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Warren W. Wood

Publications and source records attributed to Warren W. Wood.

30 records · Page 2Linked to original sources

Concentration history during pumping from a leaky aquifer with stratified initial concentration

Analytical and numerical solutions are employed to examine the concentration history of a dissolved substance in water pumped from a leaky aquifer. Many aquifer systems are characterized by stratification, for example, a sandy layer overlain by a clay layer. To obtain information about separate hydrogeologic units, aquifer pumping tests are often conducted with a well penetrating only one of the layers. When the initial concentration distribution is also stratified (the concentration varies with elevation only), the concentration breakthrough in the pumped well may be interpreted to provide information on aquifer hydraulic and transport properties. To facilitate this interpretation, we present some simple analytical and numerical solutions for limiting cases and illustrate their application to a fractured bedrock/glacial drift aquifer system where the solute of interest is dissolved radon gas. In addition to qualitative information on water source, this method may yield estimates of effective porosity and saturated thickness (or fracture transport aperture) from a single-hole test. Little information about dispersivity is obtained because the measured concentration is not significantly affected by dispersion in the aquifer.

Conference Paper↗

Solute geochemistry of the Snake River plain regional aquifer system, Idaho and eastern Oregon

Four geochemical approaches were used to determine chemical reactions controlling solute concentrations in the Snake River Plain regional aquifer system: (1) calculation of a solute balance within the aquifer, (2) identification of weathered products in the aquifer frame- work, (3) comparison of thermodynamic mineral saturation indices with plausible solute reactions, and (4) comparison of stable-isotope ratios of the solutes with those in the aquifer framework. Solutes in the geo- thermal groundwater system underlying the main aquifer were examined by calculating thermodynamic mineral saturation indices, stable-isotope ratios, geothermometry, and radiocarbon dating. Water budgets, hydrologic arguments, and isotopic analyses for the eastern Snake River Plain aquifer system demonstrate that most, if not all, water is of local meteoric and not juvenile or formation origin. Thus, the solutes must also originate within the basin. Solute balance, isotopic, mineralogic, and thermodynamic arguments suggest that about 20 per- cent of the solutes leaving the basin are derived from reactions with rocks forming the aquifer framework. Most of the remaining solutes are introduced from tributary drainage basins. Mass-balance calculations, thermodynamic arguments, and petro- graphic observations indicate that calcite and silica are precipitated in the aquifer. Petrographic evidence and thermodynamic arguments sug- gest that olivine, pyroxene, plagioclase, pyrite, and anhydrite are being weathered from the aquifer framework. Large amounts of sodium, chloride, and sulfate, relative to their concentration in the igneous rock, are being removed from the aquifer. Release of fluids from inclusions in the igneous rocks and initial flushing of grain boundaries and pores of detrital marine sediments in interbeds are believed to be a major source of these solutes. Identification and quantification of reactions controlling solute concentrations in ground water in the eastern plain indicate that the aquifer is not a large mixing vessel that simply stores and transmits water and solutes but is undergoing diagenesis and is both a source and a sink for solutes. Evaluation of solute concentrations and stable-isotope ratios of hydrogen, oxygen, carbon, and sulfur along groundwater flowpaths that transect irrigated areas suggests that irrigation water may have altered solute concentrations and isotope ratios in the eastern Snake River Plain aquifer system. The changes, however, have been small because of the similarity of solute concentrations and ratios in applied irrigation water and in native ground water, and because of rapid movement and large dispersivity of the aquifer. Reactions controlling solutes in the western Snake River basin are believed to be similar to those in the eastern basin but, because of dif- ferent hydrologic conditions, a definitive analysis could not be made. The regional geothermal system that underlies the Snake River Plain contains total dissolved solids similar to those in the overlying Snake River Plain aquifer system but contains higher concentrations of sodium, bicarbonate, silica, fluoride, sulfate, chloride, arsenic, boron, and lithium, and lower concentrations of calcium, magnesium, and hydrogen. These solutes are believed to be derived from reactions similar to those in the Snake River Plain aquifer system, except that ion exchange and hydrol- ysis play a role in controlling solute concentrations in the geothermal system. Geothermometry calculations of selected ground-water samples from known geothermal areas throughout the basin suggest that the geother- mal system is large in areal extent but has relatively low temperatures. Approximately half of the silica-quartz calculated water temperatures are greater than 90 °C. Radiocarbon dating of geothermal water in the Salmon Falls and Bruneau-Grand View areas in the south central part of the Snake River basin suggests that residence time of the geother- mal water is about 17,700 years.

Idaho;Oregon↗

Solute geochemistry of the Snake River plain regional aquifer system, Idaho and eastern Oregon

Three geochemical methods were used to determine chemical reactions that control solute concentrations in the Snake River Plain regional aquifer system: (1) Calculation of a regional solute balance within the aquifer and of mineralogy in the aquifer framework to identify solute reactions, (2) comparison of thermodynamic mineral saturation indices with plausible solute reactions, and (3) comparison of stable-isotope ratios of the ground water with those in the aquifer framework. The geothermal ground-water system underlying the main aquifer system was examined by calculating thermodynamic mineral saturation indices, stable-isotope ratios of geothermal water, geothermometry, and radiocarbon dating. Water budgets, hydrologic arguments, and isotopic analyses for the eastern Snake River Plain aquifer system demonstrate that most, if not all, water is of local meteoric and not juvenile or formation origin. Solute-balance, isotopic, mineralogic, and thermodynamic arguments suggest that about 20 percent of the solutes are derived from reactions with rocks forming the aquifer framework. Solute reactions indicate that calcite and silica are precipitated in the aquifer. Mineralogic evidence and thermodynamic arguments suggest that olivine, pyroxene, pyrite, and anhydrite are being dissolved and plagioclase is being weathered. Large amounts of sodium and chloride, relative to their concentration in the igneous rock, are being removed from the aquifer. Release of fluids from inclusions in the igneous rocks, and initial flushing of grain boundaries and pores of detrital marine sediments in interbeds are believed to be the source of the sodium chloride. Identification and quantification of reactions controlling solute concentrations in ground water in the eastern plain indicate that the aquifer is not a large mixing vessel that simply stores and transmits water and solutes but is undergoing diagenesis and is both a source and sink for solutes. Evaluation of solute concentrations and stable-isotope ratios of hydrogen, oxygen, carbon, and sulfur along ground-water flowpaths that transect irrigated areas suggests that irrigation water may have altered solute concentrations and isotope ratios in the eastern Snake River Plain aquifer system. The changes, however, have been small, owing to similarity of solute concentrations in applied irrigation water and in native ground water and rapid movement and large dispersivity of the aquifer. Reactions controlling solutes in the western Snake River basin are believed to be similar to those in the eastern basin but, because of different hydrologic conditions, a definitive analysis could not be made. The regional geothermal system that underlies the Snake River Plain contains total dissolved solids similar to those in the overlying Snake River Plain aquifer system but contains higher concentrations of sodium, bicarbonate, silica, fluoride, sulfate, chloride, arsenic, boron, and lithium, and lower concentrations of calcium, magnesium, and hydrogen. These solutes are believed to be derived from reactions similar to those in the Snake River Plain aquifer system, except that ion exchange may be a significant mechanism controlling solute concentrations in the geothermal system. Geothermometry calculations of selected ground-water samples from known geothermal areas throughout the basin suggest that the geothermal system is large in areal extent but has relatively low temperatures. Approximately half of the silica-quartz calculated water temperatures are greater than 90 degrees Celsius. Radiocarbon dating of geothermal water in the Salmon Falls and Bruneau-Grand View areas in the south-central part of the Snake River basin suggests that residence time of the geothermal water is about 17,700 years.

Idaho, Oregon↗

Aqueous geochemistry and diagenesis in the eastern Snake River Plain aquifer system, Idaho

Water budget and isotopic analyses of water in the eastern Snake River Plain aquifer system confirm that most, if not all, of the water is local meteoric in origin. Solute mass-balance arguments suggest that ∼5 × 10 9 moles of calcite and 2.6 × 10 9 moles of silica are precipitated annually in the aquifer. Isotopic evaluations of calcite and petrographic observation of silica support the low-temperature origin of these deposits. Approximately 2.8 × 10 9 moles of chloride, 4.5 × 10 9 moles of sodium, 1.4 × 10 9 moles of sulfate, and 2 × 10 9 moles of magnesium are removed annually from the aquifer framework by solution. Proposed weathering reactions are shown to be consistent with mass balance, carbon isotopes, observed mineralogy, and chemical thermodynamics. Large quantities of sodium, chloride, and sulfate are being removed from the system relative to their abundances in the rock. Sedimentary interbeds, which are estimated to compose <10% of the aquifer volume, may yield as much as 20% of the solutes generated within the aquifer. Weathering rate of the aquifer framework of the eastern Snake River Plain is 14 (Mg/km 2 )/yr or less than half the average of the North American continent. This contrasts with the rate for the eastern Snake River basin, 34 (Mg/km 2 )/yr, which is almost identical to the average for the North American continent. Identification and quantification of reactions controlling solute concentrations in ground water in the eastern plain indicate that the aquifer is not an “inert bathtub” that simply stores and transmits water and solutes but is undergoing active diagenesis and is both a source and sink for solutes.

Idaho↗

Guidelines for collection and field analysis of ground-water samples for selected unstable constituents

The unstable nature of many chemical and physical constituents in ground water requires special collection procedures and field analysis immediately after collection. This report describes the techniques and equipment commonly used in the collection and field analysis of samples for pH, temperature, carbonate, bicarbonate, specific conductance, Eh, and dissolved oxygen.

Open-File Report↗

Guidelines for collection and field analysis of ground-water samples for selected unstable constituents

The unstable nature of many chemical and physical constituents in ground water requires special collection procedures and field analysis immediately after collection. This report describes the techniques and equipment commonly used m the collection and field analysis of samples for pH, temperature, carbonate, bicarbonate, specific conductance, Eh, and dissolved oxygen.

Techniques of Water-Resources Investigations↗

Artificial recharge through a well in fissured carbonate rock, west St. Paul, Minnesota

The Prairie du Chien Group was injected with 2,754,000 gallons (368,200 cubic feet), or 10,430 cubic metres, of municipally treated water at about 100 gallons per minute (13.4 cubic feet per minute), or 6.3 litres per second, for 20 days. The injection-pipe system was designed to utilize pipe friction rather than a remote-controlled valve in the well to maintain positive pressure and eliminate air entrainment in the injection water and the escape cf dissolved gasses from the water. During the 20-day injection period the temperature of the injection water declined gradually from 15.0 &deg; to 11.2 &deg; C, and the flow rate decreased from 108 to 90 gallons per minute (6.8 to 5.7 litres per second). Analyses of test data were, in some instances, based upon hydrologic judgement as well as observations. Results of aquifer tests before and after injections indicated that the transmissivity had decreased 18 percent during the intervening injection periods; however, the specific capacity remained the same, indicating no change in transmissivity during pumping. Analysis of water-level changes in observation wells during injection indicated a reduction in transmissivity of more than 50 percent; however, the specific capacity of the injection well decreased only about 5 percent during injection. A comparison of water-level changes with the discharge or recharge rates of the three tests showed that the water-level changes in the two observation wells tapping the Prairie du Chien Group during the injection test were greater than those projected from the two aouifer pumping tests. The deviations in the water-level changes and in the analysis of aquifer-test data indicate that the methods used to analyze data from these wells may not be wholly applicable, inasmuch as anisotropic and nonhomogeneous conditions prevail in at least the Prairie du Chien part of the aquifer. The native water and the injected water averaged 0.8 and 25 milligrams per litre chloride, respectively. The chloride, utilized as a tracer, showed that the injected water was detected only in the lower part of the nearest observation well, 99 feet (30.2 metres) from the injection well. The chemistry of the water and the rock formation showed little likelihood of plugging of the recharge well by chemical precipitation. Microbiological phenomena apparently did not become a significant factor in the recharge test. The hydraulic gradient of the aquifer in October and December 1971 (before and after injection) was estimated to be N. 36 &deg; E., 0.0013, and N. 39 &deg; E., 0.0012, respectively, on the basis of measurements of water levels in the three wells in the Prairie du Chien Group. The single-well tracer-dilution method of calculation showed a hydraulic gradient of 0.0016. A longitudinal dispersivity of 280 feet (85 metres) was calculated. Such a value of dispersivity is typical of fractured reservoirs and shows that the Prairie du Chien Group is a heterogeneous aquifer. The injection test demonstrated that it is hydrologically feasible to recharge the Prairie du Chien Group and the Jordan Sandstone artificially through wells completed in the Prairie du Chien Group. The fissures in the Prairie du Chien Group act as conduits through which water spreads. The water passes into the Jordan Sandstone from the Prairie du Chien over a larger area than it would if it were injected directly into the Jordan.

Minnesota↗

Water-supply development and management alternatives for Clinton, Eaton, and Ingham Counties, Michigan

The Tri-County region, consisting of Clinton, Eaton, and Ingham Counties, is an area of 1,697 square miles in Michigan's Lower Peninsula and has as its hub the Lansing metropolitan area. The land surface ranges in altitude from about 700 to about 1,000 feet. The region receives an average of about 31 inches of precipitation each year. The population is nearing 400,000 and by 1990 will be near 600,000. Average daily water use is slightly more than 30 million gallons today; by 1980 it will be about 50 million gallons, and by 1990 it will probably be about 70 million gallons. The Tri-County region is drained by seven river systems. The median annual 7 -day mean low flows of the principal streams in these systems were measured at the point farthest downstream within the region. These values, in cubic feet per second, are as follows: Grand River, 180; Maple River, 34; Looking Glass River, 28; Red Cedar River, 30; Portage Creek, 15; Battle Creek, 20; and Thornapple River, 24-a total of 331 cubic feet per second or about 220 million gallons per day. The areal variance in 7-day low-flow runoff ranges from 0 to 0.15 cubic foot per second per square mile. The principal source of ground water in the Tri-County region is a complex aquifer system composed of the Saginaw and Grand River Formations and some of the overlying glacial sediments. This aquifer yields between 300 and 700 gallons per minute to individual wells in much of the western half of Ingham County, in the eastern half of Clinton County, in a small area in southeastern Clinton County, and in northeastern Eaton County. In some parts of the region, the glacial sediments are favorable for development of moderate to large supplies of water. Minor aquifers in the region are the Bayport, Michigan, and Marshall Formations. Providing water supplies in the future requires complete and comprehensive water-management programs. Such management programs involve determining which of several alternative water-development systems is the best. Some of the chief factors and methods that must be considered when planning these systems are combined use of ground and surface water, artificial recharge, treatment of wastes, use of storage reservoirs, and importation of water from the Great Lakes.

Michigan↗

Rapid reaction rates between water and a calcareous clay as observed by specific-ion electrodes

Specific-ion electrodes were used to simultaneously determine the activity changes of calcium, hydrogen, sodium, fluoride, and divalent ions when 50 g of a natural, untreated material containing calcium-rich mixed-layer illite-montmorillonite clay, quartz sand, and calcium carbonate was added to 250 ml of natural Canadian River water containing 220 mg/1 Na. Calcium and magnesium were displaced from the clay by the sodium; the exchanged and dissolved noncarbonate calcium precipitated as calcium carbonate, and the magnesium remained in solution. Fluoride entered into both a rapid reaction and a long-term reaction, indicating solution from the material. The pH decreased rapidly. The reactions for all observed ions, other than fluoride, were faster than the response time of their respective electrodes and were complete in less than one minute. Rapid solution of material containing calcium, magnesium, sodium, and fluoride was also observed when a duplicate sample of the earth material was added to distilled water; pH also changed rapidly in this mixture. These results suggest that many important water-rock reactions can be considered nearly instantaneous for purposes of digital modeling of the geochemical changes during artificial recharge.

Journal of Research of the U.S. Geological Survey↗

Availability of water in Kalamazoo County, southwestern Michigan

Kalamazoo County comprises an area of 572 square miles in the southwestern part of Michigan. It includes parts of the Kalamazoo, St. Joseph, and Paw Paw River basins, which drain into Lake Michigan. The northern two-thirds of the county is drained by the Kalamazoo River and its tributaries. A small area in the western piart of the county is drained by the Paw Paw River, and the rest, by tributaries of the St. Joseph River. Glacial deposits, containing sand and gravel, form an upper aquifer and a lower aquifer underlying large parts of the county. Areas of high transmissibility and thick saturated deposits are sufficiently localized to be considered as separate ground-water reservoirs having limited areal extent and definite hydrologic boundaries. Ground-water runoff from the basins constitutes a large part of the streamflow. Hydrograph separation shows that ground-water runoff composed 65 and 73 percent of the discharge of Kalamazoo River at Comstock and 75 and 79 percent of the discharge of Portage River near Vicksburg in 1965 and 1966, respectively. Based on the hydrologic budgets for the same years, ground-water recharge was 9.1 and 9.0 inches in the Kalamazoo River basin and 12.2 and 11.6 inches in the St. Joseph River basin. Ground-water recharge in the Kalamazoo River basin extrapolated for the 34-year period 1933-66 ranged from 4 to 13 inches and averaged 9 inches. In the St. Joseph River basin average recharge was about 9 inches for the same period. There is a wide range in runoff in the county. Augusta Creek, Portage Creek near Kalamazoo, and Gourdneck Creek have the highest annual runoff and maintain high yields even during periods of deficient precipitation. Spring Brook also reflects large ground-water contributions to streamflow. Storage in these basins could provide additional water during low flows for municipal and industrial needs. The primary use of lakes in the county is for recreational and esthetic purposes. Maintaining lake levels is therefore of the utmost importance. Levels at Crooked and Eagle Lakes have been maintained by pumping from lower aquifers. Diversion of water from Gourdneck Creek to West and Austin Lakes has helped in maintaining levels. Several relatively undeveloped lakes could be utilized as reservoirs whose storage could be used to augment streamflow or for water supply. Water in streams is generally of good chemical quality; however, several streams, including the Kalamazoo River downstream from Kalamazoo, have been degraded by municipal and industrial waste disposal. Water in the lakes is generally of good chemical quality with the exception of Barton Lake, which has been degraded by waste disposal. There is sufficient surface water available in Kalamazoo County to meet requirements for development of large quantities of water. The total available supply (average discharge of a stream) is about 680 mgd (million gallons per day). The dependable supply (7-day Q 2 , or average 7-day low flow having a recurrence interval of 2 years) is about 303 mgd. By developing artificial recharge facilities, surface runoff during winter and spring could be utilized to recharge ground-water reservoirs. Surface-water withdrawal in 1966 was about 58 mgd, of which 33 mgd was withdrawn from the Kalamazoo River. The quantity of water now being withdrawn from the ground and surface sources is small compared to the total that may be obtained in the area through full utilization of these resources. Mathematical models were used to simulate hydrologic conditions in the ground-water reservoirs and to evaluate maximum drawdowns for periods of little or no recharge. The practical limits of development as determined for the ground-water reservoirs are estimated to be at the following average withdrawal rates: Kalamazoo, 39 .mgd; Schoolcraft, 17 mgd; Kalamazoo-Portage, 24 mgd; and several small reservoirs, 67 mgd. These total 147 mgd. Further development would require additional artificial recharge facilities. Average ground-water withdrawal in 1966 was about 54 mgd. The Kalamazoo River ground-water reservoir furnished about 28 mgd, the Kalamazoo-Portage ground-water reservoir, about 21 mgd, and the other reservoirs, about 5 mgd. Thus, further development without artificial recharge is estimated to be about 11 mgd in the Kalamazoo River reservoir, 17 mgd in the Schoolcraft reservoir, 62 mgd in the several small reservoirs, and only 3 mgd in the Kalamazoo-Portage reservoir. The ground water is generally of good chemical quality and is suitable for most uses; however, it is Usually very hard and may contain objectionable amounts of iron. Some deterioration of water quality- has .been observed in several areas because of seepage from stockpiles of industrial minerals. The presence of many inland lakes, streams having high ground-water runoff, and, in places, relatively undeveloped ground-water reservoirs provides -flexibility in water management.

Michigan↗

Chemical quality of Michigan streams

Concentrations of chemical constituents of Michigan streams exhibit regional patterns that are primarily a function of geology and evapotranspiration. However, in some areas waste disposal by municipal and industrial organizations has altered the natural distribution and concentrations of dissolved material. Concentration and areal distribution of chemical constitutents were found to change very little from high spring to low summer flow conditions.

Michigan↗