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Vance C. Kennedy

Publications and source records attributed to Vance C. Kennedy.

At least 19 recordsLinked to original sources

Long-term frozen storage of stream water samples for dissolved orthophosphate, nitrate plus nitrite, and ammonia analysis

Many researchers have used freezing as an effective, short-term, water sample preservation method for subsequent nutrient analysis. In this study, filtered samples held at −16±2°C for 4–8 years were reanalyzed for orthophosphate, nitrate plus nitrite, and ammonia. Orthophosphate and ammonia concentrations decreased by 0.2 μg P/L and 5 μg N/L, respectively, at mean concentrations of 69.4 μg P/L and 246 μg N/L. Nitrate plus nitrite increased by 1.1 μg N/L at a mean concentration of 139.1 μg N/L. An anaerobic well sample proved to be unsuitable for freezing because it lost significant amounts of orthophosphate during the freezing process. None of the differences observed over long periods of frozen storage were more than twice the estimated standard deviation of the analytical methods used in the study. The small changes observed demonstrate the effectiveness of frozen storage as a means of nutrient preservation in water samples that are unaffected by the freezing process itself.

Water Resources Research↗

Kinetic analysis of strontium and potassium sorption onto sands and gravels in a natural channel

A kinetic, first-order mass transfer model was used to describe the sorption of strontium onto sand- and gravel-sized streambed sediments. Rate parameters, empirically determined for strontium, allowed for the prediction of potassium sorption with moderate success. The model parameters varied significantly with particle size. The sorption data were collected during an experimental injection of several elements into a small mountain pool-and-riffle stream. The sorption process onto sand- and gravel-sized sediment was relatively slow compared to changes in the dissolved concentrations.

Water Resources Research↗

Interactions of solutes and streambed sediment: 1. An experimental analysis of cation and anion transport in a mountain stream

An experimental injection was performed to study the transport of stream water solutes under conditions of significant interaction with streambed sediments in a mountain pool-and-riffle stream. Experiments were conducted in Little Lost Man Creek, Humboldt County, California, in a period of low flow duringwhich only a part of the bank-full channel held active surface flow. The injection of chloride and several trace cations lasted 20 days. In this report we discuss the results of the first 24 hours of the injection and survey the results of the first 10 days. Solute-streambed interactions of two types were observed. First, the physical transport of the conservative tracer, chloride, was affected by intergravel flow and stagnant watt, zones created by the bed relief. Second, the transport of the cations (strontium, potassium, and lithium) was appreciably modified by sorption onto streambed sediment. In the stream the readily observable consequence of the solute-streambed interactions was an attenuation of the dissolved concentration of each of the tracers. The attenuation in the stream channel occurred concurrently with the storage of tracers in the streambed via both physical and chemical processes. All tracers were subsequently present in shallow wells dug several meters from the wetted part of the channel. Sediment samples collected approximately 3 weeks after the start of the injection contained increased concentrations of the injected cations.

California↗

Rhodamine-WT dye losses in a mountain stream environment

A significant fraction of rhodamine WT dye was lost during a short term multitracer injection experiment in a mountain stream environment. The conservative anion chloride and the sorbing cation lithium were concurrently injected. In-stream rhodamine WT concentrations were as low as 45 percent of that expected, based on chloride data. Concentration data were available from shallow‘wells’dug near the stream course and from a seep of suspected return flow. Both rhodamine WT dye and lithium were nonconservative with respect to the conservative chloride, with rhodamine WT dye closely following the behavior of the sorbing lithium. Nonsorption and sorption mechanisms for rhodamine WT loss in a mountain stream were evaluated in laboratory experiments. Experiments evaluating nonsorption losses indicated minimal losses by such mechanisms. Laboratory experiments using sand and gravel size streambed sediments show an appreciable capacity for rhodamine WT sorption. The detection of tracers in the shallow wells and seep indicates interaction between the stream and the flow in the surrounding subsurface, intergravel water, system. The injected tracers had ample opportunity for intimate contact with materials shown in the laboratory experiments to be potentially sorptive. It is suggested that in the study stream system, interaction with streambed gravel was a significant mechanism for the attenuation of rhodamine WT dye (relative to chloride).

Journal of the American Water Resources Associatio↗

Dynamics of added nitrate and phosphate compared in a northern California woodland stream

Injections of NO 3 and PO 4 were made during September 1975 into Little Lost Man Creek, a small pristine stream in Redwood National Park, California. Chloride, a conservative constituent, was added in a known ratio to the nutrients. Nutrient loss at a downstream point was calculated using concentration of added Cl as a reference. Nitrate nitrogen (NO 3 ‐N), added for 4 h, reached 920 μg/1 (above 5 μg/1 background) just below the injection point, but increased only to 405 μg/1 at 310 m downstream. The concentration decrease was attributed to dispersion and to uptake by stream biota. Percent of NO 3 ‐N lost decreased with increasing concentration of NO 3 ‐N. Phosphate phosphorus (PO 4 ‐P) was added a week after the NO 3 ‐N for 3 h, causing a concentration increase of 296 μg/1 (above 13 μg/1 background) just below the injection point, of 161 μg/1 at 90 m downstream, and of 98 μg/1 at 310 m. Percent loss of PO 4 ‐P at downstream sites increased with increasing PO 4 ‐P concentration and also for a short period after peak concentration occurred, but then decreased as PO 4 ‐P concentration continued decreasing. Differences in stream response to added NO 3 ‐N and PO 4 ‐P are attributed to differing rates of reaction with biota and differing degrees of interaction with abiotic stream solids.

California↗

In situ retention-transport response to nitrate loading and storm discharge in a third-order stream

Nitrate retention was assayed in a 264-m reach of a third-order stream, Little Lost Man Creek, Humboldt County, California, USA. Nitrate budgets (24-48 hours) were calculated under background conditions, and during four other intervals of modified nitrate concentration caused by nutrient amendment or storm-enhanced discharge. Under background, low-flow conditions, the reach was a source of nitrate to downstream communities. Retention during the first 36 hours of nitrate amendment was dominated by storage in the hyporheic zone and later by biotic uptake as storage zones became saturated (plateau concentration). The increase in net retention caused by increased nitrate concentration decreased output/input (O/I) ratio from 1.11 before amendment to 0.61 after 36 hours, and to 0.86 after transient storage zones were filled. Dilution, caused by a nearly four-fold increase in discharge, increased biotic retention and also export as previously stored nitrate leached from the hyporheic zone into the channel. Nitrate continued to leach from the hyporheic zone seven days after the amendment ended. This type of response may enhance biotic nutrient cycling by providing waters of higher nutrient concentration to partially scoured epilithic surfaces following reset of the benthic community by a major storm.

California↗

Retention and transport of nutrients in a third-order stream: Channel processes

Chloride was injected as a conservative tracer with nitrate to examine nitrate retention (storage plus biotic uptake) and transport in a 327—m reach of a third—order stream draining a forested basin in northwestern California. Prior to injections, diel patterns of nutrient concentrations were measured under background conditions. Nitrate concentration of stream water increased downstream, indicating that the reach was a source of dissolved inorganic nitrogen to downstream communities under background, low—flow conditions, despite uptake by photoautotrophs. At the onset of continuous solute injection over a 10—d period, timing the passage of the solute front indicated that storage dominated nitrate retention. Instantaneous concentration differences at the base of the reach at hour 24 indicated that biotic uptake accounted for 13% of the nitrate amendment while hydrologic storage constituted 29%. Corrected for groundwater dilution (11.7%), saturation of the stream's channel and hyporheic zones was not complete until 6.8 d of continuous injection. By day 3 nitrate retention was dominated by biotic processes. Biotic uptake was greatest during daylight hours indicating retention by photoautotrophs, but also occurred during darkness. After 10 d of continuous injection, mass balance calculations indicated that 29% of N (339 g) was retained from the total injected (1155 g), while the balance of injected nitrate was transported downstream. Storage of NO 3 — N was 117 g or 10% while biotic uptake was 222 g or 19%. Periphyton biomass on slides, chlorophyll a both on slides and on natural cobbles, and net community primary production all indicated a lag in periphyton response to nitrate amendment. Earliest indicators of a biotic response to nutrient amendment were decreases in both tissue C/N and epilithic respiration.

Ecology↗

Summary of geochemical transport experiments and models for solute-sediment interactions in streams

A variety of in-stream experiments have been conducted in small, mountain streams to investigate in-stream solute transport, interactions between surface and subsurface flows, and geochemical interactions between solutes and sediments. Models for cation transport have been developed. The emphasis has been on attempting to demonstrate the relative roles of physical transport processes and geochemical reactions. A summary of experiments conducted in three streams is presented.

Conference Paper↗

Results of a solute transport experiment at Uvas Creek, September 1972, California

A 3-hour constant-rate injection of chloride, strontium, and sodium was made into Uvas Creek, Santa Clara County, California, to determine solute transport and sorption properties of a small stream. Seven observation stations were selected within a 635-m reach of the stream where water samples were collected before, during and after the injection. Size-sorted stream sediments placed in the stream prior to the injection were sampled to determine sediment sorption properties. Dissolved solute concentration data are presented in both original and normalized forms to illustrate the different transport properties of the three solutes. Sorbed concentrations are tabulated as a function of both time and grain size. Calculations of streamflow and sorptive distribution coefficient are given.

California↗

Transport and dispersion of fluorescent tracer particles for the dune-bed condition, Atrisco Feeder Canal near Bernalillo, New Mexico

A fluorescent tracer technique was used to study the rates of transport and dispersion of sediment particles of various diameters and specific gravities for a dune-bed condition in an alluvial channel, Atrisco Feeder Canal near Bernalillo, N. Mex. The total transport rates of bed material measured by the steady-dilution and spatial-integration procedures were within the range of transport rates computed by the modified Einstein procedure. Lateral dispersion of the tracer particles increased with increase in the size of the tracer particles, whereas longitudinal dispersion decreased. The velocities of the tracer particles decreased with increase in the size of the tracer particles; dependence on particle diameter was large for the small particles, small for the large particles. Tracers were found at larger depths in the bed than would be expected on the basis of the sizes of the dunes in the channel. (Woodard-USGS)

Professional Paper↗

Geochemistry of the Mattole River in Northern California

The chemical composition of streams can vary greatly with changing discharge during storm runoff. These chemical changes are related to the pathways of various water parcels from the time they fall as rain until they enter the stream, and to the interactions between water and sediment during transport downstream. In order to understand better the chemical variations during storms, an extensive investigation was made of the Mattole River, a chemically clean coastal stream in Mendocino County, California. The Mattole drains a topographically mature basin of 620 sw km which has relief of about 1200 m, a long summer dry season, and mean annual rainfall of about 2300 mm. The stream flow is composed of seasonally varying proportions of four flow components, namely, surface runoff, quick-return flow (rainfall having brief and intimate contact with the soil before entering the surface drainage), delayed-return flow, and base runoff. Each component is identified by its characteristic chemistry and by the time delay between rainfall and entrance into the stream. Information is also presented on rain chemistry, adsorption reactions of suspended sediments in the fresh and brackish environments, and compositional variation of river sediments with particle size. (Woodard-USGS)

Open-File Report↗

Transport and dispersion of fluorescent tracer particles for the dune-bed condition, Atrisco Feeder Canal near Bernalillo, New Mexico

A tracer technique in which mineral particles were coated with fluorescent dyes was used to study the rates of transport and dispersion of sediment particles`of various diameters and specific gravities for a dune-bed condition in an alluvial channel. The experiment was conducted in the Atrisco Feeder Canal near Bernalillo, N. Mex., between May 1 and July 14, 1967. A continuous point source of tracers, approximated by injections at 5- or 10-minute intervals, was maintained for 7 days so that the steady-dilution procedure could be used to calculate the transport rate of bed material. After termination of the injection process, the spatial-integration procedure was used to follow the movement of the tracers downstream and to calculate the transport rate. Samples of the bed material in transport and the accompanying tracers moving along the surface of the dune bed were obtained periodically throughout the study with the "dustpan" sampler especially designed for fluorescent tracer studies. In addition, the spatial distributions of the tracers in the dune bed were determined three times during the study by core sampling.

New Mexico↗

Sediment transported by Georgia streams

A reconnaissance investigation of the sediment transported by selected Georgia streams during the period December 1957 to June 1959 was made to provide a general understanding of the physical quality of stream water in Georgia and to supply facts needed in planning more detailed work. The investigation was made by studying the variation of sediment concentration and sediment load with stream discharge at 33 sites and by relating the available data to topographic, geologic, climatic, and soil conditions in the State. In the Blue Ridge Mountains area of northern Georgia the great relief, moderately heavy precipitation, fast runoff, and loamy soils cause sediment concentrations and sediment loads which are above average for the State. During periods of moderate to low streamflow, the concentration of suspended sediment ranges from 1 to 25 ppm (parts per million). After heavy rainfall, sediment concentration increases rapidly as water discharge rises, and occasionally exceeds 1,000 ppm before decreasing again. The concentration may reach a maximum and decrease before the discharge peak is reached. A major part of the annual sediment load can be carried during a short period of time because of the great increase in both water discharge and sediment concentration during floods. The lower Coastal Plain differs from the mountainous areas in several respects. The topography is gently rolling to almost level, precipitation and runoff are less than average for the State, and topsoils generally consist of hard and loamy sand. Concentration of suspended sediment in streamflow commonly ranges from 1 to 20 ppm during periods of low to moderate discharge and increases to 15 to 60 ppm at high discharge. Because of the small increase in concentration with increasing stream discharge, the sediment load varies approximately in proportion to the discharge. The sediment characteristics of streams in the Piedmont, the Valley and Ridge area. and the upper Coastal Plain are intermediate .between those of the Blue Ridge area and the lower Coastal Plain. Comparison of suspended load with estimated bed load in a few Georgia streams suggests th.at bed load is less than 20 percent of the suspended load for most streams. Factors which appear to be most important in causing variation in sediment yield in Georgia are topographic relief, soil texture, and location of dams. Variations in other factors such as precipitation, runoff, covering vegetation, drainage area, and channel types serve to modify the effects of the major factors. In general, Georgia stream water is of good quality. Water of some streams is of exceptionally fine quality and contains less than 30 ppm combined dissolved and suspended solids during at least 90 percent of the time. Knowledge of the nature and cause of variation in water quality will permit the most effective use of Georgia streams.

Georgia↗