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T.E. Ruble

Publications and source records attributed to T.E. Ruble.

2 recordsLinked to original sources

Unconventional shale-gas systems: The Mississippian Barnett Shale of north-central Texas as one model for thermogenic shale-gas assessment

Shale-gas resource plays can be distinguished by gas type and system characteristics. The Newark East gas field, located in the Fort Worth Basin, Texas, is defined by thermogenic gas production from low-porosity and low-permeability Barnett Shale. The Barnett Shale gas system, a self-contained source-reservoir system, has generated large amounts of gas in the key productive areas because of various characteristics and processes, including (1) excellent original organic richness and generation potential; (2) primary and secondary cracking of kerogen and retained oil, respectively; (3) retention of oil for cracking to gas by adsorption; (4) porosity resulting from organic matter decomposition; and (5) brittle mineralogical composition. The calculated total gas in place (GIP) based on estimated ultimate recovery that is based on production profiles and operator estimates is about 204 bcf/section (5.78 ?? 109 m3/1.73 ?? 104 m3). We estimate that the Barnett Shale has a total generation potential of about 609 bbl of oil equivalent/ac-ft or the equivalent of 3657 mcf/ac-ft (84.0 m3/m3). Assuming a thickness of 350 ft (107 m) and only sufficient hydrogen for partial cracking of retained oil to gas, a total generation potential of 820 bcf/section is estimated. Of this potential, approximately 60% was expelled, and the balance was retained for secondary cracking of oil to gas, if sufficient thermal maturity was reached. Gas storage capacity of the Barnett Shale at typical reservoir pressure, volume, and temperature conditions and 6% porosity shows a maximum storage capacity of 540 mcf/ac-ft or 159 scf/ton. Copyright ?? 2007. The American Association of Petroleum Geologists. All rights reserved.

American Association of Petroleum Geologists Bulle↗

Comparison of petroleum generation kinetics by isothermal hydrous and nonisothermal open-system pyrolysis

This study compares kinetic parameters determined by open-system pyrolysis and hydrous pyrolysis using aliquots of source rocks containing different kerogen types. Kinetic parameters derived from these two pyrolysis methods not only differ in the conditions employed and products generated, but also in the derivation of the kinetic parameters (i.e., isothermal linear regression and non-isothermal nonlinear regression). Results of this comparative study show that there is no correlation between kinetic parameters derived from hydrous pyrolysis and open-system pyrolysis. Hydrous-pyrolysis kinetic parameters determine narrow oil windows that occur over a wide range of temperatures and depths depending in part on the organic-sulfur content of the original kerogen. Conversely, open-system kinetic parameters determine broad oil windows that show no significant differences with kerogen types or their organic-sulfur contents. Comparisons of the kinetic parameters in a hypothetical thermal-burial history (2.5 ??C/my) show open-system kinetic parameters significantly underestimate the extent and timing of oil generation for Type-US kerogen and significantly overestimate the extent and timing of petroleum formation for Type-I kerogen compared to hydrous pyrolysis kinetic parameters. These hypothetical differences determined by the kinetic parameters are supported by natural thermal-burial histories for the Naokelekan source rock (Type-IIS kerogen) in the Zagros basin of Iraq and for the Green River Formation (Type-I kerogen) in the Uinta basin of Utah. Differences in extent and timing of oil generation determined by open-system pyrolysis and hydrous pyrolysis can be attributed to the former not adequately simulating natural oil generation conditions, products, and mechanisms.

Organic Geochemistry↗