Geology topics

Troy D. Rutter

Publications and source records attributed to Troy D. Rutter.

7 recordsLinked to original sources

USGS2025

Comparative toxicity of aircraft deicers, runway deicers, and road salt in winter airport runoff

Aircraft deicer and anti-icer formulations and airfield pavement deicer formulations are commonly used at airports that experience freezing precipitation. In addition, road salt is often applied in urban areas surrounding airports. This mixture of deicers in receiving streams can be toxic to aquatic organisms. A 17-year study of deicers and toxicity in runoff samples from sites in and near Milwaukee Mitchell International Airport included bioassay testing of Ceriodaphnia dubia , Pimephales promelas , Raphidocelis subcapitata , and Aliivibrio fischeri concurrently with quantification of freezing-point depressants that represent presence of the various deicers. Propylene glycol was monitored to represent aircraft deicers and anti-icers, acetate and formate were monitored to represent airfield pavement deicers, and chloride was monitored to represent road salt. Toxicity endpoints (e.g., lethal concentrations and inhibitive concentrations) were compiled for 19 airport deicer products and sodium chloride. Comparison of freezing-point depressant concentrations with toxicity endpoints indicated that propylene glycol, acetate, and chloride exceeded endpoint concentrations in multiple samples: more than 70% of 492 runoff samples exceeded at least one endpoint concentration with exceedances of propylene glycol and acetate-based deicer endpoints as well as road salt endpoints. Validation of these results were observed with measured toxic effects on C. dubia , P. promelas , and R. subcapitata in bioassays conducted on undiluted samples: samples with multiple deicers exceeding endpoint thresholds had greater toxicity than samples with individual deicer endpoint exceedances, and samples with no endpoint exceedances typically exhibited less toxicity than samples with only one endpoint exceedance. A comparison of additivity of toxicity quotients with bioassay results fit a log-logistic regression curve, indicating that the condition of tested organisms degraded with increasing deicer presence. These findings suggest that concurrent reduction of runoff from aircraft, airfield pavement, and road salt deicers will be needed to eliminate aquatic toxicity in adjacent watersheds.

Wisconsin↗

USGS2025

Apportionment of oxygen demand contributions from aircraft and pavement deicer freezing point depressants in airport runoff, Milwaukee, Wisconsin, 2005–2022

Aircraft anti-icers and pavement deicers improve the safety of airport operations during winter precipitation events. Runoff containing these products can contribute elevated biochemical oxygen demand (BOD) to receiving streams. We monitored runoff from Milwaukee Mitchell International Airport at one upstream site, three outfall sites, and one downstream site from 2005 to 2022 for BOD, chemical oxygen demand (COD), and freezing point depressants used in deicing and anti-icing fluids to determine the primary sources of BOD and COD in the receiving stream. The greatest concentrations of BOD, COD, and freezing point depressants occurred at the primary outfall, which drains the main terminal area, and the secondary outfall, which drains cargo operations. The greatest loadings occurred at the primary outfall; loadings were an order of magnitude less at the secondary outfall due to a small drainage area with relatively low flow volumes. At the three outfalls, median concentrations of five-day BOD (BOD 5 ) and COD were 100–1,300 mg L −1 and 200–2,100 mg L −1 respectively. Apportionment computations indicated that propylene glycol from aircraft deicers and anti-icers was responsible for at least half of the BOD 5 and COD concentrations and loadings. Acetate from pavement deicers contributed another 7%–15% at each site. These findings suggest that management actions in the primary outfall drainage area that target propylene glycol–containing deicers have the greatest potential to decrease BOD 5 in airport runoff. This work demonstrates the usefulness of BOD and COD apportionment for identifying the deicing products and locations within an airport to prioritize for reduction or recovery and treatment.

Wisconsin↗

USGS2023

Airport deicers: An unrecognized source of phosphorus loading in receiving waters

Airport ice control products contributed to total phosphorus (TP) loadings in a study of surface water runoff at a medium-sized airport from 2015 to 2021. Eleven airport ice control products had TP concentrations from 1–807 mg L –1 in liquid formulas, while solid pavement deicer had a TP concentration of 805 mg kg –1 . Product application data, formula TP concentrations, and surface water sampling results were used to estimate TP concentration and loading contributions from these ice control products to receiving streams. Airport ice control products were found to contribute to TP in 84% of the water samples collected at downstream sites during deicing events, and TP concentrations at those sites exceeded aquatic life benchmarks in 70% of samples collected during deicing. A receiving stream 6 km downstream had TP attributed to airport ice control sources in 78% of the samples. TP loadings at an upstream site and the receiving stream site were greatest during the largest runoff events as is typical in urban runoff, but this pattern was not always followed at airport outfall sites due to the influence of TP in deicer products. Products analyzed in this study are used at airports across the United States and abroad, and findings suggest that airport deicers could represent a previously unrecognized source of phosphorus to adjacent waterways.

Wisconsin↗

USGS2023

Modeled predictions of human-associated and fecal-indicator bacteria concentrations and loadings in the Menomonee River, Wisconsin using in-situ optical sensors

Human sewage contamination of waterways is a major issue in the United States and throughout the world. Models were developed for estimation of two human-associated fecal-indicator and three general fecal-indicator bacteria (HIB and FIB) using in situ optical field-sensor data for estimating concentrations and loads of HIB and FIB and the extent of sewage contamination in the Menomonee River in Milwaukee, Wisconsin. Three commercially available optical sensor platforms were installed into an unfiltered custom-designed flow-through system along with a refrigerated automatic sampler at the Menomonee River sampling location. Ten-minute optical sensor measurements were made from November 2017 to December 2018 along with the collection of 153 flow-weighted discrete water samples (samples) for HIB, FIB, dissolved organic carbon (DOC), and optical properties of water. Of those 153 samples, 119 samples were from event-runoff periods, and 34 were collected during low-flow periods. Of the 119 event-runoff samples, 43 samples were from event-runoff combined sewer overflow (CSO) influenced periods (event-CSO periods). Models included optical sensor measurements as explanatory variables with a seasonal variable as an interaction term. In some cases, separate models for event-CSO periods and non CSO-periods generally improved model performance, as compared to using all the data combined for estimates of FIB and HIB. Therefore, the CSO and non-CSO models were used in final estimations for CSO and non-CSO time periods, respectively. Estimated continuous concentrations for all bacteria markers varied over six orders of magnitude during the study period. The greatest concentrations, loads, and proportion of sewage contamination occurred during event-runoff and event-CSO periods. Comparison to water quality standards and microbial risk assessment benchmarks indicated that estimated bacteria levels exceeded recreational water quality criteria between 34 and 96% of the entire monitoring period, highlighting the benefits of high-frequency monitoring compared to traditional grab sample collection. The application of optical sensors for estimation of HIB and FIB markers provided a thorough assessment of bacterial presence and human health risk in the Menomonee River.

Wisconsin↗

USGS2021

Benzotriazole concentrations in airport runoff are reduced following changes in airport deicer formulations

A comparison of the presence of additives in airport deicers commonly used in the United States and in airport runoff was conducted with data collected before and after changes in deicer formulations. Three isomers of benzotriazoles (BTs)—4-methyl-1H-benzotriazole (4-MeBT), 5-methyl-1H-benzotriazole (5-MeBT), and 1H-benzotriazole (1H-BT)—are corrosion inhibitors added to some formulations of airport deicers and are reported to be a source of aquatic toxicity in streams receiving airport runoff. Concentrations of BT in aircraft deicers and anti-icing fluids (ADAF) were reduced over time but were not reduced in potassium acetate airfield-pavement deicer material (PDM) that was used throughout the study period. Streams receiving runoff from Milwaukee Mitchell International Airport, Milwaukee, Wisconsin, USA, were monitored from 2004 to 2019 for BTs, with concentrations of 4-MeBT varying from <0.35 to 4600 µg/L, 5-MeBT varying from <0.25 to 6600 µg/L, and 1H-BT varying from <0.25 to 150 µg/L. Median 4-MeBT concentrations at sites downstream from the airport decreased by approximately 74%, 5-MeBT by 69%, and 1H-BT by 82% following reduction in BTs in ADAF formulations, resulting in a reduction in the potential for aquatic toxicity in receiving streams. A change in residuals from regression analysis between freezing point depressants and BTs indicate that the reduction in BT concentrations in airport runoff was a result of BT reduction in ADAF formulations, but PDM may still be a substantial source of BTs in airport runoff. Because BTs are a source of aquatic toxicity in airport deicers, the reductions in BTs in the common deicers observed in this study can be used to demonstrate the potential for a reduction in the effects to aquatic organisms in airport runoff, resulting in greater likelihood of meeting aquatic toxicity requirements in airport stormwater permits, and potentially driving airports, airlines, and permit holders to advocate further reduction or elimination of BTs and other harmful contaminants in airport deicers.

Wisconsin↗

USGS2013

Effects of best-management practices in Bower Creek in the East River priority watershed, Wisconsin, 1991-2009

Hydrologic and water-quality data were collected at Bower Creek during the periods before best-management practices (BMPs), and after BMPs were installed for evaluation of water-quality improvements. The monitoring was done between 1990 and 2009 with the pre-BMP period ending in July 1994 and the post-BMP period beginning in October 2006. BMPs installed in this basin included streambank protection and fencing, stream crossings, grade stabilization, buffer strips, various barnyard-runoff controls, nutrient management, and a low degree of upland BMPs. Water-quality evaluations included base-flow concentrations and storm loads for total suspended solids, total phosphorus, and ammonia nitrogen. The only reductions detected between the base-flow samples of the pre- and post-BMP periods were in median concentrations of total phosphorus from base-flow samples, but not for total suspended solids or dissolved ammonia nitrogen. Differences in storm loads for the three water-quality constituents monitored were not observed during the study period.

Wisconsin↗

USGS2012

Effects of best-management practices in Eagle and Joos Valley Creeks in the Waumandee Creek Priority Watershed, Wisconsin, 1990-2007

In many watersheds, nonpoint-source contamination is a major contributor to water-quality problems. In response to the recognition of the importance of nonpoint sources, the Wisconsin Nonpoint Source Water Pollution Abatement Program (Nonpoint Program) was enacted in 1978. This report summarizes the results of a study to assess the effectiveness of watershed-management practices for controlling nonpoint-source contamination for the Eagle Creek and Joos Valley Creek Watersheds. Streamflow-gaging stations equipped for automated sample collection and continuous recording of stream stage were installed in July 1990 at Eagle and Joos Valley Creeks and were operated through September 2007. In October 1990, three rain gages were installed in each watershed and were operated through September 2007. Best-Management Practices (BMPs) were installed during 1993 to 2000 in Eagle and Joos Valley Creeks and were tracked throughout the study period. By the year 2000, a majority of the BMPs were implemented in the two watersheds and goals set by the Wisconsin Department of Natural Resources and the local Land Conservation Department had been achieved for the two study watersheds (Wisconsin Department of Natural Resources, 1990). The distributions of the rainstorms that produced surface runoff and storm loads were similar in the pre-BMP (1990-93) and post-BMP implementation (2000-07) periods for both Eagle and Joos Valley Creeks. The highest annual streamflow occurred at both sites in water year 1993, which corresponded to the greatest above normal nonfrozen precipitation measured at two nearby NOAA weather stations. The minimum streamflow occurred in water year 2007 at both sites. Base-flow and stormwater samples were collected and analyzed for suspended solids, total phosphorus, and ammonia nitrogen. For both Eagle and Joos Valley Creeks the median concentrations of suspended solids and total phosphorus in base flow were lower during the post-BMP period compared to the pre-BMP period and were statistically significant at the 0.05 significance level. The decrease in median concentrations of ammonia nitrogen at both sites was not statistically significant at the 0.05 significance level. Multiple linear regression analyses were used to remove the effects of climatologic conditions and seasonality from computed storm loads. For both Eagle and Joos Valley Creeks, the median storm loads for suspended solids, total phosphorus, and ammonia nitrogen were lower during the post-BMP period compared to the pre-BMP period and were statistically significant at the 0.05 significance level. The decreases in storm-load regression residuals from the pre- to the post-BMP periods for both Eagle and Joos Valley Creeks were statistically significant for all three constituents at the 0.05 significance level and indicated an apparent improvement in water-quality in the post-BMP period. Because the rainfall characteristics for individual storms in the pre- and post-BMP periods are likely to be different, separate pre- and post-BMP regressions were used to estimate the theoretical pre- and post-BMP storm loads to allow estimates of precent reductions between the pre- and post-BMP periods. The estimated percent reductions in storm loads for suspended solids, total phosphorus, and ammonia nitrogen were 89, 77, and 66 respectively for Eagle Creek and 84, 67, and 60 respectively for Joos Valley Creek. The apparent improvement in water quality is attributed to the implemented BMPs and to a reduction in the number of cattle in the watersheds.

Wisconsin↗