Shanying Li | Geology Reports

USGS2024

The role of clay minerals in the preservation of organic matter in sediments of Qinghai Lake, NW China

The role of saline lake sediments in preserving organic matter has long been recognized. In order to further understand the preservation mechanisms, the role of clay minerals was studied. Three sediment cores, 25, 57, and 500 cm long, were collected from Qinghai Lake, NW China, and dissected into multiple subsamples. Multiple techniques were employed, including density fractionation, X-ray diffraction, scanning and transmission electron microscopy (SEM and TEM), total organic carbon (TOC) and carbon compound analyses, and surface area determination. The sediments were oxic near the water-sediment interface, but became anoxic at depth. The clay mineral content was as much as 36.8%, consisting mostly of illite, chlorite, and halloysite. The TEM observations revealed that organic matter occurred primarily as organic matter-clay mineral aggregates. The TOC and clay mineral abundances are greatest in the mid-density fraction, with a positive correlation between the TOC and mineral surface area. The TOC of the bulk sediments ranges from 1 to 3% with the non-hydrocarbon fraction being predominant, followed by bitumen, saturated hydrocarbon, aromatic hydrocarbons, and chloroform-soluble bitumen. The bimodal distribution of carbon compounds of the saturated hydrocarbon fraction suggests that organic matter in the sediments was derived from two sources: terrestrial plants and microorganisms/algae. Depthrelated systematic changes in the distribution patterns of the carbon compounds suggest that the oxidizing conditions and microbial abundance near the water-sediment interface promote degradation of labile organic matter, probably in adsorbed form. The reducing conditions and small microbial biomass deeper in the sediments favor preservation of organic matter, because of the less labile nature of organic matter, probably occurring within clay mineral-organic matter aggregates that are inaccessible to microorganisms. These results have important implications for our understanding of mechanisms of organic matter preservation in saline lake sediments.

Qinghai Lake↗

USGS2017

Activation of a small ephemeral lake in southern Jordan during the last full glacial period and its paleoclimatic implications

Playas, or ephemeral lakes, are one of the most common depositional environments in arid and semiarid lands worldwide. Playa deposits, however, have mostly been avoided as paleoclimatic archives because they typically contain exceptionally low concentrations of organic material, making 14 C dating difficult. Here, we describe a technique for concentrating organic matter in sediments for radiocarbon dating and apply it to playa sediments recovered from a 2.35 m sediment core from a small playa in southern Jordan. Based on 14 C ages of the organic concentrate fraction, the playa was active from ~29 to 21 ka, coincident with the last major high stand of Paleolake Lisan and wet conditions recorded by other paleoclimatic proxies in the southernmost Levant during the last full glacial period (35–20 ka). The timing and spatial pattern of these records suggests that the increased moisture was likely derived from more frequent and deeper eastern Mediterranean (EM) cyclones associated with the intensification of the westerlies. The presence of full glacial pluvial deposits in southern Jordan (29°N), and the lack of similarly aged deposits in the northern Arabian Peninsula to the south, suggests that the southerly limit of the incursion of EM cyclones during last full glacial period was ~28°N.

Khabrat Ratiya↗