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W. A. Duffield

Publications and source records attributed to W. A. Duffield.

At least 19 recordsLinked to original sources
USGS2012

Distribution of Quaternary rhyolite domes of the Coso Range, California: implications for extent of the geothermal anomaly.

38 separate domes and flows of phenocryst-poor, high-silica rhyolite of similar major element chemical composition were erupted over the past 1My from vents arranged in a crudely S-shaped array atop a granitic horst in the Coso Range, California. Most of the extrusions are probably less than about 0.3My old. The central part of the rhyolite field is characterized by high heat flow, low apparent resistivity, and substantial fumarolic activity indicative of an active geothermal system.

California↗
USGS2001

The San Francisco volcanic field, Arizona

Northern Arizona's San Francisco Volcanic Field, much of which lies within Coconino and Kaibab National Forests, is an area of young volcanoes along the southern margin of the Colorado Plateau. During its 6-million-year history, this field has produced more than 600 volcanoes. Their activity has created a topographically varied landscape with forests that extend from the Pi?on-Juniper up to the Bristlecone Pine life zones. The most prominent landmark is San Francisco Mountain, a stratovolcano that rises to 12,633 feet and serves as a scenic backdrop to the city of Flagstaff.

Fact Sheet↗
USGS1999

A geochemical reconnaissance of the Alid volcanic center and geothermal system, Danakil depression, Eritrea

Geological and geochemical studies indicate that a high-temperature geothermal system underlies the Alid volcanic center in the northern Danakil depression of Eritrea. Alid is a very late-Pleistocene structural dome formed by shallow intrusion of rhyolitic magma, some of which vented as lavas and pyroclastic flows. Fumaroles and boiling pools distributed widely over an area of ~10 km2 on the northern half of Alid suggest that an active hydrothermal system underlies much of that part of the mountain. Geothermometers indicate that the fumarolic gases are derived from a geothermal system with temperatures >225??C. The isotopic composition of condensed fumarolic steam is consistent with these temperatures and implies that the source water is derived primarily from either lowland meteoric waters or fossil Red Sea water, or both. Some gases vented from the system (CO2, H2S and He) are largely magmatic in origin. Permeability beneath the volcanic center may be high, given the amount of intrusion-related deformation and the active normal faulting within the Danakil depression.Geological and geochemical studies indicate that a high-temperature geothermal system underlies the Alid volcanic center in the northern Danakil depression of Eritrea. Alid is a very late-Pleistocene structural dome formed by shallow intrusion of rhyolitic magma, some of which vented as lavas and pyroclastic flows. Fumaroles and boiling pools distributed widely over an area of approx. 10 km2 on the northern half of Alid suggest that an active hydrothermal system underlies much of that part of the mountain. Geothermometers indicate that the fumarolic gases are derived from a geothermal system with temperatures >225??C. The isotopic composition of condensed fumarolic steam is consistent with these temperatures and implies that the source water is derived primarily from either lowland meteoric waters or fossil Red Sea water, or both. Some gases vented from the system (CO2, H2S and He) are largely magmatic in origin. Permeability beneath the volcanic center may be high, given the amount of intrusion-related deformation and the active normal faulting within the Danakil depression.

Geothermics↗
USGS1998

A model that helps explain Sr-isotope disequilibrium between feldspar phenocrysts and melt in large-volume silicic magma systems

Feldspar phenocrysts of silicic volcanic rocks are commonly in Sr-isotopic disequilibrium with groundmass. In some cases the feldspar is more radiogenic, and in others it is less radiogenic. Several explanations have been published previously, but none of these is able to accommodate both senses of disequilibrium. We present a model by which either more- or less-radiogenic feldspar (or even both within a single eruptive unit) can originate. The model requires a magma body open to interaction with biotite- and feldspar-bearing wall rock. Magma is incrementally contaminated as wall rock melts incongruently. Biotite preferentially melts first, followed by feldspar. Such melting behavior, which is supported by both field and experimental studies, first contaminates magma with a relatively radiogenic addition, followed by a less-radiogenic addition. Feldspar phenocrysts lag behind melt (groundmass of volcanic rock) in incorporating the influx of contaminant, thus resulting in Sr-isotopic disequilibrium between the crystals and melt. The sense of disequilibrium recorded in a volcanic rock depends on when eruption quenches the contamination process. This model is testable by isotopic fingerprinting of individual feldspar crystals. For a given set of geologic boundary conditions, specific core-to-rim Sr-isotopic profiles are expectable. Moreover, phenocrysts that nucleate at different times during the contamination process should record different and predictable parts of the history. Initial results of Sr-isotopic fingerprinting of sanidine phenocrysts from the Taylor Creek Rhyolite are consistent with the model. More tests of the model are desirable.Feldspar phenocrysts of silicic volcanic rocks are commonly in Sr-isotopic disequilibrium with groundmass. In some cases the feldspar is more radiogenic, and in others it is less radiogenic. Several explanations have been published previously, but none of these is able to accommodate both senses of disequilibrium. We present a model by which either more- or less-radiogenic feldspar (or even both within a single eruptive unit) can originate. The model requires a magma body open to interaction with biotite- and feldspar-bearing wall rock. Magma is incrementally contaminated as wall rock melts incongruently. Biotite preferentially melts first, followed by feldspar. Such melting behavior, which is supported by both field and experimental studies, first contaminates magma with a relatively radiogenic addition, followed by a less-radiogenic addition. Feldspar phenocrysts lag behind melt (groundmass of volcanic rock) in incorporating the influx of contaminant, thus resulting in Sr-isotopic disequilibrium between the crystals and melt. The sense of disequilibrium recorded in a volcanic rock depends on when eruption quenches the contamination process. This model is testable by isotopic fingerprinting of individual feldspar crystals. For a given set of geologic boundary conditions, specific core-to-rim Sr-isotopic profiles are expectable. Moreover, phenocrysts that nucleate at different times during the contamination process should record different and predictable parts of the history. Initial results of Sr-isotopic fingerprinting of sanidine phenocrysts from the Taylor Creek Rhyolite are consistent with the model. More tests of the model are desirable.

Journal of Volcanology and Geothermal Research↗
USGS1992

Compositional gradients in large reservoirs of silicic magma as evidenced by ignimbrites versus Taylor Creek Rhyolite lava domes

The Taylor Creek Rhyolite of southwest New Mexico consists of 20 lava domes and flows that were emplaced during a period of a few thousand years or less in late Oligocene time. Including genetically associated pyroclastic deposits, which are about as voluminous as the lava domes and flows, the Taylor Creek Rhyolite represents roughly 100 km3 of magma erupted from vents distributed throughout an area of several hundred square kilometers. Major-element composition is metaluminous to weakly peraluminous high-silica rhyolite and is nearly constant throughout the lava field. The magma reservoir for the Taylor Creek Rhyolite was vertically zoned in trace elements, 87Sr/86Sr, and phenocryst abundance and size. Mean trace-element concentrations, ranges in concentrations, and element-pair correlations are similar to many subalkaline silicic ignimbrites. However, the polarity of the zonation was opposite that in reservoirs for ignimbrites, for most constituents. For example, compared to the Bishop Tuff, only 87Sr/86Sr and Sc increased upward in both reservoirs. Quite likely, a dominant but nonerupted volume of the magma reservoir for the Taylor Creek Rhyolite was zoned like that for the Bishop Tuff, whereas an erupted, few-hundred-meter-thick cap on the magma body was variably contaminated by roof rocks whose contribution to this part of the magma system moderated relatively extreme trace-element concentrations of uncontaminated Taylor Creek Rhyolite but did not change the sense of correlation for most element pairs. The contaminant probably was a Precambrian rock of broadly granitic composition and with very high 87Sr/86Sr. Although examples apparently are not yet reported in the literature, evidence for a similar thin contaminated cap on reservoirs for large-volume silicic ignimbrites may exist in the bottom few meters of ignimbrites or perhaps only in the pumice fallout that normally immediately precedes ignimbrite emplacement. 87Sr/86Sr in sanidine phenocrysts of the Taylor Creek Rhyolite is higher than that of their host whole rocks. Covariation of this isotope ratio with sanidine abundance and size indicates positive correlations for all three features with decreasing distance to the roof of the magma reservoir. The sanidine probably is more radiogenic than host whole rock because growing phenocrysts partly incorporated Sr from the first partial melt of roof rocks, which contained the highly radiogenic Sr of Precambrian biotite ?? hornblende, whereas diffusion was too slow for sanidine to incorporate much of the Sr from subsequently produced less radiogenic partial melt of roof rocks, before eruption quenched the magma system. Disequilibrium between feldspar phenocrysts and host groundmass is fairly common for ignimbrites, and a process of contamination similar to that for the Taylor Creek Rhyolite may help explain some of these situations. ?? 1992 Springer-Verlag.

Contributions to Mineralogy and Petrology↗
USGS1992

Evidence for the reversal of gradients in the uppermost parts of silicic magma reservoirs

Evidence from large-volume ignimbrites indicates that the source-magma reservoirs for most of these voluminous silicic pyroclastic deposits contained monotonic vertical chemical gradients at the time of eruption. However, gradients from a large-volume magma reservoir that produced a group of penecontemporaneous silicic lava domes, but no ignimbrite, show a reversal of the usual ignimbrite pattern. This reversal originated by modification of the usual pattern through minor assimilation of partially melted roof rocks. Eruptions that produced these domes apparently just tapped the uppermost part of their source reservoir. They thereby provide a high-resolution instantaneous view of this variably contaminated part of the magma system. Although not yet reported in the literature, similar reversals should be recorded in other groups of penecontemporaneous silicic domes and perhaps also in the lowermost parts of ignimbrites or in their underlying coeruptive Plinian deposits. The long-standing paradigm for monotonic zoning in large-volume reservoirs of silicic magma may require modification.

Geology↗
USGS1990

The Taylor Creek Rhyolite of New Mexico: a rapidly emplaced field of lava domes and flows

The Tertiary Taylor Creek Rhyolite of southwest New Mexico comprises at least 20 lava domes and flows. Each of the lavas was erupted from its own vent, and the vents are distributed throughout a 20 km by 50 km area. The volume of the rhyolite and genetically associated pyroclastic deposits is at least 100 km3 (denserock equivalent). The rhyolite contains 15%-35% quartz, sanidine, plagioclase, ??biotite, ??hornblende phenocrysts. Quartz and sanidine account for about 98% of the phenocrysts and are present in roughly equal amounts. With rare exceptions, the groundmass consists of intergrowths of fine-grained silica and alkali feldspar. Whole-rock major-element composition varies little, and the rhyolite is metaluminous to weakly peraluminous; mean SiO2 content is about 77.5??0.3%. Similarly, major-element compositions of the two feldsparphenocryst species also are nearly constant. However, whole-rock concentrations of some trace-elements vary as much as several hundred percent. Initial radiometric age determinations, all K-Ar and fission track, suggest that the rhyolite lava field grew during a period of at least 2 m.y. Subsequent 40Ar/39Ar ages indicate that the period of growth was no more than 100 000 years. The time-space-composition relations thus suggest that the Taylor Creek Rhyolite was erupted from a single magma reservoir whose average width was at least 30 km, comparable in size to several penecontemporaneous nearby calderas. However, this rhyolite apparently is not related to a caldera structure. Possibly, the Taylor Creek Phyolite magma body never became sufficiently volatile rich to produce a large-volume pyroclastic eruption and associated caldera collapse, but instead leaked repeatedly to feed many relatively small domes and flows. The new 40Ar/39Ar ages do not resolve preexisting unknown relative-age relations among the domes and flows of the lava field. Nonetheless, the indicated geologically brief period during which Taylor Creek Rhyolite magma was erupted imposes useful constraints for future evaluation of possible models for petrogenesis and the origin of trace-element characteristics of the system. ?? 1990 Springer-Verlag.

Bulletin of Volcanology↗
USGS1990

Temperature, size, and depth of the magma reservoir for the Taylor Creek Rhyolite, New Mexico

The 55 km3 mid-Tertiary Taylor Creek Rhyolite in southwestern New Mexico consists of 20 lava domes and flows. This rhyolite is metaluminous to weakly peraluminous. Compositional zonation in feldspar phenocrysts is very minor and nonsystematic. The compositions of each feldspar species vary little throughout the suite of analyzed samples. This chemical homogeneity of phenocrysts reflects similar whole-rock homogeneity and suggests that the lavas were tapped from a single large reservoir of magma. Ages of sanidine phenocrysts determined using 40Ar/39Ar indicate that the Taylor Creek Rhyolite lavas were emplaced during a period of less than 0.42 my. and possibly less than 0.13 m.y., which is consistent with the single-reservoir scenario. Two-feldspar geothermometry suggests that Taylor Creek Rhyolite phenocrysts crystallized at about 775??C, at an assumed pressure of 2 kbar. Fe-Ti-oxide geothermometry suggests phenocryst growth at about 800??C. Experimental studies suggest that quartz and potassium-feldspar crystals that grow from H2O-undersaturated granitic magmas should exhibit resorption texture, a texture ubiquitous to Taylor Creek Rhyolite quartz and sanidine phenocrysts. We tentatively conclude that the Taylor Creek Rhyolite magma was H2O undersaturated and subliquidus at an unspecified pressure greater than 0.5 kbar during phenocryst growth and that Taylor Creek Rhyolite pyroclastic deposits formed because volatile saturation developed during the ascent of magma to sites of eruption. -from Authors

American Mineralogist↗
USGS1988

KAr ages, chemical composition and geothermal significance of cenozoic basalt near the Jordan rift

Late Cenozoic mafic lavas crop out locally along the Jordan rift. Some of these lavas are spatially associated with thermal springs, and this association has prompted some workers to hypothesize that the hot water derives its thermal energy from the shallow, still hot intrusive roots of the volcanic rocks. However, all of the volcanic rocks appear to represent mantle-derived mafic magma that rose rather quickly to the Earth's surface, without filling crustal reservoirs within which differentiation would have produced evolved, derivative products. Moreover, the lavas are too old and of too small a volume to represent the surface expression of an active reservoir of magma within the crust. These interpretations of the volcanic geology are consistent with conclusions drawn from the chemistry of the thermal water; the water has equilibrated with host rocks at no more than 110°C, probably at depths of 2–3 km. Thus, thermal springs along the Jordan rift appear to reflect heating during circulation through a regional regime of average crustal heat flow (Galanis et at. , 1986). The magmatic activity may only be a second or third order contributor to this heat flow.

Geothermics↗
USGS1987

Petrologic characteristics of the 1982 and pre-1982 eruptive products of El Chichon volcano, Chiapas, Mexico

Studies on a suite of rocks from this volcano indicate that the juvenile materials of the 1982 and pre-1982 eruptions of the volcano have essentially the same mineralogy and chemistry. Data suggest that chemical composition changed little over the 0.3 m.y. sample period. Modally, plagioclase is the dominant phenocryst, followed by amphibole, clinopyroxene and minor phases including anhydrite. Plagioclase phenocrysts show complex zoning: the anorthite-rich zones are probably the result of changing volatile P on the magma and may reflect the changes in the volcano's magma reservoir in response to repetitive, explosive eruptive activity.-R.E.S.

Chiapas↗
USGS1986

Deformation of poorly consolidated sediment during shallow emplacement of a basalt sill, Coso Range, California

A 150-m-long, wedge-shaped unit of folded and faulted marly siltstone crops out between undeformed sedimentary rocks on the north flank of the Coso Range, California. The several-meter-thick blunt end of this wedge abuts the north margin of a basaltic sill of comparable thickness. Chaotically deformed siltstone crops out locally at the margin of this sill, and at one locality breccia pipes about one meter in diameter crosscut the sill. The sill extends about 1 km south up the paleoslope, where it merges through continuous outcrop with a lava flow that in turn extends 1.4 km to a vent area marked by more than 100 m of agglutinate and scoria. Apparently, lava extruded at this vent flowed onto unconsolidated sediments, burrowed into them, and fed a sill at about 40 m depth within the sedimentary sequence. The sill initially propagated by wedging between sedimentary beds, but eventually began to push some beds ahead of itself, forming a remarkable train of folds in the process. The sediments apparently were wet at the time of sill emplacement, because hydrothermal alteration is common near the contact between the two rock types and because the breccia pipes that crosscut the sill apparently resulted from phreatic explosions of pore water heated at the base of the cooling sill. Comparison of deformation of the host material at the Coso locality with that reportedly caused by emplacement of sills elsewhere indicates that the character of deformation differs greatly among the various localities. The specific response of host material depends upon such parameters as initial properties of magma and host material, rate of sill growth and attendant rate of strain of host material, and depth of sill emplacement. Some properties may change considerably during an intrusive-deformational episode, thus complicating accurate reconstruction of such an event.

Bulletin of Volcanology↗