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Sharon A. Fitzgerald

Publications and source records attributed to Sharon A. Fitzgerald.

12 recordsLinked to original sources

Characterization of water-quality and bed-sediment conditions in Currituck Sound, North Carolina, prior to the Mid-Currituck Bridge construction, 2011–18

The North Carolina Turnpike Authority plans to improve transportation in the Currituck Sound area by constructing a two-lane bridge—the Mid-Currituck Bridge—across Currituck Sound from the mainland to the Outer Banks, North Carolina. The results of the final environmental impact statement for the project indicate potential water-quality and habitat effects for Currituck Sound associated with the bridge and roadway improvements. The primary objective of this study is to characterize water-quality conditions and bed-sediment chemistry in the vicinity of the planned Mid-Currituck Bridge, providing a baseline for evaluating the potential effects of bridge construction and bridge deck runoff on environmental conditions in Currituck Sound. From August 2011 through January 2018, water-quality and bed-sediment samples were collected from five sampling stations along the planned bridge alignment. Samples were analyzed for numerous characteristics, including physical properties and constituents that are associated with bridge deck stormwater runoff and are important to estuarine waters. The analyzed characteristics included dissolved oxygen, pH, specific conductance, turbidity, suspended solids, metals, nutrients, semi-volatile organic compounds, bacteria, chlorophyll a, cyanotoxins, and phytoplankton abundance. The most common constituents with concentrations above applicable State and Federal water-quality thresholds included chlorophyll a, pH, turbidity, Enterococci, and pentachlorophenol. Few bed-sediment samples had constituent concentrations that exceeded applicable sediment-quality guidelines. Results indicated that water sampled along the planned bridge alignment was well mixed vertically and horizontally but varied temporally. Seasonal changes in water quality best explained the variations in water-quality conditions in Currituck Sound during the study. Wind conditions also influenced water levels and water-quality conditions. Turbidity and concentrations of particle-associated constituents tended to be higher when water levels were lower, possibly reflecting the increased resuspension of bottom materials from wind-driven wave action.

North Carolina

Assessing water quality from highway runoff at selected sites in North Carolina with the Stochastic Empirical Loading and Dilution Model (SELDM)

In 2015, the U.S. Geological Survey (USGS) entered into a cooperative agreement with the North Carolina Department of Transportation (NCDOT) to develop a North Carolina-enhanced variation of the national Stochastic Empirical Loading and Dilution Model (SELDM) with available North Carolina-specific streamflow and water-quality data and to demonstrate use of the model by documenting selected simulation scenarios. The USGS developed the national SELDM in cooperation with the Federal Highway Administration (FHWA) to provide the tools and techniques necessary for performing stormwater-quality simulations. SELDM uses a stochastic mass-balance approach to estimate combinations of flows, concentrations, and loads of stormwater constituents from the site of interest (often a highway catchment; nonhighway areas, such as a large impervious area at a shopping center complex, also can be used) and the basin upstream from the stormwater outfall to assess the risk for adverse effects of runoff. SELDM also can be used to simulate the effectiveness of volume reduction, hydrograph extension, and water-quality concentration reductions by stormwater best management practices (BMPs), which are designed to help mitigate the effects of runoff on receiving water bodies. Some of the statistical inputs needed for the North Carolina-enhanced SELDM were either calculated or augmented using local or regional data from North Carolina. Streamflow statistics used by SELDM were determined for 266 streamgages across North Carolina on the basis of data available through the 2015 water year. Recession ratio statistics used for triangular hydrographs were also developed for 30 streamgages across the State. The NCDOT identified previous research reports on highway-runoff and BMP studies in North Carolina for review of potential data addition to the national FHWA Highway-Runoff Database (HRDB). Following USGS review of these data, a total of 25,087 event mean concentration values and 1,140 storm events for 39 highway-runoff sites and 195 analytes were uploaded to the national HRDB from six North Carolina highway-runoff research reports and a recent USGS bridge deck runoff study. Using data for 27 streamgages in North Carolina, a total of 57 water-quality transport curves were developed for seven constituents for use in simulating water-quality conditions in the upstream basin. Performance data for three BMPs (bioretention, grass strip or swale, and wetland channel) from NCDOT research data were incorporated into the North Carolina-enhanced SELDM for volume-reduction statistics, including the effectiveness of treating four water-quality constituents (total suspended solids, total nitrogen, total phosphorus, nitrate plus nitrite) and turbidity. Simulations using the North Carolina-enhanced SELDM are presented for two hypothetical upstream basins in the Piedmont ecoregion and one hypothetical highway site to demonstrate how simulations can be used to provide risk-based information about potential effects of stormwater runoff on downstream water quality and the potential for mitigating those risks by using BMPs. The first group of simulations explores the stochastic variability in dilution factors (the ratio of the highway runoff to the total downstream stormflow) for a hypothetical Piedmont rural creek having drainage areas ranging from 1 to 100 square miles. The second group of simulations examines dilution factors based on variations in precipitation, streamflow, and recession ratios for two hypothetical Piedmont upstream basins (rural and urban) where the drainage area was held constant at 25 square miles. These simulations indicate the sensitivity of results to variations in each of the three variables. The third group of simulations examines the effects of varied concentrations in the upstream basin on water-quality conditions downstream from the highway crossing. Variations in upstream water-quality conditions for three constituents (suspended sediment concentration, total nitrogen, and total phosphorus) are based on water-quality transport curves selected from among the 57 curves developed as part of this study to represent low-, medium-, and high-concentration statistics. Simulations completed for this third group also examine the potential effects of grass swale and bioretention BMP treatment on total nitrogen and total phosphorus concentrations in highway runoff. The BMP performance data from the NCDOT research reports were applied in this group of simulations. The stochastic mass-balance approach used in SELDM analyses and simulations provides a strong tool for engineers and water-resource managers to use in exploring a wide range of possible hydrologic and water-quality inputs and their effects on downstream water quality. The results of this study can not only aid engineers and managers in planning for potential adverse effects of runoff at site-specific locations, they can also help the USGS and other Federal and State agencies with oversight responsibilities in stormwater-quality issues to continue gathering data on potential water-quality effects in receiving streams.

North Carolina

Water quality and bed sediment quality in the Albemarle Sound, North Carolina, 2012–14

The Albemarle Sound region was selected in 2012 as one of two demonstration sites in the Nation to test and improve the design of the National Water Quality Monitoring Council’s National Monitoring Network (NMN) for U.S. Coastal Waters and Tributaries. The goal of the NMN for U.S. Coastal Waters and Tributaries is to provide information about the health of our oceans, coastal ecosystems, and inland influences on coastal waters for improved resource management. The NMN is an integrated, multidisciplinary, and multi-organizational program using multiple sources of data and information to augment current monitoring programs. This report presents and summarizes selected water-quality and bed sediment-quality data collected as part of the demonstration project conducted in two phases. The first phase was an occurrence and distribution study to assess nutrients, metals, pesticides, cyanotoxins, and phytoplankton communities in the Albemarle Sound during the summer of 2012 at 34 sites in Albemarle Sound, nearby sounds, and various tributaries. The second phase consisted of monthly sampling over a year (March 2013 through February 2014) to assess seasonality in a more limited set of constituents including nutrients, cyanotoxins, and phytoplankton communities at a subset (eight) of the sites sampled in the first phase. During the summer of 2012, few constituent concentrations exceeded published water-quality thresholds; however, elevated levels of chlorophyll a and pH were observed in the northern embayments and in Currituck Sound. Chlorophyll a , and metals (copper, iron, and zinc) were detected above a water-quality threshold. The World Health Organization provisional guideline based on cyanobacterial density for high recreational risk was exceeded in approximately 50 percent of water samples collected during the summer of 2012. Cyanobacteria capable of producing toxins were present, but only low levels of cyanotoxins below human health benchmarks were detected. Finally, 12 metals in surficial bed sediments were detected at levels above a published sediment-quality threshold. These metals included chromium, mercury, copper, lead, arsenic, nickel, and cadmium. Sites with several metal concentrations above the respective thresholds had relatively high concentrations of organic carbon or fine sediment (silt plus clay), or both and were predominantly located in the western and northwestern parts of the Albemarle Sound. Results from the second phase were generally similar to those of the first in that relatively few constituents exceeded a water-quality threshold, both pH and chlorophyll a were detected above the respective water-quality thresholds, and many of these elevated concentrations occurred in the northern embayments and in Currituck Sound. In contrast to the results from phase one, the cyanotoxin, microcystin was detected at more than 10 times the water-quality threshold during a phytoplankton bloom on the Chowan River at Mount Gould, North Carolina in August of 2013. This was the only cyanotoxin concentration measured during the entire study that exceeded a respective water-quality threshold. The information presented in this report can be used to improve understanding of water-quality conditions in the Albemarle Sound, particularly when evaluating causal and response variables that are indicators of eutrophication. In particular, this information can be used by State agencies to help develop water-quality criteria for nutrients, and to understand factors like cyanotoxins that may affect fisheries and recreation in the Albemarle Sound region.

North Carolina, Virginia

Effect of land-applied biosolids on surface-water nutrient yields and groundwater quality in Orange County, North Carolina

Land application of municipal wastewater biosolids is the most common method of biosolids management used in North Carolina and the United States. Biosolids have characteristics that may be beneficial to soil and plants. Land application can take advantage of these beneficial qualities, whereas disposal in landfills or incineration poses no beneficial use of the waste. Some independent studies and laboratory analysis, however, have shown that land-applied biosolids can pose a threat to human health and surface-water and groundwater quality. The effect of municipal biosolids applied to agriculture fields is largely unknown in relation to the delivery of nutrients, bacteria, metals, and contaminants of emerging concern to surface-water and groundwater resources. Therefore, the North Carolina Department of Environment and Natural Resources (NCDENR) collaborated with the U.S. Geological Survey (USGS) through the 319 Nonpoint Source Program to better understand the transport of nutrients and bacteria from biosolids application fields to groundwater and surface water and to provide a scientific basis for evaluating the effectiveness of the current regulations. The USGS conducted a paired agricultural watershed study in the Collins Creek and Cane Creek Reservoir watersheds in Orange County, North Carolina. Field activities were conducted from March 2011 through May 2013 at two field study sites, including biosolids field application sites owned by Orange County Water and Sewer Authority (OWASA) in the Collins Creek watershed and a background study site in the Cane Creek watershed that has no fields receiving biosolids applications. Samples of biosolids source material and soil were collected from the land-application fields for laboratory analyses. Soil samples were also collected from a background agricultural field in the Cane Creek watershed that has never received land-applied municipal biosolids. Shallow groundwater samples were collected quarterly from new monitoring wells installed by NCDENR along the edge of the biosolids land-application fields and a background agricultural field for laboratory analyses. Two surface-water monitoring sites were established on Collins Creek to compute continuous streamflow and collect discrete baseflow and stormwater runoff water-quality data upstream and downstream from the biosolids land-application fields. Surface water-quality samples were also collected for baseflow and stormwater runoff conditions at an existing USGS streamgage on Cane Creek to monitor water-quality conditions in the background study watershed. The study primarily focused on nutrients and bacteria; however, data for field properties and water-quality constituents, including metals, major ions, and contaminants of emerging concern (household-, industrial-, and agricultural-use compounds, pharmaceutical compounds, hormones, and antibiotics) also were collected and used in the analyses. There were no exceedances of the 10 elements with designated U.S. Environmental Protection Agency (EPA) ceiling concentrations for land-applied biosolids in any of the biosolids samples. Treatment processes and storage techniques used by OWASA are effective in eliminating Escherichia coli and fecal coliform bacteria from biosolids. Copper, molybdenum, total Kjeldahl nitrogen, and total phosphorus were elevated in the soil from biosolids land-application fields relative to the background field. The relative richness of these constituents in the biosolids land-application fields is consistent with biosolids being the source of the elevated concentrations given the relatively high concentrations of these constituents in the biosolids samples that were collected. Shallow groundwater in the transitional zone wells, which were located adjacent to and topographically downgradient from all the biosolids land-application fields, were found to be statistically different and had higher nitrate concentrations (medians greater than 12 milligrams per liter) than all the other wells sampled as part of the study. Surface-water nutrient concentrations and yields, primarily nitrate, were higher at the monitoring site on Collins Creek downstream from the biosolids land-application fields than the other study sites that drained watersheds without biosolids land application. The largest differences in concentrations between sites were measured at baseflow conditions, which indicate that the main cause of these differences, particularly between Cane Creek and the Collins Creek site downstream from the OWASA application fields, is related to nitrate contribution from the shallow groundwater. Contaminants of emerging concern were detected in approximately 40 percent of the laboratory analyses of the biosolids samples and more frequently in soil samples from the biosolids land-application fields (approximately 40 percent of laboratory analyses) relative to the soil samples from the background field (approximately 12 percent of laboratory analyses). However, contaminants of emerging concern detected in the laboratory analysis for this study do not appear to be good indicators of human-waste contaminants derived from land-applied biosolids in groundwater or surface-water because the number of detections and concentrations at the background wells and surface-water monitoring sites are similar to or higher than those at wells and monitoring sites adjacent to or downstream from the biosolids land-application fields. The data, analysis, and conclusions associated with this study can be used by regulatory agencies, resource managers, and wastewater-treatment operators to (1) better understand the quantity and characteristics of nutrients, bacteria, metals, and contaminants of emerging concern that are transported away from biosolids land-application fields to surface water and groundwater under current regulations for the purposes of establishing effective total maximum daily loads (TMDLs) and restoring impaired water resources, (2) assess how well existing regulations protect waters of the State and potentially recommend effective changes to regulations or land-application procedures, and (3) establish a framework for developing guidance on effective techniques for monitoring and regulatory enforcement of permitted biosolids land-application fields.

North Carolina

Baseline well inventory and groundwater-quality data from a potential shale gas resource area in parts of Lee and Chatham Counties, North Carolina, October 2011-August 2012

Records were obtained for 305 wells and 1 spring in northwestern Lee and southeastern Chatham counties, North Carolina. Well depths ranged from 26 to 720 feet and yields ranged from 0.25 to 100 gallons per minute. A subset of 56 wells and 1 spring were sampled for baseline groundwaterquality constituents including the following: major ions; dissolved metals; nutrients; dissolved gases (including methane); volatile and semivolatile organic compounds; glycols; isotopes of strontium, radium, methane (if sufficient concentration), and water; and dissolved organic and inorganic carbon. Dissolved methane gas concentrations were low, ranging from less than 0.00007 (lowest reporting level) to 0.48 milligrams per liter. Concentrations of nitrate, boron, iron, manganese, sulfate, chloride, total dissolved solids, and measurements of pH exceeded federal and state drinking water standards in a few samples. Iron and manganese concentrations exceeded the secondary (aesthetic) drinking water standard in approximately 35 to 37 percent of the samples.

North Carolina

Water-quality characteristics indicative of wastewater in selected streams in the upper Neuse River Basin, Durham and Orange Counties, North Carolina, from 2004 to 2013

Data were collected during three time periods to assess the effects of wastewater treatment and disposal practices on the occurrence of selected contaminants indicative of wastewater in the upper Neuse River Basin, North Carolina. The first phase of data collection, December 2004 to June 2005, and the second phase, April to October 2008, addressed the effects of point and nonpoint sources of wastewater effluent on stream quality during baseflow conditions. Point-source effects were assessed by sampling a municipal wastewater treatment plant outfall and sites on the Eno River upstream and downstream from the outfall. Water-quality data suggest that the wastewater treatment plant effluent contributed to increases in concentrations of nitrogen and carbamazepine at the downstream site. Nonpoint source effects were assessed by sampling seven small streams that drained an undeveloped area and residential areas served by either centralized or onsite wastewater treatment systems. Samples were analyzed for inorganic constituents, including nutrients, ions, and metals; organic compounds considered indicative of wastewater contamination; antibiotics, optical brighteners, and fecal coliform bacteria. Hypothesized differences in water quality between the sites with primarily centralized and onsite wastewater treatment were not apparent, likely due to the relatively large heterogeneity of the sites within each category. During the third phase of data collection, May 2012 to January 2013, data were collected to address the suitability of optical brighteners as tracers of wastewater in small streams during streamflow recession. Samples were collected at five small streams following periods of rainfall and analyzed for optical brighteners, specific conductance nutrients, and selected hormones. Optical brighteners were absent in the undeveloped catchment but were present in the recession period after rainfall events in catchments with centralized though possibly leaky sewage treatment and areas with onsite treatment. Sand filter systems in areas with onsite treatment appear to change the effluent flow and retention characteristics such that optical brighteners were present both before and after rainfall events. Nitrate plus nitrite, as nitrogen concentrations in samples from this last study phase generally were larger than those collected during baseflow conditions in the previous phases of this study.

North Carolina

Characterization of stormwater runoff from bridges in North Carolina and the effects of bridge deck runoff on receiving streams

In 2008, the North Carolina General Assembly passed House Bill 2436 that required the North Carolina Department of Transportation (NCDOT) to study the water-quality effects of bridges on receiving streams. In response, the NCDOT and the U.S. Geological Survey (USGS) collaborated on a study to provide information necessary to address the requirements of the Bill. To better understand the effects of stormwater runoff from bridges on receiving streams, the following tasks were performed: (1) characterize stormwater runoff quality and quantity from a representative selection of bridges in North Carolina; (2) measure stream water quality upstream from selected bridges to compare bridge deck stormwater concentrations and loads to stream constituent concentrations and loads; and (3) determine if the chemistry of bed sediments upstream and downstream from selected bridges differs substantially based on presence or absence of a best management practice for bridge runoff.

North Carolina

Nutrient, trace-element, and ecological history of Musky Bay, Lac Courte Oreilles, Wisconsin, as inferred from sediment cores

Sediment cores were collected from Musky Bay, Lac Courte Oreilles, and from surrounding areas in 1999 and 2001 to determine whether the water quality of Musky Bay has declined during the last 100 years or more as a result of human activity, specifically cottage development and cranberry farming. Selected cores were analyzed for sedimentation rates, nutrients, minor and trace elements, biogenic silica, diatom assemblages, and pollen over the past several decades. Two cranberry bogs constructed along Musky Bay in 1939 and the early 1950s were substantially expanded between 1950?62 and between 1980?98. Cottage development on Musky Bay has occurred at a steady rate since about 1930, although currently housing density on Musky Bay is one-third to one-half the housing density surrounding three other Lac Courte Oreilles bays. Sedimentation rates were reconstructed for a core from Musky Bay by use of three lead radioisotope models and the cesium-137 profile. The historical average mass and linear sedimentation rates for Musky Bay are 0.023 grams per square centimeter per year and 0.84 centimeters per year, respectively, for the period of about 1936?90. There is also limited evidence that sedimentation rates may have increased after the mid-1990s. Historical changes in input of organic carbon, nitrogen, phosphorus, and sulfur to Musky Bay could not be directly identified from concentration profiles of these elements because of the potential for postdepositional migration and recycling. Minor- and trace-element profiles from the Musky Bay core possibly reflect historical changes in the input of clastic material over time, as well as potential changes in atmospheric deposition inputs. The input of clastic material to the bay increased slightly after European settlement and possibly in the 1930s through 1950s. Concentrations of copper in the Musky Bay core increased steadily through the early to mid-1900s until about 1980 and appear to reflect inputs from atmospheric deposition. Aluminum- normalized concentrations of calcium, copper, nickel, and zinc increased in the Musky Bay core in the mid-1990s. However, concentrations of these elements in surficial sediment from Musky Bay were similar to concentrations in other Lac Courte Oreilles bays, nearby lakes, and soils and were below probable effects concentrations for aquatic life. Biogenic-silica, diatom-community, and pollen profiles indicate that Musky Bay has become more eutrophic since about 1940 with the onset of cottage development and cranberry farming. The water quality of the bay has especially degraded during the last 25 years with increased growth of aquatic plants and the onset of a floating algal mat during the last decade. Biogenic silica data indicate that diatom production has consistently increased since the 1930s. Diatom assemblage profiles indicate a shift from low-nutrient species to higher-nutrient species during the 1940s and that aquatic plants reached their present density and/or composition during the 1970s. The diatom Fragilaria capucina (indicative of algal mat) greatly increased during the mid-1990s. Pollen data indicate that milfoil, which often becomes more common with elevated nutrients, became more widespread after 1920. The pollen data also indicate that wild rice was present in the eastern end of Musky Bay during the late 1800s and the early 1900s but disappeared after about 1920, probably because of water-level changes more so than eutrophication.

Wisconsin

Distribution and transport of polychlorinated biphenyls and associated particulates in the Hayton Millpond, south branch Manitowoc River, 1993-95

The distribution and transport of polychlorinated biphenyl (PCB) congeners was determined at two sites on Pine Creek and at the Hayton Millpond on the South Branch of the Manitowoc River in Wisconsin during 1993-95. PCB congener compositions were analyzed in the operationally defined dissolved phase, suspended particulate phase, and surficial bed sediments (0-2 centimeters depth) several times throughout the sampling period. The relative abundances of PCB congeners in the suspended particles and in surficial bed sediments were generally similar to each other and to a known Aroclor mixture (1254). PCB congener composites in the operationally defined dissolved phase were higher in the less chlorinated congeners in keeping with their lower hydrophobicity and higher predicted solubility relative to the more chlorinated congeners. Suspended particle-associated PCB concentrations exhibited two patterns: (1) a cyclical variation in spring and summer associated with algal growth, and (2) episodic increases associated with resuspension of bed sediments during storms. Computed total suspended-solids (TSS) load at the millpond outlet was as high as 920 tons over a 3-month period (June 30-Sept. 30, 1993). Annual TSS loads for the following two years were lower, 610 and 500 tons, respectively. Total PCB concentrations in the water column varied at the millpond outlet, ranging from 34 to 302 nanograms per liter, whereas concentrations upstream on Pine Creek were as high as 563 nanograms per liter. In general, 70 percent of PCB's in the water column were associated with suspended particles. The total congener-summation PCB (SPCB) concentration regression equation incorporated the universal soil loss coefficent to represent erosion of assumedly PCB-free sediment from fields upstream from the millpond. The SPCB load based on the regression relation was 3.4 kilograms during the 3-month high-flow interval (June 30-Sept. 30, 1993). Subsequent annual SPCB loads for the next two water years were 3.5 and 2.3 kilograms, respectively.

Wisconsin

Water quality in the Western Lake Michigan Drainages, Wisconsin and Michigan, 1992-95

This report is intended to summarize major findings that emerged between 1992 and 1995 from the water-quality assessment of the Western Lake Michigan Drainages Study Unit and torelate these findings to water-quality issues of regional and national concern. The information in primarily intended for those who are involved in water-resource management. Yet, the information contained here may also interest those who simply wish to know more about the quality of water in the rivers and aquifers in the area where they live.

Michigan, Wisconsin

The Fox River PCB transport study: Stepping stone to a healthy Great Lakes ecosystem

Polychlorinated Biphenyls (PCBs) in the Great Lakes Despite being banned since the 1970's, polychlorinated biphenyls (PCBs) continue to pose a threat to the environment because of their persistence and toxicity to organisms ranging from minute algae to fish, waterfowl, and human beings. PCBs, a set of 209 related chlorinated organic compounds, had various industrial uses such as in hydraulic fluids, cutting oils, sealants, and pesticides. Despite the manufacturing ban in the mid-1970's, PCBs remain ubiquitous in the environment. In the Laurentian Great Lakes of the Midwest. PCBs and other toxic compounds contaminate bottom sediments at almost all designated "areas of concern" (AOC)(figure 1, upper left inset). The International Joint Commission, a binational group from Canada and the United States, has identified these AOCs in their efforts to restore and protect Great Lakes ecosystems. One such area, the Fox River which flows into Green Bay, has been the focus of much scientific study in an effort to improve not only that river but to apply lessons learned to other AOCs. The final goal is a healthy Great Lakes food chain with fish and waterfowl that are safe to consume.

Fox River, Great Lakes, Lake Winnebago