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T. Elias

Publications and source records attributed to T. Elias.

10 recordsLinked to original sources

Sulfur dioxide emission rates from Kilauea Volcano, Hawaii, 2007-2010

Kīlauea Volcano has one of the longest running volcanic sulfur dioxide (SO 2 ) emission rate databases on record. Sulfur dioxide emission rates from Kīlauea Volcano were first measured by Stoiber and Malone (1975) and have been measured on a regular basis since 1979 (Elias and Sutton, 2007, and references within). Compilations of SO 2 emission-rate and wind-vector data from 1979 through 2006 are available on the USGS Web site (Elias and others, 1998; Elias and Sutton, 2002; Elias and Sutton, 2007). This report updates the database, documents the changes in data collection and processing methods, and highlights how SO 2 emissions have varied with eruptive activity at Kīlauea Volcano for the interval 2007–2010.

Hawai'i

Enhancement of the volcanogenic "bromine explosion" via reactive nitrogen chemistry (Kīlauea volcano, Hawai'i)

Since the first detection of bromine monoxide in volcanic plumes attention has focused on the atmospheric synthesis and impact of volcanogenic reactive halogens. We report here new measurements of BrO in the volcanic plume emitted from Kīlauea volcano – the first time reactive halogens have been observed in emissions from a hotspot volcano. Observations were carried out by ground-based Differential Optical Absorption Spectroscopy in 2007 and 2008 at Pu'u' O ' o crater, and at the 2008 magmatic vent that opened within Halema'uma'u crater. BrO was readily detected in the Halema'uma'u plume (average column amount of 3×1015 molec cm −2 ) and its abundance was strongly correlated with that of SO 2 . However, anticorrelation between NO 2 and SO 2 (and BrO) abundances in the same plume strongly suggest an active role of NO x in reactive halogen chemistry. The calculated SO 2 /BrO molar ratio of ~1600 is comparable to observations at other volcanoes, although the BrO mixing ratio is roughly double that observed elsewhere. While BrO was not observed in the Pu'u' O ' o plume this was probably merely a result of the detection limit of our measurements and based on understanding of the Summit and East Rift magmatic system we expect reactive halogens to be formed also in the Pu'u' O ' o emissions. If this is correct then based on the long term SO 2 flux from Pu'u' O ' o we calculate that Kīlauea emits ~480 Mg yr −1 of reactive bromine and may thus represent an important source to the tropical Pacific troposphere.

Hawaii

Puhimau thermal area: a window into the upper east rift zone of Kilauea Volcano, Hawaii?

We report the results of two soil CO 2 efflux surveys by the closed chamber circulation method at the Puhimau thermal area in the upper East Rift Zone (ERZ) of Kilauea volcano, Hawaii. The surveys were undertaken in 1996 and 1998 to constrain how much CO 2 might be reaching the ERZ after degassing beneath the summit caldera and whether the Puhimau thermal area might be a significant contributor to the overall CO 2 budget of Kilauea. The area was revisited in 2001 to determine the effects of surface disturbance on efflux values by the collar emplacement technique utilized in the earlier surveys. Utilizing a cutoff value of 50 g m −2 d −1 for the surrounding forest background efflux, the CO 2 emission rates for the anomaly at Puhimau thermal area were 27 t d −1 in 1996 and 17 t d −1 in 1998. Water vapor was removed before analysis in all cases in order to obtain CO 2 values on a dry air basis and mitigate the effect of water vapor dilution on the measurements. It is clear that Puhimau thermal area is not a significant contributor to Kilauea's CO 2 output and that most of Kilauea's CO 2 (8500 t d −1 ) is degassed at the summit, leaving only magma with its remaining stored volatiles, such as SO 2 , for injection down the ERZ. Because of the low CO 2 emission rate and the presence of a shallow water table in the upper ERZ that effectively scrubs SO 2 and other acid gases, Puhimau thermal area currently does not appear to be generally well suited for observing temporal changes in degassing at Kilauea.

Hawaii

Carbon dioxide emission rate of Kīlauea Volcano: Implications for primary magma and the summit reservoir

We report a CO 2 emission rate of 8500 metric tons per day (t d −1 ) for the summit of Kīlauea Volcano, several times larger than previous estimates. It is based on three sets of measurements over 4 years of synchronous SO 2 emission rates and volcanic CO 2 /SO 2 concentration ratios for the summit correlation spectrometer (COSPEC) traverse. Volcanic CO 2 /SO 2 for the traverse is representative of the global ratio for summit emissions. The summit CO 2 emission rate is nearly constant, despite large temporal variations in summit CO 2 /SO 2 and SO 2 emission rates. Summit CO 2 emissions comprise most of Kīlauea's total CO 2 output (∼9000 t d −1 ). The bulk CO 2 content of primary magma determined from CO 2 emission and magma supply rate data is ∼0.70 wt %. Most of the CO 2 is present as exsolved vapor at summit reservoir depths, making the primary magma strongly buoyant. Turbulent mixing with resident reservoir magma, however, prevents frequent eruptions of buoyant primary magma in the summit region. CO 2 emissions confirm that the magma supply enters the edifice through the summit reservoir. A persistent several hundred parts per million CO 2 anomaly arises from the entry of magma into the summit reservoir beneath a square kilometer area east of Halemaumau pit crater. Since most of the CO 2 in primary magma is degassed in the summit, the summit CO 2 emission rate is an effective proxy for the magma supply rate. Both scrubbing of SO 2 and solubility controls on CO 2 and S in basaltic melt cause high CO 2 /SO 2 in summit emissions and spatially uncorrelated distributions of CO 2 and SO 2 in the summit plume.

Journal of Geophysical Research B: Solid Earth

Sun photometer and lidar measurements of the plume from the Hawaii Kilauea Volcano Pu'u O'o vent: Aerosol flux and SO2 lifetime

Aerosol optical depths and lidar measurements were obtained under the plume of Hawaii Kilauea Volcano on August 17, 2001, ∼9 km downwind from the erupting Pu'u O'o vent. Measured aerosol optical depths (at 500 nm) were between 0.2–0.4. Aerosol size distributions inverted from the spectral sun photometer measurements suggest the volcanic aerosol is present in the accumulation mode (0.1–0.5 micron diameter), which is consistent with past in situ optical counter measurements. The aerosol dry mass flux rate was calculated to be 53 Mg d −1 . The estimated SO 2 emission rate during the aerosol measurements was ∼1450 Mg d −1 . Assuming the sulfur emissions at Pu'u O'o vent are mainly SO 2 (not aerosol), this corresponds to a SO 2 half-life of 6.0 hours in the atmosphere.

Hawaii

Implications for eruptive processes as indicated by sulfur dioxide emissions from Kilauea Volcano, Hawai'i, 1979-1997

Kı̄lauea Volcano, Hawai‘i, currently hosts the longest running SO 2 emission-rate data set on the planet, starting with initial surveys done in 1975 by Stoiber and his colleagues. The 17.5-year record of summit emissions, starting in 1979, shows the effects of summit and east rift eruptive processes, which define seven distinctly different periods of SO 2 release. Summit emissions jumped nearly 40% with the onset (3 January 1983) of the Pu`u `Ō`ō-Kūpaianaha eruption on the east rift zone (ERZ). Summit SO 2 emissions from Kı̄lauea showed a strong positive correlation with short-period, shallow, caldera events, rather than with long-period seismicity as in more silicious systems. This correlation suggests a maturation process in the summit magma-transport system from 1986 through 1993. During a steady-state throughput-equilibrium interval of the summit magma reservoir, integration of summit-caldera and ERZ SO 2 emissions reveals an undegassed volume rate of effusion of 2.1×10 5 m 3 /d. This value corroborates the volume-rate determined by geophysical methods, demonstrating that, for Kı̄lauea, SO 2 emission rates can be used to monitor effusion rate, supporting and supplementing other, more established geophysical methods. For the 17.5 years of continuous emission rate records at Kı̄lauea, the volcano has released 9.7×10 6 t (metric tonnes) of SO 2 , 1.7×10 6 t from the summit and 8.0×10 6 t from the east rift zone. On an annual basis, the average SO 2 release from Kı̄lauea is 4.6×10 5 t/y, compared to the global annual volcanic emission rate of 1.2×10 7 t/y.

Journal of Volcanology and Geothermal Research

Volcano fixes nitrogen into plant-available forms

Hawaiian montane ecosystems developing on recent tephra deposits contain more fixed nitrogen than conventional sources can explain. Heath and Huebert (1999) demonstrated that cloud water interception is the mechanism by which this extra nitrogen is deposited, but could not identify its source. We show here that atmospheric dinitrogen is fixed at the surface of active lava flows, producing concentrations of NO which are higher than those found in most urban rush hour air pollution. Over a period of hours this NO is blown away from the island and oxidized to nitrate. Interruptions in the trade wind flow can return this nitrate to the island to be deposited in cloud water. Thus, fixation on active lava flows is able to provide nitrogen to developing ecosystems on flows emplaced earlier.

Biogeochemistry

Multispectral thermal infrared mapping of sulfur dioxide plumes: A case study from the East Rift Zone of Kilauea Volcano, Hawaii

The synoptic perspective and rapid mode of data acquisition provided by remote sensing are well suited for the study of volcanic SO 2 plumes. In this paper we describe a plume-mapping procedure that is based on image data acquired with NASA's airborne thermal infrared multispectral scanner (TIMS) and apply the procedure to TIMS data collected over the East Rift Zone of Kilauea Volcano, Hawaii, on September 30, 1988. These image data covered the Pu‘u ‘O ‘o and Kupaianaha vents and a skylight in the lava tube that was draining the Kupaianaha lava pond. Our estimate of the SO 2 emission rate from Pu‘u ‘O ‘o (17–20 kg s −1 ) is roughly twice the average of estimates derived from correlation spectrometer (COSPEC) measurements collected 10 days prior to the TIMS overflight (10 kg s −1 ). The agreement between the TIMS and COSPEC results improves when we compare SO 2 burden estimates, which are relatively independent of wind speed. We demonstrate the feasibility of mapping Pu‘u ‘O ‘o - scale SO 2 plumes from space in anticipation of the 1998 launch of the advanced spaceborne thermal emission and reflectance radiometer (ASTER).

Journal of Geophysical Research B: Solid Earth

Volcanic gases create air pollution on the Island of Hawai’i

In a handful of molten magma weighing about a pound, there is less than a tenth of an ounce, by weight, of idssolved gas-roughly the same weight as a pinch of table salt. Yet this tiny amount of gas produces spectacular lava foundations hundreds of meters high (see accompanying photograph). The fountain occurs as magma reaches the surface, because dissolved volcanic gases exolve and expand tremendously as pressure on the magma is released. Anyone who has shaken a bottle of soda and opened it quickly has received the full value of this basic principle of physics. Gases are dissolved in magma at depth, where pressures within Earth's crust are very great-many thousands of pounds per square inch. As the magma rises to the surface and erupts, the pressure decreases, and gas is released. The main gases dissolved in magma are water vapor, carbon dioxide, and sulfur gases, with lesser amounts of others, such as hydrogen, carbon monoxide, hydrochloric acid, and hydrofluoric acid. In our pinch-of-salt-to-a-handful-of-magma illustration above, most of the "pinch" is water vapor, followed by lesser amounts of carbon dioxide and sulfur gases with a few "grains" of hydrogen and other acid gases. The current eruption of Kilauea produces large quantities of volcanic gases that contribute to "volcanic air pollution." In this article we discuss the nature of the gases released from Kilauea, hoe we study them, and what happened to the gases in the environment after they are released.

Hawaii