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Stephane Le Mouelic

Publications and source records attributed to Stephane Le Mouelic.

10 recordsLinked to original sources
USGS2024

Geological context and significance of the clay-sulfate transition region in Mount Sharp, Gale crater, Mars: An integrated assessment based on orbiter and rover data

On Mars, phyllosilicate (“clay”) minerals are often associated with older terrains, and sulfate minerals are associated with younger terrains, and this dichotomy is taken as evidence that Mars’ surface dried up over time. Therefore, in situ investigation of the Mount Sharp strata in Gale crater, which record a shift from dominantly clay-bearing to sulfate-bearing minerals, as seen in visible−near-infrared orbital reflectance spectra, is a key science objective for the Mars Science Laboratory (MSL) Curiosity rover mission. Here, we present regional (orbiter-based) and in situ (rover-based) evidence for a low-angle erosional unconformity that separates the lacustrine and marginal lacustrine deposits of the Carolyn Shoemaker formation from the dominantly eolian deposits of the lower Mirador formation within the orbitally defined clay-sulfate transition region. The up-section record of wetter (Carolyn Shoemaker formation) to drier (lower Mirador formation) depositional conditions is accompanied by distinct changes in diagenesis. Clay minerals occur preferentially within the Carolyn Shoemaker formation and are absent within the lower members of the Mirador formation. At and above the proposed unconformity, strata are characterized by an increase in diagenetic nodules enriched in X-ray amorphous Mg-sulfate. Early clay formation in the Carolyn Shoemaker formation may have created a hydraulic barrier such that later migrating magnesium- and sulfur-rich fluids accumulated preferentially within the lower members of the Mirador formation. The proposed unconformity may have also acted as a fluid conduit to further promote Mg-sulfate nodule formation at the Carolyn Shoemaker−Mirador formation boundary. These results confirm an association of the clay-sulfate transition with the drying of depositional environments, but they also suggest that at least some orbital sulfate signatures within the region are not time-congruent with the environmental signals extracted from primary sedimentology. Our findings highlight that complex interactions among primary depositional environment, erosion, and diagenesis contribute to the transition in clay-sulfate orbital signatures observed in the stratigraphy of Mount Sharp.

GSA Bulletin↗
USGS2022

Bedrock geochemistry and alteration history of the clay-bearing Glen Torridon region of Gale crater, Mars

Glen Torridon is a topographic trough located on the slope of Aeolis Mons, Gale crater, Mars. It corresponds to what was previously referred to as the “clay-bearing unit”, due to the relatively strong spectral signatures of clay minerals (mainly ferric smectites) detected from orbit. Starting in January 2019, the Curiosity rover explored Glen Torridon for more than 700 sols (Martian days). The objectives of this campaign included acquiring a detailed understanding of the geologic context in which the clay minerals were formed and determining the intensity of aqueous alteration experienced by the sediments. Here, we present the major-element geochemistry of the bedrock as analyzed by the ChemCam instrument. Our results reveal that the two main types of bedrock exposures identified in the lower part of Glen Torridon are associated with distinct chemical compositions (K-rich and Mg-rich), for which we are able to propose mineralogical interpretations. Moreover, the topmost stratigraphic member exposed in the region displays a stronger diagenetic overprint, especially at two locations close to the unconformable contact with the overlying Stimson formation, where the bedrock composition significantly deviates from the rest of Glen Torridon. Overall, the values of the Chemical Index of Alteration determined with ChemCam are elevated by Martian standards, suggesting the formation of clay minerals through open system weathering. However, there is no indication that the alteration was stronger than in some terrains previously visited by Curiosity , which in turn implies that the enhanced orbital signatures are mostly controlled by non-compositional factors.

Journal of Geophysical Research E: Planets↗
USGS2022

Overview of the morphology and chemistry of diagenetic features in the clay-rich Glen Torridon Unit of Gale Crater, Mars

The clay-rich Glen Torridon region of Gale crater, Mars, was explored between sols 2300 and 3007. Here, we analyzed the diagenetic features observed by Curiosity , including veins, cements, nodules, and nodular bedrock, using the ChemCam, Mastcam, and Mars Hand Lens Imager instruments. We discovered many diagenetic features in Glen Torridon, including dark-toned iron- and manganese-rich veins, magnesium- and fluorine-rich linear features, Ca-sulfate cemented bedrock, manganese-rich nodules, and iron-rich strata. We have characterized the chemistry and morphology of these features, which are most widespread in the higher stratigraphic members in Glen Torridon, and exhibit a wide range of chemistries. These discoveries are strong evidence for multiple generations of fluids from multiple chemical endmembers that likely underwent redox reactions to form some of these features. In a few cases, we may be able to use mineralogy and chemistry to constrain formation conditions of the diagenetic features. For example, the dark-toned veins likely formed in warmer, highly alkaline, and highly reducing conditions, while manganese-rich nodules likely formed in oxidizing and circumneutral conditions. We also hypothesize that an initial enrichment of soluble elements, including fluorine, occurred during hydrothermal alteration early in Gale crater history to account for elemental enrichment in nodules and veins. The presence of redox-active elements, including Fe and Mn, and elements required for life, including P and S, in these fluids is strong evidence for habitability of Gale crater groundwater. Hydrothermal alteration also has interesting implications for prebiotic chemistry during the earliest stages of the crater’s evolution and early Mars.

JGR - Planets↗
USGS2017

Chemistry of diagenetic features analyzed by ChemCam at Pahrump Hills, Gale crater, Mars

The Curiosity rover's campaign at Pahrump Hills provides the first analyses of lower Mount Sharp strata. Here we report ChemCam elemental composition of a diverse assemblage of post-depositional features embedded in, or cross-cutting, the host rock. ChemCam results demonstrate their compositional diversity, especially compared to the surrounding host rock: (i) Dendritic aggregates and relief enhanced features, characterized by a magnesium enhancement and sulfur detection, and interpreted as Mg-sulfates; (ii) A localized observation that displays iron enrichment associated with sulfur, interpreted as Fe-sulfate; (iii) Dark raised ridges with varying Mg- and Ca-enriched compositions compared to host rock; (iv) Several dark-toned veins with calcium enhancement associated with fluorine detection, interpreted as fluorite veins. (v) Light-toned veins with enhanced calcium associated with sulfur detection, and interpreted as Ca-sulfates. The diversity of the Pahrump Hills diagenetic assemblage suggests a complex post-depositional history for fine-grained sediments for which the origin has been interpreted as fluvial and lacustrine. Assessment of the spatial and relative temporal distribution of these features shows that the Mg-sulfate features are predominant in the lower part of the section, suggesting local modification of the sediments by early diagenetic fluids. In contrast, light-toned Ca-sulfate veins occur in the whole section and cross-cut all other features. A relatively late stage shift in geochemical conditions could explain this observation. The Pahrump Hills diagenetic features have no equivalent compared to targets analyzed in other locations at Gale crater. Only the light-toned Ca-sulfate veins are present elsewhere, along Curiosity's path, suggesting they formed through a common late-stage process that occurred at over a broad area.

Icarus↗
USGS2016

The potassic sedimentary rocks in Gale Crater, Mars, as seen by ChemCam Onboard Curiosity

The Mars Science Laboratory rover Curiosity encountered potassium-rich clastic sedimentary rocks at two sites in Gale Crater, the waypoints Cooperstown and Kimberley. These rocks include several distinct meters thick sedimentary outcrops ranging from fine sandstone to conglomerate, interpreted to record an ancient fluvial or fluvio-deltaic depositional system. From ChemCam Laser-Induced Breakdown Spectroscopy (LIBS) chemical analyses, this suite of sedimentary rocks has an overall mean K 2 O abundance that is more than 5 times higher than that of the average Martian crust. The combined analysis of ChemCam data with stratigraphic and geographic locations reveals that the mean K 2 O abundance increases upward through the stratigraphic section. Chemical analyses across each unit can be represented as mixtures of several distinct chemical components, i.e., mineral phases, including K-bearing minerals, mafic silicates, Fe-oxides, and Fe-hydroxide/oxyhydroxides. Possible K-bearing minerals include alkali feldspar (including anorthoclase and sanidine) and K-bearing phyllosilicate such as illite. Mixtures of different source rocks, including a potassium-rich rock located on the rim and walls of Gale Crater, are the likely origin of observed chemical variations within each unit. Physical sorting may have also played a role in the enrichment in K in the Kimberley formation. The occurrence of these potassic sedimentary rocks provides additional evidence for the chemical diversity of the crust exposed at Gale Crater.

Journal of Geophysical Research↗
USGS2016

ChemCam activities and discoveries during the nominal mission of the Mars Science Laboratory in Gale crater, Mars

At Gale crater, Mars, ChemCam acquired its first laser-induced breakdown spectroscopy (LIBS) target on Sol 13 of the landed portion of the mission (a Sol is a Mars day). Up to Sol 800, more than 188 000 LIBS spectra were acquired on more than 5800 points distributed over about 650 individual targets. We present a comprehensive review of ChemCam scientific accomplishments during that period, together with a focus on the lessons learned from the first use of LIBS in space. For data processing, we describe new tools that had to be developed to account for the uniqueness of Mars data. With regard to chemistry, we present a summary of the composition range measured on Mars for major-element oxides (SiO 2 , TiO 2 , Al 2 O 3 , FeO T , MgO, CaO, Na 2 O, K 2 O) based on various multivariate models, with associated precisions. ChemCam also observed H, and the non-metallic elements C, O, P, and S, which are usually difficult to quantify with LIBS. F and Cl are observed through their molecular lines. We discuss the most relevant LIBS lines for detection of minor and trace elements (Li, Rb, Sr, Ba, Cr, Mn, Ni, and Zn). These results were obtained thanks to comprehensive ground reference datasets, which are set to mimic the expected mineralogy and chemistry on Mars. With regard to the first use of LIBS in space, we analyze and quantify, often for the first time, each of the advantages of using stand-off LIBS in space: no sample preparation, analysis within its petrological context, dust removal, sub-millimeter scale investigation, multi-point analysis, the ability to carry out statistical surveys and whole-rock analyses, and rapid data acquisition. We conclude with a discussion of ChemCam performance to survey the geochemistry of Mars, and its valuable support of decisions about selecting where and whether to make observations with more time and resource-intensive tools in the rover's instrument suite. In the end, we present a bird's-eye view of the many scientific results: discovery of felsic Noachian crust, first observation of hydrated soil, discovery of manganese-rich coatings and fracture fills indicating strong oxidation potential in Mars' early atmosphere, characterization of soils by grain size, and wide scale mapping of sedimentary strata, conglomerates, and diagenetic materials.

Journal of Analytical Atomic Spectrometry↗
USGS2010

Detection and mapping of hydrocarbon deposits on Titan

We report the identification of compounds on Titan's surface by spatially resolved imaging spectroscopy methods through Titan's atmosphere, and set upper limits to other organic compounds. We present evidence for surface deposits of solid benzene (C 6 H 6 ), solid and/or liquid ethane (C 2 H 6 ), or methane (CH 4 ), and clouds of hydrogen cyanide (HCN) aerosols using diagnostic spectral features in data from the Cassini Visual and Infrared Mapping Spectrometer (VIMS). Cyanoacetylene (2-propynenitrile, IUPAC nomenclature, HC 3 N) is indicated in spectra of some bright regions, but the spectral resolution of VIMS is insufficient to make a unique identification although it is a closer match to the feature previously attributed to CO 2 . We identify benzene, an aromatic hydrocarbon, in larger abundances than expected by some models. Acetylene (C 2 H 2 ), expected to be more abundant on Titan according to some models than benzene, is not detected. Solid acetonitrile (CH 3 CN) or other nitriles might be candidates for matching other spectral features in some Titan spectra. An as yet unidentified absorption at 5.01- μ m indicates that yet another compound exists on Titan's surface. We place upper limits for liquid methane and ethane in some locations on Titan and find local areas consistent with millimeter path lengths. Except for potential lakes in the southern and northern polar regions, most of Titan appears “dry.” Finally, we find there is little evidence for exposed water ice on the surface. Water ice, if present, must be covered with organic compounds to the depth probed by 1–5- μ m photons: a few millimeters to centimeters.

Journal of Geophysical Research - Planets↗
USGS2009

Mapping products of Titan's surface

Remote sensing instruments aboard the Cassini spacecraft have been observed the surface of Titan globally in the infrared and radar wavelength ranges as well as locally by the Huygens instruments revealing a wealth of new morphological features indicating a geologically active surface. We present a summary of mapping products of Titan's surface derived from data of the remote sensing instruments onboard the Cassini spacecraft (ISS, VIMS, RADAR) as well as the Huygens probe (DISR) that were achieved during the nominal Cassini mission including an overview of Titan's recent nomenclature.

Book chapter↗
USGS2007

Near-infrared spectral mapping of Titan's mountains and channels

We investigate the spectral reflectance properties of channels and mountain ranges on Titan using data from Cassini's Visual and Infrared Mapping Spectrometer (VIMS) obtained during the T9 encounter (26 December 2005). We identify the location of channels and mountains using synthetic aperture radar maps obtained from Cassini's RADAR instrument during the T13 (30 April 2006) flyby. Channels are evident even in VIMS imaging with spatial resolution coarser than the channel size. The channels share spectral characteristics with Titan's dark blue terrain (e.g., the Huygens landing site) that is consistent with an enhancement in water ice content relative to the rest of Titan. We use this fact to measure widths of ???1 km for the largest channels. Comparison of the data sets shows that in our study area within the equatorial bright spectral unit east of Xanadu, mountains are darker and bluer than surrounding smooth terrain. These results are consistent with the equatorial bright terrain possessing a veneer of material that is thinner in the regions where there are mountains and streambeds that have likely undergone more recent and extensive erosion. We suggest a model for the geographic relationship of the dark blue, dark brown, and equatorial bright spectral units based on our findings.

Journal of Geophysical Research E: Planets↗