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Taryn Lopez

Publications and source records attributed to Taryn Lopez.

At least 19 recordsLinked to original sources

Erupted volume during the 2014–2023 Semisopochnoi unrest and eruption constrained by multi-platform InSAR and volcanic gas observations

Volcano deformation data provide important constraints on magma dynamics during volcanic unrest and eruptions. From these observations, we can estimate subsurface pressure changes and relate them to volume change in the reservoir. However, because magma and rock are compressible, this volume change cannot be directly equated with eruptive volume. When we combine geodetic analyses with gas observations, petrologic constraints, volatile solubility modeling, and magma compressibility equations, however, we can estimate realistic lower and upper bounds of eruptive volume. Leveraging multi‐platform InSAR time series and satellite SO 2 data, we apply these methods to the 2014–2023 unrest and eruption of Semisopochnoi, Alaska. We find that this phreatomagmatic eruption sequence was fed by a spherical magma source at 6.5–7.5 km depth bsl, centered beneath the caldera, ∼5 km offset to the east from the vent. Volatile solubility modeling indicates that ∼50% of the initial dissolved CO 2 has exsolved at depths consistent with the geodetic source depth, increasing the magma compressibility. Combining geodetic model constraints with SO 2 observations, petrologic constraints, solubility models, and magma compressibility findings yields 12–32 Mm 3 as the most‐likely juvenile, dense‐rock equivalent eruptive volume, with a best estimate of 20 Mm 3 . Stress change modeling suggests that the local stress field encouraged conduit formation west of the pre‐eruptive inflation center, and that the 2014 M7.9 Rat Island earthquake, ∼65 km to the west of Semisopochnoi, reduced the compressive stress underneath the volcano, supporting prolonged eruptive activity.

Alaska↗

Identifying precursors and tracking pulses of magma ascent in multidisciplinary data during the 2018–2023 phreatomagmatic eruption at Semisopochnoi Island, Alaska

The 2018–2023 phreatomagmatic eruptions at Semisopochnoi Island, Alaska produced abundant long-period (LP) seismicity, harmonic and broadband tremor, and explosion signals over several well-monitored periods of eruption and quiescence. The corresponding dataset provides an excellent opportunity to investigate precursory and syn -eruptive geophysical signals of long-lived phreatomagmatic eruptions using multiparameter observations. We generated explosion and LP event catalogs through novel implementations of the REDPy ( Hotovec-Ellis, 2024 ) repeating event detector in mid-2021 following a network upgrade and the onset of a new phase of the eruption. The hundreds of detected explosions show a high degree of infrasound waveform similarity over more than a year, indicating a repeating source mechanism likely associated with explosive magma-water interaction. The seismic LP catalog shows that events began over a month prior to renewed explosive activity at the beginning of August 2021, and that lower frequency index (FI) LPs were generated in the week prior to the onset of explosions. We applied a recently developed machine learning tool (VOISS-Net, Tan et al., 2024 ) to catalog abundant broadband and harmonic seismic tremor recorded before and during the renewed explosive activity, along with LPs and explosions. The tremor catalogs complement the LP and explosion catalogs by filling out the seismic sequence with the dominant signal types. Together, these catalogs reveal a seismic sequence of renewed unrest that started with several weeks of LP events, followed by LPs with lower FI values and harmonic tremor in the days prior to explosive activity, and finally the onset of discrete explosions and broadband eruption tremor. We interpret this sequence as the ascent of a new pulse of magma that first interacted with the hydrothermal/groundwater system to produce LPs, followed by harmonic tremor, and that ultimately drove explosive magma-water interactions and periods of continuous ash emissions. The 2021 seismic sequence, in combination with long-term records of satellite SO 2 emissions, deformation from interferometric synthetic aperture radar (InSAR) analysis, ash sample analysis, infrasound, and volcano tectonic seismicity, allows us to interpret the entire 9-year period of unrest and eruption that began with an intrusion and earthquake swarm in 2014.

Alaska↗

Vent-specific unrest at Pavlof Volcano, Alaska: Insights from multidisciplinary data

Pavlof Volcano, a frequently active volcano in the Aleutian arc, has erupted six times between 2007 and 2022. Many Pavlof Volcano eruptions lack detectable precursory seismicity or ground deformation, making them challenging to forecast. Since 2007, these eruptions have ranged from Strombolian to Subplinian (VEI 2–3), with their characteristics seemingly related to their active vent location. Summit vent eruptions tend to be abrupt and explosive, while southeast flank vent eruptions tend to be more effusive and longer-lived. To better understand Pavlof Volcano’s plumbing system and improve eruption forecasts, we integrate geophysical, petrologic, and satellite-based thermal infrared and gas data to conduct a multidisciplinary data synthesis for eruptions between 2007 and 2022. Notably, a recently developed volcano seismicity detection model reveals unique pre- and syn-eruptive seismic tremor regimes associated with each vent system. The summit vent eruptions show greater tremor diversity and resurgent eruptive behavior, whereas the southeast flank vent eruptions show a steady tremor transition over a single eruptive phase. We use local infrasound data and air-to-ground coupled waves to build explosion catalogs, revealing gas-rich explosions during the 2021–2022 eruption from the summit vent, which was previously thought to be inactive during that eruption. Whole-rock composition and ash analyses indicate a near-uniform basaltic andesite composition spanning multiple eruptions, and a consistent anomalous presence of altered olivines in erupted material. We use these findings to propose a new conceptual model for Pavlof Volcano’s plumbing system: a shallow T-junction outlet controlling seismic tremor diversity and the partitioning of gas-charged magma; and an elongated, heated conduit transporting magma from depth and storing partly molten, residual magma between eruptions. We suggest that magma ascent rate and vent sealing modulate eruption style at Pavlof Volcano, where the T-junction directs rapidly ascending, gas-rich magma to the summit vent, and diverts slower rising, gas-poor magma towards the southeast flank vent.

Alaska↗

From field station to forecast: Managing data at the Alaska Volcano Observatory

The Alaska Volcano Observatory (AVO) uses multidisciplinary data to monitor and study dozens of active and potentially active volcanoes. Here, we provide an overview of internally and externally generated data types, tools and resources used in their management, and challenges faced. Data sources include the following: (1) a multiparameter (seismic, infrasound, GNSS, web cameras) ground-based monitoring network that spans 3000 km and transmits data in real time; (2) a variety of satellite-borne sensors that provide information about surface change and volcanic emissions; (3) geologic and gas field campaigns; and (4) other external data products that provide situation awareness. Each data type requires distinct acquisition, processing, storage, visualization, and archiving approaches. AVO uses a variety of externally and internally developed tools to handle individual data types as well as multidisciplinary volcanological data. A primary tool is the Geologic Database of Information on Volcanoes in Alaska (GeoDIVA), which stores detailed, searchable information on more than 140 volcanoes and over 1000 eruptions and unrest events, including images, eruption descriptions, and geologic station and sample data, metadata, and analyses. It interacts with other internal tools that store monitoring reports and other operational records. Additional data management resources used by AVO assist with alarms and alerts, state-of-health monitoring, and multiparameter visualization. Requirements for 24/7 accessibility, the ever-expanding portfolio of data, and transitioning new tools from development to operations are all challenges faced by AVO and other volcano observatories. AVO strives to meet FAIR data practices and ensure that data are available to national and international community efforts using external repositories as well as those hosted by AVO and its parent institutions.

Alaska↗

Automatic identification and quantification of volcanic hotspots in Alaska using HotLINK: The hotspot learning and identification network

An increase in volcanic thermal emissions can indicate subsurface and surface processes that precede, or coincide with, volcanic eruptions. Space-borne infrared sensors can detect hotspots—defined here as localized volcanic thermal emissions—in near-real-time. However, automatic hotspot detection systems are needed to efficiently analyze the large quantities of data produced. While hotspots have been automatically detected for over 20 years with simple thresholding algorithms, new computer vision technologies, such as convolutional neural networks (CNNs), can enable improved detection capabilities. Here we introduce HotLINK: the Hotspot Learning and Identification Network, a CNN trained to detect hotspots with a dataset of −3,800 satellite-based, Visible Infrared Imaging Radiometer Suite (VIIRS) images from Mount Veniaminof and Mount Cleveland volcanoes, Alaska. We find that our model achieves an accuracy of 96% (F1-score 0.92) when evaluated on −1,700 unseen images from the same volcanoes, and 95% (F1-score 0.67) when evaluated on −3,000 images from six additional Alaska volcanoes (Augustine Volcano, Bogoslof Island, Okmok Caldera, Pavlof Volcano, Redoubt Volcano, Shishaldin Volcano). In comparison with an existing threshold-based hotspot detection algorithm, MIROVA (Coppola et al., Geological Society, London, Special Publications, 2016, 426, 181–205), our model detects 22% more hotspots and produces 12% fewer false positives. Additional testing on −700 labeled Moderate Resolution Imaging Spectroradiometer (MODIS) images from Mount Veniaminof demonstrates that our model is applicable to this sensor’s data as well, achieving an accuracy of 98% (F1-score 0.95). We apply HotLINK to 10 years of VIIRS data and 22 years of MODIS data for the eight aforementioned Alaska volcanoes and calculate the radiative power of detected hotspots. From these time series we find that HotLINK accurately characterizes background and eruptive periods, similar to MIROVA, but also detects more subtle warming signals, potentially related to volcanic unrest. We identify three advantages to our model over its predecessors: 1) the ability to detect more subtle volcanic hotspots and produce fewer false positives, especially in daytime images; 2) probabilistic predictions provide a measure of detection confidence; and 3) its transferability, i.e., the successful application to multiple sensors and multiple volcanoes without the need for threshold tuning, suggesting the potential for global application.

Alaska↗

2020 Volcanic activity in Alaska—Summary of events and response of the Alaska Volcano Observatory

The Alaska Volcano Observatory responded to eruptions, volcanic unrest or suspected unrest, increased seismicity, and other significant activity at nine volcanic centers in Alaska in 2020. The most notable volcanic activity in 2020 was an eruption of Shishaldin Volcano, which produced lava flows, lahars, and ash. Mount Cleveland had one small ash-producing eruption in June but was quiet thereafter. Other activity documented in 2020 consisted of elevated seismicity at the volcanoes Mount Veniaminof, Pavlof Volcano, Makushin Volcano, Atka volcanic complex (Korovin Volcano), Great Sitkin Volcano, and Semisopochnoi Island. Finally, the resuspension of ash deposited during the 1912 Novarupta-Katmai eruption was documented on three occasions.

Alaska↗

Estimates of volcanic mercury emissions from Redoubt Volcano, Augustine Volcano, and Mount Spurr eruption ash

Ash is a potential sink of volcanically sourced atmospheric mercury (Hg), and the concentration of particle-bound Hg may provide constraints on Hg emissions during eruptions. We analyze Hg concentrations in 227 bulk ash samples from the Mount Spurr (1992), Redoubt Volcano (2009), and Augustine Volcano (2006) volcanic eruptions to investigate large-scale spatial, temporal, and volcanic-source trends. We find no significant difference in Hg concentrations in bulk ash by distance or discrete eruptive events at each volcano, suggesting that in-plume reactions converting gaseous Hg 0 to adsorbed Hg 2+ are happening on shorter timescales than considered in this study (minutes) and any additional in-plume controls are not discernable within intra-volcanic sample variability. However, we do find a significant difference in Hg concentration of ash among volcanic sources, which indicates that volcanoes may emit comparatively high or low quantities of Hg. We combine our Hg findings with total mass estimates of ashfall deposits to calculate minimum, first-order Hg emissions of 8.23 t Hg for Mount Spurr (1992), 1.25 t Hg for Redoubt Volcano (2009), and 0.16 t Hg for Augustine Volcano (2006). In particular, we find that Mount Spurr is a high Hg emitting volcano, and that its 1992 particulate Hg emissions likely contributed substantially to the global eruptive volcanic Hg budget for that year. Based on our findings, previous approaches that use long-term Hg/SO 2 mass ratios to estimate eruptive total Hg under-account for Hg emitted in explosive events, and global volcanogenic Total Hg estimates need revisiting.

Alaska↗

Tracking carbon from subduction to outgassing along the Aleutian-Alaska Volcanic Arc

Subduction transports volatiles between Earth’s mantle, crust, and atmosphere, ultimately creating a habitable Earth. We use isotopes to track carbon from subduction to outgassing along the Aleutian-Alaska Arc. We find substantial along-strike variations in the isotopic composition of volcanic gases, explained by different recycling efficiencies of subducting carbon to the atmosphere via arc volcanism and modulated by subduction character. Fast and cool subduction facilitates recycling of ~43 to 61% sediment-derived organic carbon to the atmosphere through degassing of central Aleutian volcanoes, while slow and warm subduction favors forearc sediment removal, leading to recycling of ~6 to 9% altered oceanic crust carbon to the atmosphere through degassing of western Aleutian volcanoes. These results indicate that less carbon is returned to the deep mantle than previously thought and that subducting organic carbon is not a reliable atmospheric carbon sink over subduction time scales.

Alaska↗

Quantifying eruptive and background seismicity, deformation, degassing, and thermal emissions at volcanoes in the United States during 1978–2020

An important aspect of volcanic hazard assessment is determination of the level and character of background activity at a volcano so that deviations from background (called unrest) can be identified. Here, we compile the instrumentally recorded eruptive and noneruptive activity for 161 US volcanoes between 1978 and 2020. We combine monitoring data from four techniques: seismicity, ground deformation, degassing, and thermal emissions. To previous work, we add the first comprehensive survey of US volcanoes using medium-spatial resolution satellite thermal observations, newly available field surveys of degassing, and new compilations of seismic and deformation data. We report previously undocumented thermal activity at 30 volcanoes using data from the spaceborne ASTER sensor during 2000–2020. To facilitate comparison of activity levels for all US volcanoes, we assign a numerical classification of the Activity Intensity Level for each monitoring technique, with the highest ranking corresponding to an eruption. There are 96 US volcanoes (59%) with at least one type of detected activity, but this represents a lower bound: For example, there are 12 volcanoes where degassing has been observed but has not yet been quantified. We identify dozens of volcanoes where volcanic activity is only measured by satellite (45% of all thermal observations), and other volcanoes where only ground-based sensors have detected activity (e.g., all seismic and 62% of measured degassing observations). Our compilation provides a baseline against which future measurements can be compared, demonstrates the need for both ground-based and remote observations, and serves as a guide for prioritizing future monitoring efforts.

Journal of Geophysical Research↗

Linking subsurface to surface using gas emission and melt inclusion data at Mount Cleveland volcano, Alaska

Mount Cleveland is one of Alaska's most active volcanoes, yet little is known about the magmatic system driving persistent and dynamic volcanic activity. Volcanic gas and melt inclusion (MI) data from 2016 were combined to investigate shallow magmatic processes. SO 2 emission rates were between 166 and 324 t/day and the H 2 O/SO 2 was 600 ± 53, whereas CO 2 and H 2 S were below detection. Olivine‐, clinopyroxene‐, and plagioclase‐hosted MIs have up to 3.8 wt.% H 2 O, 514 ppm CO 2 , and 2,320 ppm S. Equilibration depths, based on MI H 2 O contents, suggest that a magmatic column extended from 0.5 to 3.0 km (~10–60 MPa). We used MI data to empirically model open‐system H‐C‐S degassing from 0 to 12 km and found that a column of magma between 0.5 and 3 km could produce the measured gas H 2 O/SO 2 ratio. However, additional magma deeper than 3 km is required to sustain emissions over periods greater than days to weeks, if the observed vent dimension is a valid proxy for the conduit. Assuming an initial S content of 2,320 ppm, the total magma supply needed to sustain the annual SO 2 flux was 5 to 9.8 Mm 3 /yr, suggesting a maximum intrusive‐to‐extrusive ratio of 13:1. The model predicts degassing of <50 t/day CO 2 for July 2016, which corresponds to a maximum predicted CO 2 /SO 2 of 0.2. Ultimately, frequent recharge from deeper, less degassed magma is required to drive the continuous activity observed over multiple years. During periods of recharge we would expect lower H 2 O/SO 2 and measurable volcanic CO 2 .

Alaska↗

Forecasting, detecting, and tracking volcanic eruptions from space

Satellite monitoring of volcanic activity typically includes four primary observations: (1) deformation and surface change, (2) gas emissions, (3) thermal anomalies, and (4) ash plumes. These phenomena are imaged by remote sensing data that span the electromagnetic spectrum, from microwave to ultraviolet energy and including visible and infrared wavelengths. The primary uses of satellite data in volcanology are forecasting, detecting, and tracking eruptive activity. Eruptions are often preceded by a number of indicators that are detectable from space, including surface deformation, subtle increases in surface temperature, and elevated gas emissions. The first indications of eruption, especially at remote volcanoes, are often identified in satellite data by strong thermal anomalies and/or the presence of ash and gas in the atmosphere, the recognition of which can be automated for rapid eruption detection. Once an eruption is in progress, space-based imagery of all types can track activity over time, providing information on the emplacement of volcanic deposits, the presence and character of ash plumes, and potential changes in the character of the eruption, all of which aid hazards assessment. Activity at Agung volcano, Indonesia, during 2017–2019, offers an excellent example of the importance of remote sensing datasets for forecasting, detecting, and tracking eruptions. Challenges to exploiting current and future satellite data include ensuring regular acquisitions over active volcanoes and developing tools for automated analysis of the massive volume of imagery for volcano-related signals.

Remote Sensing in Earth Systems Sciences↗

Constraints on eruption processes and event masses for the 2016–2017 eruption of Bogoslof volcano, Alaska, through evaluation of IASI satellite SO2 masses and complementary datasets

Bogoslof volcano, Alaska, experienced at least 70 explosive eruptions between 12 December 2016 and 31 August 2017. Due to its remote location and limited local monitoring network, this eruption was monitored and characterized primarily using remote geophysical and satellite techniques. SO 2 emissions from Bogoslof were persistently detected by the Infrared Atmospheric Sounding Interferometer (IASI) satellite sensors. Of Bogoslof’s 70 explosive events, 50% produced measurable SO 2 masses ranging from 0.1 to 21.5 kt, with a median and standard deviation of 0.7 ± 4.0 kt SO 2 , respectively. Here, we compare IASI-derived SO 2 masses from Bogoslof events to complementary geophysical datasets to provide insights into eruption source processes, namely the degree of seawater scrubbing of water-soluble SO 2 and variations in magma flux. Correlations with the number of lightning strokes and infrasound energy are expected to indicate magma-flux as a controlling process, while correlations with infrasound frequency index are expected to indicate variations in vent-water content as a controlling factor. These comparisons suggest that the measured SO 2 masses are primarily a function of eruption magnitude (degassed magma mass) and that scrubbing of SO 2 emissions by vent seawater may have exerted a minor effect on the observed SO 2 masses. SO 2 masses were combined with petrologic constraints on melt inclusion and matrix glass S concentrations to calculate degassed magma masses and volumes. The cumulative SO 2 -derived degassed magma mass and estimated volume (dense-rock equivalent) for the full Bogoslof eruption were found to be 2.8 × 10 10 kg and 9.3 × 10 6 m 3 , respectively. When individual event masses are compared against event masses calculated using an empirical plume-height method, a strong correlation is found ( R 2 = 0.83), with better than order-of-magnitude agreement in most cases. These estimates of eruption masses provide useful information on the magnitude, behavior, and associated hazards of the 2016–2017 eruption, and potentially future unrest at Bogoslof volcano.

Alaska↗

Using conceptual models to relate multiparameter satellite data to subsurface volcanic processes in Latin America

Satellite data have been extensively used to identify volcanic behavior. However, the physical subsurface processes causing any individual manifestation of activity can be ambiguous. We propose a classification scheme for the cause of unrest that simultaneously considers three multiparameter satellite observations. The scheme is based on characteristics of the volcanic system (open, closed, and eruptive) and unrest mechanisms (intrusion, evolution, and withdrawal) occurring at shallow depths in the volcanic system. We applied these models to satellite observations acquired at 47 of the most active volcanoes in Latin America. Of the volcanoes studied, 44 had a robust enough dataset for classification and were clustered into 4 groups and 10 subgroups with common behavioral characteristics. By identifying that these volcanoes can be clustered into a number of groupings significantly less than the number of volcanoes, we have demonstrated that commonalities in behavior patterns exist among diverse volcanic systems. Identifying volcanoes with similar characteristics underpins the use of past observations at one volcano to forecast activity at another and diverges from typical volcanic groupings, which are focused on geologic parameters (i.e., composition, volcano type, and tectonic setting). Based on satellite data alone, we have identified preeruptive intrusion prior to 15 eruptions at 12 different volcanoes, magma evolution prior to 18 eruptions at 13 volcanoes, and magma withdrawal at 3 eruptions and 3 volcanoes. Improvements to the spatial and temporal resolution are needed to make these relations robust. This classification scheme provides a framework for future automated clustering of volcanoes.

Geochemistry, Geophysics, Geosystems↗

A post-eruption study of gases and thermal waters at Okmok Volcano, Alaska

We report here on the first focused study of gas discharges and thermal spring waters at Okmok Volcano since the 2008 phreatomagmatic eruptions. Results include the first compositional gas data from Okmok with minimal air contamination and the first data on magmatic carbon in Okmok spring waters. Chemical and isotopic analyses of the waters and gases are used to assess the character of Okmok fluids eight years after the eruptions ceased. Gases from vents on intracaldera Cone C have high concentrations of H2 and contain H2S rather than SO2, demonstrating the influence of a hydrothermal system, while isotope values of carbon ( 10.2 to 8.9‰) and helium (~8 RA) confirm the presence of magma-derived volatiles. Estimates of equilibrium temperatures for the Cone C gas are ~230 ± 30 ºC. A much cooler reservoir with a maximum temperature of ~55 ºC feeds the intracaldera warm springs. Based on discharge measurements of creeks draining the caldera, the total heat output of the warm springs is estimated to be about 32 MW. Gas data from a single location of steaming ground at the Geyser Bight geothermal area southwest of the Okmok Caldera are given. The gas is typical of geothermal gases with high concentrations of H2S and an air-corrected helium isotope ratio of 7.15 RA.

Alaska↗

Seismo-acoustic evidence for vent drying during shallow submarine eruptions at Bogoslof volcano, Alaska

Characterizing the state of the volcanic vent is key for interpreting observational datasets and accurately assessing volcanic hazards. This is particularly true for remote, complex eruptions such as the 2016–2017 Bogoslof volcano, Alaska eruption sequence. Bogoslof’s eruptions in this period were either shallow submarine or subaerial, or some combination of both. Our results demonstrate how low-frequency sound waves (infrasound), integrated with seismic and satellite data, can provide unique insight into shallow vent processes, otherwise not available. We use simple metrics, such as the infrasound frequency index (FI), event duration, and acoustic-seismic amplitude ratio, to look at changes in the elastic energy radiation and infer changes in seawater access to the vent. Satellite imagery before and after selected eruptions is used to ground-truth inferences on vent conditions. High FI and gradual increases in infrasound frequency content at Bogoslof correspond with transitions from submarine to subaerial vent conditions and a diminished or absent role of water, likely resulting in a drying out of the vent region. Event durations generally correlate with high FI and the range of FI values for each event, suggesting long duration events were more effective at drying out the vent region. A trend from low to high acoustic-seismic amplitude ratios for some long duration events also suggests an increase in acoustic efficiency as the vent dried out. We demonstrate that infrasound can serve as a robust indicator of seawater involvement for Bogoslof and other shallow submarine eruptions that may not be inferable from other datasets, particularly in near-real-time.

Alaska↗

The emissions of CO2 and other volatiles from the world’s subaerial volcanoes

Volcanoes are the main pathway to the surface for volatiles that are stored within the Earth. Carbon dioxide (CO 2 ) is of particular interest because of its potential for climate forcing. Understanding the balance of CO 2 that is transferred from the Earth’s surface to the Earth’s interior, hinges on accurate quantification of the long-term emissions of volcanic CO 2 to the atmosphere. Here we present an updated evaluation of the world’s volcanic CO 2 emissions that takes advantage of recent improvements in satellite-based monitoring of sulfur dioxide, the establishment of ground-based networks for semi-continuous CO 2 -SO 2 gas sensing and a new approach to estimate key volcanic gas parameters based on magma compositions. Our results reveal a global volcanic CO 2 flux of 51.3 ± 5.7 Tg CO 2 /y (11.7 × 10 11 mol CO 2 /y) for non-eruptive degassing and 1.8 ± 0.9 Tg/y for eruptive degassing during the period from 2005 to 2015. While lower than recent estimates, this global volcanic flux implies that a significant proportion of the surface-derived CO 2 subducted into the Earth’s mantle is either stored below the arc crust, is efficiently consumed by microbial activity before entering the deeper parts of the subduction system, or becomes recycled into the deep mantle to potentially form diamonds.

Scientific Reports↗

Evaluation of Redoubt Volcano's sulfur dioxide emissions by the Ozone Monitoring Instrument

The 2009 eruption of Redoubt Volcano, Alaska, provided a rare opportunity to compare satellite measurements of sulfur dioxide (SO 2 ) by the Ozone Monitoring Instrument (OMI) with airborne SO 2 measurements by the Alaska Volcano Observatory (AVO). Herein we: (1) compare OMI and airborne SO 2 column density values for Redoubt's tropospheric plume, (2) calculate daily SO 2 masses from Mount Redoubt for the first three months of the eruption, (3) develop simple methods to convert daily measured SO 2 masses into emission rates to allow satellite data to be directly integrated with the airborne SO 2 emissions dataset, (4) calculate cumulative SO 2 emissions from the eruption, and (5) evaluate OMI as a monitoring tool for high-latitude degassing volcanoes. A linear correlation (R 2 ~ 0.75) is observed between OMI and airborne SO 2 column densities. OMI daily SO 2 masses for the sample period ranged from ~ 60.1 kt on 24 March to below detection limit, with an average daily SO 2 mass of ~ 6.7 kt. The highest SO 2 emissions were observed during the initial part of the explosive phase and the emissions exhibited an overall decreasing trend with time. OMI SO 2 emission rates were derived using three methods and compared to airborne measurements. This comparison yields a linear correlation (R 2 ~ 0.82) with OMI-derived emission rates consistently lower than airborne measurements. The comparison results suggest that OMI's detection limit for high latitude, springtime conditions varies from ~ 2000 to 4000 t/d. Cumulative SO 2 masses calculated from daily OMI data for the sample period are estimated to range from 542 to 615 kt, with approximately half of this SO 2 produced during the explosive phase of the eruption. These cumulative masses are similar in magnitude to those estimated for the 1989–90 Redoubt eruption. Strong correlations between daily OMI SO 2 mass and both tephra mass and acoustic energy during the explosive phase of the eruption suggest that OMI data may be used to infer relative eruption size and explosivity. Further, when used in conjunction with complementary datasets, OMI daily SO 2 masses may be used to help distinguish explosive from effusive activity and identify changes in lava extrusion rates. The results of this study suggest that OMI is a useful volcano monitoring tool to complement airborne measurements, capture explosive SO 2 emissions, and provide high temporal resolution SO 2 emissions data that can be used with interdisciplinary datasets to illuminate volcanic processes.

Alaska↗

Degassing of CO2, SO2, and H2S associated with the 2009 eruption of Redoubt Volcano, Alaska

The 2009 eruption of Redoubt Volcano, Alaska was particularly well monitored for volcanic gas emissions. We report 35 airborne measurements of CO 2 , SO 2 , and H 2 S emission rates that span from October 2008 to August 2010. The magmatic system degassed primarily as a closed system although minor amounts of open system degassing were observed in the 6 months prior to eruption on March 15, 2009 and over 1 year following cessation of dome extrusion. Only 14% of the total CO 2 was emitted prior to eruption even though high emissions rates (between 3630 and 9020 t/d) were observed in the final 6 weeks preceding the eruption. A minor amount of the total SO 2 was observed prior to eruption (4%), which was consistent with the low emission rates at that time (up to 180 t/d). The amount of the gas emitted during the explosive and dome growth period (March 15–July 1, 2009) was 59 and 66% of the total CO 2 and SO 2 , respectively. Maximum emission rates were 33,110 t/d CO 2 , 16,650 t/d SO 2 , and 1230 t/d H 2 S. Post-eruptive passive degassing was responsible for 27 and 30% of the total CO 2 and SO 2 , respectively. SO 2 made up on average 92% of the total sulfur degassing throughout the eruption. Magmas were vapor saturated with a C- and S-rich volatile phase, and regardless of composition, the magmas appear to be buffered by a volatile composition with a molar CO 2 /SO 2 ratio of ~ 2.4. Primary volatile contents calculated from degassing and erupted magma volumes range from 0.9 to 2.1 wt.% CO 2 and 0.27–0.56 wt.% S; whole-rock normalized values are slightly lower (0.8–1.7 wt.% CO 2 and 0.22–0.47 wt.% S) and are similar to what was calculated for the 1989–90 eruption of Redoubt. Such contents argue that primary arc magmas are rich in CO 2 and S. Similar trends between volumes of estimated degassed magma and observed erupted magma during the eruptive period point to primary volatile contents of 1.25 wt.% CO 2 and 0.35 wt.% S. Assuming these values, up to 30% additional unerupted magma degassed in the year following final dome emplacement.

Alaska↗