Geology topics

Terrence Blackburn

Publications and source records attributed to Terrence Blackburn.

4 recordsLinked to original sources

USGS2025

Kiloyear cycles of carbonate and Mg-silicate replacement at Von Damm hydrothermal vent field

The Von Damm vent field (VDVF) on the Mid-Cayman Rise in the Caribbean Sea is unique among modern hydrothermal systems in that the chimneys and mounds are almost entirely composed of talc. We analyzed samples collected in 2020 and report that in addition to disordered talc of variable crystallinity, carbonates are a major class of mineral at VDVF. The carbonate minerals include aragonite, calcite, magnesium-rich calcite, and dolomite. Talc and carbonate mineral textures indicate that, rather than replacing volcanic host rock, they precipitate from the mixing of hydrothermal fluids and seawater at the seafloor, occurring in chimneys and surrounding rubble. Alternating precipitation of this mineral assemblage is pervasive, with carbonate minerals typically being succeeded by talc, and with indications that in some cases talc and carbonate minerals replace one another. Stable carbon isotopic data indicate the carbonate minerals originate from the mixing of seawater and hydrothermal fluid, which is supported by U-Th data. Radiocarbon calcite ages and talc 234 U- 230 Th isochron ages indicate mineral ages spanning over thousands to tens of thousands of years. Analyses of these samples illustrate a dynamic system that transitions from carbonate-dominated to Mg-silicate−dominated precipitation over time scales of thousands of years. Our observations raise questions regarding the eventual fate of seafloor precipitates and whether carbonate and silicate minerals in such settings are sequestered and represented in the rock record.

Geology↗

USGS2025

Bølling-Allerød productivity in the subarctic Pacific driven by seasonal upwelling

The Bølling-Allerød deglacial event is marked by high diatom productivity and opal deposition throughout the subarctic Pacific. This opal could either constitute a strengthened biological pump and thus carbon sequestration, or a weakened biological pump and release of marine-sequestered CO 2 to the atmosphere. We quantify silicic acid supply at IODP Site U1340 in the Bering Sea using biogenic opal and δ 30 Si of Coscinodiscus , a diatom genus. These records, along with diatom environmental indicators, suggest the Bølling-Allerød had high silicic acid availability related to a shift from stratification to seasonal upwelling dynamics. We thus propose the primary cause of the high productivity event was increased macronutrient supply from vertical exchange that injected old, nutrient-rich, CO 2 -rich waters into the surface. Enhanced CO 2 release from the subarctic Pacific may help explain critical intervals of CO 2 rise that occur at the onsets of the Bølling-Allerød and PreBoreal.

Geophysical Research Letters↗

USGS2025

The influence of nodule versus crust morphology on the composition of seamount-hosted ferromanganese minerals

Ferromanganese mineral precipitation in the global oceans is ubiquitous, occurring in the form of both crusts and nodules at a broad range of depths and seafloor terrains. Although ferromanganese crusts and nodules are both composed of ferromanganese minerals, mineralogy and mean element concentrations compiled for regional crust versus nodule occurrences differ. Notably, most published compilations compare nodules from abyssal plain sediments to crusts forming on seamounts, and do not address the question as to whether mineral morphology may affect the composition of crusts and nodules in addition to environmental factors. To address this, we have compiled a dataset of co-located hydrogenetic (seawater sourced) open-ocean ferromanganese crusts and seamount-hosted nodules. The preliminary data presented here support our hypothesis that co-located crusts and nodules exhibit similar compositions, both in terms of their mineralogy and mean element concentrations, as well as overall variance in concentrations for any given element. These data indicate that local processes influence sample-to-sample variation in both crusts and nodules, in contrast to broader ferromanganese variation reported between open-ocean seamounts- hosted crusts and abyssal plain-hosted nodules.

Conference Paper↗

USGS2020

Genesis and evolution of ferromanganese crusts from the summit of Rio Grande Rise, southwest Atlantic Ocean

The Rio Grande Rise (RGR) is a large elevation in the Atlantic Ocean and known to host potential mineral resources of ferromanganese crusts (Fe–Mn), but no investigation into their general characteristics have been made in detail. Here, we investigate the chemical and mineralogical composition, growth rates and ages of initiation, and phosphatization of relatively shallow-water (650–825 m) Fe–Mn crusts dredged from the summit of RGR by using computed tomography, X-ray diffraction, 87 Sr/ 86 Sr ratios, U–Th isotopes, and various analytical techniques to determine their chemical composition. Fe–Mn crusts from RGR have two distinct generations. The older one has an estimated age of initiation around 48–55 Ma and was extensively affected by post-depositional processes under suboxic conditions resulting in phosphatization during the Miocene (from 20 to 6.8 Ma). As a result, the older generation shows characteristics of diagenetic Fe–Mn deposits, such as low Fe/Mn ratios (mean 0.52), high Mn, Ni, and Li contents and the presence of a 10 Å phyllomanganate, combined with the highest P content among crusts (up to 7.7 wt %). The younger generation is typical of hydrogenetic crusts formed under oxic conditions, with a mean Fe/Mn ratio of 0.75 and mean Co content of 0.66 wt %, and has the highest mean contents of Bi, Nb, Ni, Te, Rh, Ru, and Pt among crusts formed elsewhere. The regeneration of nutrients from local biological productivity in the water column is the main source of metals to crusts, providing mainly metals that regenerate rapidly in the water column and are made available at relatively shallow water depths (Ni, As, V, and Cd), at the expense of metals of slower regeneration (Si and Cu). Additionally, important contributions of nutrients may derive from various water masses, especially the South Atlantic Mode Water and Antarctic Intermediate Water (AAIW). Bulk Fe–Mn crusts from the summit of RGR plateau are generally depleted in metals considered of greatest economic interest in crusts like Co, REE, Mo, Te, and Zr, but are the most enriched in the critical metals Ni and Li compared to other crusts. Further investigations are warranted on Fe–Mn crusts from deeper-water depths along the RGR plateau and surrounding areas, which would less likely be affected by phosphatization.

Rio Grande Rise↗