those on the Baron Fork and 5 times greater than those on Flint Creek. Runoff components of the annual total phosphorus load ranged from 58.7 to 96.8 percent from 1997-2001. Base-flow and runoff loads were generally greatest in spring (March through May) or summer (June through August), and were least in fall (September through November). Total yields of phosphorus ranged from 107 to 797 pounds per year per square mile. Greatest yields were at Flint Creek near Kansas (365 to 797 pounds per year per square mile) and the least yields were at Baron Fork at Eldon (107 to 440 pounds per year per square mile). Estimated mean flow-weighted concentrations were more than 10 times greater than the median and were consistently greater than the 75th percentile of flow-weighted phosphorus concentrations in samples collected at relatively undeveloped basins of the United States (0.022 milligram per liter and 0.037 milligram per liter, respectively). In addition, flow-weighted phosphorus concentrations in 1999-2001 at all Illinois River stations and at Flint Creek near Kansas were equal to or greater than the 75th percentile of all National Water-Quality Assessment program stations in the United States (0.29 milligram per liter). The annual average phosphorus load entering Lake Tenkiller was about 577,000 pounds per year, and more than 86 percent of the load was transported to the lake by runoff.The Illinois River and tributaries, Flint Creek and the Baron Fork, are designated scenic rivers in Oklahoma. Recent phosphorus increases in streams in the basin have resulted in the growth of excess algae, which have limited the aesthetic benefits of water bodies in the basin, especially the Illinois River and Lake Tenkiller. The Oklahoma Water Resources Board has established a standard for total phosphorus not to exceed the 30- day geometric mean concentration of 0.037 milligram per liter in Oklahoma Scenic Rivers. Data from water-quality samples from 1997 to 2001 were used to summarize phosphorus concentrations and estimate phosphorus loads, yields, and flowweighted concentrations in the Illinois River basin. Phosphorus concentrations in the Illinois River basin generally were significantly greater in runoff-event samples than in base-flow samples. Phosphorus concentrations generally decreased with increasing base flow, from dilution, and increased with runoff, possibly because of phosphorus resuspension, stream bank erosion, and the addition of phosphorus

Arkansas, Oklahoma↗

Statistical analysis of stream water-quality data and sampling network design near Oklahoma City, central Oklahoma, 1977-1999

Water-quality data collected from 1993-99 at five sites on Bluff, Deer, and Chisholm Creeks and from 1988-99 at five sites in the North Canadian River indicated that there were significant differences in constituent values among sites for water properties, major ions, trace elements, nutrients, turbidity, pesticides, and bacteria. Concentrations of dissolved solids and sulfate generally decreased as streams flowed through the Oklahoma City urban area. Concentrations of organic carbon, nitrogen and phosphorus compounds, lindane, and 2,4-D, and frequencies of detection of pesticides increased in the North Canadian River as it flowed through the urban area. Volatile organic compounds were not detected in samples collected quarterly from 1988-90 at sites on the North Canadian River. Concentrations of some compounds, including dissolved oxygen, sulfate, chloride, ammonia, manganese, diazinon, dieldrin, and fecal coliform bacteria periodically exceeded Federal or state water-quality standards at some sites. Regression analyses were used to identify trends in constituent concentrations related to streamflow, season, and time. Trends for some constituents were indicated at all sites, but most trends were sitespecific. Seasonal trends were evident for several constituents: suspended solids, organic nitrogen, and biochemical oxygen demand were greatest during summer. Dissolved oxygen, ammonia, and nitrite plus nitrate-nitrogen were greatest during winter. Concentrations of dissolved oxygen, fluoride, sulfate, total suspended solids, iron, and manganese generally increased with time. Concentrations of chloride, nitrite plus nitrate-nitrogen, dissolved phosphorus, dissolved orthophosphate, biochemical oxygen demand, dieldrin, and lindane decreased with time. There was relatively little change in land use from the late 1970s to the mid-1990s due to relatively modest rates of population growth in the study area during that period. Most changes in water quality in these streams and rivers may be due to changes in chemical use and wastewater treatment practices. The sampling network was evaluated with respect to areal coverage, sampling frequency, and analytical schedules. Areal coverage could be expanded to include one additional watershed that is not part of the current network. A new sampling site on the North Canadian River might be useful because of expanding urbanization west of the city, but sampling at some other sites could be discontinued or reduced based on comparisons of data between the sites. Additional real-time or periodic monitoring for dissolved oxygen may be useful to prevent anoxic conditions in pools behind new low-water dams. The sampling schedules, both monthly and quarterly, are adequate to evaluate trends, but additional sampling during flow extremes may be needed to quantify loads and evaluate water-quality during flow extremes. Emerging water-quality issues may require sampling for volatile organic compounds, sulfide, total phosphorus, chlorophyll- a , Esherichia coli , and enterococci, as well as use of more sensitive laboratory analytical methods for determination of cadmium, mercury, lead, and silver.

Oklahoma↗

Hydrology and water quality near Bromide Pavilion in Chickasaw National Recreation Area, Murray County, Oklahoma, 2000

The Bromide Pavilion in Chickasaw National Recreation Area drew many thousands of people annually to drink the mineral-rich waters piped from nearby Bromide and Medicine Springs. Periodic detection of fecal coliform bacteria in water piped to the pavilion from the springs, low yields of the springs, or flooding by adjacent Rock Creek prompted National Park Service officials to discontinue piping of the springs to the pavilion in the 1970s. Park officials would like to resume piping mineralized spring water to the pavilion to restore it as a visitor attraction, but they are concerned about the ability of the springs to provide sufficient quantities of potable water. Pumping and sampling of Bromide and Medicine Springs and Rock Creek six times during 2000 indicate that these springs may not provide sufficient water for Bromide Pavilion to supply large numbers of visitors. A potential problem with piping water from Medicine Spring is the presence of an undercut, overhanging cliff composed of conglomerate, which may collapse. Evidence of intermittent inundation of the springs by Rock Creek and seepage of surface water into the spring vaults from the adjoining creek pose a threat of contamination of the springs. Escherichia coli, fecal coliform, and fecal streptococcal bacteria were detected in some samples from the springs, indicating possible fecal contamination. Cysts of Giardia lamblia and oocysts of Cryptosporidium parvum protozoa were not detected in the creek or the springs. Total culturable enteric viruses were detected in only one water sample taken from Rock Creek.

Oklahoma↗