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T. H. Druitt

Publications and source records attributed to T. H. Druitt.

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Compositional zonation and cumulus processes in the Mount Mazama magma chamber, Crater Lake, Oregon

The 6845 ± 50 BP climactic eruption of Mount Mazama discharged 47 ± 9 km 3 of vertically zoned calc-alkaline magma, affording a virtually complete section through the chamber. Evidence for two andesitic parents with different trace-element (particularly Sr) and water contents is preserved in the ejecta. Prior to eruption, a dominant volume of rhyodacite was underlain successively by high-Sr andesite, high-Sr crystal mushes, and low-Sr crystal mushes. Intergranular liquids in the high-Sr magmas were probably richer in water than those in the low-Sr magmas. Thermal continuity throughout the ejecta favours eruption from a single, zoned reservoir. Insight into chamber development is given by preclimactic rhyodacitic lavas and tephra erupted between about 30,000 BP and the climactic eruption. The oldest of these lavas, contaminated derivatives of low-Sr magma, contain crystal-poor magmatic inclusions of low-Sr andesite; the youngest has inclusions of high-Sr andesite and, like rhyodacitic pumice in the climactic ejecta, is hybrid magma containing an admixed high-Sr component. A model for steady-state growth of the chamber is inferred whereby repeated recharge, first by low-Sr then high-Sr andesite (± basalt), builds up a cumulate succession, while derivative liquid fractionates convectively, segregates, and mixes with an incrementally growing silicic volume. The magma chamber at Mount Mazama may provide insight into the evolution of some granitoid plutons.

Oregon

Chapter 1: Previous research

Santorini has fascinated and stimulated explorers and scholars since ancient times. Jason and the Argonauts were apparently visitors to the islands and described a giant called Talos. Molten metal flowed from his feet and he threw stones at them. The island is perhaps best known for the paroxysmal eruption that took place in the Late Bronze Age at the height of the Minoan civilization that dominated Crete and the Aegean region. The legend of Atlantis, in which a whole city sank beneath the sea in a single day and night, is plausibly based on the effects of this eruption on the Minoan Civilization. The geographer Strabo described the eruption of 197 bc in the following way: ... for midway between Thera and Therasia fires broke forth from the sea and continued for four days, so that the whole sea boiled and blazed, and the fires cast up an island which was gradually elevated as though by levers and consisted of burning masses... This introduction gives a brief synopsis of research on the volcano since this dramatic chronicle was written. Research on Santorini has contributed substantial advances not only in the understanding of Santorini itself but to general principles in volcanology and petrology. three centres for lava eruptions on Therasia and northern Thera: the Peristeria, Simandiri and Skaros-Therasia Volcanoes.

Santorini

Chapter 2: Geological and tectonic setting of Santorini

Santorini lies in an area of complex extensional and subduction-related tectonics in a continental environment (Jackson 1994). The region has had a long geological history with large changes occurring during the Alpine orogeny and in the Late Tertiary as a consequence of post-collisional extension and major re-adjustments of the plate boundaries. The Aegean region is thought to be moving towards the southwest where the Aegean microplate overrides the Eastern Mediterranean sea floor. The collision has created the Hellenic trench to the south of Crete where the eastern Mediterranean sea floor is subducting beneath the Aegean Sea at 5-6 cm a-1. Santorini is one of several Quaternary volcanoes that define the present day active volcanic arc related to this subduction zone (Fig. 2.1). We here provide a synopsis of the broader geological and tectonic context of Santorini within the Aegean area. The geology, isotope geochemistry and geochronology of the crystalline basement of the southern Aegean is of particular relevance as it is likely that the Santorini magmas have interacted extensively with the continental crust. Geochemical evidence presented in Chapters 6 and 7 confirms this prediction. We also give a synopsis of the Quaternary Aegean Island Arc, of which Santorini is the most active centre.

Santorini

Chapter 3: Development of the Santorini volcanic field in space and time

Santorini is one of the largest Quaternary volcanic centres of the Aegean Region. The caldera cliffs preserve well-exposed sequences of lavas and pyroclastic deposits, which record the long development of the volcano in space and time. These include the products of 12 major explosive eruptions and the dissected remains of several ancient lava shields, stratovolcanoes, and lava-dome complexes. The former existence of multiple eruptive centres scattered over the present-day islands shows that Santorini is best considered as a volcanic field , which probably also continues under the sea (Heiken & McCoy 1984). Santorini is best known for the Minoan eruption of the late Bronze Age (Bond & Sparks 1976; Heiken & McCoy 1984; Sparks & Wilson 1990), but some of the previous explosive eruptions may have been as large (Druitt et al . 1989). The occurrence of repeated explosive eruptions has triggered formation of at least four large calderas, such that the present-day caldera is a composite structure (Druitt & Francaviglia 1992). Santorini is potentially one of the most dangerous volcanoes in Europe, having had numerous eruptions in historic times, some of them with significant explosive components (Fytikas et al . 1990 a ).

Santorini

Chapter 4: Compositional zoning and petrology of the Thera pyroclastics

Compositional zoning is a common feature of pyroclastic deposits erupted from calderas worldwide (Smith 1979; Hildreth 1981; Bacon & Druitt 1988; De Silva 1991; Feeley & Davidson 1994). Compositionally zoned tuffs provide a geologically instantaneous snapshot of the vertical stratigraphy and density stratification in the chamber immediately before eruption. Magma bodies are commonly zoned in density, with light, relatively cool, silicic magma overlying hotter, more mafic magma. Vertical zonation can arise by a number of processes, including crystallization and convective fractionation on the chamber.

Santorini

Chapter 5: Cumulate nodules in the Thera pyroclastics

Gabbroic and dioritic nodules are common in some horizons of the Thera pyroclastics. These nodules contain pyroxene as the main ferromagnesian phase in contrast to the early Akrotiri centre, which contain nodules with abundant hornblende (Nicholls 1971a; Pichler & Kussmaul 1972). Calcsilicate nodules and gabbroic nodules have also been recognized in Santorini lavas (Fouqu6 1879; Nicholls 1971a). Previous studies of Santorini volcanic rocks indicate that crystal fractionation has played an important role in generating the compositional range basalt-andesite-dacite-rhyodacite (Nicholls 1971a; Mann 1983; Huijsmans 1985; Barton & Huijsmans 1986). This interpretation is also consistent with much of the petrological data presented in Chapter 4 and the geochemical data and models presented in Chapter 6. However, disequilibrium phenocryst assemblages in some lavas (Huijsmans 1985; Chapter 4), banded pumice clasts in many pyroclastic deposits (Druitt et al. 1989; Chapters 4), isotopic disequilibria in phenocrysts (Pyle et al. 1988; Chapters 6 and 7) and complex zoning patterns in plagioclase crystals (Stamatelopoulou-Seymour et al. 1990) indicate that magma mixing has also occurred. In addition, trace element and isotopic abundances can be interpreted in terms of assimilation of continental crust during fractionation (Barton et al. 1983; Stamatelopoulou-Seymour et al. 1990; Chapter 6). The nodules provide information on petrogenetic processes that have influenced the evolution of Santorini magmas. Their petrology is documented in this chapter and compared with that of associated juvenile ejecta. The nodules are identified as cumulates from andesitic and dacitic magmas, con- firming the importance of fractional crystallization in the petrogenesis of Santorini magmas. They also demonstrate that mafic plutonic rocks can be formed from intermediate to silicic magmas.

Santorini

Chapter 6 Geochemistry, isotopic composition and petrogenetic modelling of the Thera pyroclastics

This chapter examines the major element, trace element, and isotope geochemistry of the Thera pyroclastics, and places it in the context of the geochemical evolution of the whole volcanic field. Geochemical studies to date have been undertaken predominantly on the lavas, and the pyroclastic succession has been relatively neglected. The data on the pyroclastics are taken from Druitt (1983), Mellors (1988), Pyle (19906), and Edwards (1994). Wholerock analyses and sample descriptions are given in Appendix 2. Most analyses are of a single pumice or scoria lump, although some are combinations of several small clasts and a few are compositionally banded. The rock classification scheme used throughout the memoir is shown in Fig. 6.1. Previous isotopic studies on Santorini are also largely confined to the lavas, and no detailed studies had been carried out on the pyroclastic rocks. In this chapter we present new 87 Sr/ 86 Sr, 143 Nd/ 144 Nd, 206 Pb/ 204 Pb, 207 Pb/ 204 Pb, 208 Pb/ 204 Pb and δ 18 О isotopic data on 40 samples of the Thera pyroclastics. We also include some measurements of hydrogen isotopes. Methods of geochemical and isotopic analysis are described in Appendix 1. This chapter also presents some quantitative models of fractional crystallization and assimilation of crustal rocks. The geochemical data and models point towards the importance of crystal fractionation, magma mixing and assimilation of continental crust in magma genesis at Santorini. The chapter also documents temporal changes in geochemical features of Santorini magmas.

Santorini

Chapter 7: Studies of short-lived radionuclides in Santorini volcanics

Disequilibria between the short-lived radioactive nuclides 226 Ra, 230 Th and 238 U in young volcanic rocks can be used both for dating the time of crystallisation of a rock, and as isotopic tracers of the sources of magmas and the chemical evolution of volcanic systems. The principles of these methods have been reviewed extensively elsewhere (Condomines et al . 1988; Gill et al . 1992; Gill & Condomines 1992; Macdougall 1995). In this chapter, we present new 238 U- 230 Th- 226 Ra disequilibria data for the Thera pyroclastics and for selected lavas. These data complement the radiogenic isotopic data presented in Chapter 6 on the compositional evolution through time of the pyroclastic ejecta. In particular, we find that the ( 230 Th/ 232 Th) isotopic ratio corrected to the time of eruption varies in a systematic way with time through the second cycle of the Thera pyroclastics and variations in this ratio are correlated with the variations of 87 Sr/ 86 Sr, 143 Nd/ 144 Nd and Pb isotopes.

Santorini

Chapter 8: The evolution of Santorini

There now follows a synthesis of the main results of this study. We interpret the observations in terms of the interplay between magmatic, tectonic and volcanic processes and place these processes within a global context. Santorini has displayed a wide variety of igneous and volcanic phenomena over a period of at least 650 000 years of almost continuous and focused volcanism. Perhaps the most intriguing issues are the causes of volcanic and magmatic cyclicity, the secular variations in magma composition and the way in which magmatic processes have influenced the style of volcanism.

Santorini

Appendix 1: Analytical methods and errors

Thirty eight K-Ar and eight 40Ar/39Ar high-precision age determinations were made at the US Geological Survey, Menlo Park, on a total of 22 rocks from the entire volcanic field. Duplicate or triplicate determinations were carried out on 14 samples in order to improve analytical precision. All ages were measured on whole-rock samples selected after thin-section examination. Most of the samples meet the usual criteria for whole-rock dating (Mankinen © Dal-rymple 1972), but some contain minor amounts of glass and a few samples are very glassy. The samples selected for dating were crushed to 0.5-lmm (-18 to +35 mesh). For K-Ar dating aliquots weighing c. 25 g were used for the Ar measurements. A 10 g aliquot was ground to -200 mesh and splits of the powder were used for K20 measurements, which were made in duplicate on each of two separate splits of sample powder by flame photometry after lithium metaborate fusion and dissolution (Ingamells 1970). Ar analyses were by isotope-dilution mass spectrometry using a high-purity (>99.9%) 38Ar tracer and techniques and equipment described previously (Dalrymple & Lanphere 1969). All samples for Ar extraction were baked overnight at 280°C. Mass analyses were done on a 22.68 cm radius, multiple-collector mass spectrometer with a nominal 90° sector magnet, using automated data collection (Stacey etal 1981). Errors given for the calculated K-Ar ages of individual measurements are estimates of the standard deviation of analytical precision. The errors were calculated using formulae derived by Cox & Dalrymple (1967) and Dalrymple & Lanphere (1969).

Geological Society, London, Memoirs

Appendix 2: Tabulated analytical data

Details of analytical methods and errors are given in Appendix 1. bd means below detection and na not analysed. Samples numbers which begin with the letter S are from Druitt (1983) and those that begin with LS are from Edwards (1994). Sample numbers which begin with the number 8 are either from Mellors (1988) or Pyle (1990 b ). Subunits of each major tuff of the Thera pyroclastics are denoted by upper case letters (A to D). These are listed in Table 3.4. In the case of the minor sequences (Appendix 2.3), the sequence abbreviations (M6 to M8) are shown in Fig. 3.17 and the individual unit abbreviations (CD1 to CD10) are from Edwards (1994).

Geological Society, London, Memoirs

Mobility of pyroclastic flows and surges at the Soufriere Hills Volcano, Montserrat

The Soufriere Hills Volcano on Montserrat has produced avalanche-like pyroclastic flows formed by collapse of the unstable lava dome or explosive activity. Pyroclastic flows associated with dome collapse generate overlying dilute surges which detach from and travel beyond their parent flows. The largest surges partially transform by rapid sedimentation into dense secondary pyroclastic flows that pose significant hazards to distal areas. Different kinds of pyroclastic density currents display contrasting mobilities indicated by ratios of total height of fall H , run-out distance L , area inundated A and volume transported V . Dome-collapse flow mobilities (characterised by either L/H or A/V 2/3 ) resemble those of terrestrial and extraterrestrial cold-rockfalls (Dade and Huppert, 1998). In contrast, fountain-fed pumice flows and fine-grained, secondary pyroclastic flows travel slower but, for comparable initial volumes and heights, can inundate greater areas.

Geophysical Research Letters

Petrology of the zoned calcalkaline magma chamber of Mount Mazama, Crater Lake, Oregon

Evolution of the magma chamber at Mount Mazama involved repeated recharge by two types of andesite (high-Sr and low-Sr), crystal fractionation, crystal accumulation, assimilation, and magma mixing (Bacon and Druitt 1988). This paper addresses the modal compositions, textures, mineral chemistry and magmatic temperatures of (i) products of the 6845±50 BP climactic eruption, (ii) blocks of partially fused granitoid wallrock found in the ejecta, and (iii) preclimactic rhyodacitic lavas leaked from the chamber in late Pleistocene and early Holocene time. Immediately prior to the climactic eruption the chamber contained ≳ 40 km 3 of rhyodacite (10 vol% plag + opx + aug + hb + mt + ilm, ∼880° C) overlying high-Sr andesite and cumulus-crystal mush (28–51 vol% plag + hb ± opx ± aug + mt ± ilm, 880° to ≥950° C), which in turn overlay low-Sr crystal mush (50–66 vol% plag + opx + aug ± hb ± ol + mt + ilm, 890° to ≥950† C). Despite the well known compositional gap in the ejecta, no thermal discontinuity existed in the chamber. Pre-eruptive water contents of pore liquids in most high-Sr and low-Sr mushes were 4–6 wt%, but on average the high-Sr mushes were slightly richer in water. Although parental magmas of the crystal mushes were andesitic, xenocrysts of bytownite and Ni-rich magnesian olivine in some scoriae record the one-time injection of basalt into the chamber. Textures in ol-bearing scoriae preserve evidence for the reactions ol + liq = opx and ol + aug + liq(+ plag?) = hb, which occurred in andesitic liquids at Mount Mazama. Strontium abundances in plagioclase phenocrysts constrain the petrogenesis of preclimactic and climactic rhyodacites. Phenocryst cores derived from high-Sr and low-Sr magmas have different Sr contents which can be resolved by microprobe. Partition coefficients for plagioclase in andesitic to rhyolitic glasses range from 2 to 7, and increase as glass %SiO 2 increases. Evolved Pleistocene rhyodacites (∼30–25,000 BP) and rhyodacites of the Holocene Llao Rock center (7015±45 BP) contain Sr-poor plagioclase and are derivatives from low-Sr magma. Rhyodacites of the Pleistocene Sharp Peak domes, Holocene Cleetwood flow (∼6850 BP), and climactic ejecta contain discrete Sr-rich and Sr-poor plagioclase phenocryst populations and are hybrids produced by mixing low-Sr rhyodacite (containing Sr-poor plag + opx + aug) with a more mafic high-Sr magma (with Sr-rich plag [ + hb?]). The data reinforce the conclusions of crystal-liquid mixing calculations (Bacon and Druitt 1988), and suggest some important refinements to the magma chamber model.

Oregon

Compositional evolution of the zoned calcalkaline magma chamber of Mount Mazama, Crater Lake, Oregon

The climactic eruption of Mount Mazama has long been recognized as a classic example of rapid eruption of a substantial fraction of a zoned magma body. Increased knowledge of eruptive history and new chemical analyses of ∼350 wholerock and glass samples of the climactic ejecta, preclimactic rhyodacite flows and their inclusions, postcaldera lavas, and lavas of nearby monogenetic vents are used here to infer processes of chemical evolution of this late Pleistocene — Holocene magmatic system. The 6845±50 BP climactic eruption vented ∼50 km 3 of magma to form: (1) rhyodacite fall deposit; (2) welded rhyodacite ignimbrite; and (3) lithic breccia and zoned ignimbrite, these during collapse of Crater Lake caldera. Climactic ejecta were dominantly homogeneous rhyodacite (70.4±0.3% SiO 2 ), followed by subordinate andesite and cumulate scoriae (48–61% SiO 2 ). The gap in wholerock composition reflects mainly a step in crystal content because glass compositions are virtually continuous. Two types of scoriae are distinguished by different LREE, Rb, Th, and Zr, but principally by a twofold contrast in Sr content: High-Sr (HSr) and low-Sr (LSr) scoriae. HSr scoriae were erupted first. Trace element abundances indicate that HSr and LSr scoriae had different calcalkaline andesite parents; basalt was parental to some mafic cumulate scoriae. Parental magma compositions reconstructed from scoria wholerock and glass data are similar to those of inclusions in preclimactic rhyodacites and of aphyric lavas of nearby monogenetic vents. Preclimactic rhyodacite flows and their magmatic inclusions give insight into evolution of the climactic chamber. Evolved rhyodacite flows containing LSr andesite inclusions were emplaced between ∼30000 and ∼25000 BP. At 7015±45 BP, the Llao Rock vent produced a zoned rhyodacite pumice fall, then rhyodacite lava with HSr andesite inclusions. The Cleetwood rhyodacite flow, emplaced immediately before the climactic eruption and compositionally identical to climactic rhyodacite (volatile-free), contains different HSr inclusions from Llao Rock. The change from LSr to HSr inclusions indicates replenishment of the chamber with andesite magma, perhaps several times, in the latest Pleistocene to early Holocene. Modeling calculations and wholerock-glass relations suggest than: (1) magmas were derived mainly by crystallization differentiation of andesite liquid; (2) evolved preclimactic rhyodacite probably was derived from LSr andesite; (3) rhyodacites contain a minor component of partial melt from wall rocks, and (4) climactic and compositionally similar rhyodacites probably formed by mixing of evolved rhyodacite with HSr derivative liquid(s) after replenishment of the chamber with HSr andesite magma. Density considerations permit a model for growth and evolution of the chamber in which andesite recharge magma ponded repeatedly between cumulates and rhyodacite magma. Convective cooling of this andesite resulted in rapid crystallization and upward escape of buoyant derivative liquid which mixed with overlying, convecting rhyodacite. The evolved rhyodacites were erupted early in the chamber's history and(or) near its margins. Postcaldera andesite lavas may be hybrids composed of LSr cumulates mixed with remnant climactic rhyodacite. Younger postcaldera rhyodacite probably formed by fractionation of similar andesite and assimilation of partial melts of wallrocks. Uniformity of climactic rhyodacite suggests homogeneous silicic ejecta from other volcanoes resulted from similar replenishment-driven convective mixing. Calcalkaline pluton compositions and their internal zonation can be interpreted in terms of the Mazama system frozen at various times in its history.

Oregon

Lithic breccia and ignimbrite erupted during the collapse of Crater Lake Caldera, Oregon

The climactic eruption of Mount Mazama (6845 y.B.P.) vented a total of ∼50 km 3 of compositionally zoned rhyodacitic to basaltic magma from: (a) a single vent as a Plinian pumice fall deposit and the overlying Wineglass Welded Tuff, and (b) ring vents as ignimbrite and coignimbrite lithic breccia accompanying the collapse of Crater Lake caldera. New field and grain-size data for the ring-vent products are presented in this report. The coarse-grained, poorly bedded, clast-supported lithic breccia extends as far as 18 km from the caldera center. Like the associated ignimbrite, the breccia is compositionally zoned both radially and vertically, and silicic, mixed, and mafic types can be recognized, based on the proportion of rhyodacitic pumice. Matrix fractions in silicic breccias are depleted of fines and are lithic- and crystal-enriched relative to silicic ignimbrite due to vigorous gas sorting during emplacement. Ignimbrite occurs as a proximal veneer deposit overlying the breccia, a medial (∼ 8 to ∼ 25 km from the caldera center), compositionally zoned valley fill as much as > 110 m thick, and an unzoned distal (⪖ 20 km) facies which extends as far as 55 km from the caldera. Breccia within ∼ 9 km of the caldera center is interpreted as a coignimbrite lag breccia formed within the deflation zone of the collapsing ring-vent eruption columns. Expanded pyroclastic flows of the deflation zone were probably vertically graded in both size and concentration of blocks, as recently postulated for some turbidity currents. An inflection in the rate of falloff of lithic-clast size within the lithic breccia at ∼ 9 km may mark the outer edge of the deflation zone or may be an artifact of incomplete exposure. The onset of ring-vent activity at Mt. Mazama was accompanied by a marked increase in eruptive discharge. Pyroclastic flows were emplaced as a semicontinuous stream, as few ignimbrite flow-unit boundaries are evident. As eruption from the ring vents progressed, flow-runout distance and the extent of breccia deposition decreased due to (a) greater internal flow friction, and (b) decreasing eruption column heights. Effect (b) probably resulted from a progressive decrease in magmatic gas content and discharge rate. Waning discharge may have been promoted by the tapping of more viscous, crystal-rich magma, collapse of conduit walls, and declining caldera collapse rate.

Oregon

On the formation of calderas during ignimbrite eruptions

Many large calderas result from the eruption of substantial volumes (tens or hundreds of km3) of silicic pyroclastics. Such events often begin with an airfall phase and progress to the generation of voluminous ignimbrites1-3. We propose here that many such eruptions involve two well-defined stages, based on a simple analysis of magma chamber pressure variations during an eruption. The first stage begins when an overpressured magma chamber fractures the country rock and forms a conduit to the surface. The chamber pressure decreases rapidly to values less than lithostatic pressure. We show that only small to moderate volumes of magma, representing a small fraction of the total chamber, can be erupted during this stage. In the second stage, caldera collapse results from a further decrease in magma pressure, which causes the chamber roof to fracture catastrophically and deform. Subsidence of the roof attempts to re-establish lithostatic pressures within the chamber and can drive substantial volumes of magma to the surface. Geological relationships in pyroclastic deposits associated with large caldera eruptions provide independent evidence for this model. ?? 1984 Nature Publishing Group.

Nature