Geology topics

William F. Waite

Publications and source records attributed to William F. Waite.

At least 55 records · Page 3Linked to original sources

USGS2019

India National Gas Hydrate Program Expedition 02 Summary of Scientific Results: Gas hydrate systems along the eastern continental margin of India

The primary objectives of the India National Gas Hydrate Program Expedition 02 (NGHP-02) were to obtain new data on the occurrence of gas hydrate systems and to advance the understanding of the controls on the formation of gas hydrate accumulations in the offshore of India. In accordance with the ultimate overall goal of the NGHP effort to assess the energy resource potential of marine gas hydrates in India, particular focus was placed on the exploration and evaluation of gas hydrate occurrences at high saturations in sand-rich systems. NGHP-02 operations were conducted from 3-March-2015 to 28-July-2015 off the eastern coast of India and included logging while drilling (LWD) operations at 25 locations, and coring and wireline logging operations at 10 locations, in the Krishna-Godavari and Mahanadi Basins. The formation of highly concentrated gas hydrate accumulations, which are more suitable for energy extraction, requires the presence of relatively coarse-grained sediments with porosity needed to support the migration and accumulation of gas, and the nucleation of gas hydrate. The results of downhole logging, coring and formation pressure testing operations during NGHP-02 have confirmed the presence of extensive sand-rich depositional systems throughout the deepwater portions of the Krishna-Godavari and Mahanadi Basins. Two areas of Krishna-Godavari Basin, referred to as Areas B and C, contain substantial gas hydrate accumulations in sand-rich systems and therefore represent ideal candidate sites for future gas hydrate production testing. This summary and technical report includes a comprehensive synthesis of the geologic, geophysical, geochemical, and physical property data acquired during NGHP-02 as it relates to the controls on gas hydrate occurrence, particularly with regards to sand-hosted accumulations. In the Mahanadi Basin, despite the confirmation of extensive reservoir capacity, gas supply at the NGHP-02 sites was insufficient to charge the reservoirs with gas hydrates. In the Krishna-Godavari Basin, extensive reservoir systems were confirmed with sediment grain-sizes ranging from coarse-silts to gravels. These reservoirs range from fully- to partially filled with gas hydrate. The gas is determined to be from only microbial sources, and in part migrated into the reservoirs from deeper systems. The controls on gas hydrate occurrence are complex and varied; and include substantial reservoir heterogeneity and sufficient permeability throughout the reservoirs and seals that allowed pervasive fluid flow into and through the hydrate-bearing systems. These discoveries are the most significant confirmation of the exploration approach that focuses on direct detection of hydrate reservoirs supported by comprehensive petroleum systems analyses.

Journal of Marine and Petroleum Geology↗

USGS2018

Impact of pore fluid chemistry on fine-grained sediment fabric and compressibility

Fines, defined here as grains or particles, less than 75 μm in diameter, exist nearly ubiquitously in natural sediment, even those classified as coarse. Macroscopic sediment properties, such as compressibility, which relates applied effective stress to the resulting sediment deformation, depend on the fabric of fines. Unlike coarse grains, fines have sizes and masses small enough to be more strongly influenced by electrical interparticle forces than by gravity. These electrical forces acting through pore fluids are influenced by pore fluid chemistry changes. Macroscopic property dependence on pore fluid chemistry must be accounted for in sediment studies involving subsurface flow and sediment stability analyses, as well as in engineered flow situations such as groundwater pollutant remediation, hydrocarbon migration, or other energy resource extraction applications. This study demonstrates how the liquid limit‐based electrical sensitivity index can be used to predict sediment compressibility changes due to pore fluid chemistry changes. Laboratory tests of electrical sensitivity, sedimentation, and compressibility illustrate mechanisms linking microscale and macroscale processes for selected pure, end‐member fines. A specific application considered here is methane extraction via depressurization of gas hydrate‐bearing sediment, which causes a dramatic pore water salinity drop concurrent with sediment being compressed by the imposed effective stress increase.

Journal of Geophysical Research↗

USGS2018

Archie’s saturation exponent for natural gas hydrate in coarse-grained reservoirs

Accurately quantifying the amount of naturally occurring gas hydrate in marine and permafrost environments is important for assessing its resource potential and understanding the role of gas hydrate in the global carbon cycle. Electrical resistivity well logs are often used to calculate gas hydrate saturations, S h , using Archie's equation. Archie's equation, in turn, relies on an empirical saturation parameter, n . Though n = 1.9 has been measured for ice‐bearing sands and is widely used within the hydrate community, it is highly questionable if this n value is appropriate for hydrate‐bearing sands. In this work, we calibrate n for hydrate‐bearing sands from the Canadian permafrost gas hydrate research well, Mallik 5L‐38, by establishing an independent downhole S h profile based on compressional‐wave velocity log data. Using the independently determined S h profile and colocated electrical resistivity and bulk density logs, Archie's saturation equation is solved for n, and uncertainty is tracked throughout the iterative process. In addition to the Mallik 5L‐38 well, we also apply this method to two marine, coarse‐grained reservoirs from the northern Gulf of Mexico Gas Hydrate Joint Industry Project: Walker Ridge 313‐H and Green Canyon 955‐H. All locations yield similar results, each suggesting n ≈ 2.5 ± 0.5. Thus, for the coarse‐grained hydrate bearing ( S h > 0.4) of greatest interest as potential energy resources, we suggest that n = 2.5 ± 0.5 should be applied in Archie's equation for either marine or permafrost gas hydrate settings if independent estimates of n are not available.

Journal of Geophysical Research B: Solid Earth↗

USGS2017

Geomechanical analysis of initial stage of gas production from interbedded hydrate-bearing sediment

Geomechanical stability of marine hydrate reservoirs during gas production by depressurization is the focus of this study. The reservoir considered here consists of thin hydrate rich sandy layers interbedded with mud layers. Because of the input parameter uncertainties involved, it is prudent from a geomechanical perspective to estimate the likely bounds of potential responses. A decoupled approach is presented herein for which the pressure and hydrate saturation in the sediments during gas production are obtained from multiphase flow computation, but could also be synthesized from various scenarios. This procedure is illustrated with sample problems.

Conference Paper↗

USGS2017

What has been learned from pressure cores

The advancement of pressure core acquisition and analysis technology in recent decades has enabled detailed imaging and direct measurement of naturally occurring hydrate-bearing sediments and has shed light onto hydrate habits, formation processes, fundamental physical properties, and hydrate deposit responses during gas production. This paper reviews the development and capabilities of the pressure core technology, discusses insights learned from hydrate-bearing pressure cores and inherent limitations of this technology, and concludes with suggestions for potential applications of pressure core technology for investigating hydrate deposits.

Conference Paper↗

USGS2015

Hydro-bio-geomechanical properties of hydrate-bearing sediments from Nankai Trough

Natural hydrate-bearing sediments from the Nankai Trough, offshore Japan, were studied using the Pressure Core Characterization Tools (PCCTs) to obtain geomechanical, hydrological, electrical, and biological properties under in situ pressure, temperature, and restored effective stress conditions. Measurement results, combined with index-property data and analytical physics-based models, provide unique insight into hydrate-bearing sediments in situ. Tested cores contain some silty-sands, but are predominantly sandy- and clayey-silts. Hydrate saturations S h range from 0.15 to 0.74, with significant concentrations in the silty-sands. Wave velocity and flexible-wall permeameter measurements on never-depressurized pressure-core sediments suggest hydrates in the coarser-grained zones, the silty-sands where S h exceeds 0.4, contribute to soil-skeletal stability and are load-bearing. In the sandy- and clayey-silts, where S h < 0.4, the state of effective stress and stress history are significant factors determining sediment stiffness. Controlled depressurization tests show that hydrate dissociation occurs too quickly to maintain thermodynamic equilibrium, and pressure–temperature conditions track the hydrate stability boundary in pure-water, rather than that in seawater, in spite of both the in situ pore water and the water used to maintain specimen pore pressure prior to dissociation being saline. Hydrate dissociation accompanied with fines migration caused up to 2.4% vertical strain contraction. The first-ever direct shear measurements on never-depressurized pressure-core specimens show hydrate-bearing sediments have higher sediment strength and peak friction angle than post-dissociation sediments, but the residual friction angle remains the same in both cases. Permeability measurements made before and after hydrate dissociation demonstrate that water permeability increases after dissociation, but the gain is limited by the transition from hydrate saturation before dissociation to gas saturation after dissociation. In a proof-of-concept study, sediment microbial communities were successfully extracted and stored under high-pressure, anoxic conditions. Depressurized samples of these extractions were incubated in air, where microbes exhibited temperature-dependent growth rates.

Journal of Marine and Petroleum Geology↗

USGS2013

Gas hydrate formation rates from dissolved-phase methane in porous laboratory specimens

Marine sands highly saturated with gas hydrates are potential energy resources, likely forming from methane dissolved in pore water. Laboratory fabrication of gas hydrate-bearing sands formed from dissolved-phase methane usually requires 1–2 months to attain the high hydrate saturations characteristic of naturally occurring energy resource targets. A series of gas hydrate formation tests, in which methane-supersaturated water circulates through 100, 240, and 200,000 cm 3 vessels containing glass beads or unconsolidated sand, show that the rate-limiting step is dissolving gaseous-phase methane into the circulating water to form methane-supersaturated fluid. This implies that laboratory and natural hydrate formation rates are primarily limited by methane availability. Developing effective techniques for dissolving gaseous methane into water will increase formation rates above our observed (1 ± 0.5) × 10 −7 mol of methane consumed for hydrate formation per minute per cubic centimeter of pore space, which corresponds to a hydrate saturation increase of 2 ± 1% per day, regardless of specimen size.

Geophysical Research Letters↗

USGS2012

Hydrate morphology: Physical properties of sands with patchy hydrate saturation

The physical properties of gas hydrate-bearing sediments depend on the volume fraction and spatial distribution of the hydrate phase. The host sediment grain size and the state of effective stress determine the hydrate morphology in sediments; this information can be used to significantly constrain estimates of the physical properties of hydrate-bearing sediments, including the coarse-grained sands subjected to high effective stress that are of interest as potential energy resources. Reported data and physical analyses suggest hydrate-bearing sands contain a heterogeneous, patchy hydrate distribution, whereby zones with 100% pore-space hydrate saturation are embedded in hydrate-free sand. Accounting for patchy rather than homogeneous hydrate distribution yields more tightly constrained estimates of physical properties in hydrate-bearing sands and captures observed physical-property dependencies on hydrate saturation. For example, numerical modeling results of sands with patchy saturation agree with experimental observation, showing a transition in stiffness starting near the series bound at low hydrate saturations but moving toward the parallel bound at high hydrate saturations. The hydrate-patch size itself impacts the physical properties of hydrate-bearing sediments; for example, at constant hydrate saturation, we find that conductivity (electrical, hydraulic and thermal) increases as the number of hydrate-saturated patches increases. This increase reflects the larger number of conductive flow paths that exist in specimens with many small hydrate-saturated patches in comparison to specimens in which a few large hydrate saturated patches can block flow over a significant cross-section of the specimen.

Journal of Geophysical Research B: Solid Earth↗

USGS2011

Anomalous waveforms observed in laboratory-formed gas hydrate-bearing and ice-bearing sediments

Acoustic transmission measurements of compressional, P, and shear, S, wave velocities rely on correctly identifying the P- and S-body wave arrivals in the measured waveform. In cylindrical samples for which the sample is much longer than the acoustic wavelength, these body waves can be obscured by high-amplitude waveform features arriving just after the relatively small-amplitude P-body wave. In this study, a normal mode approach is used to analyze this type of waveform, observed in sediment containing gas hydrate or ice. This analysis extends an existing normal-mode waveform propagation theory by including the effects of the confining medium surrounding the sample, and provides guidelines for estimating S-wave velocities from waveforms containing multiple large-amplitude arrivals.

Journal of the Acoustical Society of America↗

USGS2011

Physical properties of sediment from the Mount Elbert Gas Hydrate Stratigraphic Test Well, Alaska North Slope

This study characterizes cored and logged sedimentary strata from the February 2007 BP Exploration Alaska, Department of Energy, U.S. Geological Survey (BPXA-DOE-USGS) Mount Elbert Gas Hydrate Stratigraphic Test Well on the Alaska North Slope (ANS). The physical-properties program analyzed core samples recovered from the well, and in conjunction with downhole geophysical logs, produced an extensive dataset including grain size, water content, porosity, grain density, bulk density, permeability, X-ray diffraction (XRD) mineralogy, nuclear magnetic resonance (NMR), and petrography. This study documents the physical property interrelationships in the well and demonstrates their correlation with the occurrence of gas hydrate. Gas hydrate (GH) occurs in three unconsolidated, coarse silt to fine sand intervals within the Paleocene and Eocene beds of the Sagavanirktok Formation: Unit D-GH (614.4 m-627.9 m); unit C-GH1 (649.8 m-660.8 m); and unit C-GH2 (663.2 m-666.3 m). These intervals are overlain by fine to coarse silt intervals with greater clay content. A deeper interval (unit B) is similar lithologically to the gas-hydrate-bearing strata; however, it is water-saturated and contains no hydrate. In this system it appears that high sediment permeability (k) is critical to the formation of concentrated hydrate deposits. Intervals D-GH and C-GH1 have average "plug" intrinsic permeability to nitrogen values of 1700 mD and 675 mD, respectively. These values are in strong contrast with those of the overlying, gas-hydrate-free sediments, which have k values of 5.7 mD and 49 mD, respectively, and thus would have provided effective seals to trap free gas. The relation between permeability and porosity critically influences the occurrence of GH. For example, an average increase of 4% in porosity increases permeability by an order of magnitude, but the presence of a second fluid (e.g., methane from dissociating gas hydrate) in the reservoir reduces permeability by more than an order of magnitude.

Alaska↗

USGS2011

Inter-laboratory comparison of wave velocity measures.

This paper presents an eight-laboratory comparison of compressional and shear wave velocities measured in F110 Ottawa sand. The study was run to quantify the physical property variations one should expect in heterogeneous, multiphase porous materials by separately quantifying the variability inherent in the measurement techniques themselves. Comparative tests were run in which the sand was dry, water-saturated, partially water-saturated, partially ice-saturated and partially hydrate-saturated. Each test illustrates a collection of effects that can be classified as inducing either specimen-based or measurement-based variability. The most significant variability is due to void ratio variations between samples. Heterogeneous pore-fill distributions and differences in measurement techniques also contribute to the observed variability, underscoring the need to provide detailed sample preparation and system calibration information when reporting wave velocities in porous media.

Book↗

USGS2011

Laboratory formation of non-cementing, methane hydrate-bearing sands

Naturally occurring hydrate-bearing sands often behave as though methane hydrate is acting as a load-bearing member of the sediment. Mimicking this behavior in laboratory samples with methane hydrate likely requires forming hydrate from methane dissolved in water. To hasten this formation process, we initially form hydrate in a free-gas-limited system, then form additional hydrate by circulating methane-supersaturated water through the sample. Though the dissolved-phase formation process can theoretically be enhanced by increasing the pore pressure and flow rate and lowering the sample temperature, a more fundamental concern is preventing clogs resulting from inadvertent methane bubble formation in the circulation lines. Clog prevention requires careful temperature control throughout the circulation loop.

Conference Paper↗

USGS2010

Methane hydrate-bearing seeps as a source of aged dissolved organic carbon to the oceans

Marine sediments contain about 500–10,000 Gt of methane carbon1, 2, 3, primarily in gas hydrate. This reservoir is comparable in size to the amount of organic carbon in land biota, terrestrial soils, the atmosphere and sea water combined1, 4, but it releases relatively little methane to the ocean and atmosphere5. Sedimentary microbes convert most of the dissolved methane to carbon dioxide6, 7. Here we show that a significant additional product associated with microbial methane consumption is methane-derived dissolved organic carbon. We use Δ14C and δ13C measurements and isotopic mass-balance calculations to evaluate the contribution of methane-derived carbon to seawater dissolved organic carbon overlying gas hydrate-bearing seeps in the northeastern Pacific Ocean. We show that carbon derived from fossil methane accounts for up to 28% of the dissolved organic carbon. This methane-derived material is much older, and more depleted in 13C, than background dissolved organic carbon. We suggest that fossil methane-derived carbon may contribute significantly to the estimated 4,000–6,000 year age of dissolved organic carbon in the deep ocean8, and provide reduced organic matter and energy to deep-ocean microbial communities.

Nature Geoscience↗

USGS2010

S-Wave Normal Mode Propagation in Aluminum Cylinders

Large amplitude waveform features have been identified in pulse-transmission shear-wave measurements through cylinders that are long relative to the acoustic wavelength. The arrival times and amplitudes of these features do not follow the predicted behavior of well-known bar waves, but instead they appear to propagate with group velocities that increase as the waveform feature's dominant frequency increases. To identify these anomalous features, the wave equation is solved in a cylindrical coordinate system using an infinitely long cylinder with a free surface boundary condition. The solution indicates that large amplitude normal-mode propagations exist. Using the high-frequency approximation of the Bessel function, an approximate dispersion relation is derived. The predicted amplitude and group velocities using the approximate dispersion relation qualitatively agree with measured values at high frequencies, but the exact dispersion relation should be used to analyze normal modes for full ranges of frequency of interest, particularly at lower frequencies.

Scientific Investigations Report↗

USGS2009

Physical properties of hydrate‐bearing sediments

Methane gas hydrates, crystalline inclusion compounds formed from methane and water, are found in marine continental margin and permafrost sediments worldwide. This article reviews the current understanding of phenomena involved in gas hydrate formation and the physical properties of hydrate‐bearing sediments. Formation phenomena include pore‐scale habit, solubility, spatial variability, and host sediment aggregate properties. Physical properties include thermal properties, permeability, electrical conductivity and permittivity, small‐strain elastic P and S wave velocities, shear strength, and volume changes resulting from hydrate dissociation. The magnitudes and interdependencies of these properties are critically important for predicting and quantifying macroscale responses of hydrate‐bearing sediments to changes in mechanical, thermal, or chemical boundary conditions. These predictions are vital for mitigating borehole, local, and regional slope stability hazards; optimizing recovery techniques for extracting methane from hydrate‐bearing sediments or sequestering carbon dioxide in gas hydrate; and evaluating the role of gas hydrate in the global carbon cycle.

Reviews of Geophysics↗

USGS2009

High-frequency normal mode propagation in aluminum cylinders

Acoustic measurements made using compressional-wave (P-wave) and shear-wave (S-wave) transducers in aluminum cylinders reveal waveform features with high amplitudes and with velocities that depend on the feature's dominant frequency. In a given waveform, high-frequency features generally arrive earlier than low-frequency features, typical for normal mode propagation. To analyze these waveforms, the elastic equation is solved in a cylindrical coordinate system for the high-frequency case in which the acoustic wavelength is small compared to the cylinder geometry, and the surrounding medium is air. Dispersive P- and S-wave normal mode propagations are predicted to exist, but owing to complex interference patterns inside a cylinder, the phase and group velocities are not smooth functions of frequency. To assess the normal mode group velocities and relative amplitudes, approximate dispersion relations are derived using Bessel functions. The utility of the normal mode theory and approximations from a theoretical and experimental standpoint are demonstrated by showing how the sequence of P- and S-wave normal mode arrivals can vary between samples of different size, and how fundamental normal modes can be mistaken for the faster, but significantly smaller amplitude, P- and S-body waves from which P- and S-wave speeds are calculated.

Scientific Investigations Report↗

USGS2008

Estimating pore-space gas hydrate saturations from well log acoustic data

Relating pore-space gas hydrate saturation to sonic velocity data is important for remotely estimating gas hydrate concentration in sediment. In the present study, sonic velocities of gas hydrate–bearing sands are modeled using a three-phase Biot-type theory in which sand, gas hydrate, and pore fluid form three homogeneous, interwoven frameworks. This theory is developed using well log compressional and shear wave velocity data from the Mallik 5L-38 permafrost gas hydrate research well in Canada and applied to well log data from hydrate-bearing sands in the Alaskan permafrost, Gulf of Mexico, and northern Cascadia margin. Velocity-based gas hydrate saturation estimates are in good agreement with Nuclear Magneto Resonance and resistivity log estimates over the complete range of observed gas hydrate saturations.

Geochemistry, Geophysics, Geosystems↗

USGS2008

Physical properties of repressurized samples recovered during the 2006 National Gas Hydrate Program expedition offshore India

As part of an international cooperative research program, the U.S. Geological Survey (USGS) and researchers from the National Gas Hydrate Program (NGHP) of India are studying the physical properties of sediment recovered during the NGHP-01 cruise conducted offshore India during 2006. Here we report on index property, acoustic velocity, and triaxial shear test results for samples recovered from the Krishna-Godavari Basin. In addition, we discuss the effects of sample storage temperature, handling, and change in structure of fine-grained sediment. Although complex, sub-vertical planar gas-hydrate structures were observed in the silty clay to clayey silt samples prior to entering the Gas Hydrate And Sediment Test Laboratory Instrument (GHASTLI), the samples yielded little gas post test. This suggests most, if not all, gas hydrate dissociated during sample transfer. Mechanical properties of hydrate-bearing marine sediment are best measured by avoiding sample depressurization. By contrast, mechanical properties of hydrate-free sediments, that are shipped and stored at atmospheric pressure can be approximated by consolidating core material to the original in situ effective stress.

Conference Paper↗