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Tia-Marie Scott

Publications and source records attributed to Tia-Marie Scott.

12 recordsLinked to original sources

Groundwater quality in the Mohawk and western New York River Basins, New York, 2016

Water samples were collected from July through December 2016 from 9 production wells and 13 domestic wells in the Mohawk River Basin, and from 17 production wells and 17 domestic wells in the western New York River Basins. The samples were collected and processed by using standard U.S. Geological Survey methods and were analyzed for 320 physicochemical properties and constituents, including dissolved gases, major ions, nutrients, trace elements, pesticides, volatile organic compounds, radionuclides, and indicator bacteria, to characterize groundwater quality in the basins. Analytical results are provided in the companion U.S. Geological Survey data release titled “Groundwater Quality Data From the Mohawk and Western New York River Basins, New York, 2016.” The Mohawk River Basin study area covers 3,500 square miles in New York. Of the 22 wells sampled in the Mohawk River Basin, 8 are completed in sand and gravel, and 14 are completed in bedrock aquifers. Most constituents in the samples from the Mohawk River Basin were present in concentrations below the maximum contaminant levels used in public supply drinking-water regulations by the New York State Department of Health and the U.S. Environmental Protection Agency. Values for some of the properties and concentrations of some constituents—pH, color, iron, manganese, aluminum, sodium, chloride, dissolved solids, radon-222, and heterotrophic plate count—sometimes equaled or exceeded primary, secondary, or proposed drinking-water standards. The western New York River Basins study area covers 5,340 square miles in western New York and includes parts of the Lake Erie and Niagara River Basins, the western Lake Ontario Basin (between the Niagara River and Genesee River Basins), and the Allegheny River Basin. Of the 34 wells sampled in the western New York River Basins, 16 are completed in sand and gravel, and 18 are completed in bedrock aquifers. Most constituents in the samples from the western New York River Basins were present in concentrations below the maximum contaminant levels used in public supply drinking-water regulations by the New York State Department of Health and the U.S. Environmental Protection Agency. Values for some of the properties and concentrations of some constituents—color, chloride, sodium, dissolved solids, iron, manganese, aluminum, arsenic, barium, radon-222, methane, total coliform bacteria, fecal coliform bacteria, and Escherichia coli bacteria—sometimes equaled or exceeded primary, secondary, or proposed drinking-water standards.

New York

Groundwater quality in the Delaware, Genesee, and St. Lawrence River Basins, New York, 2015

The U.S. Geological Survey, in cooperation with the New York State Department of Environmental Conservation, collected groundwater samples from 5 production wells and 5 domestic wells in the Delaware River Basin, 8 production wells and 7 domestic wells in the Genesee River Basin, and 1 municipal well, 7 production wells, and 13 domestic wells in the St. Lawrence River Basin in New York. All samples were collected from May through November 2015 in an effort to characterize groundwater quality in these basins. The samples were collected and processed by using standard U.S. Geological Survey procedures and were analyzed for 148 physiochemical properties and constituents, including dissolved gases, major ions, nutrients, trace elements, pesticides, volatile organic compounds, radionuclides, and indicator bacteria. The Delaware River Basin study area covers 2,360 square miles (mi 2 ) in southeastern New York. Of the 10 wells sampled in the Delaware River Basin, 3 are completed in sand and gravel, and 7 are completed in bedrock. Groundwater in the Delaware River Basin was generally of good quality, although properties and concentrations of some constituents—pH, iron, manganese, aluminum, radon-222, and total coliform bacteria—sometimes equaled or exceeded primary, secondary, or proposed drinking-water standards. The constituent most frequently detected in concentrations exceeding drinking-water standards (10 of 10 samples) was radon-222. The Genesee River Basin study area includes the entire 2,439 mi 2 of the basin in western New York. Of the 15 wells sampled in the Genesee River Basin, 6 are completed in sand and gravel, and 9 are completed in bedrock. Groundwater in the Genesee River Basin was generally of good quality, although properties and concentrations of some constituents—chloride, sodium, dissolved solids, iron, manganese, aluminum, arsenic, radon-222, methane, total coliform bacteria, fecal coliform bacteria, and Escherichia coli bacteria—sometimes equaled or exceeded primary, secondary, or proposed drinking-water standards. The constituent most frequently detected in concentrations exceeding drinking-water standards (12 of 15 samples) was radon-222. The St. Lawrence River Basin study area includes the entire 5,650 mi 2 of the basin in northeastern New York. Of the 21 wells sampled in the St. Lawrence River Basin, 7 are completed in sand and gravel, and 14 are completed in bedrock. Groundwater in the St. Lawrence River Basin was generally of good quality, although properties and concentrations of some constituents—pH, chloride, sodium, dissolved solids, iron, manganese, sulfate, nitrate, radon-222, total coliform bacteria, fecal coliform bacteria, and Escherichia coli bacteria—sometimes equaled or exceeded primary, secondary, or proposed drinking-water standards. The constituent most frequently detected in concentrations exceeding drinking-water standards (14 of 21 samples) was radon-222.

New York

Pharmaceutical manufacturing facility discharges can substantially increase the pharmaceutical load to U.S. wastewaters

Discharges from pharmaceutical manufacturing facilities (PMFs) previously have been identified as important sources of pharmaceuticals to the environment. Yet few studies are available to establish the influence of PMFs on the pharmaceutical source contribution to wastewater treatment plants (WWTPs) and waterways at the national scale. Consequently, a national network of 13 WWTPs receiving PMF discharges, six WWTPs with no PMF input, and one WWTP that transitioned through a PMF closure were selected from across the United States to assess the influence of PMF inputs on pharmaceutical loading to WWTPs. Effluent samples were analyzed for 120 pharmaceuticals and pharmaceutical degradates. Of these, 33 pharmaceuticals had concentrations substantially higher in PMF-influenced effluent (maximum 555,000 ng/L) compared to effluent from control sites (maximum 175 ng/L). Concentrations in WWTP receiving PMF input are variable, as discharges from PMFs are episodic, indicating that production activities can vary substantially over relatively short (several months) periods and have the potential to rapidly transition to other pharmaceutical products. Results show that PMFs are an important, national-scale source of pharmaceuticals to the environment.

Science of the Total Environment

Groundwater quality in the Lake Champlain and Susquehanna River basins, New York, 2014

In a study conducted by the U.S. Geological Survey in cooperation with the New York State Department of Environmental Conservation, groundwater samples were collected from 6 production wells and 7 domestic wells in the Lake Champlain Basin and from 11 production wells and 9 domestic wells in the Susquehanna River Basin in New York. All samples were collected from June through December 2014 to characterize groundwater quality in these basins. The samples were collected and processed using standard procedures of the U.S. Geological Survey and were analyzed for 148 physiochemical properties and constituents, including dissolved gases, major ions, nutrients, trace elements, pesticides, volatile organic compounds, radionuclides, and indicator bacteria. The Lake Champlain Basin study area covers the 3,050 square miles of the basin in northeastern New York; the remaining part of the basin is in Vermont and Canada. Of the 13 wells sampled in the Lake Champlain Basin, 6 are completed in sand and gravel, and 7 are completed in bedrock. Groundwater in the Lake Champlain Basin was generally of good quality, although properties and concentrations of some constituents— fluoride, iron, manganese, dissolved solids, sodium, radon-222, total coliform bacteria, fecal coliform bacteria, and Escherichia coli bacteria—sometimes equaled or exceeded primary, secondary, or proposed drinking-water standards. The constituent most frequently detected in concentrations exceeding drinking-water standards (5 of 13 samples) was radon-222. The Susquehanna River Basin study area covers the entire 4,522 square miles of the basin in south-central New York; the remaining part of the basin is in Pennsylvania. Of the 20 wells sampled in the Susquehanna River Basin, 11 are completed in sand and gravel, and 9 are completed in bedrock. Groundwater in the Susquehanna River Basin was generally of good quality, although properties and concentrations of some constituents—pH, chloride, sodium, dissolved solids, iron, manganese, aluminum, arsenic, barium, gross-alpha radioactivity, radon-222, methane, total coliform bacteria, and fecal coliform bacteria—sometimes equaled or exceeded primary, secondary, or proposed drinking-water standards. As in the Lake Champlain Basin, the constituent most frequently detected in concentrations exceeding drinking-water standards (13 of 20 samples) was radon-222.

New York

Complex mixtures, complex responses: Assessing pharmaceutical mixtures using field and laboratory approaches

Pharmaceuticals are present in low concentrations (<100&thinsp;ng/L) in most municipal wastewater effluents but may be elevated locally because of factors such as input from pharmaceutical formulation facilities. Using existing concentration data, the authors assessed pharmaceuticals in laboratory exposures of fathead minnows ( Pimephales promelas ) and added environmental complexity through effluent exposures. In the laboratory, larval and mature minnows were exposed to a simple opioid mixture (hydrocodone, methadone, and oxycodone), an opioid agonist (tramadol), a muscle relaxant (methocarbamol), a simple antidepressant mixture (fluoxetine, paroxetine, venlafaxine), a sleep aid (temazepam), or a complex mixture of all compounds. Larval minnow response to effluent exposure was not consistent. The 2010 exposures resulted in shorter exposed minnow larvae, whereas the larvae exposed in 2012 exhibited altered escape behavior. Mature minnows exhibited altered hepatosomatic indices, with the strongest effects in females and in mixture exposures. In addition, laboratory-exposed, mature male minnows exposed to all pharmaceuticals (except the selective serotonin reuptake inhibitor mixture) defended nest sites less rigorously than fish in the control group. Tramadol or antidepressant mixture exposure resulted in increased splenic T lymphocytes. Only male minnows exposed to whole effluent responded with increased plasma vitellogenin concentrations. Female minnows exposed to pharmaceuticals (except the opioid mixture) had larger livers, likely as a compensatory result of greater prominence of vacuoles in liver hepatocytes. The observed alteration of apical endpoints central to sustaining fish populations confirms that effluents containing waste streams from pharmaceutical formulation facilities can adversely impact fish populations but that the effects may not be temporally consistent. The present study highlights the importance of including diverse biological endpoints spanning levels of biological organization and life stages when assessing contaminant interactions.

Environmental Toxicology and Chemistry

Investigating dynamic sources of pharmaceuticals: Demographic and seasonal use are more important than down-the-drain disposal in wastewater effluent in a University City setting

Pharmaceutical pollution in surface waters poses risks to human and ecosystem health. Wastewater treatment facilities are primary sources of pharmaceutical pollutants, but little is known about the factors that affect drugs entering the wastewater stream. This paper investigates the effects of student pharmaceutical use and disposal behaviors and an annual demographic shift on pharmaceutical pollution in a university town. We sampled wastewater effluent during a ten-day annual spring student move-out period at the University of Vermont. We then interpreted these data in light of survey results that investigated pharmaceutical purchasing, use, and disposal practices among the university student population. Surveys indicated that the majority of student respondents purchased pharmaceuticals in the previous year. Many students reported having leftover drugs, though only a small portion disposed of them, mainly in the trash. We detected 51 pharmaceuticals in 80% or more of the wastewater effluent samples collected over the ten-day sampling period. Several increased in concentration after students left the area. Concentrations of caffeine and nicotine decreased weakly. Drug disposal among this university student population does not appear to be a major source of pharmaceuticals in wastewater. Increases in pharmaceutical concentration after the students left campus can be tied to an increase in the seasonal use of allergy medications directly related to pollen, as well as a demographic shift to a year-round older population, which supports national data that older people use larger volumes and different types of pharmaceuticals than the younger student population.

Vermont

Groundwater quality in the Chemung River, Eastern Lake Ontario, and Lower Hudson River Basins, New York, 2013

In a study conducted by the U.S. Geological Survey (USGS) in cooperation with the New York State Department of Environmental Conservation, water samples were collected from 4 production wells and 4 domestic wells in the Chemung River Basin, 8 production wells and 7 domestic wells in the Eastern Lake Ontario Basin, and 12 production wells and 13 domestic wells in the Lower Hudson River Basin (south of the Federal Lock and Dam at Troy) in New York. All samples were collected in June, July, and August 2013 to characterize groundwater quality in these basins. The samples were collected and processed using standard USGS procedures and were analyzed for 148 physiochemical properties and constituents, including dissolved gases, major ions, nutrients, trace elements, pesticides, volatile organic compounds, radionuclides, and indicator bacteria. The Chemung River Basin study area covers 1,744 square miles in south-central New York and encompasses the part of the Chemung River Basin that lies within New York. Two of the wells sampled in the Chemung River Basin are completed in sand and gravel, and 6 are completed in bedrock. Groundwater in the Chemung River Basin was generally of good quality, although properties and concentrations of some constituents&mdash;sodium, arsenic, aluminum, iron, manganese, radon-222, total coliform bacteria, and Escherichia coli bacteria&mdash;equaled or exceeded primary, secondary, or proposed drinking-water standards. The constituent most frequently detected in concentrations exceeding drinking-water standards (six of eight samples) was radon-222. The Eastern Lake Ontario Basin study area covers 3,225 square miles in north-central New York. The Eastern Lake Ontario Basin (between the Oswego River Basin and the St. Lawrence River Basin) includes the Mid-Northern Lake Ontario Basin, the Black River Basin, and the Chaumont River-Perch River Basin. Five of the wells sampled in the Eastern Lake Ontario Basin are completed in sand and gravel, and 10 are completed in bedrock. Groundwater in the Eastern Lake Ontario Basin was generally of good quality, although properties and concentrations of some constituents&mdash;color, pH, sodium, dissolved solids, fluoride, iron, manganese, uranium, gross-&alpha; radioactivity, radon-222, total coliform bacteria, and fecal coliform bacteria&mdash;equaled or exceeded primary, secondary, or proposed drinking-water standards. The constituent most frequently detected in concentrations exceeding drinking-water standards (10 of 15 samples) was radon-222. The Lower Hudson River Basin study area covers 5,607 square miles and encompasses the part of the Lower Hudson River Basin that lies within New York plus the parts of the Housatonic, Hackensack, Bronx, and Saugatuck River Basins that are in New York. Twelve of the wells sampled in the Lower Hudson River Basin are completed in sand-and-gravel deposits, and 13 are completed in bedrock. Groundwater in the Lower Hudson River Basin was generally of good quality, although properties and concentrations of some constituents&mdash;pH, sodium, chloride, dissolved solids, arsenic, aluminum, iron, manganese, radon-222, total coliform bacteria, fecal coliform bacteria, Escherichia coli bacteria, and heterotrophic plate count&mdash;equaled or exceeded primary, secondary, or proposed drinking-water standards. The constituent most frequently detected in concentrations exceeding drinking-water standards (20 of 25 samples) was radon-222.

New York

Mycotoxins: diffuse and point source contributions of natural contaminants of emerging concern to streams

To determine the prevalence of mycotoxins in streams, 116 water samples from 32 streams and three wastewater treatment plant effluents were collected in 2010 providing the broadest investigation on the spatial and temporal occurrence of mycotoxins in streams conducted in the United States to date. Out of the 33 target mycotoxins measured, nine were detected at least once during this study. The detections of mycotoxins were nearly ubiquitous during this study even though the basin size spanned four orders of magnitude. At least one mycotoxin was detected in 94% of the 116 samples collected. Deoxynivalenol was the most frequently detected mycotoxin (77%), followed by nivalenol (59%), beauvericin (43%), zearalenone (26%), β-zearalenol (20%), 3-acetyl-deoxynivalenol (16%), α-zearalenol (10%), diacetoxyscirpenol (5%), and verrucarin A (1%). In addition, one or more of the three known estrogenic compounds (i.e. zearalenone, α-zearalenol, and β-zearalenol) were detected in 43% of the samples, with maximum concentrations substantially higher than observed in previous research. While concentrations were generally low (i.e. < 50 ng/L) during this study, concentrations exceeding 1000 ng/L were measured during spring snowmelt conditions in agricultural settings and in wastewater treatment plant effluent. Results of this study suggest that both diffuse (e.g. release from infected plants and manure applications from exposed livestock) and point (e.g. wastewater treatment plants and food processing plants) sources are important environmental pathways for mycotoxin transport to streams. The ecotoxicological impacts from the long-term, low-level exposures to mycotoxins alone or in combination with complex chemical mixtures are unknown

Science of the Total Environment

Groundwater quality in the Upper Hudson River Basin, New York, 2012

Water samples were collected from 20 production and domestic wells in the Upper Hudson River Basin (north of the Federal Dam at Troy, New York) in New York in August 2012 to characterize groundwater quality in the basin. The samples were collected and processed using standard U.S. Geological Survey procedures and were analyzed for 148 physiochemical properties and constituents, including dissolved gases, major ions, nutrients, trace elements, pesticides, volatile organic compounds (VOCs), radionuclides, and indicator bacteria. The Upper Hudson River Basin covers 4,600 square miles in upstate New York, Vermont, and Massachusetts; the study area encompasses the 4,000 square miles that lie within New York. The basin is underlain by crystalline and sedimentary bedrock, including gneiss, shale, and slate; some sandstone and carbonate rocks are present locally. The bedrock in some areas is overlain by surficial deposits of saturated sand and gravel. Eleven of the wells sampled in the Upper Hudson River Basin are completed in sand and gravel deposits, and nine are completed in bedrock. Groundwater in the Upper Hudson River Basin was typically neutral or slightly basic; the water typically was moderately hard. Bicarbonate, chloride, calcium, and sodium were the major ions with the greatest median concentrations; the dominant nutrient was nitrate. Methane was detected in 7 samples. Strontium, iron, barium, boron, and manganese were the trace elements with the highest median concentrations. Two pesticides, an herbicide degradate and an insecticide degredate, were detected in two samples at trace levels; seven VOCs, including chloroform, four solvents, and the gasoline additive methyl tert-butyl ether (MTBE) were detected in four samples. The greatest radon-222 activity, 2,900 picocuries per liter, was measured in a sample from a bedrock well; the median radon activity was higher in samples from bedrock wells than in samples from sand and gravel wells. Coliform bacteria were detected in one sample with a maximum of 2 colony-forming units per 100 milliliters. Water quality in the Upper Hudson River Basin is generally good, but concentrations of some constituents equaled or exceeded current or proposed Federal or New York State drinking-water standards. The standards exceeded are color (1 sample), pH (3 samples), sodium (3 samples), chloride (1 sample), dissolved solids (1 sample), arsenic (1 sample), iron (2 samples), manganese (2 samples), uranium (1 sample), radon-222 (12 samples), and gross beta activities (3 samples). Total coliform bacteria were each detected in one sample. Concentrations of fluoride, sulfate, nitrate, nitrite, aluminum, antimony, barium, beryllium, cadmium, chromium, copper, lead, mercury, selenium, silver, thallium, zinc, and gross alpha activities did not exceed existing drinking-water standards in any of the samples collected. Methane concentration in one sample was greater than 28 milligrams per liter, with a concentration of 35.1 milligrams per liter.

New York

Methane occurrence in groundwater of south-central New York State, 2012: Summary of findings

A survey of methane in groundwater was undertaken to document methane occurrence on the basis of hydrogeologic setting within a glaciated 1,810-square-mile area of south-central New York that has not seen shale-gas resource development. The adjacent region in northeastern Pennsylvania has undergone shale-gas resource development from the Marcellus Shale. Well construction and subsurface data were required for each well sampled so that the local hydrogeologic setting could be classified. All wells were also at least 1 mile from any known gas well (active, exploratory, or abandoned). Sixty-six domestic wells and similar purposed supply wells were sampled during summer 2012. Field water-quality characteristics (pH, specific conductance, dissolved oxygen, and temperature) were measured at each well, and samples were collected and analyzed for dissolved gases, including methane and short-chain hydrocarbons. Carbon and hydrogen isotopic ratios of methane were measured in 21 samples that had at least 0.3 milligram per liter (mg/L) methane.

New York

Groundwater quality in the Mohawk River Basin, New York, 2011

Water samples were collected from 21 production and domestic wells in the Mohawk River Basin in New York in July 2011 to characterize groundwater quality in the basin. The samples were collected and processed using standard U.S. Geological Survey procedures and were analyzed for 148 physiochemical properties and constituents, including dissolved gases, major ions, nutrients, trace elements, pesticides, volatile organic compounds (VOCs), radionuclides, and indicator bacteria. The Mohawk River Basin covers 3,500 square miles in New York and is underlain by shale, sandstone, carbonate, and crystalline bedrock. The bedrock is overlain by till in much of the basin, but surficial deposits of saturated sand and gravel are present in some areas. Nine of the wells sampled in the Mohawk River Basin are completed in sand and gravel deposits, and 12 are completed in bedrock. Groundwater in the Mohawk River Basin was typically neutral or slightly basic; the water typically was very hard. Bicarbonate, chloride, calcium, and sodium were the major ions with the greatest median concentrations; the dominant nutrient was nitrate. Methane was detected in 15 samples. Strontium, iron, barium, boron, and manganese were the trace elements with the highest median concentrations. Four pesticides, all herbicides or their degradates, were detected in four samples at trace levels; three VOCs, including chloroform and two solvents, were detected in four samples. The greatest radon-222 activity, 2,300 picocuries per liter, was measured in a sample from a bedrock well, but the median radon activity was higher in samples from sand and gravel wells than in samples from bedrock wells. Coliform bacteria were detected in five samples with a maximum of 92 colony-forming units per 100 milliliters. Water quality in the Mohawk River Basin is generally good, but concentrations of some constituents equaled or exceeded current or proposed Federal or New York State drinking-water standards. The standards exceeded are color (1 sample), pH (1 sample), sodium (9 samples), chloride (1 sample), sulfate (2 samples), dissolved solids (7 samples), aluminum (3 samples), iron (8 samples), manganese (6 samples), radon-222 (10 samples), and bacteria (5 samples). Fecal coliform bacteria and Escherichia coli (E. coli) were each detected in one sample. Concentrations of fluoride, nitrate, nitrite, antimony, arsenic, barium, beryllium, cadmium, chromium, copper, lead, mercury, selenium, silver, thallium, zinc, and uranium, and gross alpha activities, did not exceed existing drinking-water standards in any of the samples collected. Methane concentrations in two samples were greater than 28 milligrams per liter, and the maximum measured concentration was 44.3 milligrams per liter.

New York

Occurrence of methane in groundwater of south-central New York State, 2012-systematic evaluation of a glaciated region by hydrogeologic setting

A survey of methane in groundwater was undertaken to document methane occurrence on the basis hydrogeologic setting within a glaciated 1,810-square-mile area of south-central New York along the Pennsylvania border. Sixty-six wells were sampled during the summer of 2012. All wells were at least 1 mile from any known gas well (active, exploratory, or abandoned). Results indicate strong positive and negative associations between hydrogeologic settings and methane occurrence. The hydrogeologic setting classes are based on topographic position (valley and upland), confinement or non-confinement of groundwater by glacial deposits, well completion in fractured bedrock or sand and gravel, and hydrogeologic subcategories. Only domestic wells and similar purposed supply wells with well-construction and log information were selected for classification. Field water-quality characteristics (pH, specific conductance, dissolved oxygen, and temperature) were measured at each well, and samples were collected and analyzed for dissolved gases, including methane and short-chain hydrocarbons. Carbon and hydrogen isotopic ratios of methane were measured in 21 samples that had at least 0.3 milligram per liter (mg/L) of methane. Results of sampling indicate that occurrence of methane in groundwater of the region is common—greater than or equal to 0.001 mg/L in 78 percent of the groundwater samples. Concentrations of methane ranged over five orders of magnitude. Methane concentrations at which monitoring or mitigation are indicated (greater than or equal to 10 mg/L) were measured in 15 percent of the samples. Methane concentrations greater than 0.1 mg/L were associated with specific hydrogeologic settings. Wells completed in bedrock within valleys and under confined groundwater conditions were most closely associated with the highest methane concentrations. Fifty-seven percent of valley wells had greater than or equal to 0.1 mg/L of methane, whereas only 10 percent of upland wells equaled or exceeded that concentration. Isotopic signatures differed between these groups as well. Methane in valley wells was predominantly thermogenic in origin, likely as a result of close vertical proximity to underlying methane-bearing saline groundwater and brine and possibly as a result of enhanced bedrock fracture permeability beneath valleys that provides an avenue for upward gas migration. Isotopic signatures of methane from four upland well samples indicated a microbial origin (carbon-dioxide reduction) with one sample possibly altered by microbial methane oxidation. Water samples from wells in a valley setting that indicate a mix of thermogenic and microbial methane reflect the close proximity of regional groundwater flow and underlying saline water and brine in valley areas. The microbial methane is likely produced by bacteria that utilize carbon dioxide or formational organic matter in highly reducing environments within the subregional groundwater flow system. This characterization of groundwater methane shows the importance of subsurface information (hydrogeology, well construction) in understanding methane occurrence and provides an initial conceptual framework that can be utilized in investigation of stray gas in south-central New York.

New York