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W.E. Dean

Publications and source records attributed to W.E. Dean.

At least 37 records · Page 2Linked to original sources

Stable isotopes and sediments from Pickerel Lake, South Dakota, USA: A 12ky record of environmental changes

Sedimentological parameters and stable O- and C-isotopic composition of marl and ostracode calcite selected from a 17.7-m-long core from the 8-m-deep center of Pickerel Lake, northeastern South Dakota, provide one of the longest (ca. 12ky) paleoenvironmental records from the northern Great Plains. The late Glacial to early Holocene climate in the northern Great Plains was characterized by changes from cold and wet to cold and dry, and back to cold and wet conditions. These climatic changes were controlled by fluctuations in the positions of the Laurentide ice sheet and the extent of glacial Lake Agassiz. We speculate that the cold and dry phase may correspond to the Younger Dryas event. A salinity maximum was reached between 10.3 and 9.5 ka, after which Pickerel Lake shifted from a system controlled by atmospheric changes to a system controlled by groundwater seepage that might have been initiated by the final withdrawal of Glacial Lake Agassiz. A prairie lake was established at approximately 8.7 ka, and lasted until about 2.2 ka. During this mid-Holocene prairie period, drier conditions than today prevailed, interrupted by periods of increased moisture at about 8, 4, and 2.2 ka. Prairie conditions were more likely dry and cool rather than dry and warm. The last 2.2 ka are characterized by higher climatic variability with 400-yr aridity cycles including the Medieval Warm Period and the Little Ice Age. Although the signal of changing atmospheric circulation is overprinted by fluctuations in the positions of the ice sheet and glacial Lake Agassiz during the late Glacial-Holocene transition, a combination of strong zonal circulation and strong monsoons induced by the presence of the ice sheet and high insolation may have provided mechanisms for increased precipitation. Zonal flow introducing dry Pacific air became more important during the prairie period but seems to have been interrupted by short periods of stronger meridional circulation with intrusions of moist air from the Gulf of Mexico. More frequent switching between periods of zonal and meridional circulation seem to be responsible for increased climatic variability during the last 2.2 ka.

Journal of Paleolimnology

Pleistocene to Holocene contrasts in organic matter production and preservation on the California continental margin

Organic matter in sediments from cores collected from the upper continental slope (200–2700 m) off California and southern Oregon shows marked differences in concentration and marine character between the last glacial interval (ca. 24–10 ka) and either Holocene time or last interstadial (oxygen isotope stage 3, ca. 60–24 ka). In general, sediments deposited during Holocene time and stage 3 contain higher amounts of marine organic matter than those deposited during the last glacial interval, and this contrast is greatest in cores collected off southern California. The most profound differences in stage 3 sediments are between predominantly bioturbated sediments and occasional interbeds of laminated sediments. The sediments are from cores collected within the present oxygen minimum zone on the upper continental slope from as far north as the Oregon-California border to as far south as Point Conception. These upper Pleistocene laminated sediments contain more abundant hydrogen-rich (type II) marine algal organic matter than even surface sediments that have large amounts of nonrefractory organic matter. The stable carbon-isotopic composition of the organic matter does not change with time between bioturbated and laminated sediments, indicating that the greater abundance of type II organic matter in the laminated sediments is not due to a change in source but rather represents a greater degree of production and preservation of marine organic matter. The presence of abundant, well-preserved organic matter supports the theory that the oxygen minimum zone in the northeastern Pacific Ocean was more intense, and possibly anoxic, during late Pleistocene time as a result of increased coastal upwelling that enhanced algal productivity.

California

Magnitude and significance of carbon burial in lakes, reservoirs, and peatlands

Globally, lakes are currently accumulating organic carbon (OC) at an estimated annual rate of about 42 Tgṁyr −1 . Most of the OC in all but the most oligotrophic of these lakes is autochthonous, produced by primary production in the lakes. The sediments of reservoirs accumulate an additional 160 Tg annually, and peatlands contribute 96 Tg annually. These three carbon pools collectively cover less than 2% of the Earth's surface and constitute a carbon sink of about 300 Tgṁyr −1 . Although the oceans cover 71% of the Earth's surface, they accumulate OC at a rate of only about 100 Tgṁyr −1 .

Geology

History of water-column anoxia in the Black Sea indicated by pyrite framboid size distributions

A detailed study of size distributions of framboidal pyrite in Holocene Black Sea sediments establishes the timing of a change from deposition under an oxic water column to deposition under an anoxic and sulfidic water column. In the most recent carbonate-rich sediments (Unit I) and in the organic carbon-rich sapropel (Unit II), framboid size distributions are remarkably uniform (mean diameter = 5 μm); over 95% of the framboids in Unit I and Unit II are < 7 μm in diameter. These properties of framboidal pyrite are consistent with framboid nucleation and growth within an anoxic and sulfidic water column, followed by transport to the sediment-water interface, cessation of pyrite growth due to the exhaustion of reactive iron, and subsequent burial. In contrast, the organic carbon-poor sediments of lacustrine Unit III contain pyrite framboids that are generally much larger in size (mean diameter = 10 μm). In Unit III, over 95% of the framboids are < 25 μm in diameter, 40% of framboids are between 7 μm and 25 μm, and framboids up to 50 μm in diameter are present. This distribution of sizes suggests framboid nucleation and growth within anoxic sediment porewaters. These new data on size distributions of framboidal pyrite confirm that the development of water-column anoxia in the Black Sea coincided with the initiation of deposition of laminated Unit II sapropels.

Earth and Planetary Science Letters

Evidence for Milankovitch periodicities in Cenomanian-Turonian lithologic and geochemical cycles, western interior U.S.A.

The limestone/marlstone bedding couplets of the Bridge Creek Limestone Member, Cenomanian-Turonian Greenhorn Formation, were analyzed by applying spectral techniques to high-resolution lithologic and geochemical data from a core. The results suggest that the Bridge Creek contains a complex record of orbital cyclicity. The dominant signal appears to be obliquity, but signals corresponding to precession and eccentricity were also observed. The development of the bedding couplets is interpreted to have resulted from a combination of factors, including insolation-controlled changes in higher-latitude precipitation leading to dilution/redox cycles, and in lower-latitude evaporation, leading to changes in surface water conditions and productivity cycles in the calcareous plankton. The data interpreted to reflect redox cycles appear to be more strongly influenced by obliquity, and show a weak precessional signal. In contrast, trends in the carbonate record show the opposite response. The complex bedding pattern observed in the Bridge Creek Limestone is interpreted to result from the competing influences of different orbital cycles expressed through different pathways of the depositional system, and was also affected by changes in sedimentation rates related to relative sea level fluctuations, aperiodic dilution by volcanic ash, and changes in organic-matter production and redox conditions related to a global "oceanic anoxic event". These factors complicate cycle analysis in the lower part of the member but leave a relatively undisturbed record in the upper Bridge Creek Limestone.

Journal of Sedimentary Research

Regional aridity in North America during the middle Holocene

Increased aridity throughout the Great Plains and Rocky Mountain region during the middle Holo cene has been documented from pollen records, aeolian proxy variables in lake cores, and active sand dune migration. Varve calibration provided by a continuously varved record of the Holocene from a core from Elk Lake, northwestern Minnesota, shows that the influx of aeolian clastic material increased beginning about 8 ka and ended about 3.8 ka, with peak aeolian activity at about 6 ka. If aeolian influx to Elk Lake corresponds in time to aeolian influx in other lakes and to maximum dune activity in Minnesota dune fields, then the varve calibration in Elk Lake provides precise time calibration of periods of peak aeolian activity in Minnesota. Palaeowind studies from the Minnesota dune fields show that the dominant wind direction when the dunes were active was from the northwest, the same as the dominant wind direction in dune fields throughout the Great Plains and Rocky Mountains. If the mid-Holocene aeolian activity in Minnesota was driven by an increase in westerly zonal winds, then the varve calibration can be extended to more precisely determine the timing of activity of dunes over a much broader area. We suggest that an increase in the westerly zonal wind field might have a solar-geomagnetic cause.

Holocene

Geology and geochemistry of three sedimentary-rock-hosted disseminated gold deposits in Guizhou Province, People's Republic of China

Five sedimentary-rock-hosted disseminated gold deposits have been discovered since 1980 in southwestern Guizhou Province (PRC). Submicron-sized gold is disseminated in silty carbonate and carbonaceous shale host rocks of Permian and Triassic age. Arsenic, antimony, mercury, and thallium accompany the gold. Associated hydrothermal alteration resulted in decarbonatization of limestone, silicification, and argillization, and depletion of base metals, barium, and many other elements. Organic material occurs in most host rocks and ores. It was apparently devolatilized during a regional heating event that preceded hydrothermal activity, and thus was not mobilized during mineralization, and did not affect gold deposition. The geologic setting of the Guizhou deposits includes many features that are similar to those of sedimentary-rock-hosted deposits of the Great Basin, western United States. The heavy-element suite that accompanies gold is the same, but base metals are even scarcer in the Guizhou deposits than they are in U.S. deposits. The Guizhou deposits discovered to date are smaller than most U.S. deposits and have no known spatially associated igneous rocks.

Guizhou Province

Influence of Shimada Seamount on sediment composition in the eastern tropical North Pacific

Shimada Seamount is a large, young volcanic edifice in the east-central Pacific that is not associated with any active spreading center or known hot spot. The sediments on the abyssal plain surrounding Shimada Seamount consist of pelagic clay with ferromanganese micronodules and zeolites. The pelagic clay is mostly barren of microfossils except for a few occurrences of highly corroded specimens of Radiolaria and diatoms. Eolian terrigenous material is the dominant component of the pelagic clay to a depth of at least 8 m below sea floor, with minor contributions from volcanic debris and hydrothermal and hydrogenous sources. The average amount of basaltic debris is only 0.25%, but concentrations are as high as 10% in some samples. The average hydrothermal component (metalliferous sediment) is 8.8% with a maximum of about 13% at 7.5 m below sea floor in one core. The hydrogenous component, mostly as ferromanganese micronodules, averages 4.1% with a maximum of 5.6%. There is no calcareous biogenic debris and essentially no siliceous biogenic debris. In the past, a decrease in hydrothermal components through time may have been the result of a decrease in relative importance of hydrothermal influences, or an increase in the flux of terrigenous debris transported by the northeast trade winds. Because volcanic activity is still active on Shimada Seamount, or has been in the recent past, the observed increase in relative abundance of terrigenous components probably was the result of increased wind transport and not decreased hydrothermal activity. Shimada Seamount may be an important local source of metalliferous sediment in the eastern equatorial North Pacific, and may have been an even more important source in the past.

Geochimica et Cosmochimica Acta

Tulelake, California: The last 3 million years

The Tulelake basin, formed by east-west extension and faulting during the past several million years, contains at least 550 m of lacustrine sediment. Interdisciplinary studies of a 334 m-long cored section from the town of Tulelake, California, near the center of the basin, document a 3-m.y. record of environmental changes. The core consists of a thick sequence of diatomaceous clayey, silty, and marly lacustrine sediments interbedded with numerous tephra layers. Paleomagnetic study puts the base of the core at about 3.0 Ma. Twelve widespread silicic tephra units provide correlations with other areas and complement age control provided by magnetostratigraphy; mafic and silicic tephra units erupted from local sources are also common in the core. Widespread tephra units include the Llao Rock pumice (=Tsoyawata, 7 ka), the Trego Hot Springs Bed (23 ka), and the Rockland (0.40 Ma), Lava Creek (0.62 Ma), and Rio Dell (1.5 Ma) ash beds, as well as several ash beds also found at Summer Lake, Oregon, and an ash bed originally recognized in DSDP hole 173 in the northeastern Pacific. Several tephra layers found in the core also occur in lacustrine beds exposed around the margins of the basin and elsewhere in the ancestral lacustrine system. Diatoms are present throughout the section. Pollen is present in most of the section, but some barren zones are found in the interval between 50 and 140 m; the greatest change in behavior of the pollen record takes place just above the top of the Olduvai Normal-Polarity Subchronozone. Ostracodes are present only in high-carbonate (>10% CaCO 3 ) intervals. Evolutionary changes are found in the diatom and ostracode records. Bulk geochemical analyses show significant changes in elemental composition of the sediment through time.

California

Geochemical evidence for suppression of pelagic marine productivity at the Cretaceous/Tertiary boundary

The normal, biologically productive ocean is characterized by a gradient of the 13 C/ 12 C ratio from surface to deep waters. Here we present stable isotope data from planktonic and benthic micro-fossils across the Cretaceous/Tertiary boundary in the North pacific, which reveal a rapid and complete breakdown in this biologically mediated gradient. The fluxes of barium (a proxy for organic carbon) and CaCO 3 also decrease significantly at the time of the major marine plankton extinctions. The implied substantial reduction in oceanic primary productivity persisted for ∼ 0.5 Myr before the carbon isotope gradient was gradually re-established. In addition, the stable isotope and preservational data indicate that environmental change, including cooling, began at least 200 kyr before the Cretaceous/Tertiary boundary, and a peak warming of ∼ 3 °C occurred 600 kyr after the boundary event.

Nature

Lacustrine varve formation through time

Studies using sediment traps in lakes reveal that the seasonal flux of sediment regulates both the composition and timing of deposition of materials that reach the bottoms of lakes. If the bottom waters of a lake are partly or totally anoxic, the seasonally deposited materials are preserved as annual groupings of laminae (varves). Common components that form individual laminae consist of allochthonous clastic material derived from the drainage basin, precipitated carbonate minerals, diatom frustules, iron-rich and manganese-rich flocs, autochthonous organic detritus, and autochthonous and allochthonous materials resuspended from the bottom. The "style" of varving has changed over geologic time, reflecting changes in biologic evolution and types of materials available. Precipitated iron-rich laminations were common in the middle Precambrian. Graded sets of clastic organic laminations persisted through the Precambrian, prior to the evolution of bioturbating benthic organisms. Glaciolacustrine varves appear to have retained their distinctive character through time. Carbonate-rich varves occurred sporadically in the Precambrian and Phanerozoic. With the exception of diatoms, major components of modern lacustrine varves were present through the Paleozoic and Mesozoic, and yet varves are rare in strata of these ages, and may have accumulated in marine to brackish-water environments. Diatoms were introduced into lacustrine systems in Early Tertiary time and are common components of varves from then on. Diatom laminae, combined with a greater chance for geologic preservation of younger lake deposits, have increased the number of geologically young occurrences of varved sediments. However, seasonal associations of modern varve components, and the processes they represent, are present in ancient deposits and provide clues to the interpretation of ancient environments.

Palaeogeography, Palaeoclimatology, Palaeoecology

Geochemical and climatic effects of increased marine organic carbon burial at the Cenomanian/Turonian boundary

Perhaps the most significant event in the Cretaceous record of the carbon isotope composition of carbonate 1,2 , other than the 1–2.5 ‰ negative shift in the carbon isotope composition of calcareous plankton at the Cretaceous/Tertiary boundary 3 , is the rapid global positive excursion of ∼ 2 ‰ ( 13 C enrichment) which took place between ∼ 91.5 Myr and 90.3 Myr (late Cenomanian to earliest Turonian (C/T boundary event)) 1,4,5 . This excursion has been attributed to a change in the isotope composition of the marine total dissolved carbon (TDC) reservoir resulting from an increase in rate of burial of 13 C-depleted organic carbon, which coincided with a major global rise in sea level 5 during the so-called C/T oceanic anoxic event (OAE) 6 . Here we present new data, from nine localities, which demonstrate that a positive excursion in the carbon isotope composition of organic carbon at or near the C/T boundary 7,8 is nearly synchronous with that for carbonate and is widespread throughout the Tethys and Atlantic basins (Fig. 1), as well as in more high-latitude epicontinental seas. The postulated increase in the rate of burial of organic carbon may have had a significant effect on CO 2 and O 2 concentrations in the oceans and atmosphere, and consequent effects on global climate and sedimentary facies.

Nature

15N/14N variations in Cretaceous Atlantic sedimentary sequences: Implication for past changes in marine nitrogen biogeochemistry

At two locations in the Atlantic Ocean (DSDP Sites 367 and 530) early to middle Cretaceous organic-carbon-rich beds (“black shales”) were found to have significantly lower δ 15 N values (lower 15 N/ 14 N ratios) than adjacent organic-carbon-poor beds (white limestones or green claystones). While these lithologies are of marine origin, the black strata in particular have ° 15 N values that are significantly lower than those previously found in the marine sediment record and most contemporary marine nitrogen pools. In contrast, black, organic-carbon-rich beds at a third site (DSDP Site 603) contain predominantly terrestrial organic matter and have C- and N-isotopic compositions similar to organic matter of modern terrestrial origin. The recurring 15 N depletion in the marine-derived Cretaceous sequences prove that the nitrogen they contain is the end result of an episodic and atypical biogeochemistry. Existing isotopic and other data indicate that the low 15 N relative abundance is the consequence of pelagic rather than post-depositional processes. Reduced ocean circulation, increased denitrification, and, hence, reduced euphotic zone nitrate availability may have led to Cretaceous phytoplankton assemblages that were periodically dominated by N 2 -fixing blue-green algae, a possible source of this sediment 15 N-depletion. Lack of parallel isotopic shifts in Cretaceous terrestrially-derived nitrogen (Site 603) argues that the above change in nitrogen cycling during this period did not extend beyond the marine environment.

Earth and Planetary Science Letters