Geology topics

Wayne R. Premo

Publications and source records attributed to Wayne R. Premo.

At least 19 recordsLinked to original sources

USGS2025

Re-evaluating the tectonic affinity of Proterozoic crustal provinces in the Southwest USA: Detrital zircon evidence for a Laurentian source for the Yavapai and Mojave Provinces

Models for crustal growth commonly involve the accretion of dominantly juvenile crust to continental margins. However, tracking the provenance and tectonic affinity of dominantly juvenile crustal provinces is challenging. This difficulty is highlighted by uncertainty over whether the Yavapai and Mojave Provinces, part of the >1300-km-wide system of Proterozoic orogens in southwestern Laurentia, (1) have similar crustal and tectonic histories and (2) if they formed on or near Laurentian, Australian, or Antarctic cratons. Here, we contribute new large-n detrital zircon U-Pb geochronology and Sm-Nd whole-rock isotope geochemistry to help constrain the provenance of the Yavapai Province and address these broader questions. Yavapai Province metasedimentary rocks from central Colorado in the southwestern USA have abundant pre-1.80 Ga detrital zircon grains, with ca. 1.85 Ga, 2.30 Ga, and 2.50−2.70 Ga peaks, and variable amounts of 1.79−1.78 Ga grains. Evolved whole-rock Sm-Nd isotopic compositions from these rocks, including 2.36−2.08 Ga model ages, also suggest mixing between 1.79 Ga and 1.78 Ga Yavapai Province arcs and early Proterozoic to Archean sources. Nearly identical pre-1.8 Ga detrital and inherited zircon age distributions suggest that the Yavapai and Mojave Provinces formed on and/or incorporated similar material. The Trans-Hudson orogen, and to a slightly lesser extent the Penokean orogen, provide the closest matches to the pre-1.80 Ga material in the Yavapai and Mojave Provinces. This similarity, coupled with a weaker resemblance to Australian and Antarctic sources, support a Laurentian affinity for the Yavapai and Mojave Provinces. We envision Paleoproterozoic arc formation on both oceanic crust and material of Laurentian affinity and multiple phases of arc-back-arc genesis, closure, and accretionary tectonism along the long-lived margin of the supercontinent Columbia (Nuna).

Arizona, Colorado, Idaho, New Mexico, Utah, Wyomin↗

USGS2024

Paleogene mid-crustal intrusions in the Ruby Mountains–East Humboldt Range metamorphic core complex, northeastern Nevada, USA

Middle Eocene to early Oligocene intrusions, widespread in the Ruby Mountains–East Humboldt Range metamorphic core complex, Nevada, USA, provide insights into a major Paleogene magmatic episode and its relation to tectonism in the northeastern Great Basin. These intrusions, well-exposed in upper Lamoille Canyon, range in composition from gabbro to leucomonzogranite. They form small plutons, sheets, and dikes that intrude the metamorphic and granitic infrastructure of the core complex. Two types of Paleogene monzogranite were recognized. The first is exemplified by two of the larger intrusive bodies, the Snow Lake Peak and Castle Lake intrusions, which occur as sheet-like bodies near and at the structural base of metamorphosed Neoproterozoic and Cambrian Prospect Mountain Quartzite where it is inverted above Cambrian and Ordovician marble of Verdi Peak in the Lamoille Canyon nappe. Swarms of dikes are associated with these intrusions. U-Pb (zircon) ages range ca. 40–33 Ma and typically display relatively simple and minor inheritance. The rocks have the lowest ε Hf (zircon) and ε Nd (whole rock) of any of the middle Cenozoic granites. The second type of monzogranite, Overlook type, typically occurs as thin, isolated dikes and leucosome-like bodies in Late Cretaceous granites of the infrastructure, with no obvious relationship to the large monzogranite bodies. Overlook-type monzogranite displays complex zircon inheritance, yields igneous ages ca. 37–32 Ma, and has ε Hf (zircon) and ε Nd (whole rock) identical to those of Late Cretaceous granites in the core complex. These isotopic and field data indicate that Overlook-type monzogranite formed in situ through anatexis of host Cretaceous granites. A pervasive thermal event was required to stimulate this crustal melting.

Nevada↗

USGS2024

Heterogeneous multi-stage accretionary orogenesis — Evidence from the Gunnison block in the Yavapai Province, southwest USA

Proterozoic rocks exposed in the southwestern U.S.A. represent one of the best examples of crustal growth by arc-related magmatism and accretionary orogenesis. Within the Southwest the 1.8–1.7 Ga Yavapai Province is widely regarded as a classic example of juvenile arc crust, however 1.8–2.5 Ga inherited zircon and Nd and Hf model ages have been recognized near Gunnison in central Colorado. These data have led to questions regarding the extent and nature of pre-1.8 Ga crustal material and the genesis of the Yavapai Province. We present evidence for a geochemically distinct, spatially restricted crustal block underlain by pre-1.8 Ga crust material (referred to here as the Gunnison block) in central to western Colorado within the Yavapai Province. The Gunnison block is characterized by 1.8–1.9 and 2.4–2.6 Ga inherited zircon, Pb isotopic systematics (μ = 9.8 ± 0.1, κ = 3.7 ± 0.1) elevated relative to 1.8 Ga depleted mantle values, 1.8–2.5 Ga Nd and Hf model ages, and a distinct pressure-temperature-time history. The geochemical data are consistent with mixing between juvenile 1.8 Ga and pre-1.8 Ga sources. The older crustal component is most similar to the isotopically enriched Mojave Province of eastern California and western Arizona, suggesting greater similarities between these provinces than previously recognized. Monazite and xenotime petrochronology indicate ca. 1.75–1.74, 1.72–1.69, 1.67, and 1.47–1.38 Ga tectono-metamorphic events. These data suggest that the Gunnison block accreted to other components of the Yavapai Province outboard of Laurentia at 1.75–1.74 Ga. The composite Yavapai Province was accreted to the margin of Laurentia during the 1.72–1.69 Ga Yavapai orogeny. Later overprinting is associated with the ∼1.68–1.60 Ga Mazatzal and ∼1.47–1.37 Ga Picuris orogenies. Identification of distinct crustal terranes within the Yavapai Province supports models involving multiple arcs and back-arcs that were progressively assembled prior to their accretion to Laurentia, perhaps akin to the present-day Banda Sea in Indonesia.

Yavapai Province↗

USGS2023

Geochemical evidence for evolving Proterozoic crustal thickness and orogenic styles in southwestern Laurentia

It has long been challenging for researchers to track the crustal thickness and mode(s) of crustal modification in ancient convergent margins, limiting evaluation of the tectonic styles and processes that modify continental crust during orogenesis. We present trace element igneous geochemical crustal thickness proxies that quantitatively track the crustal thickness evolution of the long-lived Proterozoic active margin in the southwestern U.S.A. We integrate these results with geobarometric data to constrain the mode of crustal modification. The data indicate a complex record of crustal thickness change in space and time and evolving orogenic styles. Geochemical proxies at 1.84–1.72 Ga are consistent with 20–40 km thick magmatic arcs that were locally thickened to ∼50 km during ∼1.75 Ga tectonism. During the Yavapai orogeny, 1.72–1.69 Ga, a ∼200-km-wide belt of 50-60 km thick crust extended from southern California to northern Colorado and was rapidly thinned and exhumed by ∼1.68 Ga. Crustal thickening and thinning during the Yavapai orogeny largely occurred by shortening and exhumation, respectively, in the upper 25 km of the crust. Subsequent 1.68–1.60 Ga tectonism involved crustal growth, local crustal thickening, and low-P, high-T metamorphism, consistent with extensional accretionary orogenesis. The 1.47–1.37 Ga Picuris orogeny was associated with 50–60 km thick crust across much of the Southwest and involved crustal shortening with ∼10 km of magmatic underplating. Advective heat from the emplacement of ferroan granites in the mid-crust likely contributed to elevated geothermal gradients and rheologically weakened the crust. Our results suggest evolving orogenic styles in the Southwest from 1.75–1.69 Ga short-lived crustal thickening associated with terrane accretion to 1.69–1.60 Ga largely extensional accretionary orogenesis, and regional, long-lived crustal thickening at 1.47–1.37 Ga involving extensive basaltic underplating. Contrasting with some recent hypotheses, our data document a complex middle Proterozoic record for the Southwest that was not orogenically quiescent or tectonically stagnant but involved complex mountain building styles.

Earth and Planetary Science Letters↗

USGS2022

40Ar/39Ar geochronology of magmatic-steam alunite from Alunite Ridge and Deer Trail Mountain, Marysvale Volcanic Field, Utah: Timing and duration of miocene hydrothermal activity associated with concealed intrusions

Porphyry and epithermal deposits are important sources of base and precious metals. Most actively mined deposits have been exhumed such that ore bodies are relatively close to the surface and are therefore locatable and economic to extract. Identifying and characterizing concealed deposits, particularly more deeply buried porphyry deposits, represents a far greater challenge for mineral exploration, and will become progressively more important as near-surface resources are gradually exhausted over time. We report high-precision 40 Ar/ 39 Ar dates for coarsely crystalline alunite that precipitated from magmatic steam in open fractures in Oligocene dacitic volcanic rocks, and a SHRIMP 206 Pb/ 238 U zircon date for one of several rhyolite dikes present at Alunite Ridge and Deer Trail Mountain, Utah. Both the magmatic-steam alunite and rhyolite dikes are related to concealed intrusions. The rhyolite dike yielded an age of 30.72 ± 0.36 Ma, which is older than a commonly cited 27.1 Ma age estimate for the Three Creeks Tuff Member of the Bullion Canyon Volcanics that is cut by the dike. 40 Ar/ 39 Ar data for samples of magmatic-steam alunite and sericite from six mines and prospects provide evidence for at least two periods of episodic hydrothermal activity at ca. 15.7–15.1 Ma and ca. 14.7–13.8 Ma, with the older and younger pulses of activity recorded at the more eastern and western sites, respectively. These two periods of hydrothermal activity are consistent with previous interpretations that Alunite Ridge and Deer Trail Mountain are underlain by two concealed porphyry stocks. 40 Ar/ 39 Ar analyses of individual bands in a sample of massive, centimeter-scale banded vein alunite yield indistinguishable ages with a weighted mean of 13.98 ± 0.12 Ma, consistent with a short-lived (≲250 ka) magmatic event with episodic vapor discharge recurring on short timescales (≲36 ka). 40 Ar/ 39 Ar geochronology of magmatic-steam alunite is a valuable tool to constrain the timing and duration of magmatic hydrothermal activity associated with unexposed intrusions and potentially porphyry deposits, and therefore may be useful in exploration.

Utah↗

USGS2020

Age and mantle sources of Quaternary basalts associated with “leaky” transform faults of the migrating Anatolia-Arabia-Africa triple junction

The Anatolia (Eurasia), Arabia, and Africa tectonic plates intersect in southeast Turkey, near the Gulf of İskenderun, forming a tectonically active and unstable triple junction (the A 3 triple junction). The plate boundaries are marked by broad zones of major, dominantly left-lateral transform faults including the East Anatolian fault zone (the Anatolia-Arabia boundary) and the Dead Sea fault zone (the Arabia-Africa boundary). Quaternary basalts occur locally within these “leaky” transform fault zones (similar to those observed within oceanic transform faults), providing evidence that mantle melting, basalt genesis, and eruption are linked to crustal deformation and faulting that extends into the upper mantle. We investigated samples of alkaline basalt (including basanite) from the Toprakkale and Karasu volcanic fields within a broad zone of transtension associated with these plate-boundary faults near the İskenderun and Amik Basins, respectively. Toprakkale basalts and basanites have 40 Ar/ 39 Ar plateau ages ranging from 810 ± 60 ka to 46 ± 13 ka, and Karasu volcanic field basalts have 40 Ar/ 39 Ar plateau ages ranging from 2.63 ± 0.17 Ma to 52 ± 16 ka. Two basanite samples within the Toprakkale volcanic field have isotopic characteristics of a depleted mantle source, with 87 Sr/ 86 Sr of 0.703070 and 0.703136, 143 Nd/ 144 Nd of 0.512931 and 0.512893, 176 Hf/ 177 Hf of 0.283019 and 0.282995, 206 Pb/ 204 Pb of 19.087 and 19.155, and 208 Pb/ 204 Pb of 38.861 and 38.915. The 176 Hf/ 177 Hf ratios of Toprakkale basalts (0.282966–0.283019) are more radiogenic than Karasu basalts (0.282837–0.282965), with some overlap in 143 Nd/ 144 Nd ratios (0.512781–0.512866 vs. 0.512648–0.512806). Toprakkale 206 Pb/ 204 Pb ratios (19.025 ± 0.001) exhibit less variation than that observed for Karasu basalts (18.800–19.324), and 208 Pb/ 204 Pb values for Toprakkale basalts (38.978– 39.103) are slightly lower than values for Karasu basalts (39.100–39.219). Melting depths estimated for the basalts from both volcanic fields generally cluster between 60 and 70 km, whereas the basanites record melting depths of ~90 km. Depth estimates for the basalts largely correspond to the base of a thin lithosphere (~60 km) observed by seismic imaging. We interpret the combined radiogenic isotope data (Sr, Nd, Hf, Pb) from all alkaline basalts to reflect partial melting at the base of the lithospheric mantle. In contrast, seismic imaging indicates a much thicker (>100 km) lithosphere beneath southern Anatolia, a substantial part of which is likely subducted African lithosphere. This thicker lithosphere is adjacent to the surface locations of the basanites. Thus, the greater melting depths inferred for the basanites may include partial melt contributions either from the lithospheric mantle of the attached and subducting African (Cyprean) slab, or from partial melting of detached blocks that foundered due to convective removal of the Anatolian lithosphere and that subsequently melted at ~90 km depth within the asthenosphere. The Quaternary basalts studied here are restricted to a broad zone of transtension formed in response to the development of the A 3 triple junction, with an earliest erupted age of 2.63 Ma. This indicates that the triple junction was well established by this time. While the current position of the A 3 triple junction is near the Amik Basin, faults and topographic expressions indicate that inception of the triple junction began as early as 5 Ma in a position farther to the northeast of the erupted basalts. Therefore, the position of the A 3 triple junction appears to have migrated to the southwest since the beginning of the Pliocene as the Anatolia-Africa plate boundary has adjusted to extrusion (tectonic escape) of the Anatolia plate. Establishment of the triple junction over the past 5 m.y. was synchronous with rollback of the African slab beneath Anatolia and associated trench retreat, consistent with Pliocene uplift in Cyprus and with the current positions of plate boundaries. The A 3 triple junction is considered to be unstable and likely to continue migrating to the southwest for the foreseeable geologic future.

Geosphere↗

USGS2019

Petrographic, geochemical, and geochronologic data for cenozoic volcanic rocks of the Tonopah, Divide, and Goldfield Mining Districts, Nevada

The purpose of this report is to summarize geochemical, petrographic, and geochronologic data for samples, principally those of unmineralized Tertiary volcanic rocks, from the Tonopah, Divide, and Goldfield mining districts of west-central Nevada (fig. 1). Much of the data presented here for the Tonopah and Divide districts are for samples collected by Bonham and Garside (1979) during geologic mapping in and around those districts, whereas much of that for samples from the Goldfield district were obtained by Ashley (1974; 1979; 1990a). Additional data were derived from samples collected between 2012–2015, as part of the Mineral Resources Program funded project titled: “Magmatic-tectonic history and component sources of major precious metal deposits in the southern Walker Lane”. A small amount of additional geochemical data for samples from each of the districts were compiled from other sources. Individual sample collectors are identified by appropriate entries in the “Collector” field (appendix 1) and published sources of geochemical data are defined by entries in the “Chem_Src” data field (appendix 1).

California, Nevada↗

USGS2018

Geologic map of the Fort Collins 30'×60' quadrangle, Larimer and Jackson Counties, Colorado, and Albany and Laramie Counties, Wyoming

The rocks and landforms of the Fort Collins 30 ′ × 60 ′ 1:100,000-scale U.S. Geological Survey quadrangle reveals a particularly complete record of geologic history in the northern Front Range of Colorado. The Proterozoic basement rocks exposed in the core of the range preserve evidence of Paleoproterozoic marine sedimentation, volcanism, and regional soft-sediment deformation, followed by regional folding and gradational metamorphism. Mesoproterozoic time was marked by intrusion of the Berthoud Plutonic Suite into crust that was structurally neutral or moderately extending in an east-northeast direction. Evidence of the late Paleozoic Anasazi uplift (Ancestral Rocky Mountains uplift) within the quadrangle is recorded by removal of Permian and older sediments and deposition of proximal Pennsylvanian and Permian strata unconformably onto the exhumed Proterozoic basement rocks. The Phanerozoic sediments indicate a steady progression of fluvial, eolian, and lacustrine environments throughout most of the Mesozoic Era which was a time of relatively slow sediment accumulation. Early Cretaceous time was marked by incursion of the Cretaceous Western Interior Seaway, a shallow-water marine embayment that persisted throughout the latter part of the Mesozoic Era. Sedimentation rates increased significantly in the latter part of this period during down-warping related to distant crustal loading by thrusting along the western continental margin. With onset of the Laramide orogeny in latest Cretaceous time, mountain building resumed in this region. This deformation placed Proterozoic rock over Cretaceous and Paleocene strata along the western margin of the Front Range and Medicine Bow Mountains. Post-Laramide time was marked by a prolonged period of weathering, erosion, and planation of the basement-rock surface, extending perhaps into late Oligocene or early Miocene time. Erosion on the eastern slope of the Front Range in late Paleogene to early Neogene time produced a broad, rolling surface surrounding residual highlands and east-trending fluvial channels filled with coarse, boulder gravel. Significant global cooling during the Pliocene led to glaciation during the Quaternary. In the Rocky Mountain region, renewed uplift allowed erosion to accentuate the topographic relief across the high mountains of the map area and established the elevations necessary to trigger accumulation of persistent snow and ice. Mountain glaciers advanced and retreated during at least three glacial-interglacial cycles during the middle and late Pleistocene in this area. Erosion continues to this day on the High Plains east of the mountain front, and progressive incision of the drainage is recorded by at least five major gravel-clad terrace and pediment surfaces along the major fluvial channels that connect to the South Platte River system.

Colorado, Wyoming↗

USGS2018

Review of the geochemistry and metallogeny of approximately 1.4 Ga granitoid intrusions of the conterminous United States

The conterminous United States hosts numerous volumetrically significant and geographically dispersed granitoid intrusions that range in age from 1.50 to 1.32 billion years before present (Ga). Although previously referred to as A-type granites, most are better described as ferroan granites. These granitoid intrusions are distributed in the northern and central Rocky Mountains, the Southwest, the northern midcontinent, and a swath largely buried beneath Phanerozoic cover across the Great Plains and into the southern midcontinent. These intrusions, with ages that are bimodally distributed between about 1.455–1.405 Ga and 1.405–1.320 Ga, are dispersed nonsystematically with respect to age across their spatial extents. Globally, although A-type or ferroan granites are genetically associated with rare-metal deposits, most U.S. 1.4 Ga granitoid intrusions do not contain significant deposits. Exceptions are the light rare-earth element deposit at Mountain Pass, California, and the iron oxide-apatite and iron oxide-copper-gold deposits in southeast Missouri. Most of the U.S. 1.4 Ga granitoid intrusions are composed of hornblende ± biotite or biotite ± muscovite monzogranite, commonly with prominent alkali feldspar megacrysts; however, modal compositions vary widely. These intrusions include six of the eight commonly identified subtypes of ferroan granite: alkali-calcic and calc-alkalic peraluminous subtypes; alkalic, alkali-calcic, and calc-alkalic metaluminous subtypes; and the alkalic peralkaline subtype. The U.S. 1.4 Ga granitoid intrusions also include variants of these subtypes that have weakly magnesian compositions. Extreme large-ion lithophile element enrichments typical of ferroan granites elsewhere are absent among these intrusions. Chondrite-normalized rare-earth element patterns for these intrusions have modest negative slopes and moderately developed negative europium anomalies. Their radiogenic isotopic compositions are consistent with mixing involving primitive, mantle-derived components and evolved, crust-derived components. Each compositional subtype can be ascribed to a relatively unique petrogenetic history. The numerically dominant ferroan, peraluminous granites probably represent low-degree, relatively high-pressure partial melting of preexisting, crust-derived, intermediate-composition granitoids. The moderately numerous, weakly magnesian, peraluminous granites probably reflect similar partial melting but at a higher degree and in a lower pressure environment. In contrast, the ferroan but metaluminous granites may be the result of extensive differentiation of tholeiitic basalt. Finally, the peralkaline igneous rocks at Mountain Pass have compositions potentially derived by differentiation of alkali basalt. The varying alkalic character of each subtype probably reflects polybaric petrogenesis and the corresponding effect of diverse mineral stabilities on ultimate melt compositions. Mantle-derived mafic magma and variably assimilated partial melts of mainly juvenile Paleoproterozoic crustal components are required to generate the relatively low initial strontium (87Sr/86Sr) and distinctive neodymium isotope compositions characteristic of the U.S. 1.4 Ga granitoid intrusions. The characteristics of these intrusions are consistent with crustal melting in an extensional/decompressional, intracratonic setting that was triggered by mantle upwelling and emplacement of tholeiitic basaltic magma at or near the base of the crust. Composite magmas, formed by mingling and mixing mantle components with partial melts of Paleoproterozoic crust, produced variably homogenized storage reservoirs that continued polybaric evolution as intrusions lodged at various crustal depths.

Scientific Investigations Report↗

USGS2018

Combined radiogenic (87Sr/86Sr, 234U/238U) and stable (δ88Sr) isotope systematics as tracers of anthropogenic groundwater contamination within the Williston Basin USA

The Williston Basin has produced oil and gas from conventional structural and stratigraphic traps for more than 60 years. The advent of horizontal drilling and hydraulic fracturing of shale in the Devonian-Mississippian Bakken Formation has increased the production of oil in this basin from areas that partially overlap the prairie pothole region of North America. Massive scale of oil production in the Williston Basin increases the risk of accidental releases of coproduced formation water (brine) into the environment. The prairie pothole region is named for a multitude of small lakes and wetlands that provide critical habitat for waterfowl and other wildlife. The increased risks raise the importance of developing robust tracers that can identify the source(s) and quantity of contamination of this premier wetland ecosystem. Radiogenic 87 Sr/ 86 Sr and 234 U/ 238 U isotope tracers are widely used in hydrological studies to detect potential sources of groundwater contamination. Here, we used paired 87 Sr/ 86 Sr and δ 88 Sr values in wetland water, which is essentially shallow groundwater at the Goose Lake and Fuller sites in Montana and North Dakota where produced water contamination was previously established. We also analyzed brines from the Bakken Formation and Mississippian Charles Formation to evaluate potential sources of contamination. This is the first attempt to combine these isotope tracers to estimate a magnitude of groundwater contamination by the oil-field produced water. Moreover, because U +6 is soluble in water under subaerial oxidizing conditions and the U +4 content is orders of magnitude lower (pg/g levels) in reducing brines, the 234 U/ 238 U isotope tracer is insensitive to brine contamination. However, it elucidates potential variability of uncontaminated end-members and, therefore, helps to improve the accuracy of estimated degrees of brine contamination based on binary mixing relationships. In addition, U isotopes in groundwater have a potential for detecting some U-rich anthropogenic contaminants (e.g., phosphate fertilizers). Using these isotopic systematics we confirm previous conclusions that surface water and shallow groundwater in two studied sites are variably contaminated by produced water and estimate the degree of the contamination at ∼7% in a sample collected close to a brine tank and <0.5% in most other samples. The U isotope analyses in combination with the Sr isotope results help outline variable groundwater pathways and uncontaminated end-members. Also, U isotopes show no appreciable groundwater contamination from U-enriched P-fertilizers. Our study in the Williston Basin demonstrates the potential of using combined radiogenic ( 87 Sr/ 86 Sr, 234 U/ 238 U) and non-traditional stable (δ 88 Sr) isotopic systematics as tracers of anthropogenic contamination in surface and groundwater systems.

Montana, North Dakota↗

USGS2018

Chapter 5: Impact of sedimentary-exhalative hydrothermal systems on marine chemistry and mass extinctions: Applications for ore genesis research and mineral exploration

Times of metal-rich brine discharge into ancient ocean basins, associated with the formation of sedimentary-exhalative (sedex) Zn-Pb-Ba ore deposits, coincided with short-duration positive excursions (“spikes”) in the global marine Sr isotope record. While these spikes are unexplained by conventional oceanic models, chronostratigraphic correlations, combined with mass balance evidence and oceanographic modeling, suggest that the flux of radiogenic Sr from sedex brines during ore formation is sufficient to explain these previously enigmatic 87 Sr/ 86 Sr spikes. We review existing 87 Sr/ 86 Sr data and present new data as verification of these global 87 Sr/ 86 Sr spikes and their correlations with the formation of giant sedex ore deposits. Major events include an 1 ×10 −4 (~0.7078–~0.7079) excursion contemporaneous with formation of the Rammelsberg deposit at ~389 Ma; spikes on the order of 1 to 3 × 10 −4 , coeval with formation of the Meggen deposit at ~381 Ma, several ore deposits in the Macmillan Pass district at ~379 to 375 Ma, and the Silvermines deposits at ~352 Ma; and two >6 × 10 −4 spikes coincident with formation of the giant Navan deposit at ~346 Ma and Red Dog deposits at ~337 Ma. Moreover, the timing of peak 87 Sr/ 86 Sr spikes correlates with global δ 13 C and δ 18 O spikes, deposition of metal-rich black shales and ironstones, metal-induced malformation (teratology) of marine organisms, and mass extinctions. The relationships among these features were poorly understood, but our new model explains how the flux of key biolimiting nutrients and metals contained in sedex brines, demonstrably equivalent to or exceeding that of the total modern riverine flux to the ocean, spurred ocean eutrophication, which, ultimately, through a series of positive feedback mechanisms, may have triggered global chemical and biological events. If, as we hypothesize, sedex hydrothermal systems are recorded in the global marine isotopic, geologic, and biological records, our findings define a new approach to the study of and exploration for sedex deposits. We demonstrate that fluid inclusion solute chemistry and isotopic and stratigraphic studies of sedex deposits, coupled with chronostratigraphic correlation and high-resolution 87 Sr/ 86 Sr isotope chemostratigraphy, can be used to answer long-standing questions about geologic processes responsible for formation of these extraordinary deposits. This approach provides evidence for the age, duration, and fluxes of fluids and metals vented into the ocean by these giant hydrothermal systems. Accordingly, the marine 87 Sr/ 86 Sr curve constitutes a global exploration tool that could be applied to assess the mineral potential of sedimentary basins. To illustrate the potential of this tool to identify favorable stratigraphic ages and basins with potential for undiscovered giant sedex deposits, we highlight several spikes, on par with those characteristic of the Red Dog and Navan deposits, which have not been correlated with known metal deposits. Given these strong temporal correlations, mass balance estimates, and results of ocean chemistry modeling, our study suggests that further work is warranted to determine the extent to which periodic venting of hydrothermal basinal brines into the ocean has influenced the evolution of marine chemistry. Ultimately, these global signatures can be applied to the study of and exploration for sedex deposits.

Book chapter↗

USGS2017

Geologic map of the upper Arkansas River valley region, north-central Colorado

This 1:50,000-scale U.S. Geological Survey geologic map represents a compilation of the most recent geologic studies of the upper Arkansas River valley between Leadville and Salida, Colorado. The valley is structurally controlled by an extensional fault system that forms part of the prominent northern Rio Grande rift, an intra-continental region of crustal extension. This report also incorporates new detailed geologic mapping of previously poorly understood areas within the map area and reinterprets previously studied areas. The mapped region extends into the Proterozoic metamorphic and intrusive rocks in the Sawatch Range west of the valley and the Mosquito Range to the east. Paleozoic rocks are preserved along the crest of the Mosquito Range, but most of them have been eroded from the Sawatch Range. Numerous new isotopic ages better constrain the timing of both Proterozoic intrusive events, Late Cretaceous to early Tertiary intrusive events, and Eocene and Miocene volcanic episodes, including widespread ignimbrite eruptions. The uranium-lead ages document extensive about 1,440-million years (Ma) granitic plutonism mostly north of Buena Vista that produced batholiths that intruded an older suite of about 1,760-Ma metamorphic rocks and about 1,700-Ma plutonic rocks. As a result of extension during the Neogene and possibly latest Paleogene, the graben underlying the valley is filled with thick basin-fill deposits (Dry Union Formation and older sediments), which occupy two sub-basins separated by a bedrock high near the town of Granite. The Dry Union Formation has undergone deep erosion since the late Miocene or early Pliocene. During the Pleistocene, ongoing stream incision by the Arkansas River and its major tributaries has been interrupted by periodic aggradation. From Leadville south to Salida as many as seven mapped alluvial depositional units, that range in age from early to late Pleistocene, record periodic aggradational events along these streams that are commonly associated with deposition of glacial outwash or bouldery glacial-flood deposits. Many previously unrecognized Neogene and Quaternary faults, some of the latter with possible Holocene displacement, have been identified on lidar (light detection and ranging) imagery which covers 59 percent of the map area. This imagery has also permitted more accurate remapping of glacial, fluvial, and mass-movement deposits and aided in the determination of their relative ages. Recently published 10 beryllium cosmogenic surface-exposure ages, coupled with our new geologic mapping, have revealed the timing and rates of late Pleistocene deglaciation. Glacial dams that impounded the Arkansas River at Clear Creek and possibly at Pine Creek failed at least three times during the middle and late Pleistocene, resulting in catastrophic floods and deposition of enormous boulders and bouldery alluvium downstream; at least two failures occurred during the late Pleistocene during the Pinedale glaciation.

Colorado↗

USGS2017

U-Pb ages and geochemistry of zircon from Proterozoic plutons of the Sawatch and Mosquito ranges, Colorado, U.S.A.: Implications for crustal growth of the central Colorado province

A broad study of zircons from plutonic rocks of the Sawatch and Mosquito ranges of west-central Colorado (U.S.A.) was undertaken to significantly refine the magmatic chronology and chemistry of this under-studied region of the Colorado province. This region was chosen because it lies just to the north of the suspected arc-related Gunnison-Salida volcano-plutonic terrane, which has been the subject of many recent investigations—and whose origin is still debated. Our new results provide important insights into the processes active during Proterozoic crustal evolution in this region, and they have important ramifications for broader-scope crustal evolution models for southwestern North America. Twenty-four new U-Pb ages and sequentially acquired rare-earth element (REE), U, Th, and Hf contents of zircon have been determined using the sensitive high-resolution ion microprobe-reverse geometry (SHRIMP-RG). These zircon geochemistry data, in conjunction with whole-rock major- and trace-element data, provide important insights into zircon crystallization and melt fractionation, and they help to further constrain the tectonic environment of magma generation. Our detailed zircon and whole-rock data support the following three interpretations: (1) The Roosevelt Granite in the southern Sawatch Range was the oldest rock dated at 1,766 ± 7 Ma, and it intruded various metavolcanic and metasedimentary rocks. Geochemistry of both whole-rock and zircon supports the contention that this granite was produced in a magmatic arc environment and, therefore, is likely an extension of the older Dubois Greenstone Belt of the Gunnison Igneous Complex (GIC) and the Needle Mountains (1,770–1,755 Ma). Rocks of the younger Cochetopa succession of the GIC, the Salida Greenstone Belt, and the Sangre de Cristo Mountains (1,740–1,725 Ma) were not found in the Sawatch and Mosquito ranges. This observation strongly suggests that the northern edge of the Gunnison-Salida arc terrane underlies the southern portion of the Sawatch and Mosquito ranges. (2) Calc-alkalic to alkali-calcic magmas intruded this region approximately 55 m.y. after the Roosevelt Granite with emplacement of pre-deformational plutons at ca. 1,710 Ma (e.g., Henry Mountain Granite and diorite of Denny Creek), and this continued for at least 30 m.y., ending with emplacement of post-deformational plutons at ca. 1,680 Ma (e.g., Kroenke Granodiorite, granite of Fairview Peak, and syenite of Mount Yale). The timing of deformation can be constrained to sometime after intrusion of the diorite of Denny Creek and likely before the emplacement of the undeformed granite of Fairview Peak. Geochemistry of both whole-rock and zircon indicates that the older group of ca. 1,710-Ma plutons formed at shallower depths, and then they intruded the younger group of more deeply generated, commonly peraluminous and sodic plutons. Although absent in the Sawatch and Mosquito ranges, Mazatzal-age (ca. 1,680–1,620 Ma) plutonic rocks are present regionally. Inherited zircon components of Mazatzal-age were found as cores in some 1.4-Ga Sawatch and Mosquito Range zircons, indicating the likelihood of a relatively local source. These combined data suggest the possibility that all were produced within a continental-margin magmatic arc created as a result of southward-migrating (slab rollback?), north-dipping subduction to the south of the region. (3) Widespread Mesoproterozoic plutonism—with emplacement at various depths and exhibiting bimodal geochemistry—is recognized in 16 different samples. An older group of predominantly peraluminous, yet magnesian granitoids (e.g., granodiorite of Sayers, granite of Taylor River, and the St. Kevin Granite) were emplaced between ca. 1,450 and 1,425 Ma. These geochemical parameters suggest moderate degrees of partial melting in a low-pressure environment. Three younger metaluminous, but ferroan plutons (diorite of Grottos, diorite of Mount Elbert, and granodiorite of Mount Harvard), probably represent a final magmatic pulse at ca. 1,416 Ma. A comprehensive treatment of zircon REE and whole-rock trace-element behavior from Proterozoic rocks is scarce. Discriminant U/Yb versus Y diagrams using zircon data show that the Sawatch and Mosquito plutons are of continental origin, not oceanic. Additional bivariate diagrams incorporating cation ratio combinations of Gd, Ce, Yb, U, Th, Hf, and Eu offer refined insight into differences in fractionation trends and depth of magma generation for the various plutons. These interpretations, on the basis of zircon trace-element data, are mirrored in the whole-rock geochemistry data.

Colorado↗

USGS2015

Geochemical, modal, and geochronologic data for 1.4 Ga A-type granitoid intrusions of the conterminous United States

Introduction The purpose of this report is to present available geochemical, modal, and geochronologic data for approximately 1.4 billion year (Ga) A-type granitoid intrusions of the United States and to make those data available to ongoing petrogenetic investigations of these rocks. A-type granites, as originally defined by Loiselle and Wones (1979), are iron-enriched granitoids (synonymous with the ferroan granitoids of Frost and Frost, 2011) that occur in an anorogenic, within-continent setting. Relative to other granitic rocks, A-type granites have high FeO*/(FeO*+MgO), high K 2 O and K 2 O/Na 2 O, are metaluminous to weakly peraluminous, and are enriched in incompatible trace elements. Loiselle and Wones (1979) further suggested that A-type granites are relatively anhydrous. Anderson (1983) provides an early compilation of data for the products of 1.4 Ga magmatism in North America and notes the spatial and temporal association of a trio of rock types, which includes gabbro to anorthosite, intermediate composition mangerite, and granitic rapakivi rocks. In North America, the majority of known A-type intrusions were emplaced between 1.5 and 1.3 Ga and are predominantly of the granitic variety (Anderson, 1983). This report addresses the broadly Mesoproterozoic-age granitic rocks of the conterminous United States. Constituents of this group of intrusive rocks were defined using a variety of spatial, compositional, and geochronologic metrics. Thomas and others (2012) provided an updated synthesis, largely based on new isotopic and geochronologic data (for example, Fisher and others, 2010), for the large-scale geologic and tectonic evolution of the eastern United States. Their findings suggest that the basement rocks of the central and southern Appalachian region are allochthonous relative to the remainder of Laurentia and were accreted along the Grenville front between 1.25 and 1.0 Ga. Accordingly, Mesoproterozoic rocks east of the Grenville front and south of the approximate latitude of New York City do not represent North American magmatism. Consequently, geochemical, modal, and geochronologic data for these rocks are not included in the compilation described herein. Further, the structural styles and compositions of granitoid rocks east of the Grenville front, mostly highly deformed gneissic rocks, are dissimilar to those characteristic of the A-type granitoid rocks described herein. A variety of compositional and age information further characterizes the 1.4 Ga A-type granitoid rocks in the conterminous United States. Most samples included in this compilation have felsic compositions, although some extend to intermediate compositions. SiO2 contents range from 56 to almost 78 weight percent, and median and mean SiO2 contents are 72.0 and 71.1 weight percent, respectively. The majority of these rocks for which modal data are available are composed of monzogranite (Streckeisen, 1976), although the dataset also contains many samples composed of granodiorite and syenogranite. A smaller group of the granitoid rocks in this dataset are composed of quartz monzodiorite and quartz monzonite, and a very small subset of samples is composed of alkali-feldspar granite, tonalite, alkali-feldspar quartz syenite, and quartz syenite (fig. 1). Many of the 1.4 Ga granitoid rocks are further characterized by medium- to coarse-grain size and are also conspicuously porphyritic; alkali feldspar phenocrysts or megacrysts (2–10 cm), often with rapakivi overgrowths, are a common feature of many of these rocks (Anderson, 1983; Anderson and Bender, 1989; Anderson and Cullers, 1978; Condie and Budding, 1979). The age of A-type magmatism in North America ranges from about 1.8 to 1.0 Ga, although Anderson (1983) suggests that more than 70 percent (by volume) of A-type magmatism in this region occurred between 1.49 and 1.41 Ga. In the conterminous United States, ages of A-type granitoid rocks are restricted to the period between about 1.49 and 1.33 Ga (Anderson, 1983; Bauer and Pollock, 1993; Bickford and Mose, 1975; Bickford, Harrower, and others, 1981; Bickford and others, 1989; Dewane and Van Schmus, 2007; Hoppe and others, 1983; Peterman and Hedge, 1968; Van Schmus and Bickford, 1981; Van Schmus and others, 1975). Using these recognition criteria, we identified A-type granitoid intrusions of the conterminous United States; for those intrusions, we compiled available geochemical, modal, isotopic (Sr and Nd) and geochronologic data for inclusion in the databases described herein. The significance of 1.4 Ga granitoid rocks relative to the geologic evolution of the conterminous United States remains unclear, despite Anderson’s (1983) compilation and synthesis of compositional data pertinent to these rocks. The large-volume magmatic events indicated by these rocks, as well as their broad geographic distribution, tectonic significance, and association with mineral deposits, underscore their importance. The broad distribution of these rocks, from the northern mid-continent to the southwestern United States (in New Mexico, Arizona, California, and southernmost Nevada), throughout the Rocky Mountains in New Mexico and Colorado (and sporadically in southern Wyoming and central Idaho), and beneath much of the Plains region (as indicated by drilling), has led to the large-scale tectonic and magmatic processes responsible for genesis of the associated magmas being actively studied. In addition, Kisvarsanyi (1972) suggests that iron-copper deposits in the St. Francois Mountains of southeastern Missouri are petrogenetically associated with 1.4 Ga A-type granitoids that occur in that region. Similarly, Dall’Agnol and others (2012) summarize important global associations between A-type granitoid rocks and a variety of important ore deposit types, particularly tin, high-field-strength elements (Zr, Hf, Nb, Ta), rare-earth elements, and iron oxide-copper-gold deposits. Consequently, the need to better understand relations between A-type granitoid rocks, tectonic setting, and magma petrogenesis, as well as their genetic associations with important types of ore deposits, suggests that developing a definitive geochemical, modal, and geochronologic database for these rocks in the conterminous United States is of considerable value.

Data Series↗

USGS2014

40Ar/39Ar Geochronology, Isotope Geochemistry (Sr, Nd, Pb), and petrology of alkaline lavas near Yampa, Colorado: migration of alkaline volcanism and evolution of the northern Rio Grande rift

Volcanic rocks near Yampa, Colorado (USA), represent one of several small late Miocene to Quaternary alkaline volcanic fields along the northeast margin of the Colorado Plateau. Basanite, trachybasalt, and basalt collected from six sites within the Yampa volcanic field were investigated to assess correlations with late Cenozoic extension and Rio Grande rifting. In this paper we report major and trace element rock and mineral compositions and Ar, Sr, Nd, and Pb isotope data for these volcanic rocks. High-precision 40Ar/39Ar geochronology indicates westward migration of volcanism within the Yampa volcanic field between 6 and 4.5 Ma, and the Sr, Nd, and Pb isotope values are consistent with a primary source in the Proterozoic subcontinental lithospheric mantle. Relict olivine phenocrysts have Mg- and Ni-rich cores, whereas unmelted clinopyroxene cores are Na and Si enriched with finely banded Ca-, Mg-, Al-, and Ti-enriched rims, thus tracing their crystallization history from a lithospheric mantle source region to one in contact with melt prior to eruption. A regional synthesis of Neogene and younger volcanism within the Rio Grande rift corridor, from northern New Mexico to southern Wyoming, supports a systematic overall southwest migration of alkaline volcanism. We interpret this Neogene to Quaternary migration of volcanism toward the northeast margin of the Colorado Plateau to record passage of melt through subvertical zones within the lithosphere weakened by late Cenozoic extension. If the locus of Quaternary alkaline magmatism defines the current location of the Rio Grande rift, it includes the Leucite Hills, Wyoming. We suggest that alkaline volcanism in the incipient northern Rio Grande rift, north of Leadville, Colorado, represents melting of the subcontinental lithospheric mantle in response to transient infiltration of asthenospheric mantle into deep, subvertical zones of dilational crustal weakness developed during late Cenozoic extension that have been migrating toward, and subparallel to, the northeast margin of the Colorado Plateau since the middle Miocene. Quaternary volcanism within this northern Rio Grande rift corridor is evidence that the rift is continuing to evolve.

Colorado↗

USGS2014

Precise determination of δ 88 Sr in rocks, minerals, and waters by double-spike TIMS: A powerful tool in the study of chemical, geologic, hydrologic and biologic processes

We present strontium isotopic ( 88 Sr/ 86 Sr and 87 Sr/ 86 Sr) results obtained by 87 Sr– 84 Sr double spike thermal ionization mass-spectrometry (DS-TIMS) for several standards as well as natural water samples and mineral samples of abiogenic and biogenic origin. The detailed data reduction algorithm and a user-friendly Sr-specific stand-alone computer program used for the spike calibration and the data reduction are also presented. Accuracy and precision of our δ 88 Sr measurements, calculated as permil (‰) deviations from the NIST SRM-987 standard, were evaluated by analyzing the NASS-6 seawater standard, which yielded δ 88 Sr = 0.378 ± 0.009‰. The first DS-TIMS data for the NIST SRM-607 potassium feldspar standard and for several US Geological Survey carbonate, phosphate, and silicate standards (EN-1, MAPS-4, MAPS-5, G-3, BCR-2, and BHVO-2) are also reported. Data obtained during this work for Sr-bearing solids and natural waters show a range of δ 88 Sr values of about 2.4‰, the widest observed so far in terrestrial materials. This range is easily resolvable analytically because the demonstrated external error (±SD, standard deviation) for measured δ 88 Sr values is typically ≤0.02‰. It is shown that the “true” 87 Sr/ 86 Sr value obtained by the DS-TIMS or any other external normalization method combines radiogenic and mass-dependent mass-fractionation effects, which cannot be separated. Therefore, the “true” 87 Sr/ 86 Sr and the δ 87 Sr parameter derived from it are not useful isotope tracers. Data presented in this paper for a wide range of naturally occurring sample types demonstrate the potential of the δ 88 Sr isotope tracer in combination with the traditional radiogenic 87 Sr/ 86 Sr tracer for studying a variety of biological, hydrological, and geological processes.

Journal of Analytical Atomic Spectrometry↗

USGS2014

Age and isotopic systematics of Cretaceous borehole and surface samples from the greater Los Angeles Basin region: Implications for the types of crust that might underlie Los Angeles and their distribution along late Cenozoic fault systems

Nine U-Pb zircon ages were determined on plutonic rocks sampled from surface outcrops and rock chips of drill core from boreholes within the greater Los Angeles Basin region. In addition, lead-strontium-neodymium (Pb-Sr-Nd) whole-rock isotopic data were obtained for eight of these samples. These results help to characterize the crystalline basement rocks hidden in the subsurface and provide information that bears on the tectonic history of the myriad of fault systems that have dissected the Los Angeles region over the past 15 m.y. Seven of the nine samples have U-Pb ages ranging from 115 to 103 Ma and whole-rock Pb-Sr-Nd isotopic characteristics that indicate the crystalline basement underneath the greater Los Angeles Basin region is mostly part of the Peninsular Ranges batholith. Furthermore, these data are interpreted as evidence for (1) the juxtaposition of mid-Cretaceous, northern Peninsular Ranges batholith plutonic rocks against Late Cretaceous plutonic rocks of the Transverse Ranges in the San Fernando Valley, probably along the Verdugo fault; (2) the juxtaposition of older northwestern Peninsular Ranges batholith rocks against younger northeastern Peninsular Ranges batholith rocks in the northern Puente Hills, implying transposition of northeastern Peninsular Ranges batholith rocks to the west along unrecognized faults beneath the Chino Basin; and (3) juxtaposition of northern Peninsular Ranges batholith plutonic rocks against Late Cretaceous plutonic rocks of the Transverse Ranges along the San Jose fault in the northern San Jose Hills at Ganesha Park. These mainly left-lateral strike-slip faults of the eastern part of the greater Los Angeles Basin region could be the result of block rotation within the adjacent orthogonal, right-lateral, Elsinore-Whittier fault zone to the west and the subparallel San Jacinto fault zone to the east. The San Andreas fault system is the larger, subparallel, driving force further to the east.

Book chapter↗

USGS2014

U-Pb zircon geochronology of plutonism in the northern Peninsular Ranges batholith, southern California: Implications for the Late Cretaceous tectonic evolution of southern California

Utilizing both sensitive high-resolution ion microprobe (SHRIMP) and conventional isotope dilution–thermal ionization mass spectrometry (ID-TIMS) methods, crystallization and/or emplacement ages have been obtained for a suite of Cretaceous intermediate-composition plutonic samples collected along a roughly E-W–trending traverse through the northern Peninsular Ranges batholith. Previously noted petrologic, mineralogic, and textural differences delineated four major zonations from west to east and raised the need for detailed geochemical and isotopic work. U-Pb zircon geochronology establishes that these zonations are essentially temporally separate. Mean 206 Pb/ 238 U ages date the three older zones from west to east at 126–107 Ma, 107–98 Ma, and 98–91 Ma. Despite petrologic differences, a relatively smooth progression of magmatism is seen from west to east. A fourth zone is defined by magmatism at ca. 85 Ma, which represents emplacement of deeper-level plutons east of the Eastern Peninsular Ranges mylonite zone in an allochthonous thrust sheet in the northeastern Peninsular Ranges batholith. The age data presented here differ slightly from those presented in earlier work for similar rocks exposed across the middle and southern portions of the Peninsular Ranges batholith in that our data define a relatively smooth progression of magmatism from west to east, and that the transition from western-type to eastern-type plutonism is interpreted to have occurred at ca. 98 Ma and not at ca. 105 Ma. The progressive involvement of older crustal components in the enrichment of eastern Peninsular Ranges batholith–type magma sources is documented by the occurrence of Proterozoic zircon inheritance within samples of the eastern part of the batholith.

Book chapter↗