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T.B. Spruill

Publications and source records attributed to T.B. Spruill.

8 recordsLinked to original sources
USGS2005

Geochemistry and characteristics of nitrogen transport at a confined animal feeding operation in a coastal plain agricultural watershed, and implications for nutrient loading in the Neuse River basin, North Carolina, 1999-2002

Chemical, geologic, hydrologic, and age-dating information collected between 1999 and 2002 were used to examine the transport of contaminants, primarily nitrogen, in ground water and the pathways to surface water in a coastal plain setting in North Carolina. Data were collected from more than 35 wells and 4 surface-water sampling sites located in a 0.59 square-mile basin to examine detailed hydrogeology and geochemical processes affecting nutrient fate and transport. Two additional surface-water sampling sites were located downstream from the primary study site to evaluate basin-scale effects. Chemical and flow data also were collected at an additional 10 sites in the Coastal Plain portion of the Neuse River basin located between Kinston and New Bern, North Carolina, to evaluate loads transported in the Neuse River and primary tributary basins. At the Lizzie Research Station study site in North Carolina, horizontal flow is induced by the presence of a confining unit at shallow depth. Age-dating, chemical, and piezometric data indicate that horizontal flow from the surficial aquifer is the dominant source of ground water to streamflow. Nitrogen applied on cultivated fields at the Lizzie Research Station is substantially reduced as it moves from recharge to discharge areas. Denitrification in deeper parts of the aquifer and in riparian zones is indicated by a characterization of redox conditions in the aquifer and by the presence of excess nitrogen gas. Direct ground-water discharge of nitrate to surface water during base-flow conditions is unlikely to be significant because of strongly reducing conditions that occur in the riparian zones of these streams. Nitrate loads from a drainage tile at the study site may account for much of the nitrate load in the receiving stream, indicating that a major source of nutrients from ground water to this stream is artificial drainage. During base-flow conditions when the streams are not flowing, it is hypothesized that the mineralization of organic matter on the streambed is the source of nitrate and(or) ammonium in the stream. Base flow is a small contributor to nitrogen loads, because both flows and inorganic nitrogen concentrations are low during summer months. Effects of a confined hog operation on ground-water quality also were evaluated. The use of sprayed swine wastes to fertilize crops at the Lizzie Research Station study site since 1995 resulted in increased concentrations of nitrate and other chemical constituents in ground water beneath spray fields when compared to ground water beneath fields treated with commercial fertilizer. The nitrate concentration in ground water from the spray field well increased by a factor of 3.5 after 4 years of spray applications. Nitrate concentrations ranged from 10 to 35 milligrams per liter, and one concentration as high as 56 milligrams per liter was observed in water from this well in spring 2002. This finding is in agreement with findings of other studies conducted in the Coastal Plain of North Carolina that nitrate concentrations were significantly higher in ground water from cultivated fields sprayed with swine wastes than from fields treated with commercial fertilizer. Loads and yields of nitrogen and phosphorus in 14 streams in the Neuse River basin were evaluated for calendar years 2000 and 2001. Data indicate that anthropogenic effects on nitrogen yields were greatest in the first-order stream studied (yields were greater than 2 tons per square mile [ton/mi2] and 1 ton/mi2 or less in second- and higher-order streams) in the Little Contentnea Creek subbasin. Nitrogen yields in streams in the Contentnea Creek subbasin ranged from 0.59 to 2 ton/mi2 with typical yields of approximately 1 ton/mi2. Contentnea Creek near Evansdale had the highest yield (2 ton/mi2), indicating that a major source of nitrogen is upstream from this station. Nitrogen yields were lower at Contentnea Creek at Hookerton in 2000 and 2001 compared to previous yi

Scientific Investigations Report↗
USGS2004

Geochemistry of shallow ground water in coastal plain environments in the southeastern United States: Implications for aquifer susceptibility

Ground-water chemistry data from coastal plain environments have been examined to determine the geochemical conditions and processes that occur in these areas and assess their implications for aquifer susceptibility. Two distinct geochemical environments were studied to represent a range of conditions: an inner coastal plain setting having more well-drained soils and lower organic carbon (C) content and an outer coastal plain environment that has more poorly drained soils and high organic C content. Higher concentrations of most major ions and dissolved inorganic and organic C in the outer coastal plain setting indicate a greater degree of mineral dissolution and organic matter oxidation. Accordingly, outer coastal plain waters are more reducing than inner coastal plain waters. Low dissolved oxygen (O2) and nitrate (NO 3-) concentrations and high iron (Fe) concentrations indicate that ferric iron (Fe (III)) is an important electron acceptor in this setting, while dissolved O2 is the most common terminal electron acceptor in the inner coastal plain setting. The presence of a wide range of redox conditions in the shallow aquifer system examined here underscores the importance of providing a detailed geochemical characterization of ground water when assessing the intrinsic susceptibility of coastal plain settings. The greater prevalence of aerobic conditions in the inner coastal plain setting makes this region more susceptible to contamination by constituents that are more stable under these conditions and is consistent with the significantly (p<0.05) higher concentrations of NO3- found in this setting. Herbicides and their transformation products were frequently detected (36% of wells sampled), however concentrations were typically low (<0.1 ??g/L). Shallow water table depths often found in coastal plain settings may result in an increased risk of the detection of pesticides (e.g., alachlor) that degrade rapidly in the unsaturated zone.

Applied Geochemistry↗
USGS2004

Effectiveness of riparian buffers in controlling ground-water discharge of nitrate to streams in selected hydrogeologic settings of the North Carolina Coastal Plain

Water-quality and hydrologic information were collected along ground-water flow paths from two well-drained and two poorly drained Coastal Plain settings in North Carolina to evaluate the relative effectiveness of riparian buffers in reducing discharge of nitrate to streams. At one well-drained site with a 100 m buffer, little or no effect was detected on surface-water quality by discharging ground water because extensive woody vegetation in the buffer was able to take up not only most nitrate, but also most ground water before discharging to the stream during the growing season (March-October). At the second well-drained site, ground water discharging to the stream from the side with a buffer contained about 2 mg/L of nitrate-nitrogen after passing through the bed of the stream compared to 6 mg/L in ground water discharging from the side with no buffer. In the poorly drained settings, nitrate in ground water decreased from about 6 mg/L in the recharge area to less than 0.02 mg/L downgradient from the riparian buffer. Ground water discharging from the side with no buffer contained 0.83 mg/L. Riparian buffers appear effective in reducing nitrate in ground water discharging to Coast Plain streams.

North Carolina↗
USGS1998

Ground-water quality in three urban areas in the Coastal Plain of the southeastern United States, 1995

Ground-water quality is generally good in three urban areas studied in the Coastal Plain of the southeastern United States涌cala and Tampa, Florida, and Virginia Beach, Virginia. The hydrology of these areas differs in that Ocala has many karst depressions but virtually no surface-water features, and Tampa and Virginia Beach have numerous surface-water features, including small lakes, streams, and swamps. Samples were collected in early 1995 from 15 wells in Ocala (8 in the surficial aquifer and 7 in the Upper Floridan aquifer), 17 wells in Tampa (8 in the surficial aquifer and 9 in the Upper Floridan aquifer), and in the summer of 1995 from 15 wells in Virginia Beach (all in the surficial aquifer). In the surficial aquifer in Ocala, the major ion water type was calcium bicarbonate in five samples and mixed (no dominant ions) in three samples, with dissolved-solids concentrations ranging from 78 to 463 milligrams per liter. In Tampa, the water type was calcium bicarbonate in one sample and mixed in seven samples, with dissolved-solids concentrations ranging from 38 to 397 milligrams per liter. In Virginia Beach, water types were primarily calcium and sodium bicarbonate water, with dissolved-solids concentrations ranging from 89 to 740 milligrams per liter. The water types and dissolved-solids concentrations reflect the presence of carbonates in the surficial aquifer materials in the Ocala and Virginia Beach areas. The major ion water type was calcium bicarbonate for all 16 samples from the upper Floridan aquifer in both Florida cities. Dissolved-solids concentrations ranged from 210 to 551 milligrams per liter in Ocala, with a median of 287 milligrams per liter, and from 187 to 362 milligrams per liter in Tampa, with a median of 244 milligrams per liter. Concentrations of nitrate nitrogen were highest in the surficial aquifer in Ocala, and one sample ex-ceeded 10 milligrams per liter, the U.S. Environmental Protection Agency maximum contaminant level for drinking water. Median nitrate concentrations were 1.2 milligrams per liter in Ocala and only 0.06 and 0.05 milligram per liter in Tampa and Virginia Beach, respectively. In Florida, some background water-quality data were available for comparison. The median nitrate concentration in Ocala was much higher than the median nitrate concentration of 0.05 milligram per liter in the background data. Median nitrate concentrations were 0.33 and 0.05 milligram per liter in samples from the Upper Floridan aquifer in Ocala and Tampa, respectively, and 0.05 milligram per liter in background samples. Of the 47 pesticides and 60 volatile organic compounds analyzed, only five pesticides and five volatile organic compounds were detected. The most commonly detected pesticide was prometon, a broad-scale herbicide, detected in samples from eight wells in Ocala (at concentrations ranging from 0.009 to 1.8 micrograms per liter), three wells in Virginia Beach (at concentrations ranging from 0.19 to 10 micrograms per liter), and from one well in Tampa (0.01 microgram per liter). The most commonly detected volatile organic compound was chloroform, which was d etected four times at concentrations ranging from 0.3 to 2.2 micrograms per liter in Ocala and Tampa. Seven volatile organic compounds were detected in one sample in Virginia Beach; most were compounds associated with petroleum and coal tar.

southeastern United States↗
USGS1995

The U. S. Geological Survey's Albemarle-Pamlico National Water-Quality Assessment Study; background and design

The Albemarle-Pamlico Study Unit is one of 20 National Water-Quality Assessment (NAWQA) studies begun in 1991 by the U.S. Geological Survey (USGS) to assess the Nation's water quality. One of the missions of the USGS is to assess the quantity and quality of the Nation's water resources. The NAWQA program was established to help accomplish this mission. The Albemarle-Pamlico Study Unit, located in Virginia and North Carolina, drains an area of about 28,000 square miles. Four major rivers, the Chowan, the Roanoke, the Tar-Pamlico and the Neuse, all drain into the Albemarle-Pamlico Sound in North Carolina. Four physiographic regions (areas of homogeneous climatic, geologic, and biological characteristics), the Valley and Ridge, Blue Ridge, Piedmont and Coastal Plain Physiographic Provinces are included within the Albemarle-Pamlico Study Unit. Until 1991, there was no single program that could answer the question, 'Are the Nation's ground and surface waters getting better, worse, or are they staying the same?' A program was needed to evaluate water quality by using standard techniques to allow assessment of water quality at local, regional, and national scales. The NAWQA Program was implemented to answer questions about the Nation's water quality using consistent and comparable methods. A total of 60 basins, or study units, will be in place by 1997 to assess the Nation's water quality.

Open-File Report↗
USGS1993

Preliminary evaluation of hydrogeology and ground-water quality in valley sediments in the vicinity of Killarney Lake, Kootenai County, Idaho

Ground water near Killarney Lake in the Coeur d'Alene River Valley, Idaho, contains arsenic, cadmium, lead, and zinc in concentrations that would make it unsuitable for a potable (drinking water) supply. Dissolved arsenic in one well was more than six times higher than the U.S. Environmental Protection Agency' s maximum contaminant level. However, ground water discharging to the Coeur d'Alene River in the area probably has minimal effects on river water quality because of poor transmissive characteristics of the fine-grained valley sediments. Hydraulic conduc- tivity values are between 1.0 x 100 and 6.3 x 100 feet per day, calculated from slug-test data from three of the six monitoring wells installed for this study; the ground-water-flow gradient is 0.0015 or less, determined from the water-level contour map; and the valley sediments are about 400 feet thick. Although the sediments near Killarney Lake do not transmit large quantifies of water, coarser grained sediments upstream from Killarney Lake. Because sediments along the Coeur d'Alene River are contaminated downstream from the South Fork Coeur d'Alene River near Enaville, where mining wastes were discharged for more than 100 years, it is possible that ground water near Cataldo could contribute significant quantities of contaminants to the Coeur d'Alene River.

Water-Resources Investigations Report↗
USGS1985

Statistical evaluation of the effects of irrigation on chemical quality of ground water and base flow in three river valleys in north-central Kansas

The chemical quality of groundwater and base flow in three alluvial valleys in Kansas has been changed as a result of 10 or more years of irrigation. Sulfate concentrations in groundwater in the Prairie Dog Creek valley statistically larger during 1981-82 than before irrigation began. Concentrations of calcium, bicarbonate, sulfate, and dissolved solids in groundwater in the Republican River valley and calcium, sodium plus potassium, sulfate, chloride, and dissolved solids in groundwater in the Smoky Hill River valley were significantly larger during 1981-82 than before irrigation began. No significant long-term changes in nitrate concentrations in groundwater were detected in any of the three valleys. Irrigation generally has not caused contamination of groundwater in the alluvium with organic pesticides for which National Primary drinking-water standards have been established. The pesticide 2, 4-D was detected, however, at concentrations of less than 2 micrograms per liter in water from several wells and surface-water sampling sites. (USGS)

Water-Resources Investigations Report↗