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Steven D. Zaugg

Publications and source records attributed to Steven D. Zaugg.

At least 37 records · Page 2Linked to original sources
USGS2008

A multi-disciplinary approach to the removal of emerging contaminants in municipal wastewater treatment plants in New York state (2003-2004)

Across the United States, there is a rapidly growing awareness of the occurrence and the toxicological impacts of natural and synthetic trace compounds in the environment. These trace compounds, referred to as emerging contaminants (ECs), are reported to cause a range of negative impacts in the environment, such as adverse effects on biota in receiving streams and interference with the normal functions of the endocrine system, which controls growth and development in living organisms.

New York↗
USGS2007

Do pharmaceuticals, pathogens, and other organic waste water compounds persist when waste water is used for recharge?

A proof-of-concept experiment was devised to determine if pharmaceuticals and other organic waste water compounds (OWCs), as well as pathogens, found in treated effluent could be transported through a 2.4 m soil column and, thus, potentially reach ground water under recharge conditions similar to those in arid or semiarid climates. Treated effluent was applied at the top of the 2.4 m long, 32.5 cm diameter soil column over 23 days, Samples of the column inflow were collected from the effluent storage tank at the beginning (T begin ) and end (T end ) of the experiment, and a sample of the soil column drainage at the base of the column (B end ) was collected at the end of the experiment. Samples were analyzed for 131 OWCs including veterinary and human antibiotics, other prescription and nonprescription drugs, widely used household and industrial chemicals, and steroids and reproductive hormones, as well as the pathogens Salmonella and Legionella . Analytical results for the two effluent samples taken at the beginning (T begin ) and end (T end ) of the experiment indicate that the number of OWCs detected in the column inflow decreased by 25% (eight compounds) and the total concentration of OWCs decreased by 46% while the effluent was in the storage tank during the 23-day experiment. After percolating through the soil column, an additional 18 compounds detected in T end (67% of OWCs) were no longer detected in the effluent (B end ) and the total concentration of OWCs decreased by more than 70%. These compounds may have been subject to transformation (biotic and abiotic), adsorption, and (or) volatilization in the storage tank and during travel through the soil column. Eight compounds—carbamazapine; sulfamethoxazole; benzophenone; 5-methyl-1H-benzotriazole; N,N-diethyltoluamide; tributylphosphate; tri(2-chloroethyl) phosphate; and cholesterol—were detected in all three samples indicating they have the potential to reach ground water under recharge conditions similar to those in arid and semiarid climates. Results from real-time polymerase chain reactions demonstrated the presence of Legionella in all three samples. Salmonella was detected only in T begin , suggesting that the bacteria died off in the effluent storage tank over the period of the experiment. This proof-of-concept experiment demonstrates that, under recharge conditions similar to those in arid or semiarid climates, some pharmaceuticals, pathogens, and other OWCs can persist in treated effluent after soil-aquifer treatment.

Ground Water Monitoring and Remediation↗
USGS2007

Pharmaceuticals and other organic wastewater contaminants within a leachate plume downgradient of a municipal landfill

Ground water samples collected from the Norman Landfill research site in central Oklahoma were analyzed as part of the U.S. Geological Survey (USGS) Toxic Substances Hydrology Program's national reconnaissance of pharmaceuticals and other organic waste water contaminants (OWCs) in ground water. Five sites, four of which are located downgradient of the landfill, were sampled in 2000 and analyzed for 76 OWCs using four research methods developed by the USGS. OWCs were detected in water samples from all of the sites sampled, with 22 of the 76 OWCs being detected at least once. Cholesterol (a plant and animal steroid), was detected at all five sites and was the only compound detected in a well upgradient of the landfill. N,Ndiethyltoluamide (DEET used in insect repellent) and tri(2-chloroethyl) phosphate (fire-retardant) were detected in water samples from all four sites located within the landfill-derived leachate plume. The sites closest to the landfill had more detections and greater concentrations of each of the detected compounds than sites located farther away. Detection of multiple OWCs occurred in the four sites located within the leachate plume, with a minimum of four and a maximum of 17 OWCs detected. Because the landfill was established in the 1920s and closed in 1985, many compounds detected in the leachate plume were likely disposed of decades ago. These results indicate the potential for long-term persistence and transport of some OWCs in ground water.

Oklahoma↗
USGS2007

Efficiency of conventional drinking-water-treatment processes in removal of pharmaceuticals and other organic compounds

Samples of water and sediment from a conventional drinking-water-treatment (DWT) plant were analyzed for 113 organic compounds (OCs) that included pharmaceuticals, detergent degradates, flame retardants and plasticizers, polycyclic aromatic hydrocarbons (PAHs), fragrances and flavorants, pesticides and an insect repellent, and plant and animal steroids. 45 of these compounds were detected in samples of source water and 34 were detected in samples of settled sludge and (or) filter-backwash sediments. The average percent removal of these compounds was calculated from their average concentration in time-composited water samples collected after clarification, disinfection (chlorination), and granular-activated-carbon (GAC) filtration. In general, GAC filtration accounted for 53% of the removal of these compounds from the aqueous phase; disinfection accounted for 32%, and clarification accounted for 15%. The effectiveness of these treatments varied widely within and among classes of compounds; some hydrophobic compounds were strongly oxidized by free chlorine, and some hydrophilic compounds were partly removed through adsorption processes. The detection of 21 of the compounds in 1 or more samples of finished water, and of 3 to 13 compounds in every finished-water sample, indicates substantial but incomplete degradation or removal of OCs through the conventional DWT process used at this plant.

Science of the Total Environment↗
USGS2006

Response to comment on “Persistence of pharmaceutical compounds and other organic wastewater contaminants in a conventional drinking-water-treatment plant”

The U.S. Geological Survey (USGS) and the Centers for Disease Control thank Dr. Till for her comments concerning our research ( Till, 2005 ) and welcome the opportunity to respond. The primary objective of our study was to evaluate the potential for organic wastewater-related contaminants (OWCs), including pharmaceuticals, to survive a conventional drinking-water-treatment process and persist in potable-water supplies ( Stackelberg et al., 2004 ). Our study was supported by two USGS laboratories: the National Water Quality Laboratory (NWQL), which provided the HPLC/ESI-MS and CLLE GC/MS data and the Ocala Water Quality and Research Laboratory (OWQRL), which provided the LC/MS data ( Stackelberg et al., 2004 ). Although discussed as distinct techniques by Dr. Till and indicated by differing acronyms to distinguish the laboratories producing the data, as described in our paper, the two LC/MS methods are very similar; they consist of a solid-phase extraction method with analysis of the extract produced using high-performance liquid chromatography coupled to an electrospray ionization mass spectrometer operated in the positive mode. The NWQL and OWQRL report ‘trace’ and ‘ultratrace’ determinations of analytes that provide significant benefit for describing the presence and fate of low-level contaminants. For mass spectral methods, an analyte is qualitatively identified by its retention time on the chromatographic column as well as the presence of two or more confirming ions with area ratios that match that of the reference standard compounds. Because of a recognized increased risk of false positives, these qualitative identification criteria are used in conjunction with abundant quality-control samples (detailed below) to confirm detection prior to making an estimate of the concentration. These qualitative identification criteria must be met before a compound is considered present (or detected) in a sample ( Oblinger Childress et al., 1999 ). When a compound has been qualitatively identified in an environmental sample (whether above or below its reporting level [RL]), it is assessed in context with associated field and laboratory blanks, field and laboratory replicates, and other data, such as appropriate laboratory reagent spikes. An environmental concentration is calculated only after determining that field and laboratory procedures did not contaminate the samples. The concentrations are then calculated from 5- to 8-point calibration curves using internal standard quantitation. Our lowest calibration standard is intentionally much lower than the RL, typically 10 times lower. The most abundant molecular or fragment ion is used for quantitation, and, for the two LC/MS methods, at least one, and where possible two, qualifier ions are used for confirmation. For the GC/MS method, with its greater degree of fragmentation, one quantitation and two qualifier ions are used. When any of the abovementioned qualitative identification criteria are not met, the analyte is considered not present and is reported as “less than” the RL.

Science of the Total Environment↗
USGS2006

Water quality in the Blue River Basin, Kansas City metropolitan area, Missouri and Kansas, July 1998 to October 2004

Water-quality data were collected from sites in the Blue River Basin from July 1998 to October. Sites upstream from wastewater-treatment plants or the combined sewer system area had lower concentrations of total nitrogen, phosphorus, organic wastewater compounds, and pharmaceuticals, and more diverse aquatic communities. Sites downstream from wastewater-treatment plants had the largest concentrations and loads of nutrients, organic wastewater compounds, and pharmaceuticals. Approximately 60 percent of the total nitrogen and phosphorus in Blue River originated from the Indian Creek, smaller amounts from the upper Blue River (from 28 to 16 percent), and less than 5 percent from Brush Creek. Nutrient yields from the Indian Creek and the middle Blue River were significantly greater than yields from the upper Blue River, lower Brush Creek, the outside control site, and other U.S. urban sites. Large concentrations of nutrients led to eutrophication of impounded Brush Creek reaches. Bottom sediment samples collected from impoundments generally had concentrations of organic wastewater and pharmaceutical compounds equivalent to or greater than, concentrations observed in streambed sediments downstream from wastewater-treatment plants. Bacteria in streams largely was the result of nonpoint-source contributions during storms. Based on genetic source-tracking, average contributions of in-stream Esherichia coli bacteria in the basin from dogs ranged from 26-32 percent of the total concentration, and human sources ranged from 28-42 percent. Macro invertebrate diversity was highest at sites with the largest percentage of upstream land use devoted to forests and grasslands. Declines in macro invertebrate community metrics were correlated strongly with increases in several, inter-related urbanization factors.

Fact Sheet↗
USGS2006

Water quality in the Blue River basin, Kansas City metropolitan area, Missouri and Kansas, July 1998 to October 2004

Water-quality data were collected from sites in the Blue River Basin from July 1998 to October. Sites upstream from wastewater-treatment plants or the combined sewer system area had lower concentrations of total nitrogen, phosphorus, organic wastewater compounds, and pharmaceuticals, and more diverse aquatic communities. Sites downstream from wastewater-treatment plants had the largest concentrations and loads of nutrients, organic wastewater compounds, and pharmaceuticals. Approximately 60 percent of the total nitrogen and phosphorus in Blue River originated from the Indian Creek, smaller amounts from the upper Blue River (from 28 to 16 percent), and less than 5 percent from Brush Creek. Nutrient yields from the Indian Creek and the middle Blue River were significantly greater than yields from the upper Blue River, lower Brush Creek, the outside control site, and other U.S. urban sites. Large concentrations of nutrients led to eutrophication of impounded Brush Creek reaches. Bottom sediment samples collected from impoundments generally had concentrations of organic wastewater and pharmaceutical compounds equivalent to or greater than, concentrations observed in streambed sediments downstream from wastewater-treatment plants. Bacteria in streams largely was the result of nonpoint-source contributions during storms. Based on genetic source-tracking, average contributions of in-stream Esherichia coli bacteria in the basin from dogs ranged from 26-32 percent of the total concentration, and human sources ranged from 28-42 percent. Macro invertebrate diversity was highest at sites with the largest percentage of upstream land use devoted to forests and grasslands. Declines in macro invertebrate community metrics were correlated strongly with increases in several, inter-related urbanization factors.

Scientific Investigations Report↗
USGS2006

Chapter 3. Determination of semivolatile organic compounds and polycyclic aromatic hydrocarbons in solids by gas chromatography/mass spectrometry

A method for the determination of 38 polycyclic aromatic hydrocarbons (PAHs) and semivolatile organic compounds in solid samples is described. Samples are extracted using a pressurized solvent extraction system. The compounds of interest are extracted from the solid sample twice at 13,800 kilopascals; first at 120 degrees Celsius using a water/isopropyl alcohol mixture (50:50, volume-to-volume ratio), and then the sample is extracted at 200 degrees Celsius using a water/isopropyl alcohol mixture (80:20, volume-to-volume ratio). The compounds are isolated using disposable solid-phase extraction (SPE) cartridges containing divinylbenzene-vinylpyrrolidone copolymer resin. The cartridges are dried with nitrogen gas, and then sorbed compounds are eluted from the SPE material using a dichloromethane/diethyl ether mixture (80:20, volume-to-volume ratio) and passed through a sodium sulfate/Florisil SPE cartridge to remove residual water and to further clean up the extract. The concentrated extract is solvent exchanged into ethyl acetate and the solvent volume reduced to 0.5 milliliter. Internal standard compounds are added prior to analysis by capillary-column gas chromatography/mass spectrometry. Comparisons of PAH data for 28 sediment samples extracted by Soxhlet and the accelerated solvent extraction (ASE) method described in this report produced similar results. Extraction of PAH compounds from standard reference material using this method also compared favorably with Soxhlet extraction. The recoveries of PAHs less than molecular weight 202 (pyrene or fluoranthene) are higher by up to 20 percent using this ASE method, whereas the recoveries of PAHs greater than or equal to molecular weight 202 are equivalent. This ASE method of sample extraction of solids has advantages over conventional Soxhlet extraction by increasing automation of the extraction process, reducing extraction time, and using less solvent. Extract cleanup also is greatly simplified because SPE replaces commonly used gel permeation chromatography. The performance of the method (as expressed by mean recoveries and mean precision) was determined using Ottawa sand, a commercially available topsoil, and an environmental stream sediment, fortified at 1.5 and 15 micrograms per compound. Recoveries of PAH and semivolatile compounds in Ottawa sand samples fortified at 1.5 micrograms averaged 88 percent ? 9.4 percent relative standard deviation, and calculated initial method detection limits per compound averaged 14 micrograms per kilogram, assuming a 25-gram sample size. The recovery for 1,2,4-trichlorobenzene is less than 60 percent; thus, the concentration of this compound will always be reported as estimated with the E remark code. The analysis of 25 alkylated PAH homolog groups also can be determined with this method with extra data analysis and review, but because of the lack of authentic reference standard compounds, these results are considered to be semiquantitative. The PAH homolog groups are quantitated using the response factor of a parent PAH method compound, if available. Precision data for the alkylated PAH homologs detected in a marine sediment standard reference material (SRM 1944) also are presented to document and demonstrate method capability.

Techniques and Methods↗
USGS2006

Determination of wastewater compounds in whole water by continuous liquid-liquid extraction and capillary-column gas chromatography/mass spectrometry

A method for the determination of 69 compounds typically found in domestic and industrial wastewater is described. The method was developed in response to increasing concern over the impact of endocrine-disrupting chemicals on aquatic organisms in wastewater. This method also is useful for evaluating the effects of combined sanitary and storm-sewer overflow on the water quality of urban streams. The method focuses on the determination of compounds that are indicators of wastewater or have endocrine-disrupting potential. These compounds include the alkylphenol ethoxylate nonionic surfactants, food additives, fragrances, antioxidants, flame retardants, plasticizers, industrial solvents, disinfectants, fecal sterols, polycyclic aromatic hydrocarbons, and high-use domestic pesticides. Wastewater compounds in whole-water samples were extracted using continuous liquid-liquid extractors and methylene chloride solvent, and then determined by capillary-column gas chromatography/mass spectrometry. Recoveries in reagent-water samples fortified at 0.5 microgram per liter averaged 72 percent ? 8 percent relative standard deviation. The concentration of 21 compounds is always reported as estimated because method recovery was less than 60 percent, variability was greater than 25 percent relative standard deviation, or standard reference compounds were prepared from technical mixtures. Initial method detection limits averaged 0.18 microgram per liter. Samples were preserved by adding 60 grams of sodium chloride and stored at 4 degrees Celsius. The laboratory established a sample holding-time limit prior to sample extraction of 14 days from the date of collection.

Techniques and Methods↗
USGS2005

Water-quality and biologic data for the Blue River basin, Kansas City metropolitan area, Missouri and Kansas, October 2000 to October 2004

This report presents water-quality and biologic data collected in the Blue River Basin, metropolitan Kansas City, Missouri and Kansas, from October 2000 to October 2004. Data were collected in cooperation with the city of Kansas City, Missouri, Water Services Department as part of an ongoing study designed to characterize long-term water-quality trends in the basin and to provide data to support a strategy for combined sewer overflow control. These data include values of physical properties, fecal indicator bacteria densities, suspended sediment, and concentrations of major ions, nutrients, trace elements, organic wastewater compounds, and pharmaceutical compounds in base-flow and stormflow stream samples and bottom sediments. Six surface-water sites in the basin were sampled 13 times during base-flow conditions and during a minimum of 7 storms. Benthic macroinvertebrate communities are described at 10 sites in the basin and 1 site outside the basin. Water-column and bottom-sediment data from impounded reaches of Brush Creek are provided. Continuous specific conductance, pH, water-quality temperature, turbidity, and dissolved oxygen data are provided for two streams-the Blue River and Brush Creek. Sampling, analytical, and quality assurance methods used in data collection during the study also are described in the report.

Kansas, Missouri↗
USGS2005

Studies examine contaminants: Pharmaceuticals, hormones and other organic wastewater contaminants in ground water resources

Ground water provides approximately 40 percent of the nation’s public water supply, and the total percentage of withdrawals for irrigation has increased from 23 percent in 1950 to 42 percent in 2000. Ground water also is a major contributor to flow in many streams and rivers in the United States and has a substantial influence on river and wetland habitats for plants and animals. Organic wastewater contaminants (OWCs) in the environment recently have been documented to be of global concern with a variety of sources and source pathways.

National Driller↗
USGS2004

Presence and distribution of organic wastewater compounds in wastewater, surface, ground, and drinking waters, Minnesota, 2000-02

Selected organic wastewater compounds (OWCs) such as household, industrial, and agricultural-use compounds, pharmaceuticals, antibiotics, and sterols and hormones were measured at 65 sites in Minnesota as part of a cooperative study among the Minnesota Department of Health, Minnesota Pollution Control Agency, and the U.S. Geological Survey. Samples were collected in Minnesota during October 2000 through November 2002 and analyzed for the presence and distribution of 91 OWCs at sites including wastewater treatment plant influent and effluent; landfill and feedlot lagoon leachate; surface water; ground water (underlying sewered and unsewered mixed urban land use, a waste dump, and feedlots); and the intake and finished drinking water from drinking water facilities. There were 74 OWCs detected that represent a wide variety of use. Samples generally comprised a mixture of compounds (average of 6 OWCs) and 90 percent of the samples had at least one OWC detected. Concentrations for detected OWCs generally were less than 3 micrograms per liter. The ten most frequently detected OWCs were metolachlor (agricultural-use herbicide); cholesterol (sterol primarily associated with animal waste); caffeine (stimulant), N,N-diethyl- meta -toluamide (DEET) (topical insect repellant); bromoform (disinfection by product); tri(2-chloroethyl)phosphate (flame-retardant and plastic component); beta -sitosterol (plant sterol that is a known endocrine disruptor); acetyl-hexamethyl-tetrahydro- naphthalene (AHTN) (synthetic musk widely used in personal care products, and a known endocrine disruptor); bisphenol-A (plastic component and a known endocrine disruptor); and cotinine (metabolite of nicotine). Wastewater treatment plant influent and effluent, landfill leachate, and ground water underlying a waste dump had the greatest number of OWCs detected. OWC detections in ground-water were low except underlying the one waste dump studied and feedlots. There generally were more OWCs detected in surface water than ground water, and there were twice as many OWCs detected in the surface water sites downstream from wastewater treatment plant (WWTP effluent than at sites not directly downstream from effluent. Comparisons among site classifications apply only to sites sampled during the study. Results of this study indicate ubiquitous distribution of measured OWCs in the environment that originate from numerous sources and pathways. During this reconnaissance of OWCs in Minnesota it was not possible to determine the specific sources of OWCs to surface, ground, or drinking waters. The data indicate WWTP effluent is a major pathway of OWCs to surface waters and that landfill leachate at selected facilities is a potential source of OWCs to WWTPs. Aquatic organism or human exposure to some OWCs is likely based on OWC distribution. Few aquatic or human health standards or criteria exist for the OWCs analyzed, and the risks to humans or aquatic wildlife are not known. Some OWCs detected in this study are endocrine disrupters and have been found to disrupt or influence endocrine function in fish. Thirteen endocrine disrupters, 3- tert -butyl-4-hydoxyanisole (BHA), 4- cumylphenol, 4- normal -octylphenol, 4- tert -octylphenol, acetyl-hexamethyl-tetrahydro-naphthalene (AHTN), benzo[α]pyrene, beta-sitosterol, bisphenol-A, diazinon, nonylphenol diethoxylate (NP2EO), octyphenol diethoxylate (OP2EO), octylphenol monoethoxylate (OP1EO), and total para -nonylphenol (NP) were detected. Results of reconnaissance studies may help regulators who set water-quality standards begin to prioritize which OWCs to focus upon for given categories of water use.

Minnesota↗
USGS2003

Response to comment on "Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999-2000: A national reconnaissance"

Till (1) raised concerns that several aspects of how we handled the data in our study (2) may have caused unintended bias. First, Till (1) considers the “median detectable concentrations” listed in Table 1 (2) to be misleading because “higher median concentrations than is actually the case” were suggested. We interpret this concern raised by Till (1) to be that some readers may misinterpret our median detectable concentration to be an overall median concentration. Our intention was to provide the reader with information that could not easily be determined independently. For example, by examining the frequency of detection (2), it could easily be determined that the overall median concentration was less than the reporting level for all but six compounds (those having a detection frequency of>50%). Our goal for providing a median detectable concentration was to give a better sense of the concentrations when a particular compound was detected. Thus, we felt the combination of frequency of detection (how often a compound was found), median detectable concentration (median concentration when a compound was detected), and maximum concentration (highest concentration measured) would provide the greatest benefit to the readers. In future reports, we will modify the table headings to ensure that overall median concentration and median detectable concentration are clearly differentiated.

Environmental Science & Technology↗
USGS2003

Chapter A5. Section 6.1.F. Wastewater, Pharmaceutical, and Antibiotic Compounds

The USGS differentiates between samples collected for analysis of wastewater compounds and those collected for analysis of pharmaceutical and antibiotic compounds, based on the analytical schedule for the laboratory method. Currently, only the wastewater laboratory method for field-filtered samples (SH1433) is an approved, routine (production) method. (The unfiltered wastewater method LC 8033 also is available but requires a proposal for custom analysis.) At this time, analysis of samples for pharmaceutical and antibiotic compounds is confined to research studies and is available only on a custom basis.

Techniques of Water-Resources Investigations↗
USGS2002

Response to comment on "Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999-2000: A national reconnaissance"

We concur with the response of Eckel to our recent publication in this Journal (1). As the author notes, the topic of emerging contaminants is currently receiving extensive media coverage and scientific notice, but there are earlier reports that foreshadow this current interest. Eckel’s comment regarding the detection of pharmaceuticals and other organic wastewater contaminants (OWC) at a Superfund landfill site (2) is well taken, as other reports confirm the presence of such compounds at waste-disposal and landfill sites (3). In fact, literature from more than 20 years ago documented the occurrence of OWCs in the environment (4-7). A significant difference between these reports and our study is that we have systematically documented the frequent presence and low concentrations of a broad suite of OWCs in a wide variety of streams across the United States.

Environmental Science & Technology↗
USGS2002

Response to comment on "Pharmaceuticals, hormones, and other organic wastewater contaminants in U.S. streams, 1999-2000: A national reconnaissance"

We thank Ericson et al. (1) for their careful review and thoughtful comments on the synthetic hormone data presented in our recent publication summarizing the results from the USGS nationwide reconnaissance for pharmaceuticals and other organic wastewater contaminants (2). Their efforts have helped raise the awareness of the difficulties in accurately measuring these compounds at the low concentrations that occur in the environment and reinforce the need for continued research in the area of analytical methods development for synthetic hormones

Environmental Science & Technology↗
USGS2002

Methods of analysis by the U.S. Geological Survey National Water Quality Laboratory-A method supplement for the determination of Fipronil and degradates in water by gas chromatography/mass spectrometry

A method for the isolation and detemrination of fipronil and four of its degradates has been developed. This method adapts an analytical method created by the U.S. Geological Survey National Water Quality Laboratory in 1995 for the determination of a broad range of high-use pesticides typically found in filtered natural-water samples. In 2000, fipronil and four of its degradates were extracted, analyzed, and validated using this method. The recoveries for these five compounds in reagent-water samples fortified at 1 microgram per liter (ug/L) avereraged 98 percent. Initial method detection limits averaged 0.0029 ug/L. The performance of these five new compounds is consistent with the performance of the compounds in the initial method, making it possible to include them in addition to the other 41 pesticides and pesticide degradates in the original method.

Open-File Report↗