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Stewart F. Clark

Publications and source records attributed to Stewart F. Clark.

10 recordsLinked to original sources

Effects of Highway Road Salting on the Water Quality of Selected Streams in Chittenden County, Vermont, November 2005-2007

A study of road-deicing chloride (Cl) concentrations and loads was conducted at three streams in Chittenden County, VT, from November 2005 to 2007. This study was done by the U.S. Geological Survey, in cooperation with the Vermont Agency of Transportation. The streams, Alder Brook, Allen Brook, and Mill Brook, were selected to represent different land uses in the upstream watershed, different road types and densities, and different geometric patterns of the roadway draining to the receiving stream to assess the relative contribution of and differences in state road-salt applications to stream Cl concentrations and loads. Water-quality samples were collected and specific conductance was measured continuously at paired stations upstream and downstream from State highways and related to Cl concentrations to assist in determining the effects of road-salting operations during winter maintenance on the levels of Cl in the streams. Mean concentrations of Cl ranged from 8.2 to 72 mg/L (milligrams per liter) in the water-quality samples collected at sampling stations upstream from State highway bridges and from 7.9 to 80 mg/L in those collected at sampling stations downstream of highway bridges. Mean Cl loads ranged from 1,100 to 4,090 lb/d (pounds per day) at upstream stations and from 1,110 to 4,200 lb/d at downstream stations. Estimated mean annual Cl loads ranged from 402,000 to 1,490,000 lb/yr (pounds per year) at upstream stations and from 405,000 to 1,530,000 lb/yr at downstream stations. Mean Cl concentrations in samples collected at the three paired stations were lowest at Mill Brook at VT 117 near Essex Junction, VT (7.9 mg/L) and highest at Allen Brook at VT 2A near Essex Junction, VT (80.7 mg/L). None of the monitored Cl concentrations in the water-quality samples collected at the three paired sampling stations exceeded either of the U.S. Environmental Protection Agency's (USEPA) recommended chronic and acute Cl toxicity criteria of 230 and 860 mg/L, respectively. A fourth stream site, a small tributary draining to Alder Brook between the upstream and downstream stations, was monitored from December 2006 to November 2007. This tributary collected runoff from a state highway and an interchange before flowing through a wetlands retention basin. The mean Cl concentration in water-quality samples collected at the tributary was 449 mg/L. The USEPA recommended chronic toxicity criterion of 230 mg/L was exceeded about 65 percent of the monitoring period. The USEPA recommended acute toxicity criterion of 860 mg/L was not exceeded. Estimated Cl loads below the State highway bridges exceeded loads above the bridges at all three paired stations during both years of the study. The differences in the annual loads between the upstream and downstream stations were 0.7, 3.0 and 14 percent at Mill, Allen, and Alder Brooks, respectively. Almost all of the difference (92 percent) at Alder Brook was due to the tributary. Cl applied by the State of Vermont for deicing purposes represented less than 20 percent of the annual estimated Cl load in all 3 streams below the state highways. The highest monthly Cl loads during the first year of the study were observed in January 2006 at all three stream stations because of an early snowmelt event. The highest monthly Cl loads during the second year of the study were observed in April 2007 at all three streams during spring snowmelt and were followed by decrease in Cl loading through the summer. Generally, the relation of Cl loads to runoff was similar at all three streams. In July and October 2007, loads increased slightly with an increase in runoff, indicating that Cl in the soils and groundwater may be contributing to the Cl levels during the summer and fall, well after the road-salting season. Cl loads in all three streams appear to be due primarily to sources in the watersheds upstream of the state highway bridge where road salt was applied and (or) Cl retained in soils and streambed

Scientific Investigations Report

Geology and preliminary hydrogeologic characterization of the cell-house site, Berlin, New Hampshire, 2003-04

At the cell-house site, thin, generally less than 20-foot thick overburden, consisting of till and demolition materials, overlies fractured crystalline bedrock. Bedrock at the site consists of gneiss with thin discontinuous lenses of chlorite schist and discontinuous tabular pegmatite. Two distinct fracture domains, with principal trends to the west and northwest, and to the north, overlap near the site. The cell-house site shows principal trends common to both domains. Gneiss is the most abundant rock at the site. Steeply dipping fractures within the gneiss terminate on subhorizontal contacts with pegmatite and on moderately dipping contacts with chlorite schist. Steeply northwest-dipping en Echelon fracture zones, parallel joint zones, and silicified brittle faults show consistent strikes to the northeast. Gently east-dipping to subhorizontal fractures, sub-parallel to gneissosity, strike northeast. The impermeable cap, barrier wall, and bedrock surface topography affect ground-water flow in the overburden. There is relatively little ground-water flow in the overburden in the capped area and a poor hydraulic connection between the overburden and the underlying bedrock over most of the site. The overburden beneath the cap may receive inflow through or beneath the barrier wall, or by flow through vertical fractures in the underlying bedrock beneath the barrier wall. The bedrock aquifer near the river is well connected to the river and head difference in the bedrock across the site are large (greater than 13 ft). Horizontal hydraulic conductivities of 0.2 to 20 ft/d were estimated for the bedrock. Individual fractures or fracture zones likely have hydraulic conductivities greater than the bulk rock. Subhorizontal fractures occur at pegmatite contacts or along chlorite schist lenses and may serve as ground-water conduits to the steeply dipping fractures in gneiss. The effective hydraulic conductivity across the site is likely to be in the low range of the estimated values (0.2 ft/d). Ground water discharges to the river from the bedrock aquifer and is greatest during periods of large river stage fluctuations.

Scientific Investigations Report

Hydrogeologic framework and water quality of the Vermont Army National Guard Ethan Allen Firing Range, northern Vermont, October 2002 through December 2003

The Ethan Allen Firing Range of the Vermont Army National Guard is a weapons-testing and training facility in a mountainous region of Vermont that has been in operation for about 80 years. The hydrologic framework and water quality of the facility were assessed between October 2002 and December 2003. As part of the study, streamflow was continuously measured in the Lee River and 24 observation wells were installed at 19 locations in the stratified drift and bedrock aquifers to examine the hydrogeology. Chemical analyses of surface water, ground water, streambed sediment, and fish tissue were collected to assess major ions, trace elements, nutrients, and volatile and semivolatile compounds. Sampling included 5 surface-water sites sampled during moderate and low-flow conditions; streambed-sediment samples collected at the 5 surface-water sites; fish-tissue samples collected at 3 of the 5 surface-water sites; macroinvertebrates collected at 4 of the 5 surface-water sites; and ground-water samples collected from 10 observation wells, and samples collected at all surface- and ground-water sites. The hydrogeologic framework at the Ethan Allen Firing Range is dominated by the upland mountain and valley setting of the site. Bedrock wells yield low to moderate amounts of water (0 to 23 liters per minute). In the narrow river valleys, layered stratified-drift deposits of sand and gravel of up to 18 meters thick fill the Lee River and Mill Brook Valleys. In these deposits, the water table is generally within 3 meters below the land surface and overall ground-water flow is from east to west. Streamflow in the Lee River averaged 0.72 cubic meters per second (25.4 cubic feet per second) between December 2002 and December 2003. Streams are highly responsive to precipitation events in this mountainous environment and a comparison with other nearby watersheds shows that Lee River maintains relatively high streamflow during dry periods. Concentrations of trace elements and nutrients in surface-water samples are well below freshwater-quality guidelines for the protection of aquatic life. Brook-trout samples collected in 1992 and 2003 show trace-metal concentrations have decreased over the past 11 years. concentrations in water samples are well below levels that restrict swimming at all five stream sites at moderate and low-flow conditions and in all observation wells. Comparisons among surface-water, streambed-sediment, and biological samples collected in 2003 to earlier studies at the Ethan Allen Firing Range indicate water-quality conditions are similar or have improved over the past 15 years. Ground water in the stratified-drift aquifers at the facility is well buffered with relatively high alkalinities and pH greater than 6. Concentrations of arsenic, cadmium, chromium, lead, nickel, uranium, and zinc were below detection levels in ground-water samples. Barium, cobalt, copper, iron, manganese, molybdenum, and strontium were the only trace elements detected in ground-water samples. Cobalt and iron were detected at low levels in two wells near Mill Brook, and copper was detected at the detection limit in one of these wells. These same two wells had concentrations of barium and manganese 2 to 10 times greater than other ground-water samples. Concentrations of nutrients are at or below detection levels in most ground-water samples. Volatile organic compounds and semivolatile organic compounds were not detected in any water samples from the Ethan Allen Firing Range.

Scientific Investigations Report

Fracture-correlated lineaments at Great Bay, southeastern New Hampshire

Analysis by remote-sensing techniques and observations of exposed bedrock structure were preliminary steps taken in a study to locate potential bedrock-fracture zones that may store and transmit ground water near Great Bay, N.H. To help correlate lineaments on the surface with fractures, structural measurements were made at exposed bedrock, largely along the shoreline of the bay, and analyzed to identify fracture trends and fracture characteristics. With these fracture data, lineament-filtering techniques, such as (1) buffer analysis around individual lineaments, (2) discrete-measurement analysis by domain, and (3) spacing-normalized analysis by domain, identified 'fracture-correlated lineaments.' Of the 927 lineaments identified in the study area (180 square kilometers), 406 (44 percent) were evaluated because they either were located within 305 meters of an outcrop with fracture data or intersected one of five 3,300-meter-square grid domain cells that encompassed the fracture data. Of the 406 lineaments, 190 (47 percent) are fracture correlated, although only 15 percent were correlated by more than one filtering technique. The large number of lineaments found in areas of thin glacial overburden and high densities of fractured outcrops suggests that filtering techniques are useful in these areas to selectively identify fracture-correlated lineaments. Fractures parallel to bedding in the Kittery Formation are open locally and often associated with vugs, with up to 1-centimeter aperture, and may provide appreciable secondary porosity in this rock unit. Discrete-measurement analysis by domain identified fracture-correlated lineaments with orientations parallel to these open and vug-filled fractures. Fracture-correlated lineaments related to closely spaced fractures were identified by the spacing-normalized analysis by domain. Analysis results may be used to indicate the potential bedrock pathways for ground-water-discharge points along the shoreline of Great Bay.

Open-File Report