Geology topics

Terry F. Rees

Publications and source records attributed to Terry F. Rees.

5 recordsLinked to original sources

USGS2017

The effect of composition of selected groundwaters from the Basin and Range Province on plutonium, neptunium, and Americium speciation

The speciation of plutonium, neptunium, and americium was determined in groundwaters from four sources in the Basin and Range Province: the lower carbonate aquifer, Nevada Test Site (NTS) (Crystal Pool); alluvial fill, Frenchman Flat, NTS (well 5C); Hualapai Valley, Arizona (Red Lake south well); and Tularosa Basin, New Mexico (Rentfrow well). The results were interpreted to indicate that plutonium and, to a lesser extent, neptunium are least soluble in reducing groundwaters containing a large concentration of sulfate ion and a small concentration of strongly complexing anions. The results further emphasize the desirability of including studies such as this among the other site-selection criteria for nuclear waste repositories.

Arizoan, Nevada, New Mexico↗

USGS2010

Comparison of photon correlation spectroscopy with photosedimentation analysis for the determination of aqueous colloid size distributions

Colloidal materials, dispersed phases with dimensions between 0.001 and 1 μm, are potential transport media for a variety of contaminants in surface and ground water. Characterization of these colloids, and identification of the parameters that control their movement, are necessary before transport simulations can be attempted. Two techniques that can be used to determine the particle-size distribution of colloidal materials suspended in natural waters are compared. Photon correlation Spectroscopy (PCS) utilizes the Doppler frequency shift of photons scattered off particles undergoing Brownian motion to determine the size of colloids suspended in water. Photosedimentation analysis (PSA) measures the time-dependent change in optical density of a suspension of colloidal particles undergoing centrifugation. A description of both techniques, important underlying assumptions, and limitations are given. Results for a series of river water samples show that the colloid-size distribution means are statistically identical as determined by both techniques. This also is true of the mass median diameter (MMD), even though MMD values determined by PSA are consistently smaller than those determined by PCS. Because of this small negative bias, the skew parameters for the distributions are generally smaller for the PCS-determined distributions than for the PSA-determined distributions. Smaller polydispersity indices for the distributions are also determined by PCS.

Water Resources Research↗

USGS2002

Notes. Characterization of plutonium in ground water near the idaho chemical processing plant

Plutonium is present in very low concentrations in ground water near the disposal well at the Idaho Chemical Processing Plant but was not detected in waters at greater distances. Because of the absence of strong complexing agents, the plutonium is present as an uncomplexed (perhaps hydrolyzed) tetravalent species, which is readily precipitated or sorbed by basalt or sediments along the ground-water flow path.

Idaho↗

USGS1998

Geohydrology of the Winchester Subbasin, Riverside County, California

The 20-square-mile Winchester structural subbasin is an alluvium-filled paleocanyon that is as much as 900 feet deep. The alluvial aquifer is composed of detrital material that generally ranges in size from clay to fine gravel; the fine and coarse materials are mixed in some places and inter- bedded in others. The apparent lenticularity of fine- and coarse-grained materials and differing water quality with depth indicate that the aquifer is partly or locally confined. A ground-water divide exists east of the town of Winchester. West of the divide, ground water moves toward and into the South Perris and the Menifee subbasins. East of the divide, ground water moves toward and into the Hemet subbasin. The components of flow direction in the Winchester?Hemet subbasins border area are complex: along the border, some water moves from the southwest corner of the Hemet subbasin into the Winchester subbasin and then eastward subparallel to the border before moving back into the Hemet subbasin. The direction of ground-water movement between the Winchester and Hemet subbasins, and the position of the ground-water divide in the central part of the Winchester subbasin, have changed with time. Prior to about 1974, ground water moved both eastward from the divide and westward from the Hemet subbasin toward a local depression of the water table caused by pumping in the eastern part of the Winchester subbasin. Comparison of spring 1970 and spring 1993 ground-water levels indicates a net rise of as much as 150 feet in the east end of the Winchester subbasin. For this same period, water levels rose about 3 to 20 feet in the western and central parts of the subbasin. Ground-water chemistry in the Winchester subbasin and adjacent subbasins varies areally and vertically. In general, sodium, calcium, chloride, and sulfate are dominant ions. Water quality is generally poor: dissolved-solids concentration exceeded 2,000 milligrams per liter throughout much of the subbasin and was highest west of the town of Winchester. Eastward along the subbasin axis (toward the Hemet subbasin), the dissolved-solids concentration decreases and the pH increases (generally greater than 7.0). Samples from two multiple-well monitoring sites at the west and east ends of the subbasin indicate that the best quality water (dissolved-solids concentrations of 395 and 483 milligrams per liter) is from the deepest wells (perforated near the alluvium- bedrock contact). Samples from the deeper wells in the eastern part of the Winchester subbasin are similar in water type to a sample from a well in the western part of the Hemet subbasin, which suggests that the water may have flowed from the Hemet subbasin; alternatively, the chemistry may reflect the influence of good-quality water flowing from the fractured bedrock basement to the alluvium in the eastern part of the Winchester subbasin. In addition, the potential problem of poor-quality water moving from the Winchester subbasin into the Hemet subbasin may not exist at all depths; fair- to good-quality water may be present below a depth of about 450 feet. Dissolved-solids concentrations in the southwest part of the Hemet subbasin ranged from about 900 milligrams per liter at well 5S/1W-19Q1 about one-quarter mile north of the Winchester?Hemet subbasin boundary to about 3,500 milligrams per liter at well 5S/2W-24C2 near the bedrock outcrops southeast of the Lakeview Mountains. High dissolved-solids concentration in the vicinity of well 5S/2W-24C2 most likely is a result of dissolution of constituents from the aquifer matrix, evaporative processes, and agricultural practices that occur in that vicinity rather than a result of flow from the Winchester subbasin. Aquifer-test results indicate that the transmissivity is about 950 feet squared per day in the eastern part of the Winchester subbasin near the boundary with the Hemet subbasin and about 72 feet squared per day in the western part of the subbasin near the boundary with th

California↗

USGS1995

Geohydrology, water quality, and nitrogen geochemistry in the saturated and unsaturated zones beneath various land uses, Riverside and San Bernardino counties, California, 1991-93

The U.S. Geological Survey, in cooperation with the Eastern Municipal Water District, the Metropolitan Water District of Southern California, and the Orange County Water District, has completed a detailed study of the Hemet groundwater basin. The quantity of ground water stored in the basin in August 1992 is estimated to be 327,000 acre-feet. Dissolved-solids concentration ranged from 380 to 700 mg/L (milligrams per liter), except in small areas where the concentration exceeded 1,000 mg/L. Nitrate concentrations exceeded the U.S. Environmental Protection Agency Maximum Contaminant Level (MCL) of 10 mg/L nitrate (as nitrogen) in the southeastern part of the basin, in the Domenigoni Valley area, and beneath a dairy in the Diamond Valley area. Seven sites representing selected land uses-- residential, turf grass irrigated with reclaimed water, citrus grove, irrigated farm, poultry farm, and dairy (two sites)--were selected for detailed study of nitrogen geochemistry in the unsaturated zone. For all land uses, nitrate was the dominant nitrogen species in the unsaturated zone. Although nitrate was seasonally present in the shallow unsaturated zone beneath the residential site, it was absent at moderate depths, suggesting negligible migration of nitrate from the surface at this time. Microbial denitrification probably is occurring in the shallow unsaturated zone. High nitrate concentrations in the deep unsaturated zone (greater than 100 ft) suggest either significantly higher nitrate loading at some time in the past, or lateral movement of nitrate at depth. Nitrate also is seasonally present in the shallow unsaturated zone beneath the reclaimed-water site, and (in contrast with the residential site), nitrate is perennially present in the deeper unsaturated zone. Microbial denitrification in the unsaturated zone and in the capillary fringe above the water table decreases the concentrations of nitrate in pore water to below the MCL before reaching the water table. Pore water in the unsaturated zone beneath the citrus grove site contains very high concentrations of nitrate. Even though there are zones of microbial denitrification, nitrate seems to be migrating downward to the water table. The presence of a shallow perched-water zone beneath the irrigated-farm site prevents the vertical movement of nitrate from the surface to the regional water table. Above the perched zone, nitrate concentrations in the unsaturated zone are variable, ranging from below the MCL to four times the MCL. Periodically, nitrate is flushed from the shallow unsaturated zone to the perched-water zone. The unsaturated zone pore-moisture quality could not be adequately addressed because of the very dry conditions in the unsaturated zone beneath the poultry-farm site. Surficial clay deposits prevent water from percolating downward. At the two dairy sites, nitrate loading in pore water at the surface was very high, as great as 7,000 mg/L. Microbial denitrification in the unsaturated zone causes such concentrations to decrease rapidly with depth. At a depth of 20 ft, nitrate concentration was less than 100 mg/L. In areas where the depth to water is less than 20 ft, nitrate loading to ground water can be very high, whereas in areas where depth to water is greater than 100 ft, most of the nitrate is microbially removed before reaching the water table.

California↗