Geology Reports⌕ Search

Geology topics

William F. Cannon

Publications and source records attributed to William F. Cannon.

At least 37 records · Page 2Linked to original sources
USGS2012

History and progress of the North American Soil Geochemical Landscapes Project, 2001-2010

In 2007, the U.S. Geological Survey, the Geological Survey of Canada, and the Mexican Geological Survey initiated a low-density (1 site per 1600 km 2 , 13323 sites) geochemical and mineralogical survey of North American soils (North American Soil Geochemical Landscapes Project). Sampling and analytical protocols were developed at a series of workshops in 20032004 and pilot studies were conducted from 20042007. The ideal sampling protocol at each site includes a sample from 05 cm depth, a composite of the soil A horizon, and a sample from the soil C horizon. The <2-mm fraction of each sample is analyzed for Al, Ca, Fe, K, Mg, Na, S, Ti, Ag, Ba, Be, Bi, Cd, Ce, Co, Cr, Cs, Cu, Ga, In, La, Li, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Sn, Sr, Te, Th, Tl, U, V, W, Y, and Zn by inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry following a near-total digestion in a mixture of HCl, HNO 3 , HClO 4 , and HF. Separate methods are used for As, Hg, Se, and total C on this same size fraction. The major mineralogical components are determined by a quantitative X-ray diffraction method. Sampling in the conterminous U.S. was completed in 2010 (c. 4800 sites) with chemical and mineralogical analysis currently underway. In Mexico, approximately 66% of the sampling (871 sites) had been done by the end of 2010 with completion expected in 2012. After completing sampling in the Maritime provinces and portions of other provinces (472 sites, 7.6% of the total), Canada withdrew from the project in 2010. Preliminary results for a swath from the central U.S. to Florida clearly show the effects of soil parent material and climate on the chemical and mineralogical composition of soils. A sample archive will be established and made available for future investigations.

Earth Science Frontiers↗
USGS2011

A national-scale geochemical and mineralogical survey of soils of the conterminous United States

In 2007, the US Geological Survey initiated a low-density (1 site per 1600 km 2 , c. 4800 sites) geochemical and mineralogical survey of soils of the conterminous USA. The ideal sampling protocol at each site includes a sample from 0–5 cm depth, a composite of the soil A horizon, and a sample from the soil C horizon. The <2-mm fraction of each sample is analyzed for Al, Ca, Fe, K, Mg, Na, S, Ti, Ag, Ba, Be, Bi, Cd, Ce, Co, Cr, Cs, Cu, Ga, In, La, Li, Mn, Mo, Nb, Ni, P, Pb, Rb, Sb, Sc, Sn, Sr, Te, Th, Tl, U, V, W, Y and Zn by inductively coupled plasma-mass spectrometry and inductively coupled plasma-atomic emission spectrometry following a near-total digestion in a mixture of HCl, HNO 3 , HClO 4 and HF. Separate methods are used for As, Hg, Se and total C on this same size fraction. The major mineralogical components are determined by a quantitative X-ray diffraction method. Sampling was completed in 2010 with chemical and mineralogical analysis currently underway. Preliminary results for a swath from the central USA to Florida clearly show the effects of soil parent material and climate on the chemical and mineralogical composition of soils. A sample archive will be established and made available for future investigations.

Conterminous United States↗
USGS2011

Midcontinent microcosm: Geology of the Atkins lake - Marengo falls area (Field trip 2)

Archean and Proterozoic rocks exposed over about 16km2 between Atkins Lake and Coffee Lake in southeastern Bayfield County (Fig. 1) chronicle almost all of the major Precambrian geologic events in the history of the southern Superior Craton. The oldest rocks are part of a locally gneissic quartz monzonite complex, the Puritan Batholith, with an igneous Rb-Sr age of 2710+140 Ma (Sims et al., 1977). At the regional scale, this complex is part of one of the youngest Archean granite-greenstone belts in the Superior Province, and it intrudes greenstones of the Neoarchean Ramsay Formation. In the Atkins Lake – Marengo River area, the Puritan Batholith is nonconformably overlain by the Paleoproterozoic (ca. 2200 Ma) Bad River Dolomite. The Bad River Dolomite is in turn separated by an unconformity from rocks of the ca. 1875 Ma Menominee Group (Palms Formation and Ironwood Iron-formation), which locally contain mafic volcanic rocks and diabase sills (Cannon et al., 2008). These Paleoproterozoic rocks provide insight into climate and biogeochemical cycles during the transition to an oxidizing atmosphere (Bekker et al., 2006) and have deformational fabrics (folds, strong cleavage, local mylonite zones) that record the ca. 1850 Ma Penokean Orogeny. The youngest rocks in the area are Mesoproterozoic basaltic lava flows (Siemens Creek Volcanics, ca. 1110 Ma) and a layered mafic complex (the Mineral Lake Intrusion, also ca. 1100 Ma), both related to the Mid-continent Rift. All of the stratified units show static contact metamorphic textures near their contacts with the Mineral Lake Intrusion. Thus the area constitutes a microcosm of the regional bedrock geology, and the cross-cutting relationships among the units provide clear constraints on the relative timing of different phases of deformation and magmatism (Cannon etal., 2008, Bjørnerud, 2010a).

Wisconsin↗
USGS2010

Immediate and long-term fire effects on total mercury in forests soils of northeastern Minnesota

Within the Boundary Waters Canoe Area Wilderness in northeastern Minnesota, soils were collected from 116 sites in areas of primarily virgin forest with fire-origin stand years (year of last recognizable stand-killing wildfire) that range from the 1759 to 1976. Median concentrations for total mercury in soils for this span of 217 years range from 0.28 ± 0.088 ppm (1759) to 0.09 ± 0.047 ppm (1976) for A-horizon soils and from 0.23 ± 0.062 ppm (1759) to 0.09 ± 0.018 ppm (1976) for O-horizon soils. A separate study of soils collected from 30 sites within an area that burned in a 2004 wildfire at Voyageurs National Park, northern Minnesota, suggested that high soil burn severity resulted in significant mercury loss from both organic and mineral soils. Integrated data from these two studies and additional regional soil data demonstrate that older forests have progressively higher mercury concentrations in O-horizon soils (r 2 = 0.423) and A-horizon soils (r 2 = 0.456). These results support the hypotheses that an important factor for mercury concentrations in forest soils is time since stand-replacing fire and that high soil burn severity has the potential to reduce the concentration of mercury in burned soils for tens to hundreds of years.

Minnesota↗
USGS2010

Total mercury, methylmercury, and selected elements in soils of the Fishing Brook watershed, Hamilton County, New York, and the McTier Creek watershed, Aiken County, South Carolina, 2008

Mercury is an element of on-going concern for human and aquatic health. Mercury sequestered in upland and wetland soils represents a source that may contribute to mercury contamination in sensitive ecosystems. An improved understanding of mercury cycling in stream ecosystems requires identification and quantification of mercury speciation and transport dynamics in upland and wetland soils within a watershed. This report presents data for soils collected in 2008 from two small watersheds in New York and South Carolina. In New York, 163 samples were taken from multiple depths or soil horizons at 70 separate locations near Fishing Brook, located in Hamilton County. At McTier Creek, in Aiken County, South Carolina, 81 samples from various soil horizons or soil depths were collected from 24 locations. Sample locations within each watershed were selected to characterize soil geochemistry in distinct land-cover compartments. Soils were analyzed for total mercury, selenium, total and carbonate carbon, and 42 other elements. A subset of the samples was also analyzed for methylmercury.

Data Series↗
USGS2010

Environmental baseline study of the Huron River Watershed, Baraga and Marquette Counties, Michigan

This report summarizes results of a study to establish water-quality and geochemical baseline conditions within a small watershed in the Lake Superior region. In 2008, the U.S. Geological Survey (USGS) completed a survey of water-quality parameters and soil and streambed sediment geochemistry of the 83 mi2 Huron River Watershed in the Upper Peninsula of Michigan. Streamflow was measured and water-quality samples collected at a range of flow conditions from six sites on the major tributaries of the Huron River. All water samples were analyzed for a suite of common ions, nutrients, and trace metals. In addition, water samples from each site were analyzed for unfiltered total and methylmercury once during summer low-flow conditions. Soil samples were collected from 31 sites, with up to 4 separate samples collected at each site, delineated by soil horizon. Streambed sediments were collected from 11 sites selected to cover most of the area drained by the Huron River system. USGS data were supplemented with ecological assessments completed in 2006 by the Michigan Department of Environmental Quality using a modified version of their Great Lakes Environmental Assessment Section procedure 51, and again during 2008 using volunteers under supervision of the Michigan Department of Natural Resources. Results from this study define a hydrological, geological, and environmental baseline for the Huron River Watershed prior to any significant mineral exploration or development. Results from the project also serve to refine the design of future regional environmental baseline studies in the Lake Superior Basin.

Scientific Investigations Report↗
USGS2009

Impact of wildfire on levels of mercury in forested watershed systems: Voyageurs National Park, Minnesota

Atmospheric deposition of mercury to remote lakes in mid-continental and eastern North America has increased approximately threefold since the mid-1800s (Swain and others, 1992; Fitzgerald and others, 1998; Engstrom and others, 2007). As a result, concerns for human and wildlife health related to mercury contamination have become widespread. Despite an apparent recent decline in atmospheric deposition of mercury in many areas of the Upper Midwest (Engstrom and Swain, 1997; Engstrom and others, 2007), lakes in which fish contain levels of mercury deemed unacceptable for human consumption and possibly unacceptable for fish-consuming wildlife are being detected with increasing frequency. In northern Minnesota, Voyageurs National Park (VNP) (fig. 1) protects a series of southern boreal lakes and wetlands situated on bedrock of the Precambrian Canadian Shield. Mercury contamination has become a significant resource issue within VNP as high concentrations of mercury in loons, bald eagle eaglets, grebes, northern pike, and other species of wildlife and fish have been found. The two most mercury-contaminated lakes in Minnesota, measured as methylmercury in northern pike ( Esox lucius ), are in VNP. Recent multidisciplinary U.S. Geological Survey (USGS) research demonstrated that the bulk of the mercury in lake waters, soils, and fish in VNP results from atmospheric deposition (Wiener and others, 2006). The study by Wiener and others (2006) showed that the spatial distribution of mercury in watershed soils, lake waters, and age-1 yellow perch ( Perca flavescens ) within the Park was highly variable. The majority of factors correlated for this earlier study suggested that mercury concentrations in lake waters and age-1 yellow perch reflected the influence of ecosystem processes that affected within-lake microbial production and abundance of methylmercury (Wiener and others, 2006), while the distribution of mercury in watershed soils seemed to be partially dependent on forest disturbance, especially the historic forest fire pattern (Woodruff and Cannon, 2002). Forest fire has an essential role in the forest ecosystems of VNP (Heinselman, 1996). Because resource and land managers need to integrate both natural wildfire and prescribed fire in management plans, the potential influence of fire on an element as sensitive to the environment as mercury becomes a critical part of their decisionmaking. A number of recent studies have shown that while fire does have a significant impact on mercury at the landscape level, the observed effects of fire on aquatic environments are highly variable and unpredictable (Caldwell and others, 2000; Garcia and Carrigan, 2000; Kelly and others, 2006; Nelson and others, 2007). Caldwell and others (2000) described an increase in methylmercury in reservoir sediments resulting from mobilization and transport of charred vegetative matter following a fire in New Mexico. Krabbenhoft and Fink (2000) attributed increases in total mercury concentrations in young-of-the-year fish in the Florida Everglades to release of mercury resulting from peat oxidation following fires. A fivefold increase in whole-body mercury accumulation by rainbow trout ( Oncorhynchus mykiss ) following a fire in Alberta, Canada, apparently resulted from increased nutrient concentrations that enhanced productivity and restructured the food web of a lake within the fire’s burn footprint (Kelly and others, 2006). For this study, we determined the short-term effects of forest fire on mercury concentrations in terrestrial and aquatic environments in VNP by comparing and contrasting mercury concentrations in forest soils, lake waters, and age-1 yellow perch for a burned watershed and an adjacent lake, with similar samples from watersheds and lakes with no fire activity (control watersheds and lakes). The concentration of total mercury in whole, 1-year-old yellow perch serves as a good biological indicator for monitoring trends in methylmercury concentrations in food webs of lakes in North America (Wiener and others, 2007). With a limited gape, age-1 yellow perch that hatched the previous year and resided in a lake for 1 year feed largely on zooplankton and small benthic invertebrates. Thus, age-1 yellow perch provide a baseline for methylmercury concentrations for individual lakes that can be compared across spatial areas. The nine appendixes that accompany this report contain the complete datasets for soils, lake waters, and age-1 yellow perch collected for this study. This report uses data from these three media to provide a framework for evaluating short-term effects of fire on mercury in forested soils and possible effects of the mobilization of mercury from soils on lake water quality and aquatic health.

Minnesota↗
USGS2008

The Gogebic Iron Range — A sample of the northern margin of the Penokean fold and thrust belt

The Gogebic iron range is an elongate belt of Paleoproterozoic strata extending from the west shore of Lake Gogebic in the upper peninsula of Michigan for about 125 km westward into northern Wisconsin. It is one of six major informally named iron ranges in the Lake Superior region and produced about 325 million tons of direct-shipping ore between 1887 and 1967. A significant resource of concentrating-grade ore remains in the western and eastern parts of the range. The iron range forms a broad, gently southward-opening arc where the central part of the range exposes rocks that were deposited somewhat north of the eastern and western parts. A fundamental boundary marking both the tectonic setting of deposition and the later deformation within the Penokean orogen lies fortuitously in an east-west direction along the range so that the central part of the range preserves sediments deposited north of that boundary, whereas the eastern and western parts of the range were deposited south of the boundary. Thus, the central part of the range provides a record of sedimentation and very mild deformation in a part of the Penokean orogen farthest from the interior of the orogen to the south. The eastern and western parts of the range, in contrast, exhibit a depositional and deformational style typical of parts closer to the interior of the orogen. A second fortuitous feature of the iron range is that the entire area was tilted from 40° to 90° northward by Mesoproterozoic deformation so that the map view offers an oblique cross section of the Paleoproterozoic sedimentary sequence and structures. Together, these features make the Gogebic iron range a unique area in which to observe (1) the lateral transition from deposition on a stable platform to deposition in a tectonically and volcanically active region, and (2) the transition from essentially undeformed Paleoproterozoic strata to their folded and faulted equivalents. Paleoproterozoic strata in the Gogebic iron range are part of the Marquette Range Supergroup. They were deposited unconformably on Neoarchean rocks consisting of a diverse volcanic suite (the Ramsay Formation) which was intruded by granitic rocks of the Puritan Quartz Monzonite. The Marquette Range Supergroup in this region consists of a basal sequence of orthoquartzite (Sunday Quartzite) and dolomite (Bad River Dolomite), both of which are part of the Chocolay Group. The group is preserved only in the eastern and western parts of the range but was probably present throughout before the erosion interval that separated it from the overlying Menominee Group. The Menominee Group consists of basal clastic rocks (Palms Formation) that grade upward into the Ironwood Iron-Formation, which is the principal iron-bearing unit of the range. The Ironwood interfingers with the Emperor Volcanic Complex in the eastern part of the range and with volcanic rocks and gabbro in the western part of the range. The Ironwood is overlain unconformably by the Tyler Formation in the central and western parts of the range and by the Tyler’s equivalent, the Copps Formation, in the eastern part of the range. Strata in the central part of the iron range are entirely sedimentary. Deposition occurred in a relatively stable tectonic setting, at least until the deposition of the Tyler Formation. The Tyler consists largely of turbidites deposited in a foreland basin in advance of accreting volcanic arcs to the south. Penokean deformation in the central part of the range was very minor; the evidence of deformation consists of steep faults with small offsets and a few bedding-parallel faults that also have small offsets and that are recognized only in mine workings. In both the eastern and western parts of the iron range, abrupt facies changes mark a passage into a more tectonically and volcanically active belt. These relationships are especially well displayed in the east where a graben, the Presque Isle trough, began to subside during deposition of the Ironwood Iron-Formation. The thickness of the Ironwood increases into the graben and its internal stratigraphy also changes. The most prominent changes in the graben are the presence of a thick volcanic unit, the Emperor Volcanic Complex of the Menominee Group, and comagmatic gabbro sills that interfinger with the Ironwood. In the western part of the range, volcanic rocks and comagmatic gabbro sills are also present in the Ironwood, but a graben that is equivalent to the Presque Isle trough is not evident. Penokean structures are well developed in both the eastern and western parts of the iron range. They consist of folds ranging from outcrop to regional scale and thrust faults which, in places, either repeated the section or detached it from Neoarchean basement. The sharp transition from the little-deformed central part of the range to the more intensely deformed eastern and western parts coincides closely with the earlier developed transition from the stable sedimentary setting in the central part to the tectonically active sedimentation in the east and west parts. The extensional structures that formed during sedimentation may have helped to control the extent of later Penokean compressional structures.

Michigan, Wisconsin↗
USGS2005

Major- and trace-element concentrations in soils from two continental-scale transects of the United States and Canada

This report contains major- and trace-element concentration data for soil samples collected from 265 sites along two continental-scale transects in North America. One of the transects extends from northern Manitoba to the United States-Mexico border near El Paso, Tex. and consists of 105 sites. The other transect approximately follows the 38th parallel from the Pacific coast of the United States near San Francisco, Calif., to the Atlantic coast along the Maryland shore and consists of 160 sites. Sampling sites were defined by first dividing each transect into approximately 40-km segments. For each segment, a 1-km-wide latitudinal strip was randomly selected; within each strip, a potential sample site was selected from the most representative landscape within the most common soil type. At one in four sites, duplicate samples were collected 10 meters apart to estimate local spatial variability. At each site, up to four separate soil samples were collected as follows: (1) material from 0-5 cm depth; (2) O horizon, if present; (3) a composite of the A horizon; and (4) C horizon. Each sample collected was analyzed for total major- and trace-element composition by the following methods: (1) inductively coupled plasmamass spectrometry (ICP-MS) and inductively coupled plasma-atomic emission spectrometry (ICPAES) for aluminum, antimony, arsenic, barium, beryllium, bismuth, cadmium, calcium, cerium, cesium, chromium, cobalt, copper, gallium, indium, iron, lanthanum, lead, lithium, magnesium, manganese, molybdenum, nickel, niobium, phosphorus, potassium, rubidium, scandium, silver, sodium, strontium, sulfur, tellurium, thallium, thorium, tin, titanium, tungsten, uranium, vanadium, yttrium, and zinc; (2) cold vapor- atomic absorption spectrometry for mercury; (3) hydride generation-atomic absorption spectrometry for antimony and selenium; (4) coulometric titration for carbonate carbon; and (5) combustion for total carbon and total sulfur.

Open-File Report↗
USGS2003

Arsenic in southeastern Michigan

Arsenic levels exceeding 10 μg/L are present in hundreds of private supply wells distributed over ten counties in eastern and southeastern Michigan. Most of these wells are completed in the Mississippian Marshall Sandstone, the principal bedrock aquifer in the region, or in Pleistocene glacial or Pennsylvanian bedrock aquifers. About 70% of ground water samples taken from more than 100 wells, have arsenic contents ≥10 μg/L with a maximum value of 220 μg/L . Water samples and continuous cores were taken from two test wells. Arsenic content of core samples ranges from <5 to more than 300 ppm, with the highest values found for pyritic black shales. Authigenic cements in the Marshall Sandstone include patchy authigenic pyrite that locally contains arsenic-rich (up to 8.5 wt. % As) domains. Bulk arsenic contents of pyrite-bearing intervals, sampled in well cuttings, are a high as 1020 ppm. Arsenic-rich pyrite is likely the ultimate source of arsenic in eastern and southeastern Michigan ground water, but evidence for pyrite oxidation at depth in bedrock aquifers is generally lacking. Pyrite oxidation may occur or have occurred in tills derived from the Marshall Sandstone and Coldwater Shale, which were found to contain arsenic-rich (up to at least 0.7 wt. % As) iron oxyhydroxides. Plausible mechanisms for widespread arsenic mobilization in eastern and southeastern Michigan ground water include weathering of pyrite in tills, reductive dissolution of iron oxyhydroxides in tills, and potentially, pyrite oxidation in bedrock aquifers, due to drawdown in wells or lowering of water-table levels in response to Pleistocene glaciation.

Michigan↗
USGS2003

The geochemical landscape of northwestern Wisconsin and adjacent parts of northern Michigan and Minnesota (geochemical data files)

This data set consists of nine files of geochemical information on various types of surficial deposits in northwestern Wisconsin and immediately adjacent parts of Michigan and Minnesota. The files are presented in two formats: as dbase files in dbaseIV form and Microsoft Excel form. The data present multi-element chemical analyses of soils, stream sediments, and lake sediments. Latitude and longitude values are provided in each file so that the dbf files can be readily imported to GIS applications. Metadata files are provided in outline form, question and answer form and text form. The metadata includes information on procedures for sample collection, sample preparation, and chemical analyses including sensitivity and precision.

Michigan, Minnesota, Wisconsin↗
USGS2003

Geochemistry of bedrock and glacial deposits in the vicinity of the Bend massive sulfide deposit, north central Wisconsin

In 1998 the U.S. Geological Survey (USGS) initiated a study to examine the natural regional environmental impact of sulfide mineralization exposed to episodic weathering and glaciation. The study focused on the Bend copper-gold massive sulfide deposit located in the Medford District of the Chequamegon National Forest in north central Wisconsin. The Bend massive sulfide deposit is a small, metal-rich sulfide body hosted by Paleoproterozoic metavolcanics. The mineralized horizon subcrops beneath 100-120 feet of glacial cover, and consists of massive pyrite and other sulfides. Bedrock and ore geochemistry are well characterized by analyses of diamond drill core provided to the USGS by Sharpe Energy and Resources. In July 1999, five rotasonic drillholes were completed through the unconsolidated Quaternary sediment, averaging about 100 feet thick, on a transect across the Bend deposit. Nearly continuous core was recovered from the surficial material along with several feet of the underlying bedrock. Samples representing the entire section were analyzed by the USGS to give a two-dimensional representation of element dispersal from the unmineralized bedrock. In addition, one hundred regional till samples were subsampled from the archives of the Quaternary Sediment Laboratory in the University of Wisconsin-Madison Department of Geology and Geophysics. These regional samples were collected mainly from Taylor County, where the Bend deposit is located, as well as contiguous parts of Clark and Marathon Counties. This open file report presents all of the geochemical data collected for this study. Additional publications describing the data in more detail are being completed.

Wisconsin↗
USGS2003

Bedrock, soil, and lichen geochemistry from Isle Royale National Park, Michigan

Isle Royale National Park, Michigan, is a large island in northeastern Lake Superior that became a national park in 1940 and was designated as a wilderness area in 1976. The relative isolation of Isle Royale (Figure 1), 25 kilometers out in Lake Superior from the Canadian mainland, its generally harsh climate, and its status as a wilderness national park have minimized human influence on the geochemical evolution of its landscape. USGS sampling on Isle Royale began in 1996 as part of a larger project on the geology of the Midcontinent rift in the Lake Superior region and continued through 2000. Sampling began with collecting bedrock samples to characterize the geochemistry of the volcanic rocks that make up the much of the island, as well as samples representative of the minor native copper mineralization found on the island. Preliminary results from the bedrock study indicated, among other findings, that basaltic bedrock on the island had no detectable mercury, but that there was an association between native copper mineralization and trace amounts of mercury (Cannon and Woodruff, 1999). This finding and the recognition by the National Park Service that 6 of 32 inland lakes on Isle Royale have mercury levels in game fish that exceed State of Michigan acceptable levels for human consumption (Kallemeyn, 2000) resulted in renewed sampling on the island focused more on environmental issues. To evaluate atmospheric inputs of mercury and other elements to soil geochemistry, regionally distributed samples of both soils and lichens were collected as paired samples across the entire island. At each soil sample site, three epiphytic (grows in trees) lichen species, Evernia mesomorpha , Hypogymnia plysodes , and Parmelia sucata , were always collected. At some sites Cladina rangiferina , a lichen that grows on bare bedrock and soil surfaces, was also collected. The occurrence of Cladina rangiferina on the island is somewhat limited, and so this lichen species was not collected at all sites. A high density of soil samples was collected within three individual watersheds (Sargent Lake, Lake Wagejo, and Lake Richie) for a localized study that evaluated the terrestrial distribution of mercury and other elements of environmental concern. These lakes were chosen using data from Kallemeyn (2000) that showed that Sargent Lake and Lake Wagejo have high mercury in fish, whereas Lake Richie, which is similar in size to Sargent Lake, does not. As part of this study on the terrestrial contribution of mercury to lakes, long cores of lake sediments were recovered from Sargent Lake and Lake Richie using a modified Livingston piston sampler. For an ancillary study that evolved from the study on the distribution of mercury in certain watersheds, some soil samples were collected to evaluate the impact of forest fire on soil geochemistry, deliberately sampling within and outside areas on the island that burned in severe forest fires in 1936. To complete bedrock sampling on the island, rock samples from the Copper Harbor Formation, a sedimentary unit that occurs on the southeastern part of the island were collected in 1999. This report presents all the geochemical data from samples collected by the USGS during this period (Figures 1 and 2). A number of reports presenting data interpretation are in preparation

Michigan↗
USGS2003

Concentrations of polynuclear aromatic hydrocarbons and inorganic constituents in ambient surface soils, Chicago, Illinois: 2001-02

Polynuclear aromatic hydrocarbon (PAH) compounds are ubiquitous in ambient surface soils in the city of Chicago, Illinois. PAH concentrations in samples collected in June 2001 and January 2002 were typically in the following order from highest to lowest: fluoranthene, pyrene, benzo(b)fluoranthene, phenanthrene, benzo(a)pyrene, chrysene, benzo(a)anthracene, benzo(k)fluoranthene, indeno(1,2,3-cd)pyrene, benzo(g,h,i)perylene, dibenzo(a,h)anthracene, and anthracene. Naphthalene, acenaphthene, acenaphthylene, and fluorene were consistently at the lowest concentrations in each sample. Concentrations of the PAH compounds showed variable correlation. Concentrations of PAH compounds with higher molecular weights typically show a higher degree of correlation with other PAH compounds of higher molecular weight, whereas PAH compounds with lower molecular weights tended to show a lower degree of correlation with all other PAH compounds. These differences indicate that high and low molecular-weight PAHs behave differentl y once released into the environment. Concentrations of individual PAH compounds in soils typically varied by at least three orders of magnitude across the city and varied by more than an order of magnitude over a distance of about 1,000 feet. Concentrations of a given PAH in ambient surface soils are affected by a variety of site-specific factors, and may be affected by proximity to industrial areas. Concentrations of a given PAH in ambient surface soils did not appear to be affected the organic carbon content of the soil, proximity to non-industrial land use, or proximity to a roadway. The concentration of the different PAH compounds in ambient surface soils appears to be affected by the propensity for the PAH compound to be in the vapor or particulate phase in the atmosphere. Lower molecular-weight PAH compounds, which are primarily in the vapor phase in the atmosphere, were detected in lower concentrations in the surface soils. Higher molecular-weight PAH compounds, which are present primarily in the particulate phase in the atmosphere, tended to be in higher concentrations in the surface soils. The apparent effect of the PAH phase in the atmosphere on the concentration of a PAH in ambient surface soils indicates that atmospheric settling of particulate matter is an important source of the PAH compounds in ambient surface soils in Chicago. The distribution of PAH compounds within the city was complex. Comparatively high concentrations were detected near Lake Michigan in the northern part of the city, in much of the western part of the city, and in isolated areas in the southern part of the city. Concentrations were lower in much of the northwestern, south-central, southwestern, and far southern parts of the city. The arithmetic mean concentration of arsenic, mercury, calcium, magnesium, phosphorus, copper, molybdenum, zinc, and selenium was from 2 to 6 times higher in ambient surface soils in the city of Chicago than in soils from surrounding agricultural areas. The arithmetic mean concentration of lead in Chicago soils was about 20 times higher. Concentrations of calcium and magnesium above those of surrounding agricultural areas appear to be related to the effects of dolomite bedrock on the chemical composition of the soil. Elevated concentrations of the remaining elements listed above indicate a potential anthropogenic source(s) of these elements in Chicago soils.

Illinois↗
USGS2002

Bedrock and soil geochemistry from Voyageurs National Park, Minnesota

Bedrock, forest floor, and mineral soil sampling in Voyageurs National Park (VNP), Minnesota in 2000 and 2001 is part of a multidisciplinary project that includes the U. S. Geological Survey, National Park Service, University of Wisconsin &ndash; La Crosse, Minnesota Pollution Control Agency, and the Minnesota Department of Natural Resources. The joint project is examining the distribution of mercury in age-1 perch, lake water, bedrock and soils for eighteen watersheds in the interior of VNP. The purpose of the project was to establish the background and baseline geochemistry for bedrock and soil in the region, and to determine terrestrial mercury sources and sinks in VNP.

Minnesota↗