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V. Sautter

Publications and source records attributed to V. Sautter.

7 recordsLinked to original sources

ChemCam activities and discoveries during the nominal mission of the Mars Science Laboratory in Gale crater, Mars

At Gale crater, Mars, ChemCam acquired its first laser-induced breakdown spectroscopy (LIBS) target on Sol 13 of the landed portion of the mission (a Sol is a Mars day). Up to Sol 800, more than 188 000 LIBS spectra were acquired on more than 5800 points distributed over about 650 individual targets. We present a comprehensive review of ChemCam scientific accomplishments during that period, together with a focus on the lessons learned from the first use of LIBS in space. For data processing, we describe new tools that had to be developed to account for the uniqueness of Mars data. With regard to chemistry, we present a summary of the composition range measured on Mars for major-element oxides (SiO 2 , TiO 2 , Al 2 O 3 , FeO T , MgO, CaO, Na 2 O, K 2 O) based on various multivariate models, with associated precisions. ChemCam also observed H, and the non-metallic elements C, O, P, and S, which are usually difficult to quantify with LIBS. F and Cl are observed through their molecular lines. We discuss the most relevant LIBS lines for detection of minor and trace elements (Li, Rb, Sr, Ba, Cr, Mn, Ni, and Zn). These results were obtained thanks to comprehensive ground reference datasets, which are set to mimic the expected mineralogy and chemistry on Mars. With regard to the first use of LIBS in space, we analyze and quantify, often for the first time, each of the advantages of using stand-off LIBS in space: no sample preparation, analysis within its petrological context, dust removal, sub-millimeter scale investigation, multi-point analysis, the ability to carry out statistical surveys and whole-rock analyses, and rapid data acquisition. We conclude with a discussion of ChemCam performance to survey the geochemistry of Mars, and its valuable support of decisions about selecting where and whether to make observations with more time and resource-intensive tools in the rover's instrument suite. In the end, we present a bird's-eye view of the many scientific results: discovery of felsic Noachian crust, first observation of hydrated soil, discovery of manganese-rich coatings and fracture fills indicating strong oxidation potential in Mars' early atmosphere, characterization of soils by grain size, and wide scale mapping of sedimentary strata, conglomerates, and diagenetic materials.

Journal of Analytical Atomic Spectrometry

ChemCam results from the Shaler outcrop in Gale crater, Mars

The ChemCam campaign at the fluvial sedimentary outcrop “Shaler” resulted in observations of 28 non-soil targets, 26 of which included active laser induced breakdown spectroscopy (LIBS), and all of which included Remote Micro-Imager (RMI) images. The Shaler outcrop can be divided into seven facies based on grain size, texture, color, resistance to erosion, and sedimentary structures. The ChemCam observations cover Facies 3 through 7. For all targets, the majority of the grains were below the limit of the RMI resolution, but many targets had a portion of resolvable grains coarser than ∼0.5 mm. The Shaler facies show significant scatter in LIBS spectra and compositions from point to point, but several key compositional trends are apparent, most notably in the average K 2 O content of the observed facies. Facies 3 is lower in K 2 O than the other facies and is similar in composition to the “snake,” a clastic dike that occurs lower in the Yellowknife Bay stratigraphic section. Facies 7 is enriched in K 2 O relative to the other facies and shows some compositional and textural similarities to float rocks near Yellowknife Bay. The remaining facies (4, 5, and 6) are similar in composition to the Sheepbed and Gillespie Lake members, although the Shaler facies have slightly elevated K 2 O and FeO T . Several analysis points within Shaler suggest the presence of feldspars, though these points have excess FeO T which suggests the presence of Fe oxide cement or inclusions. The majority of LIBS analyses have compositions which indicate that they are mixtures of pyroxene and feldspar. The Shaler feldspathic compositions are more alkaline than typical feldspars from shergottites, suggesting an alkaline basaltic source region, particularly for the K 2 O-enriched Facies 7. Apart from possible iron-oxide cement, there is little evidence for chemical alteration at Shaler, although calcium-sulfate veins comparable to those observed lower in the stratigraphic section are present. The differing compositions, and inferred provenances at Shaler, suggest compositionally heterogeneous terrain in the Gale crater rim and surroundings, and intermittent periods of deposition.

Icarus

The rock abrasion record at Gale Crater: Mars Science Laboratory results from Bradbury Landing to Rocknest

Ventifacts, rocks abraded by wind-borne particles, are found in Gale Crater, Mars. In the eastward drive from “Bradbury Landing” to “Rocknest,” they account for about half of the float and outcrop seen by Curiosity's cameras. Many are faceted and exhibit abrasion textures found at a range of scales, from submillimeter lineations to centimeter-scale facets, scallops, flutes, and grooves. The drive path geometry in the first 100 sols of the mission emphasized the identification of abrasion facets and textures formed by westerly flow. This upwind direction is inconsistent with predictions based on models and the orientation of regional dunes, suggesting that these ventifact features formed from very rare high-speed winds. The absence of active sand and evidence for deflation in the area indicates that most of the ventifacts are fossil features experiencing little abrasion today.

Journal of Geophysical Research E: Planets

Igneous mineralogy at Bradbury Rise: the first ChemCam campaign at Gale crater

Textural and compositional analyses using ChemCam Remote Micro Imager (RMI) and Laser Induced Breakdown Spectroscopy (LIBS) have been performed on 5 float rocks and coarse gravels along the first 100 meters of the Curiosity traverse at Bradbury rise. ChemCam, the first LIBS instrument sent to another planet, offers the opportunity to assess mineralogic diversity at grain-size scales (∼100μm) and, from this, lithologic diversity. Depth profiling indicates that targets are relatively free of surface coatings. One type of igneous rock is volcanic and includes both aphanitic (Coronation) and porphyritic (Mara) samples. The porphyritic sample shows dark grains that are likely pyroxene megacrysts in a finegrained mesostasis containing andesine needles. Both types have magnesium-poor basaltic compositions and in this respect are similar to the evolved Jake-Matijevic rock [Stolper et al., 2013] analyzed further along the Curiosity traverse both with APXS and ChemCam instruments. The second rock-type encountered is a coarse-grained intrusive rock (Thor Lake) showing equigranular texture with mm size crystals of feldspars and Fe-Ti oxides. Such a rock is not unique at Gale as the surrounding coarse gravels (such as Beaulieu) and the conglomerate Link are dominated by feldspathic (andesine-bytownite) clasts. Finally, alkali feldspar compositions associated with a silica polymorph have been analyzed in fractured filling material of Preble rock and in Stark, a putative pumice or an impact melt. These observations document magmatic diversity at Gale and describe the first fragments of feldspar-rich lithologies (possibly an anorthosite) that may be ancient crust transported from the crater rim and now forming float rocks, coarse gravel or conglomerate clasts.

Journal of Geophysical Research E: Planets

ChemCam results from the Shaler Outcrop in Gale Crater, Mars

The "Shaler" outcrop in Gale crater is approximately 0.7 m thick and >20 m long, and exhibits multiple well-exposed platy and cross-stratified facies [1] interpreted to be primarily fluvial sandstone deposits. The outcrop is a part of the upper Glenelg member in the Yellowknife Bay (YKB) stratigraphic section [2]. Curiosity first encountered the "Shaler" outcrop on sol 121 of the mission, and returned to the outcrop on sols 309- 324. The rugged nature of the outcrop and short time available for analysis limited opportunities for contact science, but ChemCam’s ability to remotely collect compositional and textural observations resulted in a large data set from Shaler. ChemCam conducted analyses of 29 non-soil targets at Shaler, 26 of which used laser-induced breakdown spectroscopy (LIBS) for a total of 9,180 spectra. Three observations used only the remote micro-imager (RMI). Each of the 26 LIBS targets were analyzed at between 5 and 25 points, providing a measure of the target homogeneity and in some cases transecting fine strata.

Conference Paper

Soil diversity and hydration as observed by ChemCam at Gale crater, Mars

The ChemCam instrument, which provides insight into martian soil chemistry at the submillimeter scale, identified two principal soil types along the Curiosity rover traverse: a fine-grained mafic type and a locally derived, coarse-grained felsic type. The mafic soil component is representative of widespread martian soils and is similar in composition to the martian dust. It possesses a ubiquitous hydrogen signature in ChemCam spectra, corresponding to the hydration of the amorphous phases found in the soil by the CheMin instrument. This hydration likely accounts for an important fraction of the global hydration of the surface seen by previous orbital measurements. ChemCam analyses did not reveal any significant exchange of water vapor between the regolith and the atmosphere. These observations provide constraints on the nature of the amorphous phases and their hydration.

Science

The ChemCam Instrument Suite on the Mars Science Laboratory (MSL) Rover: Science objectives and mast unit description

ChemCam is a remote sensing instrument suite on board the "Curiosity" rover (NASA) that uses Laser-Induced Breakdown Spectroscopy (LIBS) to provide the elemental composition of soils and rocks at the surface of Mars from a distance of 1.3 to 7 m, and a telescopic imager to return high resolution context and micro-images at distances greater than 1.16 m. We describe five analytical capabilities: rock classification, quantitative composition, depth profiling, context imaging, and passive spectroscopy. They serve as a toolbox to address most of the science questions at Gale crater. ChemCam consists of a Mast-Unit (laser, telescope, camera, and electronics) and a Body-Unit (spectrometers, digital processing unit, and optical demultiplexer), which are connected by an optical fiber and an electrical interface. We then report on the development, integration, and testing of the Mast-Unit, and summarize some key characteristics of ChemCam. This confirmed that nominal or better than nominal performances were achieved for critical parameters, in particular power density (>1 GW/cm 2 ). The analysis spot diameter varies from 350 μm at 2 m to 550 μm at 7 m distance. For remote imaging, the camera field of view is 20 mrad for 1024×1024 pixels. Field tests demonstrated that the resolution (˜90 μrad) made it possible to identify laser shots on a wide variety of images. This is sufficient for visualizing laser shot pits and textures of rocks and soils. An auto-exposure capability optimizes the dynamical range of the images. Dedicated hardware and software focus the telescope, with precision that is appropriate for the LIBS and imaging depths-of-field. The light emitted by the plasma is collected and sent to the Body-Unit via a 6 m optical fiber. The companion to this paper (Wiens et al. this issue) reports on the development of the Body-Unit, on the analysis of the emitted light, and on the good match between instrument performance and science specifications.

Space Science Reviews