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Thomas E. Gill

Publications and source records attributed to Thomas E. Gill.

3 recordsLinked to original sources

Dust in the Critical Zone: North American case studies

The dust cycle facilitates the exchange of particles among Earth's major systems, enabling dust to traverse ecosystems, cross geographic boundaries, and even move uphill against the natural flow of gravity. Dust in the atmosphere is composed of a complex and ever-changing mixture that reflects the evolving human footprint on the landscape. The emission, transport, and deposition of dust interacts with and connects Critical Zone processes at all spatial and temporal scales. Landscape properties, land use, and climatic factors influence the wind erosion of soil and nutrient loss, which alters the long-term ecological dynamics at erosional locations. Once in the atmosphere, dust particles influence the amount of solar radiation reaching Earth, and interact with longwave (terrestrial) radiation, with cascading effects on the climate system. Finally, the wet and dry deposition of particles influences ecosystem structure, composition, and function over both short and long-term scales. Tracking dust particles from source to sink relies on monitoring and measurement of the geochemical composition and size distribution of the particles, space-borne and ground-based remote sensing, and dust modeling. Dust is linked to human systems via land use and policies that contribute to dust emissions and the health-related consequences of particulate loads and composition. Despite the significant influence dust has in shaping coupled natural-human systems, it has not been considered a key component of the Critical Zone. Here, we demonstrate that dust particles should be included as a key component of the Critical Zone by outlining how dust interacts with and shapes Earth System processes from generation, through transport, to deposition. We synthesize current understanding from global research and identify critical data and knowledge gaps while showcasing case studies from North America.

Earth-Science Reviews

Woody plant encroachment of grassland and the reversibility of shrub dominance: Erosion, fire, and feedback processes

Many grass-dominated ecosystems in dryland regions have experienced increasing woody plant density and abundance during the past century. In many cases, this process has led to land degradation and declines in ecosystem functions. An example is the Chihuahuan Desert in the southwestern United States, which experienced different stages of shrub encroachment in the past 150 years. Among a wide variety of mechanisms to explain the grass–shrub transitions in this dryland system, soil erosion (both wind and water) and fire are particularly well studied. Here, we synthesize recent developments on the drivers and feedback in the process of shrub encroachment in the Chihuahuan Desert through the intercomparison of two Long Term Ecological Research (LTER) sites, namely Jornada and Sevilleta. Experimental and modeling studies support a conceptual framework, which underscores the important roles of erosion and fire in woody plant encroachment. Collectively, research at the Jornada LTER provided complementary, quantitative support to the well-known fertile-islands framework. Studies at the Sevilleta LTER expanded the framework, adding fire as a major disturbance to woody plants. Conceptual models derived from the synthesis represent the general understanding of shrub encroachment that emerged from research at these two sites, and can guide management interventions aimed at reducing or mitigating undesirable ecosystem state change in many other drylands worldwide.

New Mexico

The role of hydrates, competing chemical constituents, and surface composition on CLNO2 formation

Atomic chlorine (Cl • ) affects air quality and atmospheric oxidizing capacity. Nitryl chloride (ClNO 2 ) – a common Cl • source–forms when chloride-containing aerosols react with dinitrogen pentoxide (N 2 O 5 ). A recent study showed that saline lakebed (playa) dust is an inland source of particulate chloride (Cl – ) that generates high ClNO 2 . However, the underlying physiochemical factors responsible for observed yields are poorly understood. To elucidate these controlling factors, we utilized single particle and bulk techniques to determine the chemical composition and mineralogy of playa sediment and dust samples from the southwest United States. Single particle analysis shows trace highly hygroscopic magnesium and calcium Cl-containing minerals are present and likely facilitate ClNO 2 formation at low humidity. Single particle and mineralogical analysis detected playa sediment organic matter that hinders N 2 O 5 uptake as well as 10 Å-clay minerals (e.g., Illite) that compete with water and chloride for N 2 O 5 . Finally, we show that the composition of the aerosol surface, rather than the bulk, is critical in ClNO 2 formation. These findings underscore the importance of mixing state, competing reactions, and surface chemistry on N 2 O 5 uptake and ClNO 2 yield for playa dusts and, likely, other aerosol systems. Therefore, consideration of particle surface composition is necessary to improve ClNO 2 and air quality modeling.

Environmental Science Technology