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T.J. McDonald

Publications and source records attributed to T.J. McDonald.

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Dipping reflectors in the Norwegian Sea—ODP Leg 104 drilling results: LEG 104 SCIENTIFIC PARTY

Ocean Drilling Program (ODP) Leg 104 successfully completed a number of deep drill holes on the Outer V0ring Plateau and the Vering Basin during July and August 1985 (Fig. 1; Eldholm, Thiede, Taylor et al. 1986). One of the principal objectives of the leg was to drill and sample a thick oceanward-dipping wedge of seismic reflectors, known to characterize much of the multichannel seismic (MCS) profile data recorded across ocean-continent transitions in the NE Atlantic north of 55°N. Elsewhere, these reflectors have previously been the target of deep drilling during Legs 48 and 81 of the International Phase of Ocean Drilling IPOD (Montadert, Roberts et al. 1979; Roberts, Schnitker et al. 1984). These efforts met with some success, sampling only the uppermost part of the sequence and identifying a series of tholeiitic lava flows. Over the Outer V~ring Plateau, a number of MCS profiles reveal a distinct change in seismic character at the base of the well-stratified dipping reflector sequence, where an irregular surface characterized by a band of low-frequency, high-amplitude reflectors occurs. This surface is referred to as K. Prior to Leg 104, therefore, relatively little was known regarding the variation in petrographic character of the flows at depth, their evolution and origin, and particularly the character of the material below the reflector sequence. A single deep drillhole (642E) successfully recovered a section through the

Journal of the Geological Society

Organic matter at sites 642, 643, and 644, ODP Leg 104

Sedimentary extractable organic matter was analyzed at three ODP Leg 104 sites in the Norwegian Sea. Organic carbon content ranged from less than 0.1% to a maximum of 1.8%. Extractable organic matter content and unresolved complex mixture concentrations were low and randomly distributed. Low levels of aliphatic (branched and normal) and aromatic hydrocarbons were detected in all of the sediments analyzed. Total aliphatic and aromatic hydrocarbon concentrations ranged from 176 to 3,214 and 6 to 820 ppb, respectively. The concentrations of individual aliphatic (n-C15 to n-C32) and aromatic (two- to five-ring) hydrocarbons were generally less than 50 ppb and less than 10 ppb, respectively. No significant trend with sub-bottom depth was observed in either bulk organic matter or individual hydrocarbon concentrations. The predominant source of Cenozoic sedimentary hydrocarbons is concluded to be ice-rafted debris from the adjacent continent. All sites contain a mixture of recycled, mature petroleum-related and terrestrially derived hydrocarbons.

Proceedings of the Ocean Drilling Program: Scienti

Hydrocarbon gases in sediment of the Voring Plateau, Norwegian Sea

Geochemical studies at three ODP Leg 104 sites on the Wring Plateau help define the distribution of hydrocarbon gases in sediment of this prominent feature of the Norwegian continental margin. Low levels of hydrocarbon gas were encountered in sediment of the outer part of the plateau, but sediment of the inner part of the plateau is very gassy. The molecular composition of inner plateau gases ( > 99.9% methane) and the carbon isotopic composition of the methane (avg. = - 76%o relative to the PDB standard) clearly show that the gas is biogenic. Heavier hydrocarbon gases accompany this methane, and their presence is probably a result of both chemical and microbial low-temperature diagenesis. Although these heavier hydrocarbons were not detected in sediment of the outer part of the plateau during shipboard analyses, subsequent shore-based analyses showed that these compounds are present at very low concentrations. Methane in the gassy sediment of the inner part of the plateau may be present as gas hydrates, judging from sedimentological and inorganic geochemical considerations, but no discernible gas hydrates were recovered during drilling.

Proceedings of the Ocean Drilling Program: Scienti

Organic geochemistry on Leg 104

The Leg 104 organic geochemistry program consisted of monitoring (a) hydrocarbon gases, (b) organic and inorganic carbon, and (c) parameters resulting from Rock-Eval pyrolysis at three sites on the Vdring Plateau. The results amplify some of those obtained earlier on Deep Sea Drilling Project (DSDP) Leg 38. In a regional sense there is an inverse correlation between amounts of hydrocarbon gas and organic carbon. For example, significant concentrations of methane are present only at Site 644 in the inner part of the plateau where organic carbon contents are always less than 1%; in contrast, at Site 642 on the outer plateau, methane concentrations are very low (ppm range) whereas amounts of organic carbon approach 2%. Only at Site 644 are the environmental conditions such that methanogenesis is an active diagenetic process. Because of the importance of routine gas analyses to the Ocean Drilling Program (ODP), a procedure was devised to improve the use of Vacutainers for collection of gas samples. Comparison of methods for determining organic carbon showed that at Sites 643 and 644 Rock-Eval TOC could be used as a measure of organic carbon, but not at Site 642. Although no liquid or solid hydrocarbons were encountered at any of the sites, a catalog of potential organic geochemical contaminants was developed in anticipation of such a discovery.

Proceedings of the Ocean Drilling Program: Scienti